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HJ 987-2018 English PDF

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HJ 987-2018: Self-monitoring technology guidelines for pollution sources - Pesticide manufacture
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Basic data

Standard ID HJ 987-2018 (HJ987-2018)
Description (Translated English) Self-monitoring technology guidelines for pollution sources - Pesticide manufacture
Sector / Industry Environmental Protection Industry Standard
Classification of Chinese Standard Z05
Word Count Estimation 10,185
Issuing agency(ies) Ministry of Ecology and Environment

HJ 987-2018: Self-monitoring technology guidelines for pollution sources - Pesticide manufacture


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Self-monitoring technology guidelines for pollution sources - Pesticide manufacture National Environmental Protection Standard of the People's Republic Sewage unit self-monitoring technical guide Pesticide manufacturing industry Self-monitoring technology guidelines for pollution sources -Pesticide manufacture Published on.2018-12-04 2019-03-01 implementation Ministry of Ecology and Environment released i directory Foreword..ii 1 Scope 1 2 Normative references 1 3 Terms and Definitions..1 4 General requirements for self-monitoring. 2 5 Monitoring plan development. 2 6 Information records and reports 6 7 other..7 Ii preface To implement the "Environmental Protection Law of the People's Republic of China", "Water Pollution Prevention and Control Law of the People's Republic of China" National Air Pollution Prevention and Control Law, "Measures for the Administration of Pollution Discharge Permits (Trial)", guide and standardize the self-monitoring of pesticide discharge industrial units Test work, develop this standard. This standard proposes the general requirements for self-monitoring of pesticide discharge industrial pollutant discharge units, the development of monitoring plans, information records and The basic content and requirements of the report. This standard is the first release. This standard was proposed and organized by the Ministry of Ecology and Environment. This standard is mainly drafted by. China Environmental Monitoring Station, Shandong Environmental Monitoring Center Station. This standard is approved by the Ministry of Ecology and Environment on December 4,.2018. This standard has been implemented since March 1,.2019. This standard is explained by the Ministry of Ecology and Environment. 1 sewage control unit self-monitoring technical guide pesticide manufacturing industry

1 Scope of application

This standard proposes the general requirements for self-monitoring of pesticide discharge industrial pollutant discharge units, the development of monitoring plans, information records and The basic content and requirements of the report. This standard is applicable to water and gas pollutants emitted by pesticide discharge units in the production and operation stage of the pesticide manufacturing industry. And monitoring the impact on the quality of its surrounding environment. The self-monitoring requirements for self-contained thermal power generating units (plants) and supporting power boilers shall be in accordance with the self-monitoring technology of the sewage disposal unit. South Thermal Power Generation and Boiler (HJ 820) is implemented.

2 Normative references

The contents of this standard refer to the following documents or their terms. For undated references, the valid version is appropriate. Used in this standard. GB 14554 Odor Pollutant Discharge Standard GB 16297 Integrated emission standards for atmospheric pollutants HJ/T 2.3 Technical Guidelines for Environmental Impact Assessment Surface Water Environment HJ/T 91 Surface Water and Wastewater Monitoring Technical Specifications HJ/T 164 Technical Specifications for Groundwater Environmental Monitoring HJ/T 166 Technical Specifications for Soil Environmental Monitoring HJ 442 Code for Environmental Monitoring of Coastal Waters HJ 610 Environmental Impact Assessment Technical Guidelines Groundwater Environment HJ 819 General Guidelines for Self-Monitoring Technical Units of Sewage Units HJ 820 sewage unit self-monitoring technical guide thermal power generation and boiler National Directory of Hazardous Wastes (Order No. 39 of the Ministry of Environmental Protection)

3 Terms and definitions

The following terms and definitions apply to this standard. 3.1 Pesticide pesticide Refers to the prevention, control of diseases, insects, grasses, rats and other harmful organisms that endanger agriculture and forestry, and targeted adjustment Chemical synthesis of plants, insect growth, or a substance derived from organisms, other natural substances, or a mixture of several substances And its preparations. 3.2 Pesticide industry pollutant emission unit Refers to the production of diseases, insects, grasses, rats and other harmful organisms that are used to prevent and control agricultural and forestry, as well as purposeful HJ □□□-201□ a chemical synthesis that regulates the growth of plants, insects, or a substance derived from organisms, other natural substances, or substances The unit of discharge of the mixture and its preparation. 3.3 Direct discharge Refers to the behavior of sewage units directly discharging water pollutants into water bodies. 3.4 Indirect discharge Refers to the behavior of sewage units discharging water pollutants to public sewage treatment systems. 3.5 Pesticide original drug Refers to substances or materials that constitute the active ingredients of pesticides prepared or synthesized by inorganic, organic, or biological methods. 3.6 Volatile organic compounds (VOCs) Refers to an organic compound that participates in atmospheric photochemical reactions, or measures or accounts for established organic compounds according to specified methods. Object. 4 General requirements for self-monitoring The pollutant discharge unit shall check the pollution source, pollutant index and potential environmental impact of the unit, formulate a monitoring plan, and set up And maintenance monitoring facilities, carry out self-monitoring according to the monitoring plan, do quality assurance and quality control, record and save monitoring Data, publicly monitor the results to the public according to law.

5 Monitoring plan development

5.1 Wastewater discharge monitoring 5.1.1 Monitoring points All pesticide industrial sewage discharge units must set monitoring points at the total discharge port and rainwater discharge port to discharge total mercury and alkane. Mercury, total cadmium, total chromium, hexavalent chromium, total arsenic, total lead, total nickel, benzo(a)pyrene, total strontium, total silver, atrazine, fipronil It is also necessary to set monitoring points in the corresponding workshop or production facility wastewater discharge port. 5.1.2 Monitoring indicators and monitoring frequency The monitoring points, monitoring indicators and minimum monitoring frequency of wastewater discharge units shall be implemented in accordance with Table 1. Table 1 Monitoring points, indicators and minimum monitoring frequency of wastewater discharge Sewage list Bit level monitor Point Monitoring indicator Frequency of monitoring Remarks Direct emission indirect emissions Focus row Soil unit Total wastewater exhaustion hole Flow rate, pH value, chemical oxygen demand, automatic monitoring of ammonia nitrogen - Suspension, petroleum, color, day and month - HJ □□□-201□ Sewage list Bit level monitor Point Monitoring indicator Frequency of monitoring Remarks Direct emission indirect emissions Phosphate (in P) (total phosphorus) Month (automatic monitoring a) - Five-day biochemical oxygen demand monthly quarter According to the emission standard Quasi-discharge permit Certificate and other related environment Management regulations to And production process, Raw and auxiliary materials, medium And final product (pesticide original drug), Identify specific supervisors Measured indicator Industry water pollutants Emission standards released After that, from its provisions Volatile phenol, total cyanide, chlorobenzene, nitrobenzene, aniline Class, benzene, toluene, xylene, ethylbenzene, formaldehyde, total zinc, Pentachlorophenol and sodium pentachlorophenol (calculated as pentachlorophenol), dimethoate, 2–Chloro–5–chloromethylpyridine, imidazolidine, imidacloprid, three Oxazolone, p-chlorophenol, carbendazim, o-phenylenediamine, pyridine, Paraquat ion, 2,2'.6',2"-terpyridine, organic phosphorus Medicine (in P), malathion Month quarter Total organic carbon, fluoride, sulfide, adsorbable organic halogen Compound (AOX), total manganese, animal and vegetable oil Quarterly half year Workshop or Production design Waste water exhaustion hole Flow, total mercury, alkyl mercury, total cadmium, total chromium, hexavalent chromium, Total arsenic, total lead, total nickel, benzo(a)pyrene, total strontium, total Silver, atrazine, fipronil Rainwater row Put a mouth b pH, chemical oxygen demand, suspended matter day c - Non-focused Sewage list Total wastewater exhaustion hole Flow, pH, chemical oxygen demand, ammonia nitrogen month - Suspended matter, petroleum, color, 5th day BOD, Phosphate (in P) (total phosphorus), total nitrogen Quarter According to the emission standard Quasi-discharge permit Certificate and other related environment Management regulations to And production process, Raw and auxiliary materials, medium And final product (pesticide original drug), Identify specific supervisors Measured indicator Industry water pollutants Emission standards released After that, from its provisions Volatile phenol, total cyanide, chlorobenzene, nitrobenzene, aniline Class, benzene, toluene, xylene, ethylbenzene, formaldehyde, total zinc, Pentachlorophenol and sodium pentachlorophenol (calculated as pentachlorophenol), dimethoate, 2–Chloro–5–chloromethylpyridine, imidazolidine, imidacloprid, three Oxazolone, p-chlorophenol, carbendazim, o-phenylenediamine, pyridine, Paraquat ion, 2,2'.6',2"-terpyridine, organic phosphorus Medicine (in P), malathion Quarter Total organic carbon, fluoride, sulfide, adsorbable organic halogen Compound (AOX), total manganese, animal and vegetable oil Half a year Workshop or Production design Waste water exhaustion hole Flow, total mercury, alkyl mercury, total cadmium, total chromium, hexavalent chromium, Total arsenic, total lead, total nickel, benzo(a)pyrene, total strontium, total Silver, atrazine, fipronil Quarter Rainwater row Put a mouth b pH, chemical oxygen demand, suspended matter day c - Note. The monitoring indicators listed in the table, if the municipal and above environmental protection authorities in the district explicitly require the installation of automatic monitoring equipment, automatic monitoring shall be adopted. a Phosphorus-containing chemical pesticides for the production of pollutant discharge units and water environmental quality in the total phosphorus control area of the key pollutant discharge unit, the total phosphorus must be automatically monitored Measurement. b In addition to the pollutant indicators specified in the table, the pollutant discharge unit may select characteristic pollutant indicators from the discharged pollutant indicators according to actual conditions. monitor. c When the rainwater discharge port has mobile water discharge, it is monitored daily. If there is no abnormality in the monitoring year, it can be relaxed to monitor once every quarter. 5.2 Exhaust emission monitoring 5.2.1 Organized exhaust emission monitoring points, indicators and frequency 5.2.1.1 The monitoring points, indicators and minimum monitoring frequency of organized exhaust emission in each production process shall be implemented in accordance with Table 2. 5.2.1.2 Where a plurality of pollution sources or production equipment share a discharge cylinder, the monitoring points may be arranged on the common exhaust cylinder. The monitoring indicators shall cover the monitoring indicators of the corresponding pollution sources or production equipment, and the minimum monitoring frequency shall be strictly implemented. Table 2 Exhaust emission monitoring points, indicators and minimum monitoring frequency HJ □□□-201□ Production process monitoring point monitoring indicators monitoring frequency Raw materials Storage Tank exhaust pipe, etc. Volatile Organic Compound a Quarter Characteristic pollutant b year Preparation, chemical Synthesis, purification separation, Solvent recovery, workshop Ventilation system, workshop No tissue exhaust Set production process Combustion exhaust gas treatment facility exhaust Automatic monitoring of sulfur dioxide, nitrogen oxides and particulate matter Dioxin class Non-combustion exhaust gas treatment facilities, exhaust pipe, sulfur dioxide c, nitrogen oxides d, automatic monitoring of particulate matter Combustion method and non-combustion method Exhaust Volatile organic compounds a month Characteristic pollutant b half a year Biological fermentation Combustion exhaust gas treatment facility exhaust Automatic monitoring of sulfur dioxide, nitrogen oxides and particulate matter Dioxin class Non-combustion exhaust gas treatment facilities, exhaust pipe, sulfur dioxide c, nitrogen oxides d, automatic monitoring of particulate matter Combustion method and non-combustion method Exhaust Volatile organic compounds a month Odor concentration, characteristic pollutant b half a year Preparation processing Drying equipment, pulverizer, dryer, bag Installer and other exhaust pipe e Particulate matter, volatile organic compounds b quarter Wastewater treatment facility, Dangerous waste temporary storage place Exhaust Volatile Organic Compound a Quarter Odor concentration, characteristic pollutant b years Hazardous waste incinerator exhaust pipe Sulfur dioxide, nitrogen oxides, particulate matter, furnace temperature Automatic monitoring Smoke blackness, carbon monoxide, hydrogen chloride, fluorination Hydrogen, mercury and its compounds, cadmium and its compounds, (arsenic, nickel and its compounds), lead and their combination Matter, (锑, chrome, tin, copper, manganese and their combinations) Object) Dioxin class Note 1. Exhaust gas monitoring shall be synchronized to monitor flue gas parameters in accordance with the corresponding monitoring and analysis methods and technical specifications. Note 2. The monitoring indicators listed in the table, if the municipal and above environmental protection authorities in the district explicitly require the installation of automatic monitoring equipment, automatic monitoring shall be adopted. Note 3. The pollutant monitoring indicators of the national pollutant monitoring method standards have not been released, and will be implemented after the national monitoring method standards are issued. a This standard uses non-methane total hydrocarbons as a comprehensive control indicator for volatile organic matter emissions, and is subject to the emission standards for air pollutants from pesticide manufacturing industries. After the cloth, it is prescribed from it. b See the pollutants listed in GB 16297 and GB 14554, and determine the specifics according to the relevant environmental management regulations such as the environmental impact assessment document and its approval. The monitoring indicators are subject to the provisions of the pesticide manufacturing industry after the release of air pollutant emission standards. c Suitable for the production process of emitting sulfur dioxide. d Suitable for the production process of nitrogen oxides. e The principle of determining the characteristics of pollutants in the reference tank area of the reference tank area and the frequency of monitoring. 5.2.2 Unorganized exhaust emission monitoring points, indicators and frequency The monitoring points, indicators and minimum monitoring frequency of unorganized exhaust emission are implemented according to Table 3. Table 3 Unorganized exhaust emission monitoring points, indicators and minimum monitoring frequency Frequency of monitoring monitoring indicators Factory boundary particulate matter, odor concentration, volatile organic compounds a, characteristic pollutants b HJ □□□-201□ a This standard uses non-methane total hydrocarbons as a comprehensive control indicator for volatile organic matter emissions, and is subject to the emission standards for air pollutants from pesticide manufacturing industries. After the cloth, it is prescribed from it. b See GB 16297, GB 14554 listed pollutants according to environmental impact assessment documents and their approvals and other relevant environmental management regulations, determine the specific The monitoring indicators shall be stipulated after the release of the air pollutant discharge standards of the pesticide manufacturing industry. 5.3 Environmental noise monitoring at the boundary of the plant The environmental noise monitoring point setting at the boundary should follow the principle in HJ 819, mainly considering the points of the noise source in the plant. Cloth situation. Environmental noise at the boundary of the plant shall be monitored at least once a quarter, and units discharged at night shall be monitored at night. noise. If there are sensitive points around, the frequency of monitoring should be increased. Table 4 Main noise sources that should be concerned about the environmental noise distribution at the boundary of the plant Noise source main equipment Production workshop and supporting facilities Reaction equipment, distillation equipment, distillation equipment, filtration equipment, separation equipment, drying equipment, heat exchange equipment, etc. And air compressors, pumps, vacuum pumps, etc. Sewage treatment aeration equipment, sludge dewatering equipment, fans, pumps, etc. 5.4 Surrounding environment quality impact monitoring 5.4.1 Environmental Management Policy or Emission Permit, etc. [Approved for Environmental Impact Assessment only after January 1,.2015 (inclusive) If there is a specific requirement for the sewage disposal unit, it shall be implemented as required. 5.4.2 If there is no clear requirement, the pollutant discharge unit may supervise the surrounding surface water, seawater, groundwater and soil according to the actual situation. Measurement. For sewage discharge units directly discharged into surface water and seawater, HJ/T 2.3, HJ/T 91, HJ 442 and receiving The water environment management requires the setting of monitoring sections and monitoring points; the sewage disposal units that carry out groundwater and soil monitoring can be in accordance with HJ . 610, HJ/T 164, HJ/T 166 and groundwater and soil environmental management requirements set monitoring points. Monitoring indicators and minimum monitoring The frequency is performed according to Table 5. Table 5 Minimum monitoring frequency of surrounding environment quality impact monitoring indicators Target environmental monitoring indicators monitoring frequency remarks Surface water pH, five-day biochemical oxygen demand, chemical oxygen demand, ammonia nitrogen, total nitrogen, total Phosphorus, petroleum, cyanide, volatile phenol, sulfide, fluoride, zinc, Mercury, cadmium, hexavalent chromium, arsenic, lead, etc. Quarterly according to emission standards, row Pollution permit and other related rings Regulations, Production process, original and auxiliary Materials, intermediate and final production Product (pesticide drug), Identify specific monitoring fingers seawater pH, suspended matter, chemical oxygen demand, biochemical oxygen demand, petroleum, Volatile phenol, cyanide, sulfide, zinc, mercury, cadmium, total chromium, hexavalent Chromium, arsenic, lead, nickel, benzo (a) pyrene, etc. Half a year groundwater pH, color (degrees), oxygen consumption, ammonia nitrogen, volatile phenols (with phenol), Cyanide, fluoride, manganese, zinc, arsenic, mercury, lead, cadmium, hexavalent chromium, Nickel, bismuth, etc. Soil pH, mercury, cadmium, chromium, arsenic, lead, nickel, zinc, etc. 5.5 Other requirements 5.5.1 In addition to the pollutant indicators in Tables 1 to 3, the pollutant indicators in 5.5.1.1 and 5.5.1.2 should also be included in the monitoring indicators. Range, and refer to Tables 1 to 3 and HJ 819 to determine the frequency of monitoring. 5.5.1.1 Drainage permit, pollutant discharge (control) standards implemented, environmental impact assessment documents and their approvals The pollutant discharge unit approved by the environmental impact assessment after January 1,.2015 (including), and the relevant environmental management regulations Seeking indicators of pollutants. 5.5.1.2 According to the raw materials and auxiliary materials used in the production process, the production process, the intermediate and final product types, and the monitoring results Contaminant indicators in the relevant list of toxic, hazardous or preferentially controlled pollutants, or other toxic pollutants index. HJ □□□-201□ 5.5.2 The frequency of monitoring of each indicator can be improved according to the principle of determining the frequency of monitoring in HJ 819 on the basis of meeting this standard. Frequency of monitoring. 5.5.3 Sampling methods, monitoring and analysis methods, monitoring quality assurance and quality control shall be carried out in accordance with the relevant requirements of HJ 819. 5.5.4 The description and changes of the monitoring plan shall be implemented in accordance with HJ 819.

6 Information records and reports

6.1 Information Record 6.1.1 Monitoring information record Manual monitoring records and automatic monitoring of operation and maintenance records are performed in accordance with HJ 819. 6.1.2 Record of operation status of production and pollution control facilities The sewage disposal unit shall record the operation status of the production and pollution control facilities in detail, and the daily production shall also refer to the following contents. Relevant information, and organized into a ledger for future reference. 6.1.2.1 Production Health Record Record the following information for each production batch according to the type of pesticide product. a) The amount of raw materials used mainly includes the amount of raw materials, the amount of catalyst used, the amount of various solvents, the amount of adsorbent, and others. Amount of auxiliary materials, etc.; b) intermediate and final product yield, yield and material balance; c) fresh water intake, water consumption, electricity consumption, etc.; d) Record of the operational use of the main production equipment and facilities used. 6.1.2.2 Wastewater treatment facility operation record Record the amount of wastewater treatment, the amount of reuse, the rate of reuse, the direction of reuse, the amount of sludge, the amount of sludge produced (record moisture content), The name and amount of the agent used in wastewater treatment, electricity consumption, etc.; record the operation, failure and maintenance of the wastewater treatment facility. 6.1.2.3 Exhaust gas treatment facility operation record Record the name and amount of consumables such as adsorbents and filter materials used for exhaust gas treatment on a daily basis, and record the exhaust gas treatment facilities. Line, fault and maintenance conditions. 6.1.2.4 Solvent recovery equipment operation record Record the solvent name, recovery amount, replenishment amount, and solvent recovery equipment energy and consumables according to the production batch of each product. Quantity and so on. 6.1.3 General industrial solid waste and hazardous waste information records Record the amount of general industrial solid waste generated, comprehensive utilization, disposal amount and storage amount on a daily basis; Relevant requirements for waste management, record the amount of hazardous waste generated, comprehensive utilization, disposal volume, storage capacity and specific Going. The situation of raw materials or other hazardous wastes generated in the auxiliary process shall also be recorded. General industrial solid waste and hazardous waste The production situation is shown in Table 6. Table 6 General industrial solid waste and hazardous waste sources HJ □□□-201□ Source of species Hazardous Waste Residues from the filtration of hexachlorocyclopentadiene in the production of chlordane; waste from the vacuum stripping of the chlorination reactor Distillation residue from toluene recovery process in the production of acetonitrile Residues produced by filtration of diethyldithiophosphoric acid during the production of phorate Heavy fractions and distillation residues from the distillation of tetrachlorobenzene in the production of 2,4,5-trichlorophenoxyacetic acid Residues containing 2,6-dichlorophenol produced during the production of 2,4-dichlorophenoxyacetic acid Filtration, evaporation and centrifugation of residues and wastewater from vinyl bisdithiocarbamic acid and its salts Treatment of sludge; collection of product grinding and packaging processes (dust removal and ground cleaning waste collected by dust removal equipment) Waste water produced by reactors in the producti...

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