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GB/T 23937-2020 (GB/T23937-2020)

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GB/T 23937-2020: PDF in English (GBT 23937-2020)
GB/T 23937-2020
GB
NATIONAL STANDARD OF THE
PEOPLE’S REPUBLIC OF CHINA
ICS 71.060.50
G 12
Replacing GB/T 23937-2009
Sodium hydrosulfide for industrial use
工业硫氢化钠
ISSUED ON: NOVEMBER 19, 2020
IMPLEMENTED ON: OCTOBER 01, 2021
Issued by: State Administration for Market Regulation;
Standardization Administration of the People’s Republic of
China.
Table of Contents
Foreword ... 3 
1 Scope ... 5 
2 Normative references ... 5 
3 Molecular formula and relative molecular mass ... 6 
4 Classification ... 6 
5 Technical requirements ... 6 
6 Test methods ... 7 
7 Inspection rules ... 15 
8 Marking, labeling ... 16 
9 Packaging, transportation and storage ... 16 
Sodium hydrosulfide for industrial use
Warning -- According to the provisions of Chapter 6 of GB 12268-2012,
this product belongs to the 8th category of corrosive substances, which
can react with acidic substances to generate hydrogen sulfide, which is
easy to cause suffocation poisoning. Be cautious during the operation.
The personnel who use this Standard shall have hands-on experience in
formal laboratory work. This Standard does not address all possible
security issues. It is the responsibility of the user to take appropriate
safety and health measures and to ensure compliance with the conditions
which are set by the relevant national regulations.
1 Scope
This Standard specifies the classification, technical requirements, test methods,
inspection rules, marking, labeling, packaging, transportation and storage of
sodium hydrosulfide for industrial use.
This Standard applies to sodium hydrosulfide for industrial use, which is mainly
used in industries such as mineral processing, pesticides, leather making, dyes,
organic synthesis and water treatment.
2 Normative references
The following documents are indispensable for the application of this document.
For dated references, only the dated version applies to this document. For
undated references, the latest edition (including all amendments) applies to this
document.
GB 190, Packing symbol of dangerous goods
GB/T 191-2008, Packaging - Pictorial marking for handling of goods
GB/T 3049-2006, Chemical products for industrial use - General method for
determination of iron content - 1,10-Phenanthroline spectrophotometric
method
GB/T 6678, General principles for sampling chemical products
GB/T 6679, General rules for sampling solid chemical products
GB/T 6680, General rules for sampling liquid chemical products
third end points; subtract the volume that is consumed by the third end point of
the first titration; calculate the sodium carbonate content.
6.3.2 Reagents or materials
6.3.2.1 Barium chloride solution: 100 g/L.
6.3.2.2 Neutral formaldehyde solution: 37% ~ 40% aqueous solution; for the
reagent formaldehyde solution, use phenolphthalein as the indicator solution,
and use sodium hydroxide to adjust to neutral.
6.3.2.3 Hydrochloric acid standard titration solution: c(HCl) ≈ 0.1 mol/L.
6.3.2.4 Alizarin yellow GG-thymol blue mixed indicator solution:
a) Dissolve 0.1 g of alizarin yellow GG in 100 mL of 50% ethanol solution;
b) Dissolve 0.1 g of thymol blue in 100 mL of 50% ethanol solution;
c) Take 30 mL of a) and 20mL of b) and mix well.
6.3.2.5 Phenolphthalein indicator solution (10 g/L).
6.3.2.6 Bromocresol green-methyl red indicator solution.
6.3.3 Instruments and apparatuses
Acidimeter or automatic potentiometric titrator: the accuracy is 0.02 pH unit; it
is equipped with calomel electrode and glass electrode or composite electrode.
6.3.4 Test procedure
6.3.4.1 Preparation of test solution
6.3.4.1.1 Preparation of test solution A
Weigh 10 g ~ 12 g of liquid sample or 5 g of solid sample, accurate to 0.000 2
g; place it in a 500 mL volumetric flask which is pre-added with 15 mL of barium
chloride solution; use water to dilute to the mark; shake well. Use medium-
speed filter paper for dry filtration; discard the initial filtrate; collect the filtrate as
test solution A.
6.3.4.1.2 Preparation of test solution B
Weigh 10 g ~ 12 g of liquid sample or 5 g of solid sample, accurate to 0.000 2
g; dissolve it in a 500 mL volumetric flask; add water to dilute to the mark; shake
well, as test solution B.
6.3.4.2 Determination
6.3.5.2 Sodium hydrosulfide content
The sodium hydrosulfide content is calculated, as mass fraction w2 of sodium
hydrosulfide (NaHS), according to Formula (2):
Where:
V2 -- value of the volume of hydrochloric acid standard titration solution that is
consumed at the end of the second titration of the test solution that is
added with barium chloride, in milliliters (mL);
V1 -- value of the volume of hydrochloric acid standard titration solution that is
consumed at the end of the first titration of the test solution that is added
with barium chloride, in milliliters (mL);
c -- exact value of the hydrochloric acid standard titration solution concentration,
in moles per liter (mol/L);
M -- value of the molar mass of sodium hydrosulfide, in grams per mole (g/mol)
(M = 56.06);
m -- value of the sample (see 6.3.4.1.1) mass, in grams (g).
Take the arithmetic mean of the two parallel determination results as the final
result; the difference between the absolute values of the two parallel
determination results shall not exceed 0.2%.
6.3.5.3 Sodium carbonate content
The sodium carbonate content is calculated, as mass fraction w3 of sodium
carbonate (Na2CO3), according to Formula (3):
Where:
V3’ -- volume of hydrochloric acid standard titrant that is consumed at the end
of the third titration of the test solution without barium chloride, in
milliliters (mL);
V2’ -- volume of hydrochloric acid standard titrant that is consumed at the end
of the second titration of the test solution without barium chloride, in
milliliters (mL);
6.4.2.7 Starch indicator solution (10 g/L).
6.4.3 Instruments and apparatuses
Micro burette: 10 mL, division value of 0.05 mL.
6.4.4 Test procedure
6.4.4.1 Pipette 200 mL of test solution B; place it in a 500 mL volumetric flask;
successively add 60 mL of sodium carbonate solution, 120 mL of zinc sulfate
solution, 40 mL of 95% ethanol; add water to dilute to the mark; shake well; dry
filter; discard the first 20 mL of filtrate; collect the filtrate in a 500 mL conical
flask.
6.4.4.2 Pipette 100 mL of filtrate into a 250 mL conical flask; add 10 mL of glacial
acetic acid solution, 2 mL of starch indicator solution; use iodine standard
titration solution to titrate until the solution appears blue, as the end point; mark
the volume of the consumed iodine standard titration solution as V4.
6.4.4.3 Pipette another 100 mL of filtrate into another 250 mL conical flask; add
5 mL of formaldehyde solution, 10 mL of glacial acetic acid solution, 2 mL of
starch indicator solution; use iodine standard titration solution to titrate until the
solution appears blue, as the end point; mark the consumed iodine standard
titration solution as V5.
6.4.5 Test data processing
The sodium sulfite content is calculated, as mass fraction w4 of sodium sulfite
(Na2SO3), according to Formula (4):
Where:
V4 -- value of the total volume of iodine standard titration solution that is
consumed by sodium thiosulfate and sodium sulfite, in milliliters (mL);
V5 -- value of the volume of iodine standard titration solution that is consumed
by sodium thiosulfate, in milliliters (mL);
c -- actual concentration of the iodine standard titration solution, in moles per
liter (mol/L);
M1 -- value of the molar mass of sodium sulfite, in grams per mole (g/mol) (M =
126.0);
m1 -- value of the sample (see 6.3.4.1.2) mass, in grams (g).
7 Inspection rules
7.1 This Standard adopts type inspection and delivery inspection. Type
inspection and delivery inspection shall meet the following requirements:
a) All indicator items which are specified in the requirements of this Standard
are type inspection items. Under normal production conditions, type
inspection shall be carried out at least once every six months. Type
inspection shall be carried out in any of the following situations:
1) when a key production process is updated;
2) when there are changes in the main raw materials;
3) when the suspended production is resumed;
4) when it is significantly different from the previous type inspection;
5) contractual provisions.
b) The sodium hydrosulfide content, sodium sulfide content, and sodium
carbonate content indicators which are specified in the requirements of
this Standard are delivery inspection items and shall be inspected batch
by batch.
7.2 Products which are produced with the same materials and basically the
same production conditions continuously or in the same group, by the
production enterprise, are the same batch. Each batch of solid products does
not exceed 60 t; liquid products are determined according to the size of the
storage container.
7.3 Determine the number of sampling units and sampling method in
accordance with the provisions of GB/T 6678, GB/T 6679, and GB/T 6680. Mix
at least 200 g of liquid or 100 g of solid samples evenly; then, put them in two
clean and dry sample bottles or sample bags respectively; label them, marking:
manufacturer name, product name, specification, batch number or production
date. One is for analysis and inspection; the other is kept for future reference.
7.4 When any indicator of the inspection result does not meet the requirements
of this Standard, it shall sample from double the packages for re-inspection; If
any indicator the re-inspection result does not meet the requirements of this
Standard, the whole batch of products shall be judged as unqualified.
7.5 Use the rounded value comparison method that is specified in GB/T 8170
to determine whether the inspection results meet the standard.
......
 
(Above excerpt was released on 2021-04-17, modified on 2021-06-07, translated/reviewed by: Wayne Zheng et al.)
Source: https://www.chinesestandard.net/PDF.aspx/GBT23937-2020