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GB 30000.29-2013: Rules for classification and labelling of chemical -- Part 29: Hazardous to the ozone layer
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Basic data

Standard ID GB 30000.29-2013 (GB30000.29-2013)
Description (Translated English) Rules for classification and labelling of chemical -- Part 29: Hazardous to the ozone layer
Sector / Industry National Standard
Classification of Chinese Standard A80
Classification of International Standard 13.300
Word Count Estimation 17,194
Quoted Standard GB 13690; United Nations ' Globally Harmonized System of Classification and Labelling "(fourth revised edition); United Nations ' Recommendations on the Transport of Dangerous Goods Model Regulations " (seventeenth revised edition); international conventi
Regulation (derived from) National Standards Bulletin No. 20 of 2013
Issuing agency(ies) General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China
Summary This standard specifies: harm to the ozone layer has Chemicals terms and definitions, classification criteria, decision logic and labels. This standard applies to: damage to the ozone layer has according to the United Nations chemicals "Globally Harmonize

GB 30000.29-2013: Rules for classification and labelling of chemical -- Part 29: Hazardous to the ozone layer


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Rules for classification and labelling of chemical.Part 29. Hazardous to the ozone layer ICS 13.300 A80 National Standards of People's Republic of China Chemical classification and labeling specifications Part 29. harmful to the ozone layer Issued on. 2013-10-10 2014-11-01 implementation Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China Standardization Administration of China released

Foreword

Section 4 of this chapter, Chapter 6, are mandatory, the rest are recommended. GB 30000 "chemical classification and labeling norms," the expected structure and national standards will be replaced as follows. --- Part 1. General (instead of GB 13690-2009); --- Part 2. Explosives (instead of GB 20576-2006); --- Part 3. flammable gases (instead of GB 20577-2006); --- Part 4. Aerosol (instead of GB 20578-2006); --- Part 5. oxidizing gas (instead of GB 20579-2006); --- Part 6. pressurized gas (instead of GB 20580-2006); --- Part 7. flammable liquids (instead of GB 20581-2006); --- Part 8. Flammable solids (instead of GB 20582-2006); --- Part 9. Self-reactive substances and mixtures (instead of GB 20583-2006); --- Part 10. Pyrophoric liquids (instead of GB 20585-2006); --- Part 11. Spontaneous solid (instead of GB 20586-2006); --- Part 12. Self-heating substances and mixtures (instead of GB 20584-2006); --- Part 13. water, emit flammable gases and mixtures (instead of GB 20587-2006); --- Part 14. oxidizing liquid (instead of GB 20589-2006); --- Part 15. oxidizing solids (instead of GB 20590-2006); --- Part 16. Organic peroxide (instead of GB 20591-2006); --- Part 17. metallic corrosion products (instead of GB 20588-2006); --- Part 18. Acute toxicity (instead of GB 20592-2006); --- Section 19. Skin corrosion/irritation (instead of GB 20593-2006); --- Part 20. Serious eye damage/eye irritation (instead of GB 20594-2006); --- Part 21. respiratory or skin sensitization (instead of GB 20595-2006); --- Part 22. germ cell mutagenicity (instead of GB 20596-2006); --- Part 23. carcinogenic (instead of GB 20597-2006); --- Part 24. Reproductive toxicity (instead of GB 20598-2006); --- Part 25. Specific target organ toxicity - single exposure (instead of GB 20599-2006); --- Part 26. Specific target organ toxicity, repeated exposure (instead of GB 20601-2006); --- Part 27. Inhalation Hazard; --- Part 28. harmful to the aquatic environment (instead of GB 20602-2006); --- Part 29. harmful to the ozone layer; --- Part 30. Chemical workplace warning signs. This is Part 29 GB 30000's. This section drafted in accordance with GB/T 1.1-2009 given rules. This part of the United Nations' Globally Harmonized System of Classification and Labelling "(Globaly HarmonizedSystem of ClassificationandLabelingofChemicals, GHS) (fourth revised edition) about the technical content of the same. This part of the National Chemicals Management Standardization Technical Committee dangerous (SAC/TC251) and focal points. This section was drafted by. People's Republic of China Shandong Exit Inspection and Quarantine, the Ministry of Environmental Protection Chemical Registration Center, China Chemical Industry information Center. The main drafters of this section. Gengxiang Yang, Lu Ling, courtesy car east, rock wool, at dawn, Ge Haihong, saffron yellow, just reading, Barbara Feng, Lu Jian, Liang Jin. Chemical classification and labeling specifications Part 29. harmful to the ozone layer

1 Scope

This part of GB 30000 specifies the terms and definitions of the ozone layer have harmful chemicals, classification criteria, decision logic and labels. This section applies to chemicals hazardous to the ozone layer by having the United Nations' Globally Harmonized System of Classification and Labelling "(hereinafter referred to as GHS) of classification and labeling. This section does not apply to ODS containing hazardous equipment, goods and electrical appliances (such as refrigerators or air-conditioning equipment, etc.).

2 Normative references

The following documents for the application of this document is essential. For dated references, only the dated version suitable for use herein Member. For undated references, the latest edition (including any amendments) applies to this document. GB 13690 chemical classification and hazard communication General The United Nations' Globally Harmonized System of Classification and Labelling "(fourth revised edition) United Nations "on the Recommendations on the Transport of Dangerous Goods Model Regulations" (Seventeenth revised Edition) Parties to the International Convention "on Substances that Deplete the Montreal Protocol"

3 Terms and Definitions

GB 13690 and defined by the following terms and definitions apply to this document. 3.1 ODP ozonedepletingpotential; ODP The difference between the amount of a particular compound emissions relative to the same quality of trichlorofluoromethane, the entire ozone comprehensive disturbance ratio.

4 Classification Standard

Substances and mixtures classified as category 1 in Table 1. Table 1 division hazardous substances and mixtures standard for ozone Standard category Any controlled listed in the annex "on Ozone Depleting Substances Montreal Protocol" (hereinafter referred to as "the Montreal Protocol") Substance; or It is listed in Annex "Montreal Protocol" (see Appendix A) component of any mixture containing at least one concentration of not less than 0.1%

5 decision logic

Decision logic for reference only. Decision logic See Appendix B. Special Recommendations in the use of personnel responsible for classification and use of decision logic before Study Chapter 4.

6 Label

6.1 Overview 6.1.1 The label harm the ozone layer, hazard categories are specified pictograms, signal words and hazard statements the order listed. United Nations "On Recommendations on the Transport of Dangerous Goods Model Regulations" (hereinafter referred to as "Model Regulations") hazard class or category covers should be included in the label Out of each category specify the appropriate graphic signs. Harm the ozone layer assigned label elements are shown in Appendix C. 6.1.2 the hazards of ODS and mixtures classification criteria and labeling elements in Appendix D. 6.1.3 Requirements on the label information including hazard pictograms, signal words, hazard statements, precautionary statements, product identifiers and vendor logo. 6.2 hazard pictograms Hazard pictograms should use a black graphic symbol on a white background with a red frame sufficiently wide to be clearly visible. 6.3 Signal word Signal word means a label used to indicate the relative severity of the hazard and alert the reader to potentially dangerous words. Letter used in the GHS No word "Danger" and "Warning." Harm the ozone layer using only the signal word "Warning." 6.4 Hazard statement Hazard statement means assigned to a hazard class and category of the phrase used to describe the nature of the risk of a dangerous product, in the case when appropriate Also include the degree of danger. Harm the ozone layer hazard statements and precautionary statements and Table D.1 in Appendix E. 6.5 Precautionary statements Precautionary statement is a phrase (and/or pictogram) which describes minimize or prevent exposure to hazardous products or improper Storage or handling dangerous goods and adverse effects of recommended actions. To meet the requirements, there are five types of precautionary statements. general, prevention should be Anxious, storage and disposal. Harm the ozone layer Precautionary statements see Appendix E. 6.6 Product Identifier Product identifier should be used on the label 6.6.1 and product identifier should be used on the Material Safety Data Sheet is consistent. If a Substance or mixture included in the "Model Regulations", the United Nations should use the correct shipping name on the package. 6.6.2 The label should include the chemical name of the substance. The competent authorities may also request listed on the label could result in a dangerous mixture of all groups Chemical name points. 6.7 Supplier Identification The substance or mixture should be provided on the label the name of the manufacturer or supplier, address and telephone number. Example label 6.8 Example harm the ozone layer labels, see Appendix F.

Appendix A

(Normative) Accessories and provisions "Montreal Protocol" controlled substances Annex A A.1 "Montreal Protocol" in Table A.1. Annex A Table A.1 "Montreal Protocol" Category Code Substance Chemical Formula ozone-depleting potential (ODP value) a the first sort CFCl3 CFC-11 1.0 CF2Cl2 CFC-12 1.0 C2F3Cl3 CFC-113 0.8 C2F4Cl2 CFC-114 1.0 C2F5Cl CFC-115 0.6 The second category CF2BrCl halon-1211 3.0 CF3Br halon-1301 10.0 C2F4Br2 halon-2402 6.0 a The ODP is based on the estimated number of existing knowledge, which will be subject to periodic review and revision. Annex B A.2 "the Montreal Protocol" in Table A.2. Table A.2 in Annex B "Montreal Protocol" Category Code Substance Chemical Formula ozone-depleting potential (ODP value) a the first sort CF3Cl CFC-13 1.0 C2FCl5 CFC-111 1.0 C2F2Cl4 CFC-112 1.0 C3FCl7 CFC-211 1.0 C3F2Cl6 CFC-212 1.0 C3F3Cl5 CFC-213 1.0 C3F4Cl4 CFC-214 1.0 C3F5Cl3 CFC-215 1.0 C3F6Cl2 CFC-216 1.0 C3F7Cl CFC-217 1.0 The second category CCl4 CTC 1.1 The third category C2H3Cl3 1,1,1- trichloroethane b 0.1 a The ODP is based on the estimated number of existing knowledge, which will be subject to periodic review and revision. b Non-1,1,2-trichloroethane. A.3 Annex C "Montreal Protocol" in Table A.3. Table A.3 in Annex C "Montreal Protocol" Number of category codes isomer of formula substance ozone-depleting potential (ODP value) a the first sort CHFCl2 HCFC-214 1 0.04 CHF2Cl HCFC-224 1 0.055 CH2FCl HCFC-31 1 0.02 C2HFCl4 HCFC-121 2 0.01 ~ 0.04 C2HF2Cl3 HCFC-122 3 0.02 ~ 0.08 C2HF3Cl2 HCFC-123 3 0.02 ~ 0.06 CHCl2CF3 HCFC-1234 - 0.02 C2HF4Cl HCFC-124 2 0.02 ~ 0.04 CHFClCF3 HCFC-1244 - 0.022 C2H2FCl3 HCFC-131 3 0.007 ~ 0.05 C2H2F2Cl2 HCFC-132 4 0.008 ~ 0.05 C2H2F3Cl HCFC-133 3 0.02 ~ 0.06 C2H3FCl2 HCFC-141 3 0.005 ~ 0.07 CH3CFCl2 HCFC-141b4 - 0.11 C2H3F2Cl HCFC-142 3 0.008 ~ 0.07 CH3CF2Cl HCFC-142b4 - 0.065 C2H4FCl HCFC-151 2 0.003 ~ 0.005 C3HFCl6 HCFC-221 5 0.015 ~ 0.07 C3HF2Cl5 HCFC-222 9 0.01 ~ 0.09 C3HF3Cl4 HCFC-223 12 0.01 ~ 0.08 C3HF4Cl3 HCFC-224 12 0.01 ~ 0.09 C3HF5Cl2 HCFC-225 9 0.02 ~ 0.07 CF3CF2CHCl2 HCFC-225ca4 - 0.025 CF2ClCF2CHClF HCFC-225cb4 - 0.033 C3HF6Cl HCFC-226 5 0.02 ~ 0.10 C3H2FCl5 HCFC-231 9 0.05 ~ 0.09 C3H2F2Cl4 HCFC-232 16 0.008 ~ 0.10 C3H2F3Cl3 HCFC-233 18 0.007 ~ 0.23 C3H2F4Cl2 HCFC-234 16 0.01 ~ 0.28 C3H2F5Cl HCFC-235 9 0.03 ~ 0.52 C3H3FCl4 HCFC-241 12 0.004 ~ 0.09 C3H3F2Cl3 HCFC-242 18 0.005 ~ 0.13 C3H3F3Cl2 HCFC-243 18 0.007 ~ 0.12 Table A.3 (continued) Number of category codes isomer of formula substance ozone-depleting potential (ODP value) a the first sort C3H3F4Cl HCFC-244 12 0.009 ~ 0.14 C3H4FCl3 HCFC-251 12 0.001 ~ 0.01 C3H4F2Cl2 HCFC-252 16 0.005 ~ 0.04 C3H4F3Cl HCFC-253 12 0.003 ~ 0.03 C3H5FCl2 HCFC-261 9 0.002 ~ 0.02 C3H5F2Cl HCFC-262 9 0.002 ~ 0.02 C3H6FCl HCFC-271 5 0.001 ~ 0.03 The second category CHFBr2 1 1.00 CHF2Br HBFC-22B1 1 0.74 CH2FBr 1 0.73 C2HFBr4 2 0.3 ~ 0.8 C2HF2Br3 3 0.5 ~ 1.8 C2HF3Br2 3 0.4 ~ 1.6 C2HF4Br 2 0.7 ~ 1.2 C2H2FBr3 3 0.1 ~ 1.1 C2H2F2Br2 4 0.2 ~ 1.5 C2H2F3Br 3 0.7 ~ 1.6 C2H3FBr2 3 0.1 ~ 1.7 C2H3F2Br 3 0.2 ~ 1.1 C2H4FBr 2 0.07 ~ 0.1 C3HFBr6 5 0.3 ~ 1.5 C3HF2Br5 9 0.2 ~ 1.9 C3HF3Br4 12 0.3 ~ 1.8 C3HF4Br3 12 0.5 ~ 2.2 C3HF5Br2 9 0.9 ~ 2.0 C3HF6Br 5 0.7 ~ 3.3 C3H2FBr5 9 0.1 ~ 1.9 C3H2F2Br4 16 0.2 ~ 2.1 C3H2F3Br3 18 0.2 ~ 5.6 C3H2F4Br2 16 0.3 ~ 7.5 C3H2F5Br 8 0.9 ~ 1.4 C3H3FBr4 12 0.08 ~ 1.9 C3H3F2Br3 18 0.1 ~ 3.1 C3H3F3Br2 18 0.1 ~ 2.5 Table A.3 (continued) Number of category codes isomer of formula substance ozone-depleting potential (ODP value) a The second category C3H3F4Br 12 0.3 ~ 4.4 C3H4FBr3 12 0.03 ~ 0.3 C3H4F2Br2 16 0.1 ~ 1.0 C3H4F3Br 12 0.07 ~ 0.8 C3H5FBr2 9 0.04 ~ 0.4 C3H5F2Br 9 0.07 ~ 0.8 C3H6FBr 5 0.02 ~ 0.7 The third category CH2BrCl bromochloromethane 1 0.12 a The ODP is based on the estimated number of existing knowledge, which will be subject to periodic review and revision. A.4 Accessories "Montreal Protocol" E in Table A.4. Table A.4 Annex E "Montreal Protocol" Category Code Substance Chemical Formula ozone-depleting potential (ODP value) a The first CH3Br a methyl bromide 0.7 a The ODP is based on the estimated number of existing knowledge, which will be subject to periodic review and revision.

Appendix B

(Informative) Decision logic harm the ozone layer Harm the ozone layer determination logic shown in Figure B.1. Figure B.1 Decision logic hazard of ozone-depleting substances and mixtures

Appendix C

(Normative) Harm the ozone layer distribution of label elements Harm the ozone layer label elements allocated in Table C.1. Table C.1 harm the ozone layer distribution of label elements Category 1 - - - - caveat Destroyed in the upper atmosphere Ozone, endangering public Health and the environment United Nations "on the Recommendations on the Transport of Dangerous Goods Model Regulations" is not a requirement.

Appendix D

(Normative) Harm the ozone layer classification criteria and labeling elements Harm the ozone layer classification criteria and labeling elements in Table D.1. Table D.1 hazard classification criteria and labeling elements of the ozone layer Hazard category Criteria label elements 1. Substances Any of the annex, "the Montreal Protocol" is listed Controlled substances; 2. mixture Any mixture containing at least one kind of concentration of not less than 0.1% are listed in Annex "Montreal Protocol" Constituent Graphical symbols Signal word Warning Hazard statement Destruction of ozone in the upper atmosphere, Endangering public health and the environment

Appendix E

(Informative) Harm the ozone layer, hazard statements and precautionary statements E.1 Overview E.1.1 This Appendix harm the ozone layer having chemicals consistent with how to use the GHS hazard statements and precautionary statements provide guidance column Recommendations hazard statements and precautionary statements for each hazard category having harmful to the ozone layer of chemicals, see GB 13690. E.1.2 Hazard statement code. Coding E.1.2.1 hazard statements see GHS Annex 3. E.1.2.2 Each Hazard statements are assigned a unique alphanumerical code which consists of one letter and three numbers, specific as follows. a) letter "H" (for "hazard statement"); b) the first number, part number represents a different risk of setting dangerous within the meaning of the type described, as follows. --- "2" for physical hazards; --- "3" for health hazards; --- "4" on behalf of environmental hazards; c) After two numbers, the sequence number corresponding to the dangerous substance or mixture caused by intrinsic properties, such as. the explosive (code 200 to 210), flammability (codes 220-230), and the like. E.1.2.3 Unless otherwise specified, all designated hazardous descriptions should appear on the label. The competent authorities may require the hazard statements on the label In order of appearance. In addition, the combination of two or dangerous when the instructions provided above hazard statements, the competent authorities may specify, whether the group Combined hazard statement or the corresponding individual instructions written to the tag, or/supplier discretion of the manufacturer. E.1.3 together with the precautionary statements should be uniform hazard communication elements (pictograms, signal words and hazard statements) together meet the requirements of the standard label on. Additional supplemental information, such as instructions for use, may also be added at the discretion of the manufacturer/supplier and/or competent authorities. E.1.3.1 GHS precautionary statements coded see Annex 3. E.1.3.2 precautionary statements Code. E.1.3.2.1 each of the precautionary statements are assigned a unique alphanumerical code which consists of one letter and three numbers, specific as follows. a) the letter "P" (for "precautionary statement"); b) Types of a number representing the precautionary statements, as follows. --- "1" for general precautionary statements; --- "2" for prevention precautionary statements; --- "3" represents emergency precautionary statements; --- "4" for storage precautionary statements; --- "5" for disposal precautionary statements; c) After the two numbers (corresponding to the sequence number of the precautionary statements). E.1.3.2.2 precautionary statement code as a reference. Precautionary statement code is not part of the precautionary statements provisions not be used to replace the provisions of precautionary statements. E.2 General precautionary statements Which are classified as hazardous to human health or the environment of all substances and mixtures should take common sense precautions. The following general precautionary statements under the given conditions applicable GHS label (see Table E.1). Table E.1 General precautionary statements Object supplementary information coding for general precautionary statements The general public label, supplemental label information P101 If medical attention. Please bring the product container or label P102 Children are not in contact Read the label before use P103 Production workers Label, supplemental label information security technology Brochures, signs in the workplace E.3 precautionary statements harm the ozone layer Prevention of harmful ozone-depleting substances are listed in Table E.2. Table E.2 harm the ozone layer, precautionary statements Graphical symbols Exclamation Hazard Category Signal Word Hazard Statement 1 Warning H420 destroy ozone in the upper atmosphere, endangering public health and the environment Precautionary statements Prevention Emergency Storage Disposal P502 About recycling and recycling information, please consult the manufacturer/supplier

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