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Technical specification for application and issuance of pollutant permit non-ferrous metal metallurgy industry --lead and zinc smelting
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HJ 863.1-2017
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Basic data | Standard ID | HJ 863.1-2017 (HJ863.1-2017) | | Description (Translated English) | Technical specification for application and issuance of pollutant permit non-ferrous metal metallurgy industry --lead and zinc smelting | | Sector / Industry | Environmental Protection Industry Standard | | Classification of Chinese Standard | Z00 | | Word Count Estimation | 63,675 | | Date of Issue | 2017-09-29 | | Date of Implementation | 2017-09-29 | | Regulation (derived from) | Ministry of Environmental Protection Notice No. 54 of 2017 | | Issuing agency(ies) | Ministry of Ecology and Environment |
HJ 863.1-2017: Technical specification for application and issuance of pollutant permit non-ferrous metal metallurgy industry --lead and zinc smelting ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Technical specification for application and issuance of pollutant permit
non-ferrous metal metallurgy industry -lead and zinc smelting
2017-09-29 Posted
2017-09-29 Implementation
Directory
Foreword .II
1 Scope 1
2 Normative references 1
3 Terms and definitions .2
4 sewage units fill in the basic conditions required .2
5 production of sewage nodes, corresponding to the discharge and allowable emission limits 8
6 pollution prevention and control feasible technical requirements
7 Self-monitoring management requirements .16
8 environmental management accounting records and implementation report preparation requirements .3
9 Actual emissions accounting method .7
10 Compliance Decision Method .9
Appendix A (Informative) Zinc smelting waste gas pollution prevention and control feasible recommendation technology .12
Appendix B (informative) Zinc smelting wastewater pollution prevention and control feasible recommendation technology
Appendix C (Informative) Environmental Management Ledger Records Reference Table
Appendix D (informative) manual monitoring report example table .22
Appendix E (Informative) Lead and Zinc Smelter Sewage Disposal Permit Implementation Report Compilation content.23
Foreword
In order to implement the "Law of the People's Republic of China on Environmental Protection" "Law of the People's Republic of China on Prevention and Control of Air Pollution" "China
Law of the People's Republic of China on Prevention and Control of Water Pollution "and other laws and regulations and" Control of pollutant discharge permit system implementation plan "
〔2016〕 81), improve the technical support system for sewage permits, guide and standardize the lead-zinc smelting sewage unit permits
Apply for and issue work, develop this standard.
This standard specifies the lead and zinc smelting sewage units permit application and issuance of the basic conditions for reporting requirements, allowable emissions
Limit determination, actual emissions accounting, compliance assessment methods and self-monitoring, environmental management account and sewage permit
Line reports and other environmental management requirements, put forward the lead-zinc smelting industry pollution prevention and control of feasible technical requirements.
When the issuance of the permit for the issuance of sewage is issued by the issuing authority, if it is located in the area prohibited by the laws and regulations from the construction area,
The local governments shall explicitly refuse to issue emission permits for lead and zinc smelting sewage treatment units or production units to be eliminated or banned.
This standard Appendix A, Appendix B, Appendix C, Appendix D, Appendix E is an informative annex.
This standard is released for the first time.
This standard is formulated by the Ministry of Environmental Protection Planning and Finance Department, Ministry of Environmental Protection Science and Technology Standards Division.
This standard is mainly drafted by. China Academy of Environmental Sciences, Beijing Mining and Metallurgy Research Institute, Environmental Protection Department of Environmental Protection
Foreign Cooperation Center, China Nonferrous Metals Industry Association.
This standard MEP approved on September 29,.2017.
This standard since September 29,.2017 come into operation.
This standard is interpreted by the MEP.
Sewage Permit Application and Issuance Technical Specifications Nonferrous Metal Industry - Lead and Zinc Smelting
1 scope of application
This standard specifies the lead and zinc smelting sewage units permit application and issuance of the basic conditions for reporting requirements, allowable emissions
Limit determination, actual emissions accounting, compliance assessment methods and self-monitoring, environmental management account and sewage permit
Line reports and other environmental management requirements, put forward the lead-zinc smelting industry pollution prevention and control of feasible technical requirements.
This standard applies to guide lead-zinc smelting sewage units to fill in the "sewage permit application form" and the national sewage permit
Management information platform to declare the system to fill in the relevant application information for the guidance of the issuing authority to determine the lead and zinc smelting industry row
Permits permit requirements.
This standard applies to lead concentrate, zinc concentrate or lead-zinc concentrate as the main raw material of lead-zinc smelting sewage discharge units
Of the air pollutants, water pollutant discharge permit management, this standard does not apply to independent secondary lead and zinc resources of lead
Zinc Smelting Sewage Disposal Unit and Application for Sewage Disposal Permits for Recycled Lead, Recycled Zinc and Lead, Zinc Rolled Products
Work with the issuance.
This standard does not make provisions but the discharge of industrial waste water, waste gas or toxic and harmful air pollutants specified by the state of lead and zinc
Smelting sewage treatment units and other pollutant discharge facilities, with reference to the "General Guidelines for the Application and Issuance of Permits for Sewage Disposal"
Before the release of the "Permit for Discharge Permit Application and Issuance of Technical Specifications for Boiler Industry", hot water boilers and steam boilers of 65t/h and below
Reference to the implementation of this standard, issued from its provisions.
2 Normative references
The contents of this standard reference the following documents or terms. For undated references, the valid version is appropriate
Used for this standard.
GB 13271 Boiler air pollutant emission standards
GB 25466 lead, zinc industrial pollutant emission standards
Determination of Particulate Matter and Gaseous Pollutants in Exhaust of Fixed Pollution Sources GB/T 16157
HJ 493 Technical Specifications for the Preservation and Management of Water Sampling Samples
HJ 494 water sampling technical guidance
HJ 495 water quality sampling program design specifications
HJ 819 Technical Guidelines for Self-Monitoring of Sewage Disposal Units General
HJ 820 Self-Monitoring Technical Guidelines for Sewage Disposal Units Thermal Power Generation and Boilers
Technical code for treatment of lead smelter waste gas HJ 2049-2015
HJ -BAT-7 lead smelting pollution prevention and control of the best possible technical guidelines (Trial)
HJ/T 55 Guidelines for Unorganized Emissions Monitoring of Air Pollutants
HJ/T 75 Stationary Pollutant Source Discharge Continuous Monitoring Technical Specifications (Trial Implementation)
HJ/T 76 Fixed Pollutant Source Discharge Continuous Monitoring System Technical Requirements and Monitoring Methods (Trial)
HJ/T 91 Technical Specifications for Surface Water and Sewerage Monitoring
HJ/T 353 water pollution source on-line monitoring system installation technical specifications (Trial)
HJ/T 354 water pollution source on-line monitoring system acceptance Technical Specifications (Trial)
HJ/T 355 water pollution source on-line monitoring system operation and evaluation of technical specifications (Trial)
HJ/T 356 Water Pollution Source Online Monitoring System Data Validation Technical Specifications (Trial)
HJ/T 397 fixed source exhaust gas monitoring technical specifications
HJ □□ -201 □ Discharge Permit Application and Issuance Technical Specifications General
HJ □□ -201 □ self-monitoring technical guide sewage units Non-ferrous metal smelting and rolling processing
HJ □□ -201 □ Environmental Management Ledger and Drainage Permits Implementation Report Technical Specifications (Trial)
Lead and zinc smelting industrial pollution prevention and control technology policy Ministry of Environmental Protection Announcement No. 18 of.2012)
"Fixed pollution sources permit classification management directory"
"Technical requirements for the standardization of sewage outfall (Trial)" (State Environmental Protection Agency Environmental Monitoring 〔1996〕 470)
Measures for the Administration of Automatic Monitoring Facilities for Pollution Sources (Huanfa [2008] No. 6)
Circular on the Management of License for Permitting Pollution Caused by Elevated Sources in Thermal Power, Papermaking Industry and Beijing, Tianjin and Hebei Pilot Cities
Water [2016] No. 189)
3 Terms and definitions
The following terms and definitions apply to this standard.
3.1 Lead and zinc smelting pollutant emission unit
Refers to the lead concentrate, zinc concentrate or lead-zinc concentrate as the main raw material of lead and zinc smelting enterprises.
3.2 Permitted emission limits permitted emission limits
Refers to the allowable pollutants discharged by pollutant discharge units as specified in the discharge permit and the maximum discharge concentration and the maximum discharge amount.
3.3 special periods special periods
Refers to the national and local deadlines for compliance planning and other relevant environmental management requirements, the pollutant discharge of sewage units
There are special requirements of the period, including the heavy polluted weather during the period and winter prevention period and so on.
4 sewage units fill in the basic requirements
4.1 General principles
Sewage units should be in accordance with the requirements of this standard in the sewage permit management information platform to declare the system to fill out the "sewage permit
Please table "in the corresponding information table. Fill in the system drop-down menu is not included, the local environmental protection authorities have required
Fulfillment or sewage units that need to be reported, can add their own content.
Provincial environmental protection departments in accordance with environmental quality requirements to improve the management of the increase should be filled in the sewage permit management letter
Interest platform to declare the system "with the nuclear power of the local environmental protection department to increase the content of management" column.
When submitting the application information, the pollutant discharge unit should assess the status of pollution discharge and environmental management and put forward the proposal of rectifying the current environmental problems
Change measures, and fill in the sewage permit management information platform to declare the system "corrective measures" column.
The basic situation of the sewage disposal units should be reported according to the actual conditions and bear legal responsibility for the authenticity, legality and completeness of the application materials submitted.
4.2 sewage unit basic information
The basic information of the pollutant discharge unit should fill in the name of the unit, the zip code, whether it is put into production, the date of production, the place of production and operation
Heart longitude, latitude and longitude of the center of production and operation, whether the location belongs to the key area, whether there is an EIA approval document and number,
Whether there are local governments for the violation of the project identification or filing documents and symbols, whether the total amount of major pollutants distribution plan documents
And symbols, total particulate matter (t/a), total sulfur dioxide (t/a), total nitrogen oxides (NO2) indicators
(T/a) (only for special emission limits), total COD (t/a), total ammonia (t/a)
Total lead (t/a), total mercury and its compounds (t/a), total lead (t/a), total arsenic
The total amount of indicators (t/a), total cadmium indicators (t/a), total mercury indicators (t/a), the remaining items, if any, shall be filled in by the enterprises themselves.
4.3 main products and capacity
4.3.1 General principles
In reporting the main products and production capacity, should choose "lead and zinc smelting."
Sewage discharge unit should be based on the requirements of this standard to fill out the sewage permit management information platform to declare the system on the major producers
Art, production facilities, production facilities number, facility parameters, product name, production capacity and measurement units, the design of the production
Room and other options and other information.
4.3.2 The main production unit
The main production unit specific classification is as follows.
a) lead smelting. divided into preparation, melting - reduction, flue gas acid, fumigation, lead refining, copper scum treatment, public units, etc .;
b) Zinc hydrometallurgy. It is divided into preparation materials, boiling roasting, sulfuric acid from flue gas, leaching-purification, zinc electrolysis, leaching residue treatment, public units, etc.;
c) electric furnace smelting. divided into preparation, boiling roasting, flue gas acid, electric smelting, slag processing, zinc rectification, public units, etc .;
d) vertical zinc tank. divided into preparation, boiling roasting, flue gas acid, reconcile the system group, coke-off distillation, slag processing, zinc rectification, public units;
e) sealed blast furnace melting (ISP method). divided into preparation, sintering, flue gas acid, sealed blast furnace smelting, fuming,
Lead refining, copper scum treatment, zinc rectification, gas purification, public units and so on.
4.3.3 The main production process
The main production process is required, the specific requirements are as follows.
a) Lead smelting. divided into oxygen-rich bottom blowing (top blowing, side blowing) smelting - blast furnace reduction lead smelting process, oxygen-rich bottom blowing
Smelting - liquid high-lead slag direct reduction process, flash smelting (Kiefside method, lead-oxygen-flash smelting) process;
b) Zinc hydrometallurgy. Divided into conventional leaching method, high temperature and high acid method, oxygen pressure leaching method, oxygen-enriched atmospheric pressure leaching method;
c) Fire Zinc Smelting. divided into electric smelting zinc, vertical zinc smelting furnace, closed furnace method (ISP method).
4.3.4 Production facilities
Production facilities are divided into required and optional items, the specific requirements are as follows.
a) Lead smelting. The required items are the material preparation step (including the material stock, etc.), the smelting and reduction step (including the smelting furnace, reduction
Furnace, etc.), flue gas acid production process (including acid system), fuming process (fuming furnace), lead refining process (including lead
Pots, electrolyzers, electric lead pots, etc.), copper scum treatment processes (including reflex furnaces), utilities (including boilers, etc.)
Optional filling process for the preparation of crushing mill, drying kiln, smelting - reduction process of the disc casting machine, slag casting machine;
b) Zinc hydrometallurgy. the required items for the preparation process (including raw materials, etc.), boiling roasting process (including roaster,
Roaster, etc.), flue gas acid production processes (including acid system, etc.), wet leaching - purification processes (including leaching tank, purification
Trough, etc.), zinc electrolysis process (including electrolyzer, induction furnace, etc.), leaching residue treatment process (including rotary kiln, multi-hearth furnace
Etc.), utilities (including boilers, etc.), optional items include crushing mill, drying kiln, cooling cylinder, etc., zinc
Electrolysis process of the ingot machine;
c) electric furnace smelting zinc. Required items for the preparation process (including raw materials, etc.), boiling roasting process (including roasting roaster,
Roaster, etc.), smelting process (including electric furnace, rotary kiln or fuming furnace), distillation process (including zinc distillation furnace, etc.), smoke
Gas acid process (including acid system, etc.), utilities (including boilers, etc.), optional items include crushing process for the preparation process,
Drying kiln, electric furnace smelting process holding tank, condenser and so on;
d) Vertical Zinc Smelting. Required items are preparation procedures (including raw material storage), boiling roasting (including roasting roaster,
(Such as rod mill, wheel mill, pelletizing machine, etc.), coke consolidation distillation process (including coke-knot
Furnaces, vertical tank retorts, etc.), distillation residue treatment processes (including vortex melting furnaces, etc.), rectification processes (including zinc rectification furnaces
Etc.), flue gas acid production process (including acid production system), public facilities (including boiler room, gas furnace, etc.), optional
Items include the preparation process of crushing mill, drying kiln, zinc rectification process of the holding tank, condenser, etc .;
e) closed furnace method (ISP method). required items for the preparation process (including raw materials, etc.), sintering process (package
Including sintering machine, crusher, etc.), sealed blast smelting process (including closed blast furnace, etc.), flue gas acid production process (including the system
Acid system, etc.), lead electrolysis process (including melting pot, electrolytic cell, electric lead pot, etc.), copper scum treatment process (including reflection
Furnaces, etc.), zinc rectification processes (including zinc rectifiers, etc.), utilities (including boiler rooms, gasifiers, etc.), optional
Items include crushing mill preparation process, drying kiln, cooling cylinder, lead electrolytic casting machine, crude zinc rectification process
Temperature tank, condenser and so on.
4.3.5 Production Facilities Number
Production facilities number is required, the specific requirements are as follows.
a) If the production facility has the internal production facility number of the sewage disposal unit, fill in the corresponding number;
b) If no production facilities within the sewage treatment unit production facilities number, according to "on the thermal power, paper industry and Beijing
Tianjin, Hebei pilot urban elevated source pollutant discharge permit management notice "Annex 4" fixed source of pollution (water, air) series
Code Rules (Trial) "number and fill in.
4.3.6 Facilities parameters
Facilities parameters are divided into required and optional items, the specific requirements are as follows.
a) Lead smelting. smelting furnaces, reduction furnaces, melting lead pots, electric lead pans, fuming furnaces, rotary kilns, reflex furnaces
And other furnaces, processing capacity, the boiler unit production capacity of common units, raw material storage capacity is required. Others are optional
b) zinc smelting. roaster, sintering machine, closed blast furnace, electric furnace, coke oven, vertical tank distillation furnace, whirlpool furnace,
Flue gas furnace, rotary kiln, multi-hearth furnace, lead-melting pot, electric lead pot, furnace reflex furnace, processing capacity, the boiler unit
Production capacity, raw material storage capacity is required. Others are optional.
4.3.7 Product Name
Product name is required, the specific requirements are as follows.
a) lead smelting. divided into crude lead, lead, sulfuric acid, etc .;
b) Zinc smelting. divided into zinc baking, zinc, zinc, zinc, sulfuric acid and so on.
4.3.8 production capacity and measurement units
Production capacity and measurement units are required, the production capacity of the main product design capacity. Capacity and production units are measured
To million t/a.
4.3.9 Design Year of production
Design production time is required, according to the environmental impact assessment documents and approval or local government identified the non-compliance items
Or filing documents to determine the number of hours of production to complete.
4.3.10 Others
Other optional items, sewage units need to explain the contents, you can fill in.
4.4 The main raw and auxiliary materials and fuel
The main raw and auxiliary materials and fuel fill in the contents include the type of raw and auxiliary materials, raw and auxiliary materials, fuel name, fuel
Material composition, the design of the amount of use, other, the specific requirements are as follows.
a) types. divided into raw and auxiliary materials, fuel;
b) raw and auxiliary material name.
1) lead smelting. raw materials, including lead concentrate, crude lead, lead waste, accessories, including soda ash;
2) Zinc smelting. The raw materials include zinc concentrate, lead-zinc mixed concentrate, zinc oxide ore, zinc calcine, crude zinc, zinc oxide,
Zinc scrap, etc., accessories include sulfuric acid, ammonium chloride, zinc powder.
c) Ingredients of raw and auxiliary materials. The sulfur content of the main raw and auxiliary materials (dry basis), the main toxic and harmful substances and their composition
ratio;
d) Name of fuel. coal, coke, heavy oil, natural gas, etc .;
e) Fuel composition. The ash content, sulfur content, volatile content and heating value of the fuel should be reported, of which the sulfur content is required and the rest is
Optional
f) Design annual usage. The design annual usage is the annual consumption of raw and auxiliary materials and fuel matching the approved production capacity,
Bit for the million t/a or million m3/a;
g) Others. If the pollutant discharge unit needs to explain the content, can fill in;
h) The above a) -f) is required, g) is optional.
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4.5 production of sewage nodes, pollutants and pollution control facilities
4.5.1 General principles
Sewage emissions Sewage links, pollutants and pollution control facilities, including production facilities corresponding to the production of pollution links, types of pollutants,
Forms of Emissions (Organized, Unorganized), Facilities and Technologies for Pollution Control, Are Available Technologies, Number of Emissions, Emissions
Port settings are norms and types of discharge.
Wastewater, including wastewater category, type of pollutants, whereabouts of emissions, pollution control facilities and technology, whether it is feasible technology,
Discharge port number, discharge port settings and the type of discharge port.
4.5.2 Exhaust gas
4.5.2.1 pollution production process
Lead smelting, hydrometallurgical zinc, electric furnace smelting zinc, vertical zinc smelting furnace, sealed blast furnace smelting method (ISP method) of the production of pollutants node
as follows.
a) Lead smelting, including preparation, acid system (furnace flue gas), reduction furnace, fuming furnace, melting lead pot, electric lead pot,
Reflecting furnaces, boilers, environmental smoke collection;
b) Zinc hydrometallurgy includes preparation, acid preparation system (boiling roaster flue gas), leaching tank, purification tank, multi-hearth furnace, back
Rotary kiln, zinc casting, boilers, etc.
c) Furnace zinc smelting including preparation, acid system (boiling roaster flue gas), electric furnace, fuming furnace (rotary kiln), zinc
Distillation systems, boilers, environmental smoke, etc.
d) vertical zinc tank including preparation, acid system (boiling roaster flue gas), coke oven, vertical tank distillation furnace, whirlpool furnace,
Zinc distillation system, boilers, etc.
e) Closed blast furnace smelting method (ISP method) Including preparation, acid system (sintering machine flue gas), sintering head, broken
Crusher, closed-air blast furnace, fuming furnace, melting lead pot, electric lead pot, reflecting furnace, zinc rectification system, boiler, environment set smoke and so on.
4.5.2.2 types of pollutants
The types of pollutants should be determined according to GB 13271 and GB 25466, see Table 1. There are local emission standards, according to place
Emission standards to determine.
4.5.2.3 Governance Facilities
The name of the management facilities should be completed dust removal facilities, desulfurization facilities, denitrification facilities.
4.5.2.4 pollution control process
Pollution control process to fill out the dust control facilities (wet dust, electric dust, bag dust, etc.), desulfurization facilities governance
Technology (lime/limestone-gypsum method, organic solution cyclic absorption method, metal oxide absorption method, activated coke adsorption method,
Ammonia, double alkali, hydrogen peroxide desulfurization, etc.), denitration facilities governance process (SCR, SNCR, etc.).
HJ □□□ -20 □□
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4.5.3 Wastewater
4.5.3.1 Category
Lead and zinc smelting wastewater fill categories include the production of waste water (acid, acid wastewater, general production wastewater, initial rainfall) and
Domestic sewage and so on.
4.5.3.2 types of pollutants
The type of pollutants should be determined according to GB 25466, see Table 1. With local emission standards, according to loca...
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