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HJ 2542-2016

Search Result of Chinese Standard: 'HJ 2542-2016'
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HJ 2542-2016English209 Add to Cart Days<=3 Technical requirement for environmental labeling products Offset printing ink Valid HJ 2542-2016
HJ 2542-2016Chinese16 Add to Cart <=1-day [PDF from Chinese Authority, or Standard Committee, or Publishing House]

   
Detail Information of HJ 2542-2016; HJ2542-2016
Description (Translated English): (Environmental labeling products Technical requirements Offset printing ink)
Sector / Industry: Environmental Protection Industry Standard
Classification of Chinese Standard: A17
Word Count Estimation: 9,937
Date of Issue: 2016-10-17
Date of Implementation: 2017-01-01
Older Standard (superseded by this standard): HJ/T 370-2007
Regulation (derived from): Ministry of Environmental Protection Notice No.63 of 2016


HJ 2542-2016
(Environmental labeling products Technical requirements Offset printing ink)
National Environmental Protection Standard of the People 's Republic of China
Replacing HJ/T 370-2007
Environmental labeling products Technical requirements Offset printing ink
Technical requirement for environmental labeling products
Offset printing ink
2016-10-17 released
2017-01-01 Implementation
Ministry of Environmental Protection released
Directory
Preface III
1 Scope of application 1
2 normative reference document 1
3 Terms and Definitions
Basic Requirements 1
Technical content 1
6 Test Method 2
Appendix A (normative) phthalates
Appendix B (Normative Appendix) Description of Gas Chromatographic Testing of Volatile Organic Compounds in Offset Inks 4
Appendix C (normative) Gas Chromatography for the description of benzene, toluene, xylene and ethylbenzene in offset printing ink 5
Preface
For the implementation of the "People's Republic of China Environmental Protection Law" to reduce offset printing ink in the production and use of the environment and human health
Ring, protect the environment, the development of this standard.
This standard on offset printing ink production process, the product of toxic and hazardous substances limited and packaging and description of the requirements.
This standard has revised the technical requirements for "environmental labeling products" (HJ/T 370-2007). The main changes are as follows.
- Adjusted scope, terms and definitions;
- Increased restrictions on hazardous substances in the production process;
- Adjusted the limited requirements of hazardous substances in the product;
- Added packaging and description requirements.
This standard is organized by the Ministry of Environmental Protection Science and Technology Standards Division.
The main drafting of this standard. Environmental Development Department of Environmental Protection, China Daily Chemical Industry Association of ink, Beijing Green Business
Development Center, Hanghua Ink and Chemical Co., Ltd., Tianjin Toyo Ink Co., Ltd., Xinxiang City, Germany and Germany Cheung Chuan Ink Co., Ltd., Suzhou
Koswood Ink Co., Ltd.
This standard is approved by the Ministry of Environmental Protection on October 17,.2016.
This standard has been implemented since January 1,.2017, and is replaced by HJ/T 370-2007 since the date of implementation.
This standard is explained by the Ministry of Environmental Protection.
This standard replaced the previous version of the standard release.
- HJ/T 370-2007.
Environmental labeling products Technical requirements Offset printing ink
1 Scope of application
This standard specifies the terms and definitions, basic requirements, technical contents and inspection methods of offset printing ink environmental labeling products.
This standard applies to offset printing inks.
2 normative reference documents
The contents of this standard refer to the terms of the following documents. For undated references, the valid version applies to this standard.
Materials for interior decoration - Limits of hazardous substances in solvent - borne wood coatings
GB/T 15962 ink terminology
GB/T 16483 SAFETY DATA SHEET Contents AND PROJECT STATE
Paints and varnishes - Determination of volatile organic compounds (VOC) content - Gas chromatographic method GB/T 23986-2009 GB/T 23986-2009
QB 2930.1 Limits and methods for the determination of certain harmful elements in inks Part 1 Soluble elements
QB 2930.2 Limits and methods for the determination of certain harmful elements in inks - Part 2. Lead, mercury, cadmium, hexavalent chromium
3 terms and definitions
GB/T 15962 and the following terms and definitions are applicable to this standard.
3.1 offset printing ink
Applicable to all kinds of lithographic printing ink in general.
3.2 volatile organic compounds volatile organic compounds (VOC)
At any standard pressure of 101.3 kpa, any organic compound having an initial boiling point of less than or equal to 250 ° C.
4 basic requirements
4.1 product quality, safety performance should meet the requirements of the corresponding standards.
4.2 The pollutant discharge of the product manufacturer shall conform to the pollutant discharge standard stipulated by the state or local.
4.3 production enterprises in the production process should strengthen the clean production.
5 technical content
5.1 Requirements for the production process
5.1.1 No addition of halogenated hydrocarbons, isophorone, hydroquinone, p-methoxyphenol and phthalate esters listed in Appendix A.
5.1.2 Do not use asphalt as raw material.
5.1.3 Energy-curable inks do not add benzophenone (BP), isopropyl thioxanthone (ITX), 2-methyl-1- (4-methylthiophenyl) -2-
1-propanone (907) as a photoinitiator.
5.2 Product requirements
5.2.1 The limits of vegetable oil in the product shall meet the requirements of Table 1.
Table 1 Limits of Vegetable Oil in Products
Category Vegetable Oil Limit Requirement,%
Cold-set rotary offset printing ink ≥ 30
Sheetfed offset printing ink ≥ 20
Hot stamping offset printing ink ≥ 7
5.2.2 The mass fraction of aromatic hydrocarbons used in the mineral oil used in the product shall be less than 1%.
5.2.3 The volatile organic compounds (VOC), benzene, toluene, xylene and ethylbenzene in the product shall meet the requirements of Table 2, heavy metals and
Other hazardous substances should meet the requirements of QB 2930.1 and QB 2930.2.
Table 2 Hazardous substances in products limit requirements
project
Limited requirements
Heat solid rotation
Offset printing ink
Sheetlet Offset
Ink
Cold rotation
Offset printing ink
Energy curing glue
Printing ink
Volatile organic compounds (VOC),% ≤ 10 3 3 2
Benzene, toluene, xylene and ethylbenzene, mg/kg ≤ 100
5.3 Packaging and description requirements
5.3.1 Plastic packaging containers do not add PBBs, PBDEs and chlorinated paraffins (chain carbon
The number of 10-13, containing chlorine concentration of 50% or more).
5.3.2 plastic packaging containers do not add lead, cadmium, mercury plastic additives.
5.3.3 The enterprise shall provide the user with a proposal to reduce the use conditions for the release of the harmful substances.
5.3.4 The enterprise shall provide the user with the product safety technical specification in accordance with GB/T 16483.
6 test method
6.1 Technical contents 5.2.3 The detection of volatile organic compounds (VOCs) in Table 2 was carried out in accordance with the method specified in GB/T 23986-2009
Intermediate reagent selection and sample preparation were carried out as described in Appendix B.
6.2 Technical contents 5.2.3 The detection of benzene, toluene, xylene and ethylbenzene in Table 2 is carried out according to the method specified in GB 18581-2009.
Option selection and sample preparation were carried out as described in Appendix C.
6.3 Other requirements in the technical content are verified by means of document review and on-site inspection.
Appendix A
(Normative appendix)
Phthalate esters
Chinese name English name
Di-iso-nonylphthalate (DINP) phthalate Di-iso-nonylphthalate (DINP)
Di-n-octylphthalate (DNOP) Di-n-octyl phthalate
(2-ethylhexyl) phthalate Di- (2-ethylhexyl) -phthalate (DEHP)
Diisodecylphthalate (DIDP) phthalate Di-isodecylphthalate (DIDP)
Butylbenzylphthalate (BBP) Butylbenzylphthalate (BBP)
Dibutylphthalate Dibutylphthalate (DBP)
Appendix B
(Normative appendix)
Analysis of Volatile Organic Compounds in Offset Inks by Gas Chromatography
This note describes the following test steps based on the method of GB/T 23986-2009.
B.1 Reagent selection
B.1.1 Internal standard. Select ethylbenzene, n-dodecane or n-alkanes with less than 14 carbon atoms.
B.1.2 Dilution solvent. Ethanol.
B.1.3 Marker. n-tetradecane (boiling point. 253 ° C).
B.2 Sample preparation
Weigh 0.3 g of the sample (accurate to 0.1 mg) in a 25 mL Erlenmeyer flask, dilute the sample with 10 mL of dilution solvent,
Quality similar to the same standard in the sample bottle. Sealed sample vials. Placed in the ultrasonic shock in the shock for 10 minutes (after ultrasonic shock
The sample was dispersed, such as the sample is not dispersed to extend the ultrasonic shock time to the sample in ethanol dispersion), take appropriate test solution in the centrifuge
(≥ 4000 rpm) in centrifugal purification. Take the solution for testing.
B.3 Calculation
The relative correction factor ri is 1.0.
Appendix C
(Normative appendix)
Determination of Benzene, Toluene, Xylene and Ethylbenzene in Offset Inks by Gas Chromatography
The present note details the following test steps based on the method of Appendix B in GB 18581-2009.
C.1 reagent selection
C.1.1 Internal standard. methyl pyrrolidone, isobutanol and the like.
C.1.2 Dilution solvent. Ethanol.
C.2 Sample preparation
Weigh 0.3g of the sample (called quasi-to 0.1mg) in a 25mL Erlenmeyer flask, dilute the sample with 10mL dilution solvent,
The same amount of material as the internal standard in the sample bottle. Sealed sample vials. Placed in the ultrasonic oscillator in the shock for 10 minutes (after ultrasonic shock
Of the sample was dispersed, such as the sample is not dispersed to extend the ultrasonic shock time to the sample in ethanol dispersion), take appropriate amount of test solution in the centrifuge
(≥ 4000 rpm) in centrifugal purification. Take the solution for testing.
Related standard:   HJ 2543-2016
   
 
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