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GB 30770-2014: Emission standards of pollutants for stannum, antimony and mercury Industries
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Emission standards of pollutants for stannum, antimony and mercury Industries
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GB 30770-2014
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Basic data
| Standard ID | GB 30770-2014 (GB30770-2014) |
| Description (Translated English) | Emission standards of pollutants for stannum, antimony and mercury Industries |
| Sector / Industry | National Standard |
| Classification of Chinese Standard | Z60 |
| Classification of International Standard | 13.040.40 |
| Word Count Estimation | 15,175 |
| Date of Issue | 5/16/2014 |
| Date of Implementation | 7/1/2014 |
| Older Standard (superseded by this standard) | GB 8978-1996; GB 16297-1996; GB 9078-1996 |
| Quoted Standard | GB 6920; GB 7467; GB 7470; GB 7471; GB 7472; GB 7475; GB 7484; GB 7485; GB 11893; GB 11901; GB 11914; GB/T 15432; GB/T 16157; GB/T 16489; HJ/T 42; HJ/T 43; HJ/T 55; HJ/T 56; HJ/T 57; HJ/T 60; HJ/T 64.1; HJ/T 64.2; HJ/T 64.3; HJ/T 65; HJ/T 75; HJ/T 195; HJ |
| Regulation (derived from) | Ministry of Environmental Protection Notice No. 35 of 2014; National Standards Bulletin No. 11 of 2014 |
| Issuing agency(ies) | Ministry of Environmental Protection, General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China |
| Summary | This standard specifies the waters under the jurisdiction of the People's Republic of China classification and grading factors selection, technical methods, materials and finishing the investigation, the results of drawing preparation, report preparation, |
GB 30770-2014: Emission standards of pollutants for stannum, antimony and mercury Industries
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Emission standards of pollutants for stannum, antimony and mercury Industries
Tin, antimony, mercury, industrial pollutants emission standards
Emission standards of pollutants for stannum, antimony and mercury
Industries
(release
draft)
ICS
Hua Guoguo quasi-standard in the People's Republic of home
Issued on. 2014-05-16
2014-07-01 implementation
Ministry of Environmental Protection
State Quality Supervision, Inspection and Quarantine Bureau Governor total amount released home
Table of Contents
Preface .1
1 Scope .2
2 Normative references .2
3 Terms and definitions 4
4 ..5 pollutant emission control requirements
5 pollutant monitoring requirements ..10
6 implementation and supervision .12
Foreword
To implement the "People's Republic of China Environmental Protection Law", "People's Republic of China Water Pollution Prevention Law," "Great People's Republic of China
Air Pollution Prevention Law, "" People's Republic of China Marine Environmental Protection Law "and other laws, regulations and" Atmospheric Pollution Prevention Action Plan "(State
Fa [2013] No. 37), to protect the environment, prevent pollution, promote the progress of tin, antimony, mercury and industrial processes pollution control technology,
Development of this standard.
This standard specifies the tin, antimony, mercury mining and smelting industrial production process water pollutants and air pollutants emission limits, monitoring
Measurement and monitoring requirements of the regulations in key areas of water pollutants and air pollutants emission limits in particular.
This standard is the first release.
From the date of implementation of this standard, tin, antimony, mercury and industrial enterprises water and air pollutants implementation of this standard, no longer perform "Sewage
Integrated Discharge Standard "(GB 8978-1996)," Air Pollutant Emission Standards "(GB 16297-1996) and" industrial furnace atmosphere
Pollutant emission standards, "the relevant provisions (GB 9078-1996) in. Tin, antimony, mercury mining and smelting odor pollution emissions from industrial enterprises
Material, environmental noise applicable relevant national pollutant discharge standards, resulting in identification of solid waste treatment and disposal of solid waste applicable national
Pollution control standards.
This standard is tin, the basic requirements of antimony, mercury emission control of industrial pollutants. Local people's governments at the provincial level for this standard not provided
Pollutants may establish their local emission standards; this standard has been provided for projects pollutants may establish more stringent than the present standard
Quasi-local emission standards. Requires environmental impact assessment document stringent than this standard or local standards, should follow approval of the ring
Environmental impact assessment documentation requirements implemented.
This standard is developed by the Ministry of Environmental Protection Science, Technology organization.
This standard is mainly drafted by. Kunming University, Chinese Research Academy of Environmental Sciences, nonferrous metals, industrial pollution control engineering technology
Center, China Nerin Engineering Co., Ltd. (Nanchang Nonferrous Metallurgy Design and Research Institute).
This standard is approved by the Ministry of Environmental Protection April 28, 2014.
New business from July 1, 2014, implementation of the existing enterprise standards from January 1, 2015. It can also be based around local
Needs and economic and technical conditions for environmental protection, by the provincial government for approval early implementation of this standard.
The standard explanation by the Ministry of Environmental Protection.
Tin, antimony, mercury, industrial pollutants emission standards
1 Scope
This standard specifies the tin, antimony, mercury mining and smelting industrial enterprises of water and air pollutants emission limits, monitoring and control requirements,
As well as the relevant provisions of other standards implementation and supervision.
This standard applies to existing tin, antimony, mercury mining and smelting and pollutant emissions of atmospheric pollutants management of industrial enterprises water, and tin,
Environmental impact assessment antimony, mercury mining and smelting industry enterprises construction projects, environmental protection facilities design completion and acceptance of environmental protection
Water pollutants and atmospheric emissions of pollutants management after putting into operation.
This standard does not apply to tin, antimony, mercury and regeneration processing industry.
This standard applies to pollution discharge permitted by law. Established in the new location and sources of existing pollution sources in special protected areas
Management, according to "People's Republic of China Air Pollution Prevention Law," "People's Republic of China Water Pollution Prevention Law," "People's Republic of China
And the National Marine Environmental Protection Law "," People's Republic of China Solid Waste Pollution Prevention Law, "" People's Republic of China radioactive pollution
Transfection Prevention Law, "" People's Republic of China Environmental Impact Assessment Law "and other laws and relevant regulations, rules of execution.
This standard specifies water pollutant emission control requirements apply to enterprises discharge of water pollutants directly or indirectly, to its outside legal boundaries
behavior.
2 Normative references
This standard refers to the contents of the following documents or the terms.
Determination of the glass electrode method GB 6920 Water pH value
GB 7467 Water quality - Determination of hexavalent chromium diphenyl hydrazine spectrophotometry
Determination of GB 7470 Water quality dithizone spectrophotometry
GB 7471 Water quality - Determination of cadmium dithizone spectrophotometry
Determination of GB 7472 Water quality zinc dithizone spectrophotometry
GB 7475 water quality copper, zinc, lead, and cadmium - Atomic absorption spectrophotometry
GB 7484 Water quality - Determination of fluoride ion selective electrode method
Determination of total arsenic GB 7485 Water diethyl dithiocarbamate spectrophotometry silver
GB 11893 Determination of total phosphorus - Ammonium molybdate spectrophotometric method
GB 11901 Water quality Determination of suspended solids - Gravimetric method
GB 11914 Water quality Determination of chemical oxygen demand dichromate method
GB/T 15264 Ambient Air Determination of lead by flame atomic absorption spectrophotometry
Determination of GB/T 15432 Ambient Air Act by weight of total suspended particulates
GB/T 16157 Stationary source emission-Determination of particulates and gaseous pollutants sampling methods
GB/T 16489 Water quality Determination of sulfide - Methylene blue spectrophotometric method
Determination of UV HJ/T 42 Stationary source emission of nitrogen oxides spectrophotometry
HJ/T 43 Stationary source emission-Determination of nitrogen oxides hydrochloride naphthylethylenediamine spectrophotometry
HJ/T 55 fugitive emission monitoring of air pollutants Technical guidelines
HJ/T 56 stationary source emission measurement of sulfur dioxide Iodometry
Determination of HJ/T 57 stationary source emission of sulfur dioxide constant potential electrolysis
Determination of HJ/T 60 quality sulfides Iodimetry
Flame atomic HJ/T 64.1 atmosphere from stationary sources of cadmium absorption spectrophotometry
Graphite furnace atomic HJ/T 64.2 atmosphere from stationary sources of cadmium absorption spectrophotometry
HJ/T 64.3 Stationary source emission - Determination of cadmium - azobenzene aminoazobenzene acid spectrophotometry
Graphite furnace atomic HJ/T 65 atmosphere from stationary sources of tin absorption spectrophotometry
HJ/T 75 stationary sources Continuous Emission Monitoring Technical Specification (Trial)
HJ/T 195 Water quality - Determination of ammonia gas phase molecular absorption spectrometry
HJ/T 199 Determination of Water Quality Total Nitrogen gas phase molecular absorption spectrometry
HJ/T 397 stationary source emission monitoring and technical specifications
Determination of HJ/T 399 Water quality COD rapid digestion spectrophotometry
HJ 479 ambient air nitrogen oxides (NO and NO2) Determination of hydrochloric acid naphthylethylenediamine spectrophotometric
HJ 480 Ambient air - Determination of fluoride filter sampling and fluorine ion selective electrode method
HJ 481 Ambient air - Determination of fluoride lime - paper sampling and fluorine ion selective electrode method
HJ 482 Ambient air Determination of sulfur dioxide - Formaldehyde absorbing - pararosaniline spectrophotometry
Determination of mercury salts tetrachloride HJ 483 ambient air sulfur dioxide absorbing - pararosaniline spectrophotometry
Determination HJ 485 water quality copper diethyl dithiocarbamate spectrophotometry
HJ 487 Water quality Determination of fluoride - Visual colorimetry with zirconium alizarin sulfonic acid
Determination HJ 488 Water fluoride Fluor reagent spectrophotometry
HJ 535 Water quality - Determination of ammonia Nessler reagent spectrophotometric
HJ 536 Water quality - Determination of ammonia acid spectrophotometric method
HJ 537 Water quality - Determination of ammonia distillation - and titration
HJ 538 Stationary source emission of lead by flame atomic absorption spectrophotometry (provisional)
HJ 540 Determination of air and exhaust gases arsenic diethyl dithiocarbamate silver spectrophotometry (provisional)
Determination HJ 543 Stationary source emission of mercury by cold vapor atomic absorption spectrophotometry (provisional)
HJ 544 Stationary source emission of sulfuric acid mist by ion chromatography (provisional)
Determination of cold atoms HJ 597 water quality of total mercury absorption spectrophotometry
Determination of non-HJ 629 Stationary source emission of sulfur dioxide-dispersive infrared absorption method
HJ 636 Water quality Determination of total nitrogen - Alkaline potassium persulfate digestion - UV spectrophotometric method
HJ 637 water quality oil and animal and vegetable oils determination of the infrared spectrophotometry
HJ 657 air and exhaust particles measured by Inductively Coupled Plasma Mass Spectrometry lead metal element
HJ 694 water quality mercury, arsenic, selenium, bismuth and antimony Atomic Fluorescence Spectrometry
Inductively HJ 700 water quality 65 kinds of elements coupled plasma mass spectrometry
"Pollution automatic monitoring and management approach" (SEPA Order No. 28)
"Environmental Monitoring Management Measures" (SEPA Order No. 39)
3 Terms and Definitions
The following terms and definitions apply to this standard.
3.1 tin, antimony, mercury industrial stannum, antimony and mercury industries
Refers to the production of tin, antimony, mercury metals mining, dressing, smelting industrial enterprises, does not include scrap tin, antimony, mercury as raw material
Regeneration smelting industrial enterprises.
3.2 existing enterprises existing facility
Means of implementation of this standard has recently put into operation or environmental impact assessment document has passed the tin, antimony, mercury, industrial enterprises or facilities approved.
3.3 new enterprises new facility
It means the date of implementation of this standard environmental impact assessment document approved new construction, renovation and expansion of tin, antimony, mercury and industrial construction items
Head.
3.4 Public sewage system public wastewater treatment system
Refers to the collection of wastewater pollutant by pipelines, etc., to provide wastewater services to more than two units of sewage and drainage can be achieved with
Off emission standards enterprises or institutions, including all sizes and types of urban sewage treatment plants, regional (including all types of industrial parks,
Development zones and industrial gathering, etc.) waste water treatment plants, waste water treatment level it should reach two or more than two.
3.5 Direct emissions direct discharge
It refers to the emission units discharged directly to the environment of water pollutants behavior.
3.6 Indirect Emissions indirect discharge
Sewage discharge unit refers to a public sewage system water pollutants behavior.
3.7 displacement effluent volume
It refers to the amount of business to business or production facilities outside the legal boundaries of wastewater discharge, including direct or indirect relationship with the production of
Discharged waste (such as domestic sewage, cooling water, boiler plant and power plant drainage).
3.8 reference displacement unit product benchmark effluent volume per unit product
Tin production unit approved means for water pollutant discharge concentration prescribed limits on antimony, mercury displacement products.
3.9 exhaust exhaust volume
It refers to the amount of production facilities or enterprises exhaust emissions to the environment of the process exhaust gas.
3.10 per unit displacement reference benchmark exhaust volume per unit product
Tin production unit approved means for atmospheric pollutants emission concentration regulations, limits on antimony, mercury displacement products.
3.11 standard state standard condition
When the temperature is 273.15K, when the pressure of the state 101325Pa. Air pollutant emission concentration limits specified in this standard are marked
Dry gas quasi-state as a benchmark.
3.12 enterprise boundaries enterprise boundary
It refers to tin, antimony, mercury, industrial enterprises legal boundaries. If there is no legal boundary, it refers to the actual border business.
4 pollutant emission control requirements
4.1 water pollutant emission control requirements
4.1.1 is from January 1, 2015 until December 31, 2015, the implementation of existing enterprises specified in Table 1 water pollutant discharge limits.
Table 1 water pollutant discharge limits of existing enterprises
Unit. mg/L (pH value except)
Item No. pollutant limits
Direct emissions indirect emissions
Emissions monitoring location
1 pH value of 6 ~ 96 ~ 9
2 Chemical oxygen demand (CODCr) 100 200
3 TP 1.5 2.0
4 TN 2040
Ammonia 15 25 5
6 oil 510
100 (mining) 200 (mining)
7 suspension
70 (Other) 140 (Other)
Sulfide 1.0 1.5 8
Fluoride 9 10 15
10 0.5 Total copper
11 2.0 Total zinc
12 total tin 1) 4.0
13 1.0 Total Antimony
Enterprise total wastewater outfall
14 0.05 Total Mercury
15 0.1 Total cadmium
16 1.0 Total Lead
17 total arsenic 0.5
Hexavalent chromium 18 0.5
Plant or plant outfall
Dressing (m3/t ore) 1.65
2.52)
Tin, antimony smelting m3/t product 7.5
Unit production
Product reference
Displacement
Mercury smelting m3/t product 4
Displacement measuring position and pollutant emissions monitoring
Consistent position
Note. 1) as tin, antimony industrial wastewater monitoring project; 2) a multi-metal antimony ore.
4.1.2 Since January 1, 2016, the implementation of existing enterprises specified in Table 2 of water pollutant discharge limits.
4.1.3 Since July 1, 2014, implementation of new enterprises specified in Table 2 of water pollutant discharge limits.
Table 2 water pollutant discharge limits for new enterprises
Unit. mg/L (pH value except)
Item No. pollutant limits
Direct emissions indirect emissions
Emissions monitoring location
1 pH value of 6 ~ 96 ~ 9
2 Chemical oxygen demand (CODCr) 60 200
3 TP 1.0 2.0
4 TN 1540
5 Ammonia 825
6 oil 310
70 (mining) 200 (mining)
7 suspension
30 (Other) 140 (Other)
Sulfide 0.5 1.5 8
Fluoride 515 9
10 0.2 Total copper
11 1.0 Total zinc
12 total tin 1) 2.0
13 0.3 Total Antimony
Enterprise total wastewater outfall
14 total mercury 0.005
15 total cadmium 0.02
16 0.2 Total Lead
17 total arsenic 0.1
Hexavalent chromium 18 0.2
Plant or plant outfall
Dressing (m3/t ore) 1.4
2.02)
Tin, antimony smelting m3/t product 5.0
Unit product group
Quasi displacement
Mercury smelting m3/t product 2.0
Displacement measuring position and pollutant discharge
Put consistent monitoring location
Note. 1) as tin, antimony industrial wastewater monitoring project; 2) a multi-metal antimony ore.
4.1.4 according to the requirements of environmental protection work in the already high density land development, environmental carrying capacity began to weaken, or water environmental capacity
Small, fragile ecological environment, prone to severe water pollution problems need to take special measures to protect areas should be strictly controlled
Pollutant emission behavior of enterprises, enterprises in these areas to perform specified in Table 3 water pollutant discharge limits in particular.
Implementation of water pollutant discharge limits in particular geographical scope, timing, by the environmental protection department under the State Council or provincial government regulations
set.
Table 3 water pollutant discharge limits Special
Unit. mg/L (pH value except)
Item No. pollutant limits
Direct emissions indirect emissions
Emissions monitoring location
1 pH value of 6 ~ 96 ~ 9
2 Chemical oxygen demand (CODCr) 50 60
3 TP 0.5 1.0
4 TN 1015
5 Ammonia 58
6 oil 13
10 30 7 suspension
Enterprise total wastewater outfall
Sulfide 0.5 1.0 8
Fluoride 510 9
10 0.2 Total copper
11 1.0 Total zinc
12 total tin 1) 2.0
13 0.3 Total Antimony
14 total mercury 0.005
15 total cadmium 0.02
16 0.2 Total Lead
17 total arsenic 0.1
Hexavalent chromium 18 0.2
Plant or plant outfall
Dressing (m3/t ore) 1.0
1.52)
Tin, antimony smelting m3/t product 3.0
Products Unit
Reference drainage
Mercury smelting m3/t product 1.0
Displacement measuring position and pollutants
Emissions monitoring consistent position
Note. 1) as tin, antimony industrial wastewater monitoring project; 2) a multi-metal antimony ore.
4.1.5 water pollutant discharge concentration limits for the unit products, the actual situation is not higher than the reference displacement displacement. If the real unit of product
Inter displacement exceeds the reference displacement, shall formula (1) will be measured in terms of the concentration of water pollutant discharge standard water concentration, and water pollution
Standard water pollutants emission concentrations as determined whether the target emission basis. Product yield and displacement statistical period is one day.
In the company's production facilities produce two or more products, emission control requirements applicable to different countries or different industries discharge pollutants
Under the mixing of waste water treatment discharge emission standards, and the production facilities to produce and should implement the most stringent emission concentration limits specified in the standard
Value, according to equation (1) in terms of the concentration of water pollutant discharge standard water.
Group = C
QY
CN
× Σ
1 =
(1)
Where. C base - water pollutant discharge standard water concentration, mg/L;
Q total - Found drainage volume, m3;
Yi - a product yield, t;
Qi group - a product of the reference product unit displacement, m3/t;
C Real - measured water pollutant concentration, mg/t;
N - product (or ore) number of species.
If Q total and the ratio is less than 1, it places the water measured concentrations of pollutants in emissions as the basis for determining whether or not compliance.
4.2 air pollutant emission control requirements
4.2.1 is from January 1, 2015 until December 31, 2015, the implementation of existing enterprises specified in Table 4 of air pollutants emission limits.
ii QY
Table 4 air pollutant emission limits for existing enterprises
Unit. mg/m3
Name of pollutants and emission limits
produce
category
Process or
Step
Nitrogen oxides
Compound
Fluorinated
and
Compound
Part 1)
1)
And mercury
Of its
Compound 1)
Part 1)
Part 1)
Arsenic
Of its
Compound
1)
broken,
Screening - 120 - - - - - - - - - 1 mining
Others - 80 - - - - - - - - -
2 tin smelting All 75080--300688 8 0.015 0.05 0.5
3 antimony smelting All 75080--300--88 0.015 0.05 0.7
82)
0.5
4 mercury smelting All 750 80 - 300 - -. 8 0.015 - 0.7 -
5 sulfuric acid entire 9605045300688 0.015 0.5 0.05 0.05
Exhaust unit product reference
Volume (m3/tonne product) smelting 63000
Measuring position and displacement of pollutants
Emissions monitoring consistent position
Note. 1) metals and their compounds are calculated metal element; 2) to jamesonite raw materials for antimony smelting enterprises
4.2.2 Since January 1, 2016, the implementation of existing enterprises specified in Table 5 of the emissions of air pollutants concentration limits.
4.2.3 Since July 1, 2014, implementation of new enterprises specified in Table 5 of the emissions of air pollutants concentration limits.
Table 5 New business air pollutant emission concentration limits
Unit. mg/m3
Name of pollutants and emission limits
produce
category
Process or
Step
Part 1)
Part 1)
And mercury
Of its
Compound
1)
Part 1)
1)
Part 1)
Pollution
Material discharge
Prison release
Guard
broken,
Screening - 50 - - - - - - - - - 1 mining
Others - 30 - - - - - - - - -
2 tin smelting All 40030--200341 0.01 0.05 2 0.5
3 antimony smelting All 40030--200--14 0.01 0.05 0.5
twenty two)
0.5
4 mercury smelting All 400 30 - 200 - - 1 0.01 - 0.5 -
5 sulfuric acid entire 4003020200311 0.01 0.05 0.5 0.5
workshop
Or raw
Production set
Shi row
Inflator
Exhaust unit product reference
Volume (m3/tonne product) smelting 63000
Measuring position and displacement of pollutants
Emissions monitoring consistent position
Note. 1) metals and their compounds are calculated metal element; 2) to jamesonite raw materials for antimony smelting enterprises
4.2.4 according to the requirem...
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