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GB 30000.27-2013: Rules for classification and labelling of chemicals -- Part 27: Aspiration hazard
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Rules for classification and labelling of chemicals -- Part 27: Aspiration hazard
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Basic data
| Standard ID | GB 30000.27-2013 (GB30000.27-2013) |
| Description (Translated English) | Rules for classification and labelling of chemicals -- Part 27: Aspiration hazard |
| Sector / Industry | National Standard |
| Classification of Chinese Standard | A80 |
| Classification of International Standard | 13.300 |
| Word Count Estimation | 16,181 |
| Quoted Standard | GB 13690; United Nations ' Globally Harmonized System of Classification and Labelling "(GHS) (fourth revised edition); United Nations ' Recommendations on the Transport of Dangerous Goods Model Regulations " (Seventeenth Revised Edition) |
| Regulation (derived from) | National Standards Bulletin No. 20 of 2013 |
| Issuing agency(ies) | General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China |
| Summary | This standard specifies: a inhalation hazard Chemicals terms and definitions, classification criteria, decision logic and labels. This standard applies to: a inhalation hazard chemical by the United Nations ��Globally Harmonized System of Classification an |
GB 30000.27-2013: Rules for classification and labelling of chemicals -- Part 27: Aspiration hazard
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Rules for classificatioin and labelling of chemicals.Part 27. Aspiration hazard
ICS 13.300
A80
National Standards of People's Republic of China
Chemical classification and labeling specifications
Part 27. Inhalation Hazard
Part 27. Aspirationhazard
Issued on. 2013-10-10
2014-11-01 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Foreword
Section 4 of this chapter and Chapter 6 are mandatory, the rest are recommended.
GB 30000 "chemical classification and labeling norms," the expected structure and national standards will be replaced as follows.
--- Part 1. General (instead of GB 13690-2009);
--- Part 2. Explosives (instead of GB 20576-2006);
--- Part 3. flammable gases (instead of GB 20577-2006);
--- Part 4. Aerosol (instead of GB 20578-2006);
--- Part 5. oxidizing gas (instead of GB 20579-2006);
--- Part 6. pressurized gas (instead of GB 20580-2006);
--- Part 7. flammable liquids (instead of GB 20581-2006);
--- Part 8. Flammable solids (instead of GB 20582-2006);
--- Part 9. Self-reactive substances and mixtures (instead of GB 20583-2006);
--- Part 10. Pyrophoric liquids (instead of GB 20585-2006);
--- Part 11. Spontaneous solid (instead of GB 20586-2006);
--- Part 12. Self-heating substances and mixtures (instead of GB 20584-2006);
--- Part 13. water, emit flammable gases and mixtures (instead of GB 20587-2006);
--- Part 14. oxidizing liquid (instead of GB 20589-2006);
--- Part 15. oxidizing solids (instead of GB 20590-2006);
--- Part 16. Organic peroxide (instead of GB 20591-2006);
--- Part 17. metallic corrosion products (instead of GB 20588-2006);
--- Part 18. Acute toxicity (instead of GB 20592-2006);
--- Section 19. Skin corrosion/irritation (instead of GB 20593-2006);
--- Part 20. Serious eye damage/eye irritation (instead of GB 20594-2006);
--- Part 21. respiratory or skin sensitization (instead of GB 20595-2006);
--- Part 22. germ cell mutagenicity (instead of GB 20596-2006);
--- Part 23. carcinogenic (instead of GB 20597-2006);
--- Part 24. Reproductive toxicity (instead of GB 20598-2006);
--- Part 25. Specific target organ toxicity - single exposure (instead of GB 20599-2006);
--- Part 26. Specific target organ toxicity, repeated exposure (instead of GB 20601-2006);
--- Part 27. Inhalation Hazard;
--- Part 28. harmful to the aquatic environment (instead of GB 20602-2006);
--- Part 29. harmful to the ozone layer;
--- Part 30. Chemical workplace warning signs.
This section of Part 27 GB 30000.
This section drafted in accordance with GB/T 1.1-2009 given rules.
This part of the United Nations' Globally Harmonized System of Classification and Labelling "(Globaly HarmonizedSystem of
ClassificationandLabelingofChemicals, GHS) (fourth revised edition) about the technical content of the same.
This part of the National Chemicals Management Standardization Technical Committee dangerous (SAC/TC251) and focal points.
This section was drafted by. People's Republic of China Shandong Exit Inspection and Quarantine, China Center for Disease Control and Prevention, Occupational Health and Poison
Control.
The main drafters of this section. Zhang Shao Yan, saffron yellow, Lin Zheng, Geng Xiangyang, SONG Zhen dry, courtesy car East, Wan Min, Ai Wei Wu.
Chemical classification and labeling specifications
Part 27. Inhalation Hazard
1 Scope
This part of GB 30000 specifies the terms and definitions have inhaled harmful chemicals, classification criteria, decision logic and labels.
This section applies to an aspiration hazard chemicals under the United Nations' Globally Harmonized System of Classification and Labelling "(hereinafter referred to as
GHS) of classification and labeling.
2 Normative references
The following documents for the application of this document is essential. For dated references, only the dated version suitable for use herein
Member. For undated references, the latest edition (including any amendments) applies to this document.
GB 13690 chemical classification and hazard communication General
The United Nations' Globally Harmonized System of Classification and Labeling "(GHS) (fourth revised edition)
United Nations "on the Recommendations on the Transport of Dangerous Goods Model Regulations" (Seventeenth revised Edition)
3 Terms and Definitions
GB 13690 and defined by the following terms and definitions apply to this document.
3.1
Suction aspiration
Especially liquid or solid chemical product directly through the oral or nasal cavity, or indirectly from vomiting, enter into the trachea and lower respiratory system.
4 Classification Standard
4.1 General principles inhalation hazard classification and labeling
General principles inhalation hazard classification and labeling see GB 13690.
4.2 Considerations
Aspiration hazard general and specific precautions in Appendix A.
4.3 Classification criteria for substances
Inhalation toxicity hazard categories in Table 1.
Table 1 aspiration toxicity hazard categories
Standard category
Category 1.
It is known to cause human aspiration toxicity hazard chemicals
Product or be regarded as if they cause human aspiration toxicity
Hazardous chemicals
Substance is assigned to Category 1.
a) According to reliable high-quality human evidence a; or
b) if it is a hydrocarbon and measured at 40 ℃ kinematic viscosity of not more than 20.5mm2/s
Table 1 (continued)
Standard category
Category 2.
Because they are assumed to cause human inhalation toxicity risk
Risk and worrying chemicals
According to the existing animal studies and expert taking into account surface tension, water solubility, boiling point, and volatility make
The judge, at 40 ℃ measured kinematic viscosity is not greater than 14mm2/s substance is classified in Category 1
Substance except b
Examples of substances classified as a Category 1 are certain hydrocarbons, turpentine and pine oil.
b Under these conditions, some authorities would consider the following to be included in this category. at least three but no more than 13 carbon atoms are primary
Alcohol, isobutyl alcohol, and ketones have no more than 13 carbon atoms.
4.4 Classification criteria for mixtures
4.4.1 master mixture Classification of mixtures when data
The mixture was based on reliable and good quality human evidence classified category 1.
4.4.2 not grasp mixture Classification of mixtures when data are. bridging principles
4.4.2.1 If the mixture itself has not been tested to determine its inhalation toxicity testing, but individual components of the mixture and the test has been done
Similarly mixture have mastered sufficient data to adequately characterize the hazards of the mixture, then make the following agreed bridging principles
With these data. This ensures that the classification process to maximize the use of existing data to determine the hazardous properties of the mixture without the necessity for animal feed
Row additional testing.
4.4.2.2 Dilution
If the test was done with a diluent that does not have the risk of inhalation toxicity, and does not affect the other components of the diluent or
Inhalation toxicity of the mixture, then the new diluted mixture may be classified as the original tested mixtures to the same category. However, inhalation toxicity
Concentration of the substance should not drop below 10%.
4.4.2.3 Batches
The mixture has been done a production test batch of inhalation toxicity, it is considered virtually the same manufacturer, or in its control
Another commercial product manufactured under the same test without the toxicity of the same production batch, unless there is reason believe that the untested product batches
Toxicity times have changed significantly. If the latter occurs, a new classification is required.
4.4.2.4 Category 1 mixture of concentration
If, after testing of the mixture is classified in Category 1, and the mixture Category 1 component concentration is increased, the mixture belongs to the new generation
It should be classified as Category 1, no need to do another test.
Interpolation within one toxicity category 4.4.2.5 within range
Three components identical mixture (A, B and C), mixtures A and B tested, mixing of the same toxicity category and
C was not tested, but contain mixtures A and B are the same toxicology of the active ingredient, but the concentration of the active ingredient referred toxicology
Between concentrations in mixtures A and B, it can assume a mixture of C and A and B are in the same toxicity category.
4.4.2.6 substantially similar mixtures
Assume the following situation.
a) two mixtures.
1) AB;
2) CB.
b) the concentration of component B is the same in both mixtures.
c) a concentration of the mixture) in a mixture of equal concentrations of component A 2) in the component C.
d) Aspiration toxicity for A and C is substantially equivalent, ie they are in the same hazard category and are not expected to affect the toxicity of B; if
If a mixture of 1) or 2) have been based on the criteria in Table 1 classification, then the other mixture can be assigned the same hazard category.
4.4.3 All components of the mixture to master data or only some components of the mixture when data classification
4.4.3.1 Category 1
Movement 4.4.3.1.1 mixture which contains a total of not less than 10% is classified as a Category 1 or more components, and measured at 40 ℃ of
Viscosity of not more than 20.5mm2/s, will be classified as Category 1.
4.4.3.1.2 If the mixture separates into two or more layers, one of which contains not less than 10% is classified as a Category 1 or several groups of
Points, and measured at 40 ℃ kinematic viscosity of not more than 20.5mm2/s, then the entire mixture is classified as Category 1.
4.4.3.2 Category 2
Movement 4.4.3.2.1 mixture which contains a total of not less than 10% is classified as a Category 2 or more components, and measured at 40 ℃ of
Viscosity is not greater than 14mm2/s, it will be classified as Category 2.
Analyzing 4.4.3.2.2 When the mixture as this category, according to experts in the use of surface tension, water solubility, boiling point, and volatility made
It is extremely important, especially in the category 2 substance mixed with water situation.
4.4.3.2.3 If the mixture separates into two or more layers, one of which contains not less than 10% is classified as one or more of the group Category 2
Points and at 40 ℃ measured kinematic viscosity is not greater than 14mm2/s, then the entire mixture is classified as Category 2.
5 decision logic
Decision logic for reference only. Decision logic See Appendix B. Special Recommendations headquarters staff responsible for classification study in the use of decision logic
Chapter 4 points.
6 Label
6.1 Overview
6.1.1 For inhalation hazard labels hazard categories are specified in the order pictograms, signal words and hazard statements are listed. UN "Off
Hazard class or category in Recommendations on the Transport of Dangerous Goods Model Regulations "(Seventeenth revised Edition) (hereinafter referred to as" Model Regulations ") covered
It should be listed for each category specify the corresponding graphic logo in the label. Inhalation Hazard label allocation feature, see Appendix C.
6.1.2 Classification and labeling related to inhalation hazards, see Appendix D.
6.1.3 For yet other standardized label elements, such as the need to include precautionary statements on the label. Administrations may also request
Additional information provider may also add supplementary information. Information required on the label including hazard pictograms, signal words, hazard statements, precautionary statements
Ming, the product identifier and supplier identification and so on.
6.2 hazard pictograms
Hazard pictograms should use a black graphic symbol on a white background with a red frame sufficiently wide to be clearly visible.
6.3 Signal word
Signal word means a label used to indicate the relative severity of the hazard and alert the reader to potentially dangerous words. For inhalation hazard class
1 Do not use the signal word "Danger." For inhalation hazard category 2 use the signal word "Warning."
6.4 Hazard statement
Hazard statement means assigned to a hazard class and category of the phrase used to describe the nature of the risk of a dangerous product, in the case when appropriate
Also include the degree of danger. Risk of inhalation toxicity and are listed in Table D.1 in Appendix E.
6.5 Precautionary statements
Precautionary statement is a phrase (and/or pictogram) which describes minimize or prevent exposure to hazardous products or improper
Storage or handling dangerous goods and adverse effects of recommended actions. In order to meet the requirements, there are five types of precautionary statements. general, prevention should be
Anxious, storage and disposal. Aspiration hazard precautionary statements, see Appendix E.
6.6 Product Identifier
Product identifier should be used on the label 6.6.1 and product identifier should be used on the Material Safety Data Sheet is consistent. If a
Substance or mixture included in the "Model Regulations", the United Nations should use the correct shipping name on the package.
6.6.2 The label should include the chemical name of the substance. Administrations may require listed on the label could result in a mixture or alloy dangerous
Chemical names of all components or alloying elements.
6.7 Supplier Identification
The substance or mixture should be provided on the label the name of the manufacturer or supplier, address and telephone number.
Example label 6.8
Examples inhalation hazard labels see Appendix F.
Appendix A
(Normative)
Aspiration hazard general and specific considerations
A.1 General Considerations
A.1.1 purpose of this section is to provide a substance or mixture classifications, and mixtures of these substances may be inhaled to humanity
Dangerous toxicity.
A.1.2 inhalation toxicity including severe acute effects such as chemical pneumonia, varying degrees of pulmonary injury and death inhalation and the like.
A.1.3 Aspiration is initiated at the moment of inspiration, in the time required to breath, causing material lodges in the throat of the call
And upper gastrointestinal tract when the junction.
A.1.4 inhaled substances and mixtures may occur after swallowing vomit. This may have consequences for labeling, particularly due to acute toxicity, possible
We need to consider the recommendations after swallowing induce vomiting. However, if the substance and mixture also presents an aspiration toxicity hazard recommendation to induce vomiting may need
Should be modified.
A.2 Specific considerations
A.2.1 review of the medical literature on chemical aspiration revealed that some hydrocarbons (petroleum distillates) and certain chlorinated hydrocarbons have been shown to
Humans have an inhalation hazard. Primary alcohols and ketones inhalation hazard presented only in animal studies.
A.2.2 While the method of determining animal inhalation hazard methods already in use, but has not been standardized. The positive results from animal tests of evidence, only
There may be used as an inhalation hazard human guidance. In assessing animal inhalation toxicity data should be cautious.
A.2.3 classification criteria refer to kinematic viscosity as a reference. Formula (A.1) for power conversion between viscosity and kinematic viscosity.
Dynamic viscosity/(mPa · s)
Density/(g/cm3) =
Kinematic viscosity/(mm2/s) (A.1)
A.2.4 While the 3.1 definition of "suction" include solids into the respiratory system, but according to Table 1 b) of Category 1 or Category 2 points made
Class, will only apply to liquid substances and mixtures.
A.2.5 aerosol and aerosol products are usually distributed in sealed containers, trigger and pump sprayers and other containers. These products are classified
The key is whether there is a mass of liquid formed in the nozzle, and then may be aspirated. If the mist or aerosol from a sealed container products are fine,
It may not be a mass of liquid forms. On the other hand, if the closed container dispenses product in a stream, then there may be a mass of liquid
Formed is then sucked out. In general, trigger and pump sprayers is coarse smoke, so there may be formed that then
After being sucked out. If the button type device may be removed and contents are likely to be swallowed, then the product should be classified.
Appendix B
(Informative)
Inhalation Hazard decision logic
Figure B.1 and B.2 were given an inhalation hazard decision logic.
Figure B.1 inhalation hazard determination logic
Figure B.2 use decision logic component inhalation hazard
Appendix C
(Normative)
Aspiration hazard label elements configuration table
Table C.1 gives an inhalation hazard label elements configuration.
Table C.1 inhalation hazard label elements configuration table
Category 1 Category 2 - - -
Danger
Swallowed and enters airways
May be fatal
caveat
Swallowed and enters airways
May be harmful
"About Recommendations on the Transport of Dangerous Goods Model Regulations" is not a requirement.
Appendix D
(Normative)
Aspiration hazard classification and labeling
Table D.1 lists the inhalation hazard classification and labeling.
Table D.1 inhalation hazard classification and labeling
Hazard category Criteria Hazard communication elements
1. For substances and tested mixtures to.
a) obtained from practical experience, reliable and good quality human evidence that humans have
Inhalation toxicity including chemical pneumonia, varying degrees of pulmonary injury or suck
Into deadly;
b) measured at 40 ℃ kinematic viscosity of not more than 20.5mm2/s hydrocarbons.
2. If you do not have a whole mixture of data, use bridging principles (see 4.4.2).
3. If bridging principles do not apply, the mixture was classified as Category 1 in the following cases.
a) contains at least one ingredient has been classified as a Category 1, the concentration of not less than 10% in
40 ℃ measured kinematic viscosity is not greater than 20.5mm2/s; or
b) separated into a mixture of two or more layers, such as at least one layer contains one is classified
Component, the concentration of category 1 is not less than 10%, measured at 40 ℃ kinematic viscosity
Not more than 20.5mm2/s
Graphical symbols
Signal word Danger
Hazard statement
Swallowing and enter
Respiratory
May be fatal
1. For substances and tested mixtures to.
In addition to substances and mixtures classified as category 1, but based on animal studies and expert judgment that the
If they cause human aspiration toxicity of substances and mixtures, measured at 40 ℃ kinematic viscosity
Not more than 14mm2/s.
2. If you do not have a whole mixture of data, use bridging principles (see 4.4.2).
3. If bridging principles do not apply, the mixture was classified as Category 2 under the following conditions.
a) contains at least one ingredient classified in Category 2 at a concentration of not less than 10% in
40 ℃ kinematic viscosity measured no more than 14mm2/s; or
b) separated into a mixture of two or more layers, such as at least one layer contains one classified as category
2 component concentration of not less than 10%, measured at 40 ℃ kinematic viscosity less
To 14mm2/s
Graphical symbols
Signal word Warning
Hazard statement
Swallowing and enter
Respiratory
May be harmful
Appendix E
(Informative)
Inhalation Hazard hazard statements and precautionary statements
E.1 Overview
E.1.1 This appendix is an inhalation hazard chemicals have about how to use the line with GHS hazard statements and precautionary statements provide guidance with listed
There for each hazard class and hazard category inhalation hazard chemicals recommended precautionary statements, see GB 13690.
E.1.2 Hazard statement code.
Coding E.1.2.1 hazard statements see GHS Annex 3.
E.1.2.2 Each Hazard statements are assigned a unique alphanumerical code which consists of one letter and three numbers, specific
as follows.
a) letter "H" (for "hazard statement").
b) the first number, part number represents a different risk of setting dangerous within the meaning of the type described, as follows.
--- "2" for physical hazards;
--- "3" for health hazards;
--- "4" for environmental hazards.
c) After two numbers, the sequence number corresponding to the dangerous substance or mixture caused by intrinsic properties, such as. the explosive (code 200 to
210), flammability (codes 220-230), and the like.
E.1.2.3 Unless otherwise specified, all designated hazardous descriptions should appear on the label. The competent authorities may require the hazard statements on the label
In order of appearance. In addition, the combination of two or dangerous when the instructions provided above hazard statements, the competent authorities may specify, whether the group
Combined hazard statement or the corresponding individual instructions written to the tag, or/supplier discretion of the manufacturer.
E.1.3 together with the precautionary statements should be uniform hazard communication elements (pictograms, signal words and hazard statements) together meet the requirements of the standard label
on. Additional supplemental information, such as instructions for use, may also be added at the discretion of the manufacturer/supplier and/or competent authorities.
E.1.3.1 GHS precautionary statements coded see Annex 3.
Coding E.1.3.2 precautionary statements
E.1.3.2.1 each of the precautionary statements are assigned a unique alphanumerical code which consists of one letter and three numbers, specific
as follows.
a) the letter "P" (for "precautionary statement").
b) Types of a number representing the precautionary statements, as follows.
--- "1" for general precautionary statements;
--- "2" for prevention precautionary statements;
--- "3" represents emergency precautionary statements;
--- "4" for storage precautionary statements;
--- "5" for disposal precautionary statements.
c) After the two numbers (corresponding to the sequence number of the precautionary statements).
E.1.3.2.2 precautionary statement code as a reference. Precautionary statement code is not part of the precautionary statements provisions not be used to replace Prevention
Description provision.
E.2 General precautionary statements
Which are classified as hazardous to human health or the environment of all substances and mixtures should take common sense precautions. The following general precautionary statements giving
Under the given conditions applicable to GHS label (see Table E.1).
Table E.1 General precautionary statements
Object supplementary information coding for general precautionary statements
The general public label, supplemental label information
P101 If medical attention. Please bring the product container or label
P102 Children are not in contact
Read the label before use P103
Production workers
Label, supplemental label information security technology
Brochures, signs in the workplace
E.3 inhalation toxicity hazard statements
Inhalation toxicity hazard statements include.
--- H304 May be fatal if swallowed and enters airways;
--- H305 May be harmful if swallowed and enters airways.
E.4 inhalation hazard precautionary statements
Aspiration hazard precautionary statements Table E.2.
Table E.2 inhalation hazard precautionary statements
Graphical symbols
Health Hazards
Hazard Category Signal Word Hazard Statement
1 Danger H304 May be fatal if swallowed and enters airways
2 Warning H305 May be harmful if swallowed and enters airways
Precautionary statements
Prevention Emergency Storage Disposal
P301 P310
IF SWALLOWED. Immediately call a POISO N CENTER or doctor/physician /
Manufacturer/supplier or the competent authority to specify the appropriate emergency agency rash/staff.
P331
Do NOT induce vomiting
P405
Store locked
P501
Dispose of contents/container in accordance with local/regional/national/international regulations (to be specified)
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