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Emission standard of pollutants for rubber products industry
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GB 27632-2011
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Basic data | Standard ID | GB 27632-2011 (GB27632-2011) | | Description (Translated English) | Emission standard of pollutants for rubber products industry | | Sector / Industry | National Standard | | Classification of Chinese Standard | Z60 | | Classification of International Standard | 13.030.99 | | Word Count Estimation | 12,132 | | Date of Issue | 2011-10-27 | | Date of Implementation | 2012-01-01 | | Quoted Standard | GB/T 6920-1986; GB/T 7472-1987; GB/T 7475-1987; GB/T 11893-1989; GB/T 11894-1989; GB/T 11901-1989; GB/T 11914-1989; GB 14554-1993; GB/T 15432-1995; GB/T 16488-1996; HJ/T 38-1999; HJ/T 55-2000; HJ/T 195-2005; HJ/T 199-2005; HJ/T 397-2007; HJ/T 399-2007; HJ 505-2009; HJ 533-2009; HJ 535-2009; HJ 536-2009; HJ 537-2009; HJ 583-2010; HJ 584-2010; pollution automatic monitoring management approach State Environmental Protection Administration Order No. 28; environmental monitoring management approach SEPA Order No. 39 | | Regulation (derived from) | Department of Environmental Protection Notice No. 79 of 2011 | | Issuing agency(ies) | Ministry of Environmental Protection, General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China | | Summary | This Chinese standard specifies the rubber products industry enterprises or production facilities of water pollutants and atmospheric pollutants emission limits, surveillance and monitoring requirements, and standards implementation and supervision of relevant regulations. This standard applies to existing rubber products manufacturing enterprises or production facilities of water pollutants and air pollutant emissions management, and rubber products industry enterprises to build the project's environmental impact assessment, environmental protection, facility design, completion and commissioning of environmental acceptance water pollutants and atmospheric pollutants emission management. This standard applies to legally permissible emission behavior. The location and the newly established sources of existing pollution sources in special protected areas management, according to"The People's Republic of China Air Pollution Prevention Law", "PRC Water Pollution Prevention Law, "Marine Environmental Protection Law, "China people's Republic of solid Waste Pollution prevention Law", "PRC environmental Impact Assessment Law"and other laws, regulations and rules of the relevant regulations. This standard specifies a water pollutant emission control requirements apply to companies directly or indirectly, to its discharge water pollutants outside the legal boundaries of behavior. |
GB 27632-2011: Emission standard of pollutants for rubber products industry---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Emission standard of pollutants for rubber products industry
National Standards of People's Republic of China
Rubber products industry pollutant discharge standards
2012-01-01 Implementation.2011-10-27 Release
Ministry of Environmental Protection
The General Administration of Quality Supervision, Inspection and Quarantine issued
Content
Foreword. II
1 Scope 3
2 Normative references 3
3 Terms and Definitions..4
4 Pollutant emission control requirements.5
5 Pollutant monitoring requirements 9
6 Standard implementation.10
1 Introduction
To implement the Environmental Protection Law of the People's Republic of China, the Law of the People's Republic of China on the Prevention and Control of Water Pollution,
Law on Prevention and Control of Atmospheric Pollution, Law of the People's Republic of China on Marine Environmental Protection, and State Council on Implementing the Scientific Outlook on Development and Strengthening the Environment
Laws and regulations such as the "Decision on Protection" and "Opinions of the State Council on the Preparation of National Main Functional Area Planning" to protect the environment and prevent
This standard is formulated for the promotion of pollution, promotion of industrial production processes and pollution control technologies for rubber products.
This standard specifies the limits, monitoring and monitoring requirements for water and air pollutants in rubber products enterprises. To promote regional economy and
Coordinated development of the environment, promote the adjustment of economic structure and the transformation of economic growth mode, and guide industrial production technology and pollution control technology
The development direction of this standard specifies the special emission limits for water pollutants.
The pollutant discharge concentrations in this standard are all mass concentrations.
Rubber products industrial enterprises emit odor pollutants and environmental noises, and apply corresponding national pollutant discharge standards to produce solid waste.
The identification, treatment and disposal of substances shall be subject to national solid waste pollution control standards.
This standard is the first release.
From the date of implementation of this standard, the control of water and air pollutant emissions from rubber products industrial enterprises shall be implemented in accordance with the provisions of this standard,
Then implement the "Integrated Wastewater Discharge Standard" (GB 8978-1996) and the "Integrated Emission Standard for Air Pollutants" (GB 16297-1996)
Relevant provisions in the middle.
Local provincial people's governments may formulate local pollutant discharge standards for pollutants not specified in this standard;
For pollutants that have been prescribed, local pollutant discharge standards that are stricter than this standard may be formulated.
This standard was formulated by the Science and Technology Standards Department of the Ministry of Environmental Protection.
This standard is mainly drafted by. Tianjin Environmental Protection Research Institute, Environmental Protection Institute of the Ministry of Environmental Protection, Tianjin Rubber
Institute of Glue Industry.
This standard was approved by the Ministry of Environmental Protection on September 21,.2011.
This standard has been implemented since January 1,.2012.
This standard is explained by the Ministry of Environmental Protection.
Rubber products industry pollutant discharge standards
1 Scope of application
This standard specifies the emission limits, monitoring and emission of water pollutants and atmospheric pollutants in rubber products industrial enterprises or production facilities.
Monitoring requirements, as well as standards implementation and supervision.
This standard applies to the management of water pollutants and atmospheric pollutants in existing rubber product manufacturers or production facilities.
And environmental impact assessment of environmental protection projects for rubber products industrial enterprises, environmental protection facilities design, environmental protection acceptance and completion
Management of water pollutants and atmospheric pollutants after production.
This standard applies to the discharge of pollutants permitted by law. Site selection and special protection areas for newly established pollution sources
The management of pollution sources shall be in accordance with the Law of the People's Republic of China on the Prevention and Control of Air Pollution and the Law of the People's Republic of China on Prevention and Control of Water Pollution
Law of the People's Republic of China on Marine Environmental Protection, Law of the People's Republic of China on the Prevention and Control of Environmental Pollution by Solid Wastes,
The relevant provisions of laws, regulations and rules, such as the Environmental Impact Assessment Law of the People's Republic of China, are implemented.
The water pollutant emission control requirements specified in this standard are applicable to enterprises directly or indirectly discharging water pollution outside their legal boundaries.
The behavior of the dye.
2 Normative references
The contents of this standard refer to the following documents or their terms.
GB/T 6920-1986 Determination of water pH value - Glass electrode method
GB/T 7472-1987 Determination of zinc in water -- Dithizone spectrophotometric method
GB/T 7475-1987 Determination of copper, zinc, lead and cadmium - Atomic absorption spectrophotometric method
GB/T 11893-1989 Determination of total phosphorus in water - Ammonium molybdate spectrophotometric method
GB/T 11894-1989 Determination of total nitrogen in water - Alkaline potassium persulfate digestion - UV spectrophotometric method
GB/T 11901-1989 Determination of suspended solids by weight method
GB/T 11914-1989 Determination of chemical oxygen demand in water - Dichromate method
GB/T 16157-1996 Determination of particulate matter in fixed pollution source exhaust gas and sampling method of gaseous pollutants
Water quality -- Determination of petroleum and animal and vegetable oils - Infrared photometric method
HJ/T 38-1999 Determination of non-methane total hydrocarbons from fixed source s
HJ/T 55-2000 Technical Guidelines for the Monitoring of Unorganized Emissions of Air Pollutants
HJ/T 195-2005 Determination of ammonia nitrogen in water quality
HJ/T.199-2005 Determination of total nitrogen in water -- Gas phase molecular absorption spectroscopy
HJ/T 399-2007 Determination of chemical oxygen demand in water quality - Rapid digestion spectrophotometric method
HJ 505-2009 Water quality five-day biochemical oxygen demand (BOD5) determination dilution and inoculation method
HJ 533-2009 Determination of ambient air and exhaust ammonia - Nessler reagent spectrophotometry
HJ 535-2009 Determination of ammonia nitrogen in water quality - Nexus reagent spectrophotometric method
HJ 536-2009 Determination of ammonia nitrogen in water quality - Salicylic acid spectrophotometric method
HJ 537-2009 Determination of ammonia nitrogen in water quality - Distillation - Neutralometric titration
HJ 583-2010 Determination of Benzene in Ambient Air - Solid Adsorption/Thermal Desorption - Gas Chromatography
HJ 584-2010 Determination of benzene in ambient air Activated carbon adsorption/carbon disulfide desorption - gas chromatography
Measures for the Automatic Monitoring and Control of Pollution Sources (Order No. 28 of the State Environmental Protection Administration)
Measures for the Administration of Environmental Monitoring (Order No. 39 of the State Environmental Protection Administration)
3 Terms and definitions
The following terms and definitions apply to this standard.
3.1 Rubber Products Industry
Raw rubber (natural rubber, synthetic rubber, reclaimed rubber, etc.) as the main raw material, various compounding agents as auxiliary materials, after rubber mixing, calendering,
Extrusion, molding, vulcanization and other processes, manufacturing various types of products, mainly including tires, motorcycle tires, bicycle tires, rubber
Manufacturers of pipes, tapes, rubber shoes, latex products and other rubber products, but do not include tire retreading and reclaimed rubber production
enterprise.
3.1 Tire companies
It produces solid tires, motorcycle tires and bicycle tires with solid raw rubber as the main raw material.
3.2 Latex products company
A company that produces latex products with natural latex or synthetic latex (liquid glue) as the main raw material.
3.3 Other products companies
An enterprise that produces other rubber products other than tires and latex products.
3.4 Existing companies
Refers to the rubber product enterprise or production that has been approved for production or environmental impact assessment documents before the date of implementation of this standard.
Production facilities.
3.5 New Enterprise
Refers to the construction, renovation and expansion of rubber products industry construction approved by the environmental impact assessment document from the date of implementation of this standard.
project.
3.6 Public sewage treatment system
Refers to enterprises or machines that collect wastewater through sewage pipelines and provide wastewater treatment services to more than two pollutant discharge units.
Structure, including urban sewage treatment plants of various scales and types, including various industrial parks, development zones, and industrial clusters.
Ground, etc.) Wastewater treatment plant, etc.
3.7 Direct discharge
Refers to the behavior of pollutant discharge units directly discharging water pollutants into the environment.
3.8 Indirect emissions
Refers to the behavior of sewage units discharging water pollutants to public sewage treatment systems.
a) displacement
Refers to the amount of wastewater discharged by an enterprise or production facility outside the legal boundaries of the enterprise. Including direct or indirect relationship with production
Various types of effluent wastewater (including domestic sewage, cooling wastewater, plant boilers and power station drainage).
b) Baseline displacement
Refers to the upper limit of the wastewater discharge amount of the consumption unit rubber compound used to verify the concentration of water pollutants.
The rubber materials in this standard include natural rubber, synthetic rubber and reclaimed rubber. The latex consumption of latex products enterprises is 60% latex.
Calculation (not converted to dry glue).
3.9 Exhaust volume
Refers to the amount of industrial waste gas emitted by the enterprise or production facility to the environment through the exhaust pipe.
3.10 Reference displacement
Refers to the upper limit of the exhaust gas emissions of the consumption unit compound specified for the approval of the concentration of atmospheric pollutants.
3.11 Standard status
Refers to the state when the temperature is 273.15K and the pressure is 101325P a. Limit concentration of atmospheric pollutants specified in this standard
The values are based on the dry gas in the standard state.
3.12 Unorganized emissions
Air pollutants are not discharged irregularly through the exhaust pipe or chimney.
4 Pollutant emission control requirements
4.1 Water pollutant emission control requirements
4.1.1 From January 1,.2012 to December 31,.2013, existing enterprises implement the water pollutant discharge limits specified in Table 1.
Table 1 Limits of existing enterprise water pollutants
Unit. mg/L (except pH)
Direct emission limit
No. Pollutant Project Tire Enterprise and Other Systems
Product company
Latex products
enterprise
Indirect emission limit
Pollutant discharge supervision
Control position
1 pH 6-9 6-9 6-9
2 suspended matter 40 70 150
3 5th Biochemical Oxygen Demand (BOD5) 20 20 80
4 Chemical oxygen demand (CODcr) 100 100 300
5 ammonia nitrogen 10 15 30
6 total nitrogen 15 20 40
7 total phosphorus 0.5 0.5 1.0
8 Petroleum 5 5 10
9 total zinc - 2.0 3.5 See note 1
Enterprise wastewater discharge
Gap
Baseline displacement (m3/t glue) 9 100 See note 2
Displacement metering
Set with pollutants
Place monitoring position
Note 1. Emission limits for latex products companies.
Note 2. The baseline displacement directly discharged from the table applies to indirect emissions from the corresponding type of enterprise.
4.1.2 As of January 1,.2014, existing enterprises will implement the water pollutant discharge limits specified in Table 2.
4.1.3 From January 1,.2012, the newly-built enterprise shall implement the water pollutant discharge limit specified in Table 2.
Table 2 New enterprise water pollutant emission limit
Unit. mg/L (except pH)
Direct emission limit
No. Pollutant Project Tire Enterprise and Other Systems
Product company
Latex products
enterprise
Indirect emission limit
Pollutant discharge supervision
Control position
1 pH 6-9 6-9 6-9
2 suspended matter 10 40 150
3 5th Biochemical Oxygen Demand (BOD5) 10 10 80
4 Chemical oxygen demand (CODcr) 70 70 300
5 ammonia nitrogen 5 10 30
6 total nitrogen 10 15 40
7 total phosphorus 0.5 0.5 1.0
8 Petroleum 1 1 10
9 total zinc - 1.0 3.5 See note 1
Enterprise wastewater discharge
Gap
Baseline displacement (m3/t glue) 7 80 See note 2
Displacement metering
Set with pollutants
Place monitoring position
Note 1. Emission limits for latex products companies.
Note 2. The baseline displacement directly discharged from the table applies to indirect emissions from the corresponding type of enterprise.
4.1.4 According to the requirements of environmental protection work, the density of land development has been higher, the environmental carrying capacity has begun to weaken, or water
A place with small environmental capacity, fragile ecological environment, and prone to serious water pollution problems and requiring special protection measures
The district shall strictly control the pollution discharge behavior of the enterprise, and the enterprises in the above-mentioned areas shall implement the special discharge of water pollutants specified in Table 3.
Limit.
The geographical scope and time for the implementation of special discharge limits for water pollutants shall be determined by the competent department of environmental protection under the State Council or the people at the provincial level.
Government regulations.
Table 3 Special emission limits for water pollutants in existing and new enterprises
Unit. mg/L (except pH)
Direct emission limit
No. Pollutant Project Tire Enterprise and Other Systems
Product company
Latex products
enterprise
Indirect emission limit
Pollutant discharge supervision
Control position
1 pH 6-9 6-9 6-9
2 suspended matter 10 10 40
3 5th Biochemical Oxygen Demand (BOD5) 10 10 20
4 Chemical oxygen demand (CODcr) 50 50 70
5 ammonia nitrogen 5 5 10
6 total nitrogen 10 10 15
7 total phosphorus 0.5 0.5 0.5
8 Petroleum 1 1 1
Enterprise wastewater discharge
Gap
9 total zinc - 0.5 1.0 See note 1
Baseline displacement (m3/t glue) 4 80 See note 2
Displacement metering
Set with pollutants
Place monitoring position
Note 1. Emission limits for latex products companies.
Note 2. The baseline displacement directly discharged from the table applies to indirect emissions from the corresponding type of enterprise.
4.1.5 The concentration limit of water pollutant discharge is applicable to the fact that the actual displacement of the unit rubber is not higher than the unit displacement of the unit rubber.
condition. If the actual displacement of the unit rubber exceeds the standard displacement of the unit rubber, the measured water pollutant concentration shall be determined according to formula (1).
Converted to the water pollutants reference water discharge concentration, and the water pollutants reference water discharge concentration as a determination of whether the discharge is up to standard
Basis. The rubber consumption and displacement statistics period is one working day.
Production of two or more products at the same time in the production facilities of the enterprise, applicable to different emission control requirements or pollution in different industries
In the case of dye discharge standards and the discharge of sewage from production facilities, the emission standards shall be implemented.
Strict concentration limits and conversion of water pollutants based on formula (1).
Yi i
ρ ρ×∑ i total base real base = (1)
In the formula.
ρ base--water pollutant reference water discharge concentration, mg/L;
Total Q -- the total amount of measured drainage, m3;
iY -- the i-th product rubber consumption, t;
Base iQ - unit compound base displacement of the i-th product, m3/t;
ρ实--Measured water pollutant discharge concentration, mg/L.
If the ratio of the ratio is less than 1, the measured concentration of water pollutants is used as the basis for determining whether the emission is up to standard.
according to.
Total Q Yi iQ∑ i base
4.2 Air Pollutant Emission Control Requirements
4.2.1 From January 1,.2012 to December 31,.2013, existing enterprises will implement the air pollutant emission limits specified in Table 4.
value.
Table 4 Air pollutant emission limits of existing enterprises
No. Pollutant project production process or facility emission limit
(mg/m3)
Baseline displacement
(m3/t glue) Pollutant emission monitoring position
Tire companies and other products companies
Rubber mixing equipment 18 2600 1 particulate matter
Latex products enterprise post-vulcanization equipment 18.20000
2 Ammonia latex products enterprise impregnation, batching process equipment 30 100000
Toluene and dimethyl
Benzene total (1)
Tire companies and other products companies
Glue preparation, dipping, glue spraying
Coating and gluing device
30 -
Workshop or production facility exhaust
Tire companies and other products companies
Rubber mixing and vulcanizing equipment 20 2600
4 Non-methane total hydrocarbon tire companies and other products companies
Glue preparation, dipping, glue spraying
Coating and gluing device
120 -
Note 1. Implementation after the release of national pollutant monitoring method standards
4.2.2 As of January 1,.2014, existing enterprises will implement the atmospheric pollutant discharge limits specified in Table 5.
4.2.3 From January 1,.2012, the newly-built enterprise shall implement the air pollutant emission limit specified in Table 5.
Table 5 Limits of Air Pollutant Emissions from New Enterprises
No. Pollutant project production process or facility emission limit
(mg/m3)
Baseline displacement
(m3/t glue) Pollutant emission monitoring position
Tire companies and other products companies
Rubber mixing equipment 12.2000 1 particulate matter
Latex products enterprise post-vulcanization equipment 12 16000
2 Ammonia latex products enterprise impregnation, batching process equipment 10 80000
Toluene and dimethyl
Benzene total (1)
Tire companies and other products companies
Glue preparation, dipping, glue spraying
Coating and gluing device
15 -
Tire companies and other products companies
Rubber mixing and vulcanizing equipment 10.2000
4 Non-methane total hydrocarbon tire companies and other products companies
Glue preparation, dipping, glue spraying
Coating and gluing device
100 _
Workshop or production facility exhaust
Note 1. Implementation after the release of national pollutant monitoring method standards
4.2.4 Unorganized emissions from the plant boundary Execute the emission limits specified in Table 6.
Table 6 Unorganized emission limits for existing and new enterprise boundaries
Unit. mg/ m3
Serial number pollutant item limit
1 particulate matter 1.0
2 toluene 2.4
3 xylene 1.2
4 Non-methane total hydrocarbons 4.0
4.2.5 Emission control of odorous pollutants in rubber products industrial enterprises shall be carried out in accordance with the provisions of GB 14554.
4.2.6 Environmental protection administration responsible for supervision in the production process after the completion of environmental protection acceptance of existing enterprise production and construction projects
The competent department shall monitor the environmental quality of sensitive areas for use in surrounding living, teaching, medical care, etc. Construction project
The scope of monitoring is the surrounding sensitive area determined by environmental impact assessment; existing enterprises that have not conducted environmental impact assessment, monitoring
The scope is governed by the environmental protection administrative department, according to the characteristics and laws of the enterprise's sewage discharge and the local natural and meteorological
Conditions and other factors are determined by reference to the relevant environmental impact assessment technical guidelines. Local governments should be responsible for the environmental quality of their respective jurisdictions.
Take measures to ensure that environmental conditions meet environmental quality standards.
4.2.7 Production processes and installations that produce atmospheric pollutants must establish local or integral gas collection systems and centralized purification
Device. All exhaust pipe height should be no less than 15m, when there is a building within a radius of.200m around the exhaust pipe, the exhaust pipe
The height should also be higher than the highest building by more than 3m.
4.2.8 The concentration limit of atmospheric pollutant emission is applicable to the fact that the actual discharge capacity of the unit rubber is not higher than the standard discharge capacity of the unit rubber.
condition. If the actual discharge capacity of the unit rubber exceeds the standard discharge capacity of the unit rubber, the measured atmospheric pollutant concentration shall be converted into the atmosphere.
The concentration of the pollutants in the baseline gas emissions, and the concentration of the air pollutants as the basis for determining whether the emissions meet the standards
according to. For the conversion of the reference concentration of atmospheric pollutants, refer to the calculation of the discharge concentration of water pollutants.
formula. The rubber consumption and exhaust volume statistics period is one working day.
5 Pollutant monitoring requirements
5.1 General requirements for pollutant monitoring
5.1.1 Sampling of waste water and waste gas from enterprises shall be monitored according to the type of pollutants monitored.
The location is proceeding. Where there are wastewater and waste gas treatment facilities, they should be monitored after the treatment facility. Enterprises should monitor the relevant national pollution sources
The technical specifications require the sampling port to be set and a permanent mark must be set at the pollutant discharge monitoring position.
5.1.2 Requirements for the installation of automatic monitoring equipment for pollutant discharge in newly built enterprises and existing enterprises, in accordance with relevant laws and
Implementation of the Measures for the Administration of Dynamic Monitoring.
5.1.3 The frequency, sampling time and other requirements for monitoring the discharge of pollutants of enterprises shall be monitored by relevant national pollution sources.
The provisions of the surgical specifications are implemented.
5.1.4 The verification of the rubber consumption of the enterprise shall be based on the statutory statements.
5.1.5 The enterprise shall monitor and save the sewage discharge in accordance with the relevant laws and the Measures for the Administration of Environmental Monitoring.
Original monitoring record.
5.2 Water pollutant monitoring requirements
The method standards listed in Table 7 are used to determine the concentration of pollutants discharged from enterprises.
Table 7 Standards for determination of water pollutant concentration
No. Contaminant Project Method Standard Name Method Standard Number
1 pH value water quality determination of glass electrode method GB/T 6920-1986
2 Determination of suspended solids suspended solids - Gravimetric method GB/T 11901-1989
3 Five-day biochemical oxygen demand water quality five-day biochemical oxygen demand (BOD5) determination dilution and inoculation method HJ 505-2009
Water quality - Determination of chemical oxygen demand - Potassium dichromate method GB/T 11914-1989
4 Chemical oxygen demand
Water quality chemical oxygen demand determination - Rapid digestion spectrophotometric method HJ/T 399-2007
Determination of ammonia nitrogen in water quality - Distillation - Neutralometric titration method HJ 537-2009
Determination of ammonia ni...
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