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GB/T 3286.2-2025 English PDF

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GB/T 3286.2-2025: Methods for chemical analysis of limestone and dolomite - Part 2: Determination of silicon and aluminium content
Status: Valid

GB/T 3286.2: Evolution and historical versions

Standard IDContents [version]USDSTEP2[PDF] delivered inStandard Title (Description)StatusPDF
GB/T 3286.2-2025English439 Add to Cart 4 days [Need to translate] Methods for chemical analysis of limestone and dolomite - Part 2: Determination of silicon and aluminium content Valid GB/T 3286.2-2025
GB/T 3286.2-2012English329 Add to Cart 3 days [Need to translate] Methods for chemical analysis of limestone and dolomite -- Part 2: The determination of silicon dioxide content -- The silicomolybdic blue spectrophotometric method and the perchloric acid dehydration gravimetric method Valid GB/T 3286.2-2012
GB/T 3286.2-1998English239 Add to Cart 2 days [Need to translate] Methods for chemical analysis of limestone and dolomite--The determination of silicon dioxide content Obsolete GB/T 3286.2-1998
GB/T 3286.2-1982EnglishRFQ ASK 3 days [Need to translate] Chemical analysis of limestone and dolomite--The eriochrome black T photometric method for determination of magnesium oxide Obsolete GB/T 3286.2-1982

Basic data

Standard ID GB/T 3286.2-2025 (GB/T3286.2-2025)
Description (Translated English) Methods for chemical analysis of limestone and dolomite - Part 2: Determination of silicon and aluminium content
Sector / Industry National Standard (Recommended)
Classification of Chinese Standard D52
Classification of International Standard 73.080
Word Count Estimation 22,244
Date of Issue 2025-08-29
Date of Implementation 2026-03-01
Older Standard (superseded by this standard) GB/T 3286.2-2012, GB/T 3286.3-2012
Issuing agency(ies) State Administration for Market Regulation; Standardization Administration of China

GB/T 3286.2-2025: Methods for chemical analysis of limestone and dolomite - Part 2: Determination of silicon and aluminium content


---This is an excerpt. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.), auto-downloaded/delivered in 9 seconds, can be purchased online: https://www.ChineseStandard.net/PDF.aspx/GBT3286.2-2025
ICS 73.080 CCSD52 National Standards of the People's Republic of China Replaces GB/T 3286.2-2012 and GB/T 3286.3-2012 Chemical analysis methods for limestone and dolomite Part 2.Determination of Silicon and Aluminum Content Published on 2025-08-29 Implemented on 2026-03-01 State Administration for Market Regulation The State Administration for Standardization issued a statement.

Foreword

This document complies with the provisions of GB/T 1.1-2020 "Standardization Work Guidelines Part 1.Structure and Drafting Rules of Standard Documents". Drafting. This document is Part 2 of GB/T 3286, "Chemical Analysis Methods for Limestone and Dolomite". GB/T 3286 has been published as follows. part. ---Part 1.Determination of Calcium Oxide and Magnesium Oxide Content by Complexometric Titration and Flame Atomic Absorption Spectrometry; ---Part 2.Determination of Silicon and Aluminum Content; ---Part 4.Determination of Iron Oxide Content by 1,000-phenanthroline Spectrophotometry and Flame Atomic Absorption Spectrometry; ---Part 5.Determination of Manganese Oxide Content. Periodate Oxidation Spectrophotometry; ---Part 6.Determination of Phosphorus Content. Phosphomolybdic Blue Spectrophotometry; ---Part 7.Determination of Sulfur Content. Tube Furnace Combustion-Potassium Iodate Titration, High-Frequency Combustion Infrared Absorption Method, and Barium Sulfate Gravimetric Method; ---Part 8.Determination of Loss on Ignition by Gravimetric Method; ---Part 9.Determination of Carbon Dioxide Content by Caustic Soda-Asbestos Absorption Gravimetric Method; ---Part 10.Determination of Titanium Dioxide Content by Diantipyrin Methane Spectrophotometry; ---Part 11.Determination of the content of calcium oxide, magnesium oxide, silicon dioxide, aluminum oxide and iron oxide Wavelength dispersive X-ray fluorescence Spectroscopic method (fused glass slide method); ---Part 12.Determination of potassium oxide and sodium oxide content by flame atomic absorption spectrometry. This document replaces GB/T 3286.2-2012 "Chemical Analysis Methods for Limestone and Dolomite - Part 2.Determination of Silica Content". "Spectrophotometric Method for Determining the Desiccant Molybdenum Blue and Gravimetric Method for Dehydration with Perchloric Acid" and GB/T 3286.3-2012 "Chemical Analysis Methods for Limestone and Dolomite" Part 3.Determination of Alumina Content by Chromium Azure S Spectrophotometric Method and Complexometric Titration Method, consistent with GB/T 3286.2-2012 Aside from structural adjustments and editorial modifications, the main technical changes are as follows. a) The scope has been changed (see Chapter 1, Chapter 1 of the.2012 edition); b) Added "Determination of Silicon and Aluminum Content. Inductively Coupled Plasma Atomic Emission Spectrometry" (see Chapter 8); c) An "oxide conversion factor" has been added (see Chapter 9). Please note that some content in this document may involve patents. The issuing organization of this document assumes no responsibility for identifying patents. This document was proposed by the China Iron and Steel Association. This document is under the jurisdiction of the National Steel Standardization Technical Committee (SAC/TC183). This document was drafted by. China Certification & Inspection Group Fujian Co., Ltd., Wuhan University of Science and Technology, Wuhan Iron and Steel Co., Ltd., and Metallurgical Industry Information Technology Co., Ltd. Information Standards Research Institute. The main drafters of this document are. Li Ming, Wu Jianguang, Chen Weilong, Wang Xiaoyuan, Zhou Shuangqing, Wen Zhen, Chen Ningjie, Xu Jianping, Zhou Zheng, Bai Lizhou, and Yu. Wei Hua, Lou Yunpeng, Wang Bo, Liu Yanting, Zhang Yarong, Chen Yiting, Chen Jielin, Wang Juntian, Cheng Zhaoyang. The document replaced by this document has been released in the following versions. ---GB/T 3286.2-2012 (GB/T 3286.2-2012 replaces the following documents and previous version releases. GB/T 3286.2-) 1998 "Chemical Analysis Methods for Limestone and Dolomite. Determination of Silica Content", GB/T 3286.3-1982 "Limestone and Dolomite. Determination of Silica Content" Determination of Silica by Perchloric Acid Dehydration Gravimetric Method in Limestone Chemical Analysis, GB/T 3286.4-1988 Limestone and Dolomite Chemical Analysis Analytical Methods for the Determination of Silica by Molybdenum Blue Spectrophotometry ---GB/T 3286.3-2012 (GB/T 3286.3-2012 replaces the following documents and previous version releases. GB/T 3286.3-) 1998 "Chemical Analysis Methods for Determination of Alumina Content in Limestone and Dolomite", GB/T 3286.5-1982 "Limestone and Dolomite" Chemical Analysis Methods. Determination of Alumina by EDTA Volumetric Method; GB/T 3286.6-1982.Chemical Analysis of Limestone and Dolomite Methods. Determination of Alumina by Chromium Azurite S Spectrophotometry (《Method》).

introduction

To facilitate the detection of elements in limestone and dolomite, based on the elements to be determined and the methods used, GB/T 3286 "Limestone and Dolomite" is classified. The proposed course "Chemical Analysis Methods" is divided into the following sections. ---Part 1.Determination of Calcium Oxide and Magnesium Oxide Content by Complexometric Titration and Flame Atomic Absorption Spectrometry; ---Part 2.Determination of Silicon and Aluminum Content; ---Part 4.Determination of Iron Oxide Content by 1,000-phenanthroline Spectrophotometry and Flame Atomic Absorption Spectrometry; ---Part 5.Determination of Manganese Oxide Content. Periodate Oxidation Spectrophotometry; ---Part 6.Determination of Phosphorus Content. Phosphomolybdic Blue Spectrophotometry; ---Part 7.Determination of Sulfur Content. Tube Furnace Combustion-Potassium Iodate Titration, High-Frequency Combustion Infrared Absorption Method, and Barium Sulfate Gravimetric Method; ---Part 8.Determination of Loss on Ignition by Gravimetric Method; ---Part 9.Determination of Carbon Dioxide Content by Caustic Soda-Asbestos Absorption Gravimetric Method; ---Part 10.Determination of Titanium Dioxide Content by Diantipyrin Methane Spectrophotometry; ---Part 11.Determination of the content of calcium oxide, magnesium oxide, silicon dioxide, aluminum oxide and iron oxide Wavelength dispersive X-ray fluorescence Spectroscopic method (fused glass slide method); ---Part 12.Determination of potassium oxide and sodium oxide content by flame atomic absorption spectrometry. Chemical Analysis Methods for Limestone and Dolomite Part 2.Determination of Silicon and Aluminum Content 1.Scope This document describes the determination of silicon dioxide using the silicomolybdenum blue spectrophotometric method, the perchloric acid dehydration gravimetric method, and inductively coupled plasma atomic emission spectrometry. The alumina content was determined by spectrophotometry, complexometric titration and inductively coupled plasma atomic emission spectrometry. This document applies to the determination of silica and alumina content in limestone, dolomite, and metallurgical lime. The silica-molybdenum blue spectrophotometric method is used for determination. Range (mass fraction). Silica content 0.050%~4.00%; Perchloric acid dehydration gravimetric method, determination range (mass fraction). Silica Content greater than 2.00%; Inductively coupled plasma atomic emission spectrometry, determination range (mass fraction). silica content 0.070%~ 3.50%; Chromium Azure S spectrophotometric method, determination range (mass fraction). alumina content 0.010%~0.75%; complexometric titration method, determination range Range (mass fraction). alumina content greater than 0.50%; Inductively coupled plasma atomic emission spectrometry, determination range (mass fraction). alumina content... Quantity. 0.040%~1.00%.

2 Normative references

The contents of the following documents, through normative references within the text, constitute essential provisions of this document. Dated citations are not included. For references to documents, only the version corresponding to that date applies to this document; for undated references, the latest version (including all amendments) applies. This document. GB/T 2007.2 General Rules for Sampling and Sample Preparation of Bulk Mineral Products - Manual Sample Preparation Method GB/T 6379.1 Accuracy (correctness and precision) of measurement methods and results - Part 1.General principles and definitions GB/T 6379.2 Accuracy (correctness and precision) of measurement methods and results - Part 2.Determining the repeatability of standard measurement methods Basic methods of sex and representation GB/T 6682 Specifications and test methods for water used in analytical laboratories GB/T 8170 Rules for rounding off numerical values and the representation and determination of limiting values GB/T 12806 Laboratory Glassware - Single-mark volumetric flasks GB/T 12807 Graduated Pipettes for Laboratory Glassware GB/T 12808 Laboratory Glassware - Single-mark Pipettes JJG768 emission spectrometer 3.Terms and Definitions This document does not contain any terms or definitions that need to be defined. 4.Determination of silicon content. Molybdenum blue spectrophotometry 4.1 Principle The sample was melted with anhydrous sodium carbonate-boric acid mixed flux and leached with dilute hydrochloric acid. A portion of the solution was then isolated in approximately 0.15 mol/L hydrochloric acid medium. In this process, ammonium molybdate reacts with silicic acid to form a silicomolybdate heteropoly acid. An oxalic acid-sulfuric acid mixture is added to eliminate interference from phosphorus and arsenic, and then the mixture is reduced with ferrous ammonium sulfate solution.

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