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HJ 987-2018
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Basic data Standard ID | HJ 987-2018 (HJ987-2018) | Description (Translated English) | Self-monitoring technology guidelines for pollution sources - Pesticide manufacture | Sector / Industry | Environmental Protection Industry Standard | Classification of Chinese Standard | Z05 | Word Count Estimation | 10,185 | Issuing agency(ies) | Ministry of Ecology and Environment |
HJ 987-2018: Self-monitoring technology guidelines for pollution sources - Pesticide manufacture ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Self-monitoring technology guidelines for pollution sources - Pesticide manufacture
National Environmental Protection Standard of the People's Republic
Sewage unit self-monitoring technical guide
Pesticide manufacturing industry
Self-monitoring technology guidelines for pollution sources
-Pesticide manufacture
Published on.2018-12-04
2019-03-01 implementation
Ministry of Ecology and Environment released
i directory
Foreword..ii
1 Scope 1
2 Normative references 1
3 Terms and Definitions..1
4 General requirements for self-monitoring. 2
5 Monitoring plan development. 2
6 Information records and reports 6
7 other..7
Ii preface
To implement the "Environmental Protection Law of the People's Republic of China", "Water Pollution Prevention and Control Law of the People's Republic of China"
National Air Pollution Prevention and Control Law, "Measures for the Administration of Pollution Discharge Permits (Trial)", guide and standardize the self-monitoring of pesticide discharge industrial units
Test work, develop this standard.
This standard proposes the general requirements for self-monitoring of pesticide discharge industrial pollutant discharge units, the development of monitoring plans, information records and
The basic content and requirements of the report.
This standard is the first release.
This standard was proposed and organized by the Ministry of Ecology and Environment.
This standard is mainly drafted by. China Environmental Monitoring Station, Shandong Environmental Monitoring Center Station.
This standard is approved by the Ministry of Ecology and Environment on December 4,.2018.
This standard has been implemented since March 1,.2019.
This standard is explained by the Ministry of Ecology and Environment.
1 sewage control unit self-monitoring technical guide pesticide manufacturing industry
1 Scope of application
This standard proposes the general requirements for self-monitoring of pesticide discharge industrial pollutant discharge units, the development of monitoring plans, information records and
The basic content and requirements of the report.
This standard is applicable to water and gas pollutants emitted by pesticide discharge units in the production and operation stage of the pesticide manufacturing industry.
And monitoring the impact on the quality of its surrounding environment.
The self-monitoring requirements for self-contained thermal power generating units (plants) and supporting power boilers shall be in accordance with the self-monitoring technology of the sewage disposal unit.
South Thermal Power Generation and Boiler (HJ 820) is implemented.
2 Normative references
The contents of this standard refer to the following documents or their terms. For undated references, the valid version is appropriate.
Used in this standard.
GB 14554 Odor Pollutant Discharge Standard
GB 16297 Integrated emission standards for atmospheric pollutants
HJ/T 2.3 Technical Guidelines for Environmental Impact Assessment Surface Water Environment
HJ/T 91 Surface Water and Wastewater Monitoring Technical Specifications
HJ/T 164 Technical Specifications for Groundwater Environmental Monitoring
HJ/T 166 Technical Specifications for Soil Environmental Monitoring
HJ 442 Code for Environmental Monitoring of Coastal Waters
HJ 610 Environmental Impact Assessment Technical Guidelines Groundwater Environment
HJ 819 General Guidelines for Self-Monitoring Technical Units of Sewage Units
HJ 820 sewage unit self-monitoring technical guide thermal power generation and boiler
National Directory of Hazardous Wastes (Order No. 39 of the Ministry of Environmental Protection)
3 Terms and definitions
The following terms and definitions apply to this standard.
3.1
Pesticide pesticide
Refers to the prevention, control of diseases, insects, grasses, rats and other harmful organisms that endanger agriculture and forestry, and targeted adjustment
Chemical synthesis of plants, insect growth, or a substance derived from organisms, other natural substances, or a mixture of several substances
And its preparations.
3.2
Pesticide industry pollutant emission unit
Refers to the production of diseases, insects, grasses, rats and other harmful organisms that are used to prevent and control agricultural and forestry, as well as purposeful
HJ □□□-201□
a chemical synthesis that regulates the growth of plants, insects, or a substance derived from organisms, other natural substances, or substances
The unit of discharge of the mixture and its preparation.
3.3
Direct discharge
Refers to the behavior of sewage units directly discharging water pollutants into water bodies.
3.4
Indirect discharge
Refers to the behavior of sewage units discharging water pollutants to public sewage treatment systems.
3.5
Pesticide original drug
Refers to substances or materials that constitute the active ingredients of pesticides prepared or synthesized by inorganic, organic, or biological methods.
3.6
Volatile organic compounds (VOCs)
Refers to an organic compound that participates in atmospheric photochemical reactions, or measures or accounts for established organic compounds according to specified methods.
Object.
4 General requirements for self-monitoring
The pollutant discharge unit shall check the pollution source, pollutant index and potential environmental impact of the unit, formulate a monitoring plan, and set up
And maintenance monitoring facilities, carry out self-monitoring according to the monitoring plan, do quality assurance and quality control, record and save monitoring
Data, publicly monitor the results to the public according to law.
5 Monitoring plan development
5.1 Wastewater discharge monitoring
5.1.1 Monitoring points
All pesticide industrial sewage discharge units must set monitoring points at the total discharge port and rainwater discharge port to discharge total mercury and alkane.
Mercury, total cadmium, total chromium, hexavalent chromium, total arsenic, total lead, total nickel, benzo(a)pyrene, total strontium, total silver, atrazine, fipronil
It is also necessary to set monitoring points in the corresponding workshop or production facility wastewater discharge port.
5.1.2 Monitoring indicators and monitoring frequency
The monitoring points, monitoring indicators and minimum monitoring frequency of wastewater discharge units shall be implemented in accordance with Table 1.
Table 1 Monitoring points, indicators and minimum monitoring frequency of wastewater discharge
Sewage list
Bit level
monitor
Point
Monitoring indicator
Frequency of monitoring
Remarks
Direct emission indirect emissions
Focus row
Soil unit
Total wastewater
exhaustion hole
Flow rate, pH value, chemical oxygen demand, automatic monitoring of ammonia nitrogen -
Suspension, petroleum, color, day and month -
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Sewage list
Bit level
monitor
Point
Monitoring indicator
Frequency of monitoring
Remarks
Direct emission indirect emissions
Phosphate (in P) (total phosphorus) Month (automatic monitoring a) -
Five-day biochemical oxygen demand monthly quarter
According to the emission standard
Quasi-discharge permit
Certificate and other related environment
Management regulations to
And production process,
Raw and auxiliary materials, medium
And final product
(pesticide original drug),
Identify specific supervisors
Measured indicator
Industry water pollutants
Emission standards released
After that, from its provisions
Volatile phenol, total cyanide, chlorobenzene, nitrobenzene, aniline
Class, benzene, toluene, xylene, ethylbenzene, formaldehyde, total zinc,
Pentachlorophenol and sodium pentachlorophenol (calculated as pentachlorophenol), dimethoate,
2–Chloro–5–chloromethylpyridine, imidazolidine, imidacloprid, three
Oxazolone, p-chlorophenol, carbendazim, o-phenylenediamine, pyridine,
Paraquat ion, 2,2'.6',2"-terpyridine, organic phosphorus
Medicine (in P), malathion
Month quarter
Total organic carbon, fluoride, sulfide, adsorbable organic halogen
Compound (AOX), total manganese, animal and vegetable oil
Quarterly half year
Workshop or
Production design
Waste water
exhaustion hole
Flow, total mercury, alkyl mercury, total cadmium, total chromium, hexavalent chromium,
Total arsenic, total lead, total nickel, benzo(a)pyrene, total strontium, total
Silver, atrazine, fipronil
Rainwater row
Put a mouth b
pH, chemical oxygen demand, suspended matter day c -
Non-focused
Sewage list
Total wastewater
exhaustion hole
Flow, pH, chemical oxygen demand, ammonia nitrogen month -
Suspended matter, petroleum, color, 5th day BOD,
Phosphate (in P) (total phosphorus), total nitrogen
Quarter
According to the emission standard
Quasi-discharge permit
Certificate and other related environment
Management regulations to
And production process,
Raw and auxiliary materials, medium
And final product
(pesticide original drug),
Identify specific supervisors
Measured indicator
Industry water pollutants
Emission standards released
After that, from its provisions
Volatile phenol, total cyanide, chlorobenzene, nitrobenzene, aniline
Class, benzene, toluene, xylene, ethylbenzene, formaldehyde, total zinc,
Pentachlorophenol and sodium pentachlorophenol (calculated as pentachlorophenol), dimethoate,
2–Chloro–5–chloromethylpyridine, imidazolidine, imidacloprid, three
Oxazolone, p-chlorophenol, carbendazim, o-phenylenediamine, pyridine,
Paraquat ion, 2,2'.6',2"-terpyridine, organic phosphorus
Medicine (in P), malathion
Quarter
Total organic carbon, fluoride, sulfide, adsorbable organic halogen
Compound (AOX), total manganese, animal and vegetable oil
Half a year
Workshop or
Production design
Waste water
exhaustion hole
Flow, total mercury, alkyl mercury, total cadmium, total chromium, hexavalent chromium,
Total arsenic, total lead, total nickel, benzo(a)pyrene, total strontium, total
Silver, atrazine, fipronil
Quarter
Rainwater row
Put a mouth b
pH, chemical oxygen demand, suspended matter day c -
Note. The monitoring indicators listed in the table, if the municipal and above environmental protection authorities in the district explicitly require the installation of automatic monitoring equipment, automatic monitoring shall be adopted.
a Phosphorus-containing chemical pesticides for the production of pollutant discharge units and water environmental quality in the total phosphorus control area of the key pollutant discharge unit, the total phosphorus must be automatically monitored
Measurement.
b In addition to the pollutant indicators specified in the table, the pollutant discharge unit may select characteristic pollutant indicators from the discharged pollutant indicators according to actual conditions.
monitor.
c When the rainwater discharge port has mobile water discharge, it is monitored daily. If there is no abnormality in the monitoring year, it can be relaxed to monitor once every quarter.
5.2 Exhaust emission monitoring
5.2.1 Organized exhaust emission monitoring points, indicators and frequency
5.2.1.1 The monitoring points, indicators and minimum monitoring frequency of organized exhaust emission in each production process shall be implemented in accordance with Table 2.
5.2.1.2 Where a plurality of pollution sources or production equipment share a discharge cylinder, the monitoring points may be arranged on the common exhaust cylinder.
The monitoring indicators shall cover the monitoring indicators of the corresponding pollution sources or production equipment, and the minimum monitoring frequency shall be strictly implemented.
Table 2 Exhaust emission monitoring points, indicators and minimum monitoring frequency
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Production process monitoring point monitoring indicators monitoring frequency
Raw materials
Storage
Tank exhaust pipe, etc.
Volatile Organic Compound a Quarter
Characteristic pollutant b year
Preparation, chemical
Synthesis, purification separation,
Solvent recovery, workshop
Ventilation system, workshop
No tissue exhaust
Set production process
Combustion exhaust gas treatment facility exhaust
Automatic monitoring of sulfur dioxide, nitrogen oxides and particulate matter
Dioxin class
Non-combustion exhaust gas treatment facilities, exhaust pipe, sulfur dioxide c, nitrogen oxides d, automatic monitoring of particulate matter
Combustion method and non-combustion method
Exhaust
Volatile organic compounds a month
Characteristic pollutant b half a year
Biological fermentation
Combustion exhaust gas treatment facility exhaust
Automatic monitoring of sulfur dioxide, nitrogen oxides and particulate matter
Dioxin class
Non-combustion exhaust gas treatment facilities, exhaust pipe, sulfur dioxide c, nitrogen oxides d, automatic monitoring of particulate matter
Combustion method and non-combustion method
Exhaust
Volatile organic compounds a month
Odor concentration, characteristic pollutant b half a year
Preparation processing
Drying equipment, pulverizer, dryer, bag
Installer and other exhaust pipe e
Particulate matter, volatile organic compounds b quarter
Wastewater treatment facility,
Dangerous waste temporary storage place
Exhaust
Volatile Organic Compound a Quarter
Odor concentration, characteristic pollutant b years
Hazardous waste incinerator exhaust pipe
Sulfur dioxide, nitrogen oxides, particulate matter, furnace
temperature
Automatic monitoring
Smoke blackness, carbon monoxide, hydrogen chloride, fluorination
Hydrogen, mercury and its compounds, cadmium and its compounds,
(arsenic, nickel and its compounds), lead and their combination
Matter, (锑, chrome, tin, copper, manganese and their combinations)
Object)
Dioxin class
Note 1. Exhaust gas monitoring shall be synchronized to monitor flue gas parameters in accordance with the corresponding monitoring and analysis methods and technical specifications.
Note 2. The monitoring indicators listed in the table, if the municipal and above environmental protection authorities in the district explicitly require the installation of automatic monitoring equipment, automatic monitoring shall be adopted.
Note 3. The pollutant monitoring indicators of the national pollutant monitoring method standards have not been released, and will be implemented after the national monitoring method standards are issued.
a This standard uses non-methane total hydrocarbons as a comprehensive control indicator for volatile organic matter emissions, and is subject to the emission standards for air pollutants from pesticide manufacturing industries.
After the cloth, it is prescribed from it.
b See the pollutants listed in GB 16297 and GB 14554, and determine the specifics according to the relevant environmental management regulations such as the environmental impact assessment document and its approval.
The monitoring indicators are subject to the provisions of the pesticide manufacturing industry after the release of air pollutant emission standards.
c Suitable for the production process of emitting sulfur dioxide.
d Suitable for the production process of nitrogen oxides.
e The principle of determining the characteristics of pollutants in the reference tank area of the reference tank area and the frequency of monitoring.
5.2.2 Unorganized exhaust emission monitoring points, indicators and frequency
The monitoring points, indicators and minimum monitoring frequency of unorganized exhaust emission are implemented according to Table 3.
Table 3 Unorganized exhaust emission monitoring points, indicators and minimum monitoring frequency
Frequency of monitoring monitoring indicators
Factory boundary particulate matter, odor concentration, volatile organic compounds a, characteristic pollutants b
HJ □□□-201□
a This standard uses non-methane total hydrocarbons as a comprehensive control indicator for volatile organic matter emissions, and is subject to the emission standards for air pollutants from pesticide manufacturing industries.
After the cloth, it is prescribed from it.
b See GB 16297, GB 14554 listed pollutants according to environmental impact assessment documents and their approvals and other relevant environmental management regulations, determine the specific
The monitoring indicators shall be stipulated after the release of the air pollutant discharge standards of the pesticide manufacturing industry.
5.3 Environmental noise monitoring at the boundary of the plant
The environmental noise monitoring point setting at the boundary should follow the principle in HJ 819, mainly considering the points of the noise source in the plant.
Cloth situation. Environmental noise at the boundary of the plant shall be monitored at least once a quarter, and units discharged at night shall be monitored at night.
noise. If there are sensitive points around, the frequency of monitoring should be increased.
Table 4 Main noise sources that should be concerned about the environmental noise distribution at the boundary of the plant
Noise source main equipment
Production workshop and supporting facilities
Reaction equipment, distillation equipment, distillation equipment, filtration equipment, separation equipment, drying equipment, heat exchange equipment, etc.
And air compressors, pumps, vacuum pumps, etc.
Sewage treatment aeration equipment, sludge dewatering equipment, fans, pumps, etc.
5.4 Surrounding environment quality impact monitoring
5.4.1 Environmental Management Policy or Emission Permit, etc. [Approved for Environmental Impact Assessment only after January 1,.2015 (inclusive)
If there is a specific requirement for the sewage disposal unit, it shall be implemented as required.
5.4.2 If there is no clear requirement, the pollutant discharge unit may supervise the surrounding surface water, seawater, groundwater and soil according to the actual situation.
Measurement. For sewage discharge units directly discharged into surface water and seawater, HJ/T 2.3, HJ/T 91, HJ 442 and receiving
The water environment management requires the setting of monitoring sections and monitoring points; the sewage disposal units that carry out groundwater and soil monitoring can be in accordance with HJ .
610, HJ/T 164, HJ/T 166 and groundwater and soil environmental management requirements set monitoring points. Monitoring indicators and minimum monitoring
The frequency is performed according to Table 5.
Table 5 Minimum monitoring frequency of surrounding environment quality impact monitoring indicators
Target environmental monitoring indicators monitoring frequency remarks
Surface water
pH, five-day biochemical oxygen demand, chemical oxygen demand, ammonia nitrogen, total nitrogen, total
Phosphorus, petroleum, cyanide, volatile phenol, sulfide, fluoride, zinc,
Mercury, cadmium, hexavalent chromium, arsenic, lead, etc.
Quarterly according to emission standards, row
Pollution permit and other related rings
Regulations,
Production process, original and auxiliary
Materials, intermediate and final production
Product (pesticide drug),
Identify specific monitoring fingers
seawater
pH, suspended matter, chemical oxygen demand, biochemical oxygen demand, petroleum,
Volatile phenol, cyanide, sulfide, zinc, mercury, cadmium, total chromium, hexavalent
Chromium, arsenic, lead, nickel, benzo (a) pyrene, etc.
Half a year
groundwater
pH, color (degrees), oxygen consumption, ammonia nitrogen, volatile phenols (with phenol),
Cyanide, fluoride, manganese, zinc, arsenic, mercury, lead, cadmium, hexavalent chromium,
Nickel, bismuth, etc.
Soil pH, mercury, cadmium, chromium, arsenic, lead, nickel, zinc, etc.
5.5 Other requirements
5.5.1 In addition to the pollutant indicators in Tables 1 to 3, the pollutant indicators in 5.5.1.1 and 5.5.1.2 should also be included in the monitoring indicators.
Range, and refer to Tables 1 to 3 and HJ 819 to determine the frequency of monitoring.
5.5.1.1 Drainage permit, pollutant discharge (control) standards implemented, environmental impact assessment documents and their approvals
The pollutant discharge unit approved by the environmental impact assessment after January 1,.2015 (including), and the relevant environmental management regulations
Seeking indicators of pollutants.
5.5.1.2 According to the raw materials and auxiliary materials used in the production process, the production process, the intermediate and final product types, and the monitoring results
Contaminant indicators in the relevant list of toxic, hazardous or preferentially controlled pollutants, or other toxic pollutants
index.
HJ □□□-201□
5.5.2 The frequency of monitoring of each indicator can be improved according to the principle of determining the frequency of monitoring in HJ 819 on the basis of meeting this standard.
Frequency of monitoring.
5.5.3 Sampling methods, monitoring and analysis methods, monitoring quality assurance and quality control shall be carried out in accordance with the relevant requirements of HJ 819.
5.5.4 The description and changes of the monitoring plan shall be implemented in accordance with HJ 819.
6 Information records and reports
6.1 Information Record
6.1.1 Monitoring information record
Manual monitoring records and automatic monitoring of operation and maintenance records are performed in accordance with HJ 819.
6.1.2 Record of operation status of production and pollution control facilities
The sewage disposal unit shall record the operation status of the production and pollution control facilities in detail, and the daily production shall also refer to the following contents.
Relevant information, and organized into a ledger for future reference.
6.1.2.1 Production Health Record
Record the following information for each production batch according to the type of pesticide product.
a) The amount of raw materials used mainly includes the amount of raw materials, the amount of catalyst used, the amount of various solvents, the amount of adsorbent, and others.
Amount of auxiliary materials, etc.;
b) intermediate and final product yield, yield and material balance;
c) fresh water intake, water consumption, electricity consumption, etc.;
d) Record of the operational use of the main production equipment and facilities used.
6.1.2.2 Wastewater treatment facility operation record
Record the amount of wastewater treatment, the amount of reuse, the rate of reuse, the direction of reuse, the amount of sludge, the amount of sludge produced (record moisture content),
The name and amount of the agent used in wastewater treatment, electricity consumption, etc.; record the operation, failure and maintenance of the wastewater treatment facility.
6.1.2.3 Exhaust gas treatment facility operation record
Record the name and amount of consumables such as adsorbents and filter materials used for exhaust gas treatment on a daily basis, and record the exhaust gas treatment facilities.
Line, fault and maintenance conditions.
6.1.2.4 Solvent recovery equipment operation record
Record the solvent name, recovery amount, replenishment amount, and solvent recovery equipment energy and consumables according to the production batch of each product.
Quantity and so on.
6.1.3 General industrial solid waste and hazardous waste information records
Record the amount of general industrial solid waste generated, comprehensive utilization, disposal amount and storage amount on a daily basis;
Relevant requirements for waste management, record the amount of hazardous waste generated, comprehensive utilization, disposal volume, storage capacity and specific
Going. The situation of raw materials or other hazardous wastes generated in the auxiliary process shall also be recorded. General industrial solid waste and hazardous waste
The production situation is shown in Table 6.
Table 6 General industrial solid waste and hazardous waste sources
HJ □□□-201□
Source of species
Hazardous Waste
Residues from the filtration of hexachlorocyclopentadiene in the production of chlordane; waste from the vacuum stripping of the chlorination reactor
Distillation residue from toluene recovery process in the production of acetonitrile
Residues produced by filtration of diethyldithiophosphoric acid during the production of phorate
Heavy fractions and distillation residues from the distillation of tetrachlorobenzene in the production of 2,4,5-trichlorophenoxyacetic acid
Residues containing 2,6-dichlorophenol produced during the production of 2,4-dichlorophenoxyacetic acid
Filtration, evaporation and centrifugation of residues and wastewater from vinyl bisdithiocarbamic acid and its salts
Treatment of sludge; collection of product grinding and packaging processes (dust removal and ground cleaning waste collected by dust removal equipment)
Waste water produced by reactors in the producti...
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