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PDF similar to GB 17411-2015
Basic data | Standard ID | GB 17411-2015 (GB17411-2015) | | Description (Translated English) | [Including 2018XG1] Marine fuel oils | | Sector / Industry | National Standard | | Classification of Chinese Standard | E31 | | Classification of International Standard | 75.160.20 | | Word Count Estimation | 31,355 | | Date of Issue | 2015-12-31 | | Date of Implementation | 2016-07-01 | | Older Standard (superseded by this standard) | GB/T 17411-2012 | | Regulation (derived from) | State Standard Announcement 2015 No.43 | | Issuing agency(ies) | General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China |
GB 17411-2015: [Including 2018XG1] Marine fuel oils---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Marine fuel oils
ICS 75.160.20
E31
National Standards of People's Republic of China
Replacing GB/T 17411-2012
Marine fuel oil
[ISO 8217.2012, MOD]
Issued on. 2015-12-31
2016-07-01 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Table of Contents
Preface Ⅰ
1 Scope 1
2 Normative references 1
Classification and designation 3 2
4 3 requirements and test methods
5 Inspection Rules 3
6 packaging, labeling, transportation and storage 4
7 Safety 4
Appendix A (informative) biological products and fatty acid methyl esters (FAMEs) 8
Annex B (informative) hazardous substances 10
Annex C (informative) a sulfur content of 11
Annex D (informative) Hydrogen sulfide 12
Appendix E (normative) specific energy (calorific value) 13
Annex F (normative) ship fuel ignition residue of 15
Annex G (informative) Flash point 18
Appendix H (informative) Acid 19
Annex I (informative) sodium and vanadium 20
Appendix J (informative) catalyst powder 22
Annex K (informative) used lubricating oils 23
Annex L (informative) residual fuel oil cleanliness and compatibility 24
Annex M (informative) This standard and ISO 8217.2012 reg number control and technical differences and their causes 25
References 27
Foreword
The standard Chapter 3, Section 4, Chapter 6 and Chapter 7 are mandatory, the rest are recommended.
This standard was drafted in accordance with GB/T 1.1-2009 given rules.
This standard replaces GB/T 17411-2012 "marine fuel oil." This standard and GB/T 17411-2012 compared to major technological changes
as follows.
--- Standard recommended by the Switch mandatory;
--- Chapter 1 applies a predetermined range of the sea [ocean] marine diesel engine and boiler fuel;
--- According to the sulfur content of distillate fuel is divided into three grades, and an increase in the sulfur content of the relevant detection method (see Chapters 3 and Table 1);
--- Distillate fuel flash point by the DMZ is not lower than 43 ℃ modifications not lower than 60 ℃ (see Table 1);
--- Distillate fuels DMA and DMZ sulfur content of not more than 1.5% from the index revised to 1.0% (see Table 1);
--- RMA10 RMB30 and residual fuel oil in accordance with the number of divided sulfur content of not more than 3.5%, 0.5% and 0.1% three grades, other grades according to the sulfur content of not more than 3.5% into, two levels of 0.5% (see Table 2 );
--- Increasing the net calorific value indicators and the corresponding detection methods (see Table 2);
--- Increased cleanliness and compatibility with residual fuel oil informative annex (see Annex L).
This revised standard adopts ISO 8217.2012 "Petroleum products - Fuels (F Class) marine fuel oil specifications.
This standard and ISO 8217.2012 as compared to, in technical content and structure adjustment, Appendix M shows the structure and corresponding technical differences and their causes.
This standard by the National Standardization Technical Committee on products and lubricant oil (SAC/TC280) proposed.
This standard by the National Petroleum Products and Lubricants Standardization Technical Committee of petroleum fuels and lubricants Technical Committee (SAC/TC280/SC1) centralized.
This standard was drafted. China Research Institute of Petroleum Corp. Petrochemical, China Sinopec Fuel Oil Sales Co., Ltd., China Sinotrans Group Co., China's ship fuel limited liability company, Technical and Economic Research Institute of China Shipbuilding Industry.
Drafters of this standard. dragon Li, Xiang Xiaomin, when Xin Wei, Hu Wei, Song Yanyuan.
This standard replaces the standards previously issued as follows.
--- GB/T 17411-1998, GB/T 17411-2012.
Marine fuel oil
Warning. If you do not observe proper precautions, this product may be hazardous to your standard in the production, storage and use of the process.
This standard is not intended to present all of the safety issues related to the product recommendations. Before using this standard has the responsibility to establish appropriate safety
Full and preventive measures, and determine the applicability of regulatory limitations related.
1 Scope
This standard specifies made from petroleum and marine fuel oil classification code, requirements and test methods, inspection rules, packaging, labeling, transportation
Transport, storage and security.
This standard applies to the sea [ocean] marine diesel and fuel oil boiler. Fuel complying with this standard also applies to the same or a similar system
Stationary diesel engines and other vessels made machinery.
This standard specifies four distillate fuel oil for ships and 6 residual fuel oil. Wherein the distillate fuel for diesel emergency DMX
When in use.
Note 1. The purpose of this standard, "oil" is a term including tar sands and oil shale oil.
NOTE 2. Marine Gas Turbine Fuel technical requirements are specified in GB/T 29114 [1] in.
Note 3. The standard "sea [ocean] ship" means GB/T 7727.1-2008 [2] in 3.1. suitable for sailing boats in the ocean area.
2 Normative references
The following documents for the application of this document is essential. For dated references, only the dated version suitable for use herein
Member. For undated references, the latest edition (including any amendments) applies to this document.
GB 190 packaging and marking of dangerous goods
GB/T 260 Petroleum products - Determination of water content
GB/T 261 Flash Point by Pensky - Martens closed cup method (GB/T 261-2008, ISO 2719.2002, MOD)
GB/T 265 Petroleum products - Determination of kinematic viscosity and dynamic viscosity calculation
GB/T 384 Petroleum products - Determination of calorific value
GB/T 387 Black petroleum products - Determination of sulfur content (tube furnace method)
GB/T 508 Petroleum products - Determination of ash (GB/T 508-1985, eqvISO 6245. 1982)
GB/T 1884 crude oil and liquid petroleum products - Laboratory determination of density (density meter method) (GB/T 1884-2000, eqv
ISO 3675.1998)
GB/T 1885 Petroleum Measurement Tables (GB/T 1885-1998, eqvISO 91-2.1991)
GB/T 3535 Petroleum products - Determination of pour point (GB/T 3535-2006, ISO 3016-1994, MOD)
GB/T 4756 petroleum liquids hand sampling method (GB/T 4756-1998, eqvISO 3170. 1988)
GB/T 6986 Petroleum Determination of cloud point
GB/T 7304 Petroleum products - Determination of acid number potentiometric titration
GB/T 11137 Black petroleum products - Determination of kinematic viscosity (reverse - flow method) and calculation of dynamic viscosity
GB/T 11140 Petroleum products - Determination of sulfur content wavelength dispersive X-ray fluorescence spectrometry
GB/T 12575 Determination of vanadium content of liquid fuel (flameless atomic absorption spectrometry)
GB 13690 chemical classification and hazard communication General
GB/T 17040 Petroleum and petroleum products Determination of sulfur content - Energy Dispersive X-ray Fluorescence Spectrometry
GB/T 17144 Petroleum products - Determination of carbon residue (micro method) (GB/T 17144-1997, eqvISO 10370.1993)
GB/T 20828 diesel fuel transfer combination biodiesel (BD100)
GB/T 23801 middle distillate oil fatty acid methyl ester content - Infrared Spectroscopy
GB 30000.7-2013 Classification and Labelling of chemicals - Part 7. Flammable liquid
SH0164 petroleum product packaging, storage and delivery acceptance rules
SH/T 0172 Petroleum products - Determination of sulfur content (high temperature method)
SH/T 0175 Determination of oxidation stability of distillate fuel (acceleration method)
SH/T 0253 light petroleum products - Determination of total sulfur (power law)
SH/T 0604 crude oil and petroleum products densitometry (U-tube vibration method) (SH/T 0604-2000, eqvISO 12185.
1996)
SH/T 0689 and light hydrocarbon fuel and other oil products - Determination of total sulfur (UV fluorescence)
SH/T 0694 middle distillate fuel cetane index calculation method (four variable equation) (SH/T 0694-2000, eqvISO
4264.1995)
SH/T 0701 total residual fuel oil precipitate assay (hot filtration) (SH/T 0701-2001, eqvISO 10307-1.1993)
SH/T 0702 total residual fuel oil precipitate assay (aging method) (SH/T 0702-2001, eqvISO 10307-2.1993)
SH/T 0706 aluminum and silicon content of fuel oil assay (inductively coupled plasma atomic emission spectrometry and atomic absorption spectrometry)
(SH/T 0706-2001, eqvISO 10478.1994)
SH/T 0715 crude oil and residual fuel oil, nickel, vanadium, iron determination method (inductively coupled plasma atomic emission spectrometry)
SH/T 0765 diesel lubricity evaluation method (high-frequency reciprocating rig method) (SH/T 0765-2005, ISO 12156-1.1997,
MOD)
NB/SH/T 0842 gasoline and diesel sulfur content single wavelength dispersive X-ray fluorescence spectrometry
ISO 8216-1.2010 Petroleum products - Fuels (F category) classification - Part 1. Marine fuel type (Petroleum
products-Fuels (classF) classification-Part 1. Categoriesofmarinefuels)
ISO 14597 Petroleum products - Determination of vanadium and nickel (Wavelength Dispersive X- ray fluorescence spectrometry) (Petroleumproducts-
Determinationofvanadiumandnickelcontent-WavelengthdispersiveX-rayfluorescencespectrome-
try)
IP501 residue fuel oil, aluminum, silicon, vanadium, nickel, iron, sodium, calcium, zinc and phosphorus measured ashing, fusion and inductively coupled plasma emission
Spectroscopy (Determinationofaluminium, silicon, vanadium, nickel, iron, sodium, calcium, zincand-
phosphorusinresidualfueloilbyashing, fusionandinductivelycoupledplasmaemissionspectrome-
try)
IP570 fuel of hydrogen sulfide was measured fast liquid extraction (Determinationofhydrogensulfideinfuel
oils-Rapidliquidphaseextractionmethod)
3 Classification and designation
Accordance with the standards ISO 8216-1.2010 Group D into the marine fuel oil (distillate fuel) and the R group (residual fuel) two categories. its
The distillate fuel is divided into four kinds of DMX, DMA, DMZ and DMB etc; residual fuel into RMA, RMB, RMD, RME, RMG and
RMK other six species.
According to the sulfur content of distillate fuel into Ⅰ, Ⅱ, Ⅲ three levels; RMA and RMB according to the sulfur content of residual fuel categories are divided into Ⅰ, Ⅱ, Ⅲ
Three levels, RMD, RME, RMG and RMK residual fuel is divided into two levels.
4 requirements and test methods
4.1 This standard specifies the test methods in accordance with the detection, marine fuel oil should be in accordance with Table 1 or Table 2 of performance requirements.
4.2 fuel oil should be homogeneous mixture made from petroleum hydrocarbons, do not rule out certain properties and characteristics to improve fuel oil and added added
Agent. Fuel oil should be free of inorganic acids and used lubricants.
Note. See Appendix K.
4.3 fuel oil can not contain any substance that may cause a ship to use the exception.
4.4 DMX, DMA, DMZ, DMB distillate fuel oil should not exceed contain "trace" of the fatty acid methyl esters from biological materials
(FAME) (FAME comply with GB/T 20828 requirements). It does not allow the incorporation of artificial FAME.
Note. See Appendix A.
4.5 fuel oil should not be artificially added to the following potential effects of any additives or chemical waste.
a) endanger the safety of ships or adversely affect the mechanical properties;
b) detrimental to health;
c) increase in air pollution.
Note. See Appendix B.
5 Inspection Rules
5.1 Inspection Classification and test items
5.1.1 factory inspection
Batches of the factory inspection items include. kinematic viscosity, density, cetane index, sulfur content, acid value, flash point, water, 10% distilled residue carbon residue,
Carbon residue, pour point, cloud point, appearance, lubricating, carbon aromaticity index (CCAI).
In raw materials, production process is not likely to affect the quality of the product changes, the factory periodic inspection items include. oxidation stability, ash
, And the total precipitate (hot filtration), total precipitate (aging process), vanadium, sodium, aluminum and silicon, the net calorific value of the item, measured at least once every quarter.
NOTE. Hydrogen sulfide negotiated by both parties if detected.
5.1.2 Type inspection
Type test items to Chapter 4, Table 1 or Table 2, all of the specified items.
Type tested under the following conditions.
a) production of new products or appraisement time;
b) raw materials, production processes and other large changes that may affect product quality time;
c) the factory inspection results are quite different and the last type test results.
5.2 Batch
In the raw materials and the production process under the same conditions, each producing a jar batch.
5.3 Sampling
According to GB/T 4756 were, taken as a test sample 3L and retention samples.
5.4 determine the rules
Factory inspection and type test results comply with all relevant technical requirements of Chapter 4, it is determined that batch of qualified products.
5.5 reinspection rules
Such as factory inspection and type test results do not meet the requirements set out in Chapter 4 when, according to the provisions of GB/T 4756 from the same batch of product re
Double the amount of the sample drawn for the project failed reinspection, the reinspection results as not meet the requirements, then determine whether the product is defective.
6 packaging, labeling, transportation and storage
Marine fuels are flammable liquids according to the relevant provisions of GB 13690 and GB 190 were other products packaging, labeling, transportation
Transport, storage and delivery acceptance All products by SH0164.
7 Security
Marine fuels are flammable liquids, the danger warning note in Appendix D. The GB 30000.7-2013
1 marine distillate fuel requirements and test methods table
project
index
DMX DMA DMZ DMB
experiment method
Kinematic viscosity (40 ℃)/(mm2/s) is not greater than
not less than
5.500
1.400
6.000
2.000
6.000
3.000
11.00
2.000
GB/T 265
Density/(kg/m3) (one of the following requirements)
Not more than 15 ℃
Not more than 20 ℃
- 890.0
886.5
890.0
886.5
900.0
896.5
GB/T 1884 and
GB/T 1885a
Cetane index of not less than 45 40 40 35 SH/T 0694
Sulfur content b (mass fraction) /% ≤
1.00
0.50
0.10
1.00
0.50
0.10
1.00
0.50
0.10
1.50
0.50
0.10
GB/T 17040c
Flash point (closed)/℃ no lower than 60.0 60.0 60.0 60.0 GB/T 261 (Step A)
Hydrogen sulfide d/(mg/kg) of not more than 2.00 2.00 2.00 2.00 IP570 (Step A)
Acid value (in dollars KOH)/(mg/g) is not greater than 0.5 0.5 0.5 0.5 GB/T 7304
Total deposits (hot filtration) (mass fraction) /% not more than - - - 0.10e SH/T 0701
Oxidation stability/(mg/100mL) is not greater than 2.5 2.5 2.5 2.5f SH/T 0175
10% distilled residue of carbon residue (mass fraction) /% ≤
Carbon residue (mass fraction) /% ≤
0.30
0.30
0.30
0.30
GB/T 17144
Cloud point/℃ no more than -16 - - - GB/T 6986
Pour point g/℃ no higher than
winter
summer
---6
-6
GB/T 3535
Appearance Clear he, f, i visually
Water (volume fraction) /% not more than - - - 0.30e GB/T 260
Ash (mass fraction) /% ≤ 0.010 0.010 0.010 0.010 GB/T 508
Table 1 (continued)
experiment method
Lubrication
Corrected wear scar diameter (WS1.4) (60 ℃)/μm of not more than
520 520 520 520j SH/T 0765
a measuring method also includes SH/T 0604, disputed results in GB/T 1884 and GB/T 1885 for the arbitration method.
b although given the limits which the buyer should be limited in accordance with relevant laws and regulations of ship travel area determines the maximum sulfur content, see Appendix C.
c assay method also includes GB/T 387, GB/T 11140, SH/T 0172, SH/T 0253, SH/T 0689, NB/SH/T 0842, disputed results
When to GB/T 17040 for the arbitration, the parties recognized before the test using sulfur standard substances syndrome.
d See Appendix D, the project negotiated by both parties if detected.
e If the sample is opaque, asked to do a total precipitate (hot filtration) and test water, if the sample is transparent, the total precipitate (hot filtration) and moisture test can be
To do.
f If the sample is opaque, oxidation stability tests can not, oxidation stability limits do not apply, you should determine the total precipitate (hot filtration).
g Buyer shall ensure that the pour point requirements for shipboard equipment. Especially the ship running in cold weather conditions.
h sample injection 100mL graduated cylinder, at a temperature of 20 ℃ ~ 25 ℃, in the light of good places (non-glare and darkness) observation, there should be no visible precipitate
And water.
i If the sample opacity, lubricity test can not do, lubrication limit does not apply.
j This requirement applies to a sulfur content of less than 0.050% (500mg/kg) crystal clear fuel.
Appendix A
(Informative)
Biological products and fatty acid methyl esters (FAMEs)
A.1 biofuels and mixtures thereof
Because of the mixture of fuel and bio-fuels and bio-oil products are renewable and can reduce greenhouse gases and SOx emissions, and are
Some sectors Shipbuilding division in the potential range in alternative energy.
Present a large number of bio-fuel is exchanged through an ester reaction product, i.e. removal of ester component to produce fatty acid methyl ester, usually called
Biodiesel. Biodiesel may also contain fatty acid ethyl esters (FAEEs), their test methods and specifications are studying development.
Biofuels can also be produced by other processing methods; however, not on the use of biofuels by the general ship systems and equipment
Experience, so this standard does not express the problem, but an overview of the place in some biological FAME FAME fuel is forced to use,
Some of the problems encountered on the market.
NOTE. FAME defined in GB/T 20828.
Although FAME has good fire resistance, lubricity and easy environment to accept, but there are potential special ship environment, storage and handling
Special problems, such as.
--- Easily oxidized long-term storage;
--- Easy to absorb water and microbial growth;
--- Low temperature fluidity deterioration;
--- FAME easily deposited on the exposed surfaces, including the filter element.
In addition, FAME products from different sources, each with its own storage, handling, processing, and other aspects of engine operation and emission characteristics
Particularity.
In case you intend to use fuel containing FAME, the ship should ensure that the storage, handling, processing, ancillary equipment and mechanical systems to
And any other system components (such as oil and water separator system) and the kind of product compatibility.
This standard is specific to only raw materials derived from petroleum, and therefore does not include any biological materials. However, under the existing supply logistics case,
FAME diesel and heating oil mixed with practice, so that the ship market almost inevitably some distillate fuel containing
FAME, even as refinery processing or mixing materials containing FAME fraction cause some residual fuel oil may contain FAME.
A.2 Preventive Measures
A.2.1 ship within range of the environment, there is no universal experience relating to the storage, handling, processing and use of properties (including outboard handling), and sit
Consider using a mixture of FAME and petroleum products or 100ME safety prevention regulations. In addition, marine engines and other objects
Before using the equipment [such as oil and water separator (OWS) or outside the ship loading and unloading detector (ODM)] aspect, FAME product potential impact,
Therefore, the standard limit FAME content is "micro" level.
Note. See 4.4.
A.2.2 far, it is not easy to determine the "trace" of values.
--- On the market of products obtained from different sources of FAME, many types;
--- Since the refinery, fuel terminal or other public facility supply equipment and pipelines, there may be due to contamination caused by this value
Variety;
--- FAME detection products and related by-products of various analytical techniques there is no standard method for;
--- Under most circumstances, the impact on ship product on FAME fuel system has not yet been sufficient information.
A.2.3 use of this standard.
--- For distillate fuel (DMX, DMA, DMZ and DMB), when it is clear, according to GB/T 23801 Method Detection
Data volume fraction of not more than 0.5% of cases, are considered to be "trace";
--- For not crystal clear DMB products and all residual fuel oil, can not represent its "trace" use value, because there is no
Precision test method used. Thus, by the supply chain contamination should be treated.
A.2.4 fuel producers and suppliers should determine control in place to comply with Chapter 4, when the final delivery of fuel oil
Claim.
Appendix B
(Informative)
Harmful Substance
The exclusion criteria as specified in Chapter 4 of the incorporation of hazardous substances in the marine fuel oil should not be mixed in the presence of such substances. Not straight
Then given the determination of hazardous substances or the amount of hazardous materials, for the following reasons.
a) Each fuel oil is a complex mixture of hydrocarbons-specific;
b) various sources of raw materials can enter the marine fuel supply chain through the production, processing and transportation systems;
c) Due to the refinery, fuel terminal or other public facility supply equipment and pipelines, there may be various amounts of fuel oil pollution
Pollutants;
d) detection of these pollutants and various types of special chemical analytical techniques is no standard method for;
Under e) In most cases, there is no sufficient data to prove any one particular pollutant or a mixture of ship machinery systems,
Crew or the environment.
Thus, in addition to the requirements of this standard are listed on the provision of fuel oil cargo each submitted detailed chemical analysis is unrealistic. for
The method is to ask on behalf of the refinery, fuel terminals, or any other supply facilities, including supply barges, trucks, there are quality assurance and exchange
Management procedures to ensure compliance with Chapter 4, on the exclusion of hazardous substances requirements.
Appendix C
(Informative)
Sulfur content
IMO (International Maritime Organization) Convention on the Prevention of Pollution (ie revised MARPOL Annex Ⅵ) Ships provides marine vessels using fuel
The maximum sulfur content of fuel oil, or allow the use of technology and methods to ensure compliance with emission regulations sulfur oxides (SOx) and particulate matter. Accordingly fraction
Sulfur content of fuel oil and residual fuel oil both directly by the statute of limitations requirements. Countries have developed a ship pollutant emissions regulations,
China has also been put forward appropriate regulatory requirements. The standard limits the sulfur content of distillate fuel provides three levels in which the stage Ⅰ
ISO /CD8217.2015 Marine distillate fuel sulfur content requirements consistent, Ⅱ level in line with IMO prepared in 2020 (or 2025) with the ship
In the general area of the fuel sulfur content requirements, consistent with the current stage Ⅲ ship traveling in SOx Emission Control Area (SECA) within sulfur fuel oil
Content of the request. Residual fuel sulfur content depends on the sulfur content of harmonic components of the oil, residual fuel oil in accordance with the current domestic market situation and environmental protection
Increase requested, this revision will be divided into Ⅰ residual fuel sulfur content level (in line with current IMO ship traveling in the general area of the sulfur-containing fuel oil
Volume requirements), grade Ⅱ [prepared in accordance with IMO in 2020 (or 2025) in the general area of the ship with fuel sulfur content requirements], Ⅲ
Level [in line with the current ship traveling in SOx Emission Control Area (SECA) in the sulfur content of fuel oil requirements].
Therefore, the responsibility of the buyer of fuel oil in accordance with the design of marine engine emissions regulations, equipment and fuel to be used in the existing area
Regulatory restrictions, to determine the maximum sulfur content of fuel oil.
Appendix D
(Informative)
Hydrogen sulfide
Hydrogen sulfide is a highly toxic gas that is dangerous to human exposure to high concentrations of hydrogen sulfide gas, the extreme cases be fatal. At very low concentration
Have a special egg odor of rot at high concentrations can cause loss of smell, headache, dizziness, at very high concentrations will die immediately.
Hydrogen sulfide can be formed in the refining process, but also in storage tanks, barges and product users (consumption) of fuel in the tank gradually.
Hy...
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