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GB/T 7385-2012: Non-ionic surface active agents -- Polyethoxylated derivatives -- Iodometric determination of oxyethylene groups
Status: Valid
GB/T 7385: Evolution and historical versions
| Standard ID | Contents [version] | USD | STEP2 | [PDF] delivered in | Standard Title (Description) | Status | PDF |
| GB/T 7385-2012 | English | 229 |
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Non-ionic surface active agents -- Polyethoxylated derivatives -- Iodometric determination of oxyethylene groups
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GB/T 7385-2012
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| GB/T 7385-1994 | English | 319 |
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Non-ionic surface active agents--Polyethoxylated derivatives--Iodometric determination of oxyethylene groups
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GB/T 7385-1994
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| GB 7385-1987 | English | 199 |
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Surface active agents--Ethylene oxide adducts--Iodometric determination of oxyethylene groups
| Obsolete |
GB 7385-1987
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PDF similar to GB/T 7385-2012
Basic data
| Standard ID | GB/T 7385-2012 (GB/T7385-2012) |
| Description (Translated English) | Non-ionic surface active agents -- Polyethoxylated derivatives -- Iodometric determination of oxyethylene groups |
| Sector / Industry | National Standard (Recommended) |
| Classification of Chinese Standard | G72 |
| Classification of International Standard | 71.100.40 |
| Word Count Estimation | 10,138 |
| Older Standard (superseded by this standard) | GB/T 7385-1994 |
| Quoted Standard | GB/T 601-2002; GB/T 683-2006; GB/T 1272-2007; GB/T 1282-1996; GB/T 6682-2008 |
| Adopted Standard | ISO 2270-1989, MOD |
| Regulation (derived from) | National Standards Bulletin No. 41 of 2012 |
| Issuing agency(ies) | General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China |
| Summary | This standard specifies the iodometric determination of polyoxyethylene type surfactant oxyethylene group content. This standard applies to saturated primary alcohols, oleyl alcohol, saturated fatty acids, straight-chain and branched alkylphenol polyethox |
GB/T 7385-2012: Non-ionic surface active agents -- Polyethoxylated derivatives -- Iodometric determination of oxyethylene groups
---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
ICS71.100.40
G72
National Standards of People's Republic of China
Replacing GB/T 7385-1994
Nonionic surfactants
Polyethoxylated derivatives
Measuring the oxygen content of the vinyl Iodimetry
(ISO 2270. 1989, MOD)
Issued on. 2013-08-01 2012-12-31 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Foreword
This standard rule according to GB/T 1.1-2009 given draft.
This standard replaces GB/T 7385-1994 "nonionic surfactant polyethoxylated derivatives measured oxygen content of the vinyl
Iodimetry ", compared with the GB/T 7385-1994, the main changes are as follows.
--- Increasing the foreword;
--- Change the "starch solution" method of preparation (see 4.7,1994 version 4.7);
--- Added "blank test" (see 6.3);
--- Added "Test Report" (see Chapter 8).
This standard uses redrafted law revision adopted ISO 2270. 1989 "nonionic surfactant polyethoxylated derivatives of oxygen
Vinyl groups iodometric determination. "
This standard and ISO 2270. 1989 compared to the more structural adjustment, listed in Appendix A of this standard and ISO 2270. 1989's
Reg number control list.
This standard and ISO 2270. 1989 and the technical differences for the following reasons.
--- On normative references, this standard has been adjusted technical differences, in order to adapt our technical conditions, the adjusted situation
Focus is reflected in the status of Chapter 2, "Normative references", the specific adjustments are as follows.
● increase cited GB/T 601-2002 (see 4.6);
● increase cited GB/T 683-2006 (see 4.4);
● increase cited GB/T 1272-2007 (see 4.2);
● increase cited GB/T 1282-1996 (see 4.3);
● increase cited GB/T 6682-2008 (see 4.1);
● Remove the ISO 383. 1976 and ISO 385.1. 1984.
--- Increased 5.5, in order to test the operation more convenient, easy placement of said rod-like;
--- 1 increase in F, because "instruments and equipment" have been added to said rod-like outlet should also be given icon.
The standard proposed by China Petroleum and Chemical Industry Association.
This standard by the National Standardization Technical Committee Chemistry (specialty) surfactant Technical Committee (SAC/TC63/SC8) centralized.
This standard was drafted. Zhejiang Real Technology Co., Ltd.
The main drafters of this standard. Tangfu Wei, Ma Xiakun, Guo Xiaofeng, Ma even fixed.
This standard replaces the standards previously issued as follows.
--- GB/T 7385-1987, GB/T 7385-1994.
Nonionic surfactants
Polyethoxylated derivatives
Measuring the oxygen content of the vinyl Iodimetry
1 Scope
This standard specifies the determination of the oxygen content of poly vinyl surfactant oxyethylene groups by iodometry.
This standard applies to primary saturated fatty alcohols, oleyl alcohol, saturated fatty acids, linear and branched alkylphenols ethoxylated derivatives. If Yan
Organisms unreacted alcohols, fatty acids or alkylphenols exist, this standard applies.
If a nitrogen or sulfur-containing derivatives, oxyethylene connecting adjacent carbon atoms contain oxygen or halogen (e.g. oxygen-propenyl), an aldehyde or acetal,
Sterols, etc. This standard does not apply.
2 Normative references
The following documents for the application of this document is essential. For dated references, only the dated edition applies to this article
Member. For undated references, the latest edition (including any amendments) applies to this document.
Preparation of GB/T 601-2002 Chemical reagents Titration standard solution
GB/T 683-2006 Chemicals Methanol
GB/T 1272-2007 chemical reagents potassium iodide
GB/T 1282-1996 chemical reagents phosphate (ISO 6353-2. 1983, MOD)
GB/T 6682-2008 analytical laboratory use specifications and test methods (ISO 3696. 1987, MOD)
Principle 3
Hydroiodic acid hydrolysis of vinyl oxygen generated by the new, liberated iodine with sodium thiosulfate standard solution titration to calculate the mass of oxyethylene
Volume fraction.
The basic reaction is as follows.
RO- (CH2CH2O) nH 2nHI → nICH2-CH2I ROH nH2O
Unstable diiodo ethane is decomposed under heating.
ICH2-CH2I → C2H4 I2
NOTE. If R is an alkyl group, ROH will be converted to vinyl groups RI (oil and alcohol, all vinyl groups) will react with HI, to form a stable.
Iodide.
4 Reagents and solutions
4.1 test water
Third grade water requirements of GB/T 6682-2008 prescribed.
4.2 potassium iodide
Meet the technical requirements GB/T 1272-2007 of.
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