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Determination of butylated hydroxyl anisole (BHA), dibutylated hydroxyl toluene (BHT) and tertiary butyl hydroquinone (TBHQ) in foods
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GB/T 23373-2009
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Basic data Standard ID | GB/T 23373-2009 (GB/T23373-2009) | Description (Translated English) | Determination of butylated hydroxyl anisole (BHA), dibutylated hydroxyl toluene (BHT) and tertiary butyl hydroquinone (TBHQ) in foods | Sector / Industry | National Standard (Recommended) | Classification of Chinese Standard | X40 | Classification of International Standard | 67.050 | Word Count Estimation | 8,817 | Date of Issue | 2009-03-16 | Date of Implementation | 2009-05-01 | Quoted Standard | GB/T 6682-2008 | Regulation (derived from) | National Standard Approval Announcement 2009 No.3 (Total No.143) | Issuing agency(ies) | General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China | Summary | This standard specifies the determination of antioxidants in food butyl hydroxy anisole (BHA) by gas chromatography, dibutyl hydroxy toluene (BHT) and tert-butyl hydroquinone (TBHQ) method. This standard applies to foods BHA, BHT and TBHQ determination. This standard method detection limit: BHA2mg/kg, BHT2mg/kg, TBHQ5mg/kg. |
GB/T 23373-2009: Determination of butylated hydroxyl anisole (BHA), dibutylated hydroxyl toluene (BHT) and tertiary butyl hydroquinone (TBHQ) in foods ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Determination of butylated hydroxyl anisole (BHA), dibutylated hydroxyl toluene (BHT) and tertiary butyl hydroquinone (TBHQ) in foods
ICS 67.050
X40
National Standards of People's Republic of China
Food antioxidants butylated hydroxyanisole (BHA),
Butylated hydroxytoluene (BHT) and tert-butyl
Determination of hydroquinone (TBHQ) of
Posted 2009-03-16
2009-05-01 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Foreword
Appendix A of this standard and Appendix B is an informative annex.
This standard is proposed and managed by China National Institute of Standardization.
This standard was drafted. the National Food Quality Supervision, Inspection and Safety Center.
The main drafters of this standard. with Na Mu, Xu Hua, Zhao Yuqi, Cao Hong, ZHOU Xiang Juan, Li Wei, Liu Yanqin.
Food antioxidants butylated hydroxyanisole (BHA),
Butylated hydroxytoluene (BHT) and tert-butyl
Determination of hydroquinone (TBHQ) of
1 Scope
This standard specifies the determination by gas chromatography in food antioxidant butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT) and
T-butyl hydroquinone (TBHQ) method.
This standard applies to foods BHA, BHT and TBHQ determination.
The standard method detection limit. BHA2mg/kg, BHT2mg/kg, TBHQ5mg/kg.
2 Normative references
The following documents contain provisions which, through reference in this standard and become the standard terms. For dated references, subsequent
Amendments (not including errata content) or revisions do not apply to this standard, however, encourage the parties to the agreement are based on research
Whether the latest versions of these documents. For undated reference documents, the latest versions apply to this standard.
GB/T 6682-2008 analytical laboratory use specifications and test methods (ISO 3696. 1987, MOD)
Principle 3
Samples antioxidants with an organic solvent extraction and gel permeation chromatography purification system (GPC) purified by gas chromatography flame ionization
Of the detector, using the retention time qualitative, external standard.
4 Reagents and materials
Unless otherwise indicated, the reagents used were of analytical grade water for the two water GB/T 6682-2008 requirements.
4.1 cyclohexane.
4.2 ethyl acetate.
4.3 petroleum ether. boiling range 30 ℃ ~ 60 ℃ (distilled).
4.4 acetonitrile.
4.5 acetone.
4.6 BHA standards. purity ≥99.0%, - 18 ℃ frozen storage.
4.7 BHT standards. purity ≥99.3%, - 18 ℃ frozen storage.
4.8 TBHQ standards. purity ≥99.0%, - 18 ℃ frozen storage.
4.9 BHA, BHT, TBHQ standard stock solution. Weigh accurately BHA, BHT, TBHQ standards for each 50mg (accurate to 0.1mg),
With ethyl acetate. cyclohexane (1/1) volume to 50mL, formulated as a stock solution 1mg/mL, and at 4 ℃ refrigerator stored.
4.10 BHA, BHT, TBHQ standard solution. draw stock standard solution 0.1,0.5,1.0,2.0,3.0,4.0,5.0mL, in a group
10mL volumetric flask, ethyl acetate. cyclohexane (1/1) to volume concentration of this standard series is 0.01,0.05,0.1,0.2,0.3,0.4,
0.5mg/mL. Using now.
5. Apparatus
5.1 Gas Chromatograph (GC). equipped with a flame ionization detector (FID).
5.2 Gel Permeation Chromatography Purification System (GPC), or may be defatted equivalent separation device.
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