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HJ 863.3-2017: Technical specification for application and issuance of pollutant permit non-ferrous metal metallurgy industry - copper smelting
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Basic data

Standard ID HJ 863.3-2017 (HJ863.3-2017)
Description (Translated English) Technical specification for application and issuance of pollutant permit non-ferrous metal metallurgy industry - copper smelting
Sector / Industry Environmental Protection Industry Standard
Classification of Chinese Standard Z00
Word Count Estimation 36,382
Date of Issue 2017-09-29
Date of Implementation 2017-09-29
Regulation (derived from) Ministry of Environmental Protection Bulletin 2017 No. 54
Issuing agency(ies) Ministry of Ecology and Environment

HJ 863.3-2017: Technical specification for application and issuance of pollutant permit non-ferrous metal metallurgy industry - copper smelting


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People's Republic of China national environmental protection standards Technical specification for application and issuance of pollutant permit non-ferrous metal metallurgy industry-copper smelting 2017-09-29 Posted 2017-09-29 Implementation Ministry of Environmental Protection released Directory Foreword ii 1 Scope 1 2 Normative references 1 3 Terms and definitions .2 4 sewage units fill in the basic conditions required .2 5 emission nodes corresponding to the discharge port and allowable emission limits .7 6 pollution prevention and control of viable technical requirements .11 7 Self-monitoring management requirements 12 8 Environmental Management Ledger Records and Permit Permit Implementation Report Preparation Requirements 16 9 Actual emissions accounting method ..20 10 Compliance Decision Method 22 Appendix A (Informative) Environmental Management Ledger Records Refer to Table 25 Appendix B (Informative) Manual Monitoring Report Examples Table Appendix C (informative) Copper smelting sewage disposal units permit implementation of the report preparation 34

Foreword

In order to implement the "Law of the People's Republic of China on Environmental Protection", "Law of the People's Republic of China on Prevention and Control of Atmospheric Pollution", "Medium Law of the People's Republic of China on Prevention and Control of Water Pollution "and other laws and regulations as well as the" Control of pollutant discharge permit system implementation plan notice " No [2016] No. 81), improve the technical support system of sewage discharge permit, guide and standardize the sewage discharge permit of copper smelting sewage units Application and certification work permit, the development of this standard. This standard specifies the basic situation of application and issuance of emission permits issued by copper smelting and discharging units, and the permissible emission limit Value determination and actual emissions accounting methods, compliance assessment methods and self-monitoring, environmental management, accounting and sewage permit implementation Line reports and other environmental management requirements, put forward copper smelting industry pollution prevention and control technology and operational management requirements. When the issuance of the permit for the issuance of sewage is issued by the issuing authority, if it is located in the area prohibited by the laws and regulations from the construction area, The copper smelting sewerage units or production units that the local governments explicitly stipulate to be eliminated or banned shall not issue the sewerage permit. This standard Appendix A, Appendix B, Appendix C is an informative annex. This standard is released for the first time. This standard is formulated by the Ministry of Environmental Protection Planning and Finance Department, Ministry of Environmental Protection Science and Technology Standards Division. This standard is mainly drafted by. China Academy of Environmental Sciences, Central South University, Environmental Protection Department of Environmental Protection of Foreign Cooperation Center, China Nonferrous Metals Industry Association, MEP Environmental Engineering Assessment Center. This standard MEP approved on September 29,.2017. This standard since September 29,.2017 come into operation. This standard is interpreted by the MEP. Sewage Permit Application and Issuance Technical Specifications Nonferrous Metal Industry - Copper Smelting

1 scope of application

This standard specifies the copper smelting sewage units permit application and issuance of the basic conditions for reporting requirements, allowable emission limits Settlement, actual emissions accounting, compliance assessment methods and self-monitoring, environmental management, accounting and sewage permit implementation of the report such as ring Environmental management requirements, put forward the copper smelting sewage unit pollution control feasible technical requirements. This standard applies to guide the copper smelting sewage units to fill out the "sewage permit application form" and in the national sewage permit management information Platform reporting system to fill in the relevant application information for the guidance of the issuing authority to determine the copper smelting sewage discharge permits permit May request. This standard applies to primary ore or copper concentrate as the main raw material of copper smelting sewage units, excluding scrap copper material as raw material Smelting of pollutants emitted by the pollutant discharge units and water pollutant discharge permit management. This standard does not make provisions but the discharge of industrial wastewater, waste gas or the state of toxic and harmful atmospheric pollutants of copper smelting sewage Other pollutant discharge facilities and discharge outlets of the unit shall be implemented in accordance with the General Provisions of the Technical Specifications for the Application and Issuance of Permits for Sewage Discharges, Certificate Application and Issuance of Technical Specifications Boiler Industry "Before the release of hot water boilers and steam boilers of 65 t/h and below, the implementation of this standard, After the release from its provisions.

2 Normative references

The contents of this standard reference the following documents or terms. For undated references, the effective version applies This standard. GB 13271 Boiler air pollutant emission standards GB 25467 copper, nickel, cobalt industrial pollutant emission standards Determination of Particulate Matter and Gaseous Pollutants in Exhaust of Fixed Pollution Sources GB/T 16157 HJ 493 Technical Specifications for the Preservation and Management of Water Sampling Samples HJ 494 water sampling technical guidance HJ 495 water quality sampling program design specifications HJ 819 Technical Guidelines for Self-Monitoring of Sewage Disposal Units General HJ 820 Self-Monitoring Technical Guidelines for Sewage Disposal Units Thermal Power Generation and Boilers HJ/T 55 Guidelines for Unorganized Emissions Monitoring of Air Pollutants HJ/T 75 Stationary Pollutant Source Discharge Continuous Monitoring Technical Specifications (Trial Implementation) HJ/T 76 Fixed Pollutant Source Discharge Continuous Monitoring System Technical Requirements and Monitoring Methods (Trial) HJ/T 91 Technical Specifications for Surface Water and Sewerage Monitoring HJ/T 353 water pollution source on-line monitoring system installation technical specifications (Trial) HJ/T 354 water pollution source on-line monitoring system acceptance Technical Specifications (Trial) HJ/T 355 water pollution source on-line monitoring system operation and evaluation of technical specifications (Trial) HJ/T 356 Water Pollution Source Online Monitoring System Data Validation Technical Specifications (Trial) HJ/T 397 fixed source exhaust gas monitoring technical specifications

3 Terms and definitions

The following terms and definitions apply to this standard. 3.1 Copper smelting pollutant emission unit unit Refers to the primary ore or copper concentrate as the main raw material of copper smelting enterprises, does not include the use of scrap copper raw materials for the renewable smelting enterprises. 3.2 Permitted emission limits permitted emission limits Refers to the allowable pollutants discharged by pollutant discharge units as specified in the discharge permit and the maximum discharge concentration and the maximum discharge amount. 3.3 special periods special periods Refers to the national and local deadlines according to the planning and other relevant environmental management regulations, the pollutant discharge units have Special requirements of the period, including heavy polluted weather during the period and winter prevention period and so on.

4 sewage units fill in the basic requirements

4.1 General principles Sewage units should be in accordance with the requirements of this standard, in the sewage permit management information platform to declare the system to fill in the "sewage permit application form" In the corresponding information table. Fill in the system drop-down menu does not include the provisions of the local environmental protection departments need to fill in or sewage Units that need to fill in the report, you can add content. Provincial environmental protection department in accordance with the requirements of improving the quality of the management of environmental requirements should be filled in the sewage permit management information Ping Taiwan declaration system "with the nuclear power of local environmental protection departments to increase the management content" column. When reporting the application information, the pollutant discharge unit should assess the status of pollution discharge and environmental management and put forward rectification measures on the current environmental problems Shi, and fill in the sewage permit management information platform to declare the system "corrective measures" column. The basic situation of the sewage disposal units should be reported according to the actual conditions and bear legal responsibility for the authenticity, legality and completeness of the application materials submitted. 4.2 sewage unit basic information The basic information of the pollutant discharge unit should fill in the name of the unit, the zip code, whether it is put into production, the date of production, the center of production and operation center Degree, latitude and longitude of the place of production and operation, whether the locality belongs to the key area, whether there is an EIA approval document and number, Party government on the identification of illegal items or filing documents and symbols, whether the total amount of major pollutants distribution plan documents and symbols, particles Total amount of indicators (t/a), total sulfur dioxide indicators (t/a), total nitrogen oxides (as NO2) indicators (t/a) Total oxygen content (t/a), ammonia total nitrogen (t/a), total lead and its compounds (t/a), total arsenic and its compounds (T/a), total mercury and its compounds (t/a), total cadmium and its compounds (t/a), total lead Total arsenic total indicator (t/a), total mercury total indicator (t/a), total cadmium total indicator (t/a), the remaining (if any) Supplementary reporting. 4.3 main products and capacity 4.3.1 General requirements In reporting the main products and production capacity, should choose "copper smelting." Sewage disposal units should fill out the requirements of this standard to apply for the main production unit of the information system of sewage discharge permit management information platform, To process, production facilities, production facilities number, facility parameters, product name, production capacity and measurement units, the design of the production time Room and other options and other information. 4.3.2 The main production unit The main production units are required, the specific classification is as follows. a) fire process. preparation, smelting, blowing, fire refining, electrolytic refining, slag beneficiation, flue gas acid, public units, etc .; b) wet process. preparation, crushing, building piles, leaching, extraction, electrowinning, slag heap treatment, public units and so on. 4.3.3 The main process The main process is required, the specific requirements are as follows. a) fire process. including smelting, blowing, refining (fire and wet) process; Smelting. Divided into flash melting, oxygen-rich bottom blowing, oxygen-rich top blowing, oxygen-rich side blowing, synthetic furnace smelting and other oxygen-rich molten pool melting or rich Oxygen float smelting process. Blowing. converter, flash, top-blown immersion, the end of blowing, blowing and other blowing process side; Fire refining. divided into refining and tilting furnace refining refining refining process; wet refining mainly electrolytic refining; b) wet process. leaching - extraction - plot, heap leaching - extraction - plot and other technology. 4.3.4 Production facilities Production facilities are divided into required and optional items, the specific requirements are as follows. a) fire process. Required items for the preparation process (including raw material storage, transfer stations, crushing machines, etc.), smelting (flash furnace, top blowing Furnace, side blowing furnace, bottom blowing furnace), blowing (converter, copper matte hot stove - flash blowing furnace, bottom blowing furnace, top blowing furnace, side blowing furnace) Fire refining (anode furnace, disc casting machine), electrolytic refining (electrolyzer, electrolyte circulation tank, circulation tank), flue gas acid Towers, conversion towers, absorption towers), utilities (including chemical water treatment stations, boiler rooms, anode mud storage rooms, etc.), optional Including dry kilns, waste heat boilers and power generation systems; b) wet process. required items for the preparation process (including raw material storage, transfer stations, crushing machines, etc.), leaching (leaching tank), extraction Take - stripping (extraction tank, stripping tank, etc.) and electrowinning system (electrowinning tank, copper electrowinning tank, etc.), optional items include the preparation of dry Dry kiln; c) This standard has not yet provided for, and emissions of industrial emissions and toxic and hazardous air pollutants, a clear national and local emission standards Quasi, the corresponding production facilities are required. 4.3.5 Production Facilities Number Production facilities number is required, the specific requirements are as follows. a) If the production facility has the internal production facility number of the sewage disposal unit, fill in the corresponding number; b) If the production facilities have no internal production facilities number of sewage disposal units, then according to "on the development of thermal power, paper industry and Beijing-Tianjin-Hebei test Appendix 4 "Fixed Pollution Sources (Water, Atmosphere) Coding Rules in Notice on the Management of Urban Peril Source Discharge Permit Line) "number and fill in. 4.3.6 Facilities parameters Facilities parameters are divided into required and optional items, the specific requirements are as follows. Production facilities in smelting furnace, blowing furnace, anode furnace and other furnaces, processing capacity, the common unit of the boiler capacity, the original Library storage capacity, auxiliary system processing (storage) capacity is required, the other optional. 4.3.7 Product Name The product name is required, divided into. blister copper, copper anode, copper cathode, sulfuric acid and so on. 4.3.8 production capacity and measurement units Production capacity and measurement units are required, the production capacity of the main product design capacity. Capacity and yield measurement units are million t/a. 4.3.9 Design Year of production Design annual production time is required, should be based on the environmental impact assessment documents and approval or local government identified or prepared for non-compliance items Case file to determine the number of hours of production to complete. 4.3.10 Others Other optional items, sewage units need to explain the contents, you can fill in. 4.4 The main raw and auxiliary materials and fuel The main raw and auxiliary materials and fuel fill in the contents include the type of raw and auxiliary materials, raw and auxiliary materials, fuel name, fuel into Points, design annual usage, other, specific requirements are as follows. a) types. divided into raw and auxiliary materials, fuel; - 5 - b) raw and auxiliary material name. raw materials, including primary ore, copper concentrate, copper scrap and so on. Accessories include flux (quartz, limestone), Refining slag, soot, refining slag, slag concentrate, etc. c) Composition of raw and auxiliary materials. the proportion of sulfur elements (dry basis) of the main raw and auxiliary materials, as well as the major toxic and harmful substances, accounting for the proportion; d) Name of fuel. natural gas, heavy oil, coal, etc .; e) Fuel composition. The sulfur content (dry basis), ash content and major toxic and hazardous substances in the main fuels should be reported, accounting for ratio; f) Design annual usage. The designed annual usage is the annual consumption of raw and auxiliary materials and fuel matching the approved production capacity, in units of 10,000 t/a or 10,000 m3/a; g) Others. If the pollutant discharge unit needs to explain the content, can fill in; h) above a) - f) is required, g) is optional. 4.5 production of sewage nodes, pollutants and pollution control facilities 4.5.1 General principles Waste gas production node, pollutants and pollution control facilities, including the corresponding name of the pollutant production section, the type of pollutants, emission forms (with Organization, unorganized), pollution control facilities, whether it is viable technology, organized discharge number, whether the discharge port settings meet the requirements Seeking, discharge type. Wastewater pollutant discharge nodes, pollutants and pollution control facilities, including wastewater types, types of pollutants, whereabouts of emissions, emission laws, Pollution control facilities, discharge number, the discharge port set to meet the requirements, the type of discharge. 4.5.2 Exhaust gas 4.5.2.1 pollution production process Divided into raw material preparation, smelting, blowing, fire refining, flue gas acid, electrolysis, electricity, net liquid. 4.5.2.2 types of pollutants Pollutants should be based on GB 13271, GB 25467 to determine, see Table 1. There are local emission standards, according to local emission standards Accurate set. 4.5.2.3 pollution control facilities The name of the management facilities should be completed dust removal facilities, desulfurization facilities, denitrification facilities. 4.5.2.4 pollution control process Pollution control process Fill dust treatment facilities (wet dust removal, cyclone dust removal, electric dust removal, bag dust removal, etc.), desulfurization Facility management techniques (lime/limestone-gypsum method, organic solution cyclic absorption method, metal oxide absorption method, activated coke adsorption method, Ammonia, double alkali, hydrogen peroxide desulfurization, etc.), denitration facilities governance process (SCR, SNCR, etc.). - 6 - 4.5.3 Wastewater 4.5.3.1 Category Wastewater fill categories include production wastewater (acid, acid wastewater, general production wastewater, etc.), the initial rainwater and domestic sewage. 4.5.3.2 types of pollutants The type of pollutants should be determined according to GB 25467, see Table 1. Where there is a local emission standard, it should be determined according to local emission standards. 4.5.3.3 governance facilities Should fill in domestic sewage treatment facilities, production wastewater treatment facilities. 4.5.3.4 pollution control process Pollution control processes include the production of waste water treatment process (lime and high-density mud method, curing method, lime - iron salt (aluminum Salt), biological agents, electrochemical methods, membrane separation, etc.), domestic sewage treatment process (biological contact oxidation, sequencing batch Activated sludge treatment process, membrane bioreactor treatment process, etc.). 4.5.3.5 Fate and Emission Law Copper smelting sewage discharge units should be clear where the discharge and discharge rules. Emission to the outside is divided into no outside; discharged to the factory integrated sewage treatment station; direct access to the sea; direct access to rivers, lakes, libraries, etc. Water environment; into the city sewers (re-entry rivers, lakes, libraries); into the city sewers (re-enter the coastal waters); into the city Sewage treatment plant; into other units; industrial wastewater treatment facilities; other (including reuse, etc.). Emission laws are divided into continuous emissions, steady flow; continuous emissions, flow instability, but there are periodic laws; continuous emissions, Flow instability, but regular, and does not belong to the cyclical law; continuous discharge, flow instability, are impact emissions; continuous Emissions, unstable and erratic flows, but not impact emissions; intermittent emissions, steady flow during discharges; intermittent releases, Unstable flow during discharge but with periodic pattern; intermittent discharge, unstable flow during discharge, but regular and not Non-periodic pattern; intermittent discharge, unstable flow during discharge, impact-type discharge; intermittent discharge, discharge during discharge Stable and irregular, but not impact emissions. 4.5.4 Discharge port setting requirements According to the "technical requirements for the standardization of sewage outfall (Trial)" and the emission standards implemented by the discharge unit of the relevant emission standards Standardization of the provisions of the provisions of the actual situation to fill in the exhaust and wastewater discharge port settings meet the standardization requirements. 4.5.5 Drain port information Discharge type is divided into the main discharge port and the general discharge port, as shown in Table 1. Exhaust outlet should be reported to discharge Geographic sit Standard, height of exhaust pipe, diameter of exhaust pipe outlet, national or local pollutant emission standards, approval requirements and commitments of environmental impact assessment More stringent emission limits. Direct discharge of waste water should be reported to discharge the geographical coordinates, intermittent discharge period, receiving natural water information, Import into the receiving natural water body at the geographic coordinates and implementation of national or local pollutant discharge standards. Wastewater indirect discharge should be reported to discharge Mouth geographic coordinates, intermittent discharge period, the name of the receiving sewage treatment plant and the implementation of national or local pollutant discharge standards. Wastewater - 7 - Discharge should be set out the period of discharge of pollutants. 4.5.6 pollution control facilities and discharge number Pollution control facilities can fill in copper smelting sewage treatment unit internal number. If the copper smelting sewage unit no internal number, then according to Attachment 4 in the Notice on the Management of Permits for Emission Sources Across the Top Source Areas of Thermal Power, Paper Industry and Beijing-Tianjin-Hebei Pilot Cities Set the source of pollution (water, air) coding rules (Trial) "number and fill in. Organized discharge number should fill in the local environmental protection department in charge of the existing number, if the local environmental protection authorities did not row Release mouth number, then according to "on the thermal power, paper industry and Beijing-Tianjin-Hebei pilot cities license management of elevated sources of sewage Annex 4 "Fixed Pollution Sources (Water, Atmosphere) Code Rules (for Trial Implementation)" in the Circular of the Ministry of Agriculture, Forestry and Fisheries. 4.6 Other requirements The basic situation of the sewage unit should also include the production process flow chart (including the whole plant and the process) and plant layout plan, and Describe the main production facilities (equipment), the main raw and auxiliary materials, fuel flow, production processes and so on. Factory general plane cloth The plan should include the main production units, plant, equipment, location, indicating the plant sewage collection and transport to the contents of the same time note Ming factory area rainwater and sewage discharge port location.

5 emission nodes corresponding to the discharge port and allowable emission limits

5.1 production of sewage nodes and the corresponding discharge Emissions and waste water production and sewage nodes and corresponding discharges in Table 1. Copper smelting sewage discharge units should fill in national or local discharge standards of pollutants, environmental impact assessment approval requirements, promises more stringent Emission limits, the remaining items based on part 4.5 of this standard to fill out the pollutant discharge node and discharge information. Table 1 production of sewage nodes, discharge and pollution factor list Drainage node discharge port discharge type pollution factor Exhaust emissions organized Raw...