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Standard test method for total copper in antifouling paints
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Basic data
| Standard ID | GB/T 31409-2015 (GB/T31409-2015) |
| Description (Translated English) | Standard test method for total copper in antifouling paints |
| Sector / Industry | National Standard (Recommended) |
| Classification of Chinese Standard | G50 |
| Classification of International Standard | 87.04 |
| Word Count Estimation | 10,193 |
| Date of Issue | 2015-05-15 |
| Date of Implementation | 2015-10-01 |
| Quoted Standard | GB/T 1725-2007; GB/T 3186; GB/T 6682-2008 |
| Regulation (derived from) | National Standard Announcement 2015 No. 15 |
| Issuing agency(ies) | General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China |
| Summary | This Standard specifies the test method for the determination of total copper antifouling paint content, comprising: a principle of the method, reagents, equipment, sampling, experimental procedure, test analysis, the results of calculations, test reports. Test methods specified in this standard includes the following two: a) Method A |
GB/T 31409-2015: Standard test method for total copper in antifouling paints
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Standard test method for total copper in antifouling paints
ICS 87.040
G50
National Standards of People's Republic of China
Marine antifouling paints - Determination of total copper
Issued on. 2015-05-15
2015-10-01 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Foreword
This standard was drafted in accordance with GB/T 1.1-2009 given rules.
This standard by the National Standardization Technical Committee paint pigment (SAC/TC5) centralized.
This standard was drafted. China Shipbuilding Industry Corporation seventh twenty-five Institute, CNOOC Changzhou Paint Chemical Research Institute Co.,
Pang Beijie Paint (Kunshan) Co., Jotun COSCO Marine Coatings Co., Ltd., Haihong elderly Paint (China) Co., Ltd., Shanghai International oil
Paint Co., Ltd., Shanghai Coatings Technology Center.
The main drafters of this standard. Yao Jinghua, Zhu Yijun, Suchun Hai, Yang Lin, Wang Jian, Lirong Jun, dangerous Chunyang, Sun Ling, REN Tao, Tao Naiwang.
Marine antifouling paints - Determination of total copper
1 Scope
This standard specifies the test method for the determination of total copper antifouling paint content, comprising. a principle of the method, reagents, equipment, sampling, laboratory
Step, test and analysis, the results of calculations, test reports.
Test methods specified in this standard includes the following two.
a) Method A. electrophoresis electrode;
b) Method B. Atomic Absorption Spectrometry.
2 Normative references
The following documents for the application of this document is essential. For dated references, only the dated version suitable for use herein
Member. For undated references, the latest edition (including any amendments) applies to this document.
Determination matter content GB/T 1725-2007 Paints, varnishes and plastics non-volatile
GB/T 3186 Paints, varnishes and raw materials for paints and varnishes - Sampling
Laboratory use specifications and test methods GB/T 6682-2008 Analysis
3 PRINCIPLE OF THE METHOD
Method A. Weigh a certain amount of paint samples in the beaker to evaporate the solvent to remove organics which burned at 600 ℃ get dry
Gray, then adding an acid to digest, after dilution dissolved, insolubles were removed by filtration, the filtrate was electrolysis to precipitate copper attached to the platinum electrode.
Calculate the mass percentage of copper deposited to obtain the number of the total content of copper, which can be in terms of the content of the original copper compound.
Method B. antifouling paint dry sample with a suitable acid solution was sealed microwave digestion, the rush acid, constant volume after treatment, using flame atomic absorption
Spectroscopy or income to meet current and effective method for testing the accuracy of the analysis of each sample of the total copper content can be obtained in the antifouling paint
The percentage of the total content of copper or copper quality.
4 Reagents
Unless otherwise indicated, the reagents used in the analysis were of analytical grade water to comply with GB/T 6882-2008 requirements for secondary water. The standard
Reagents quasi involved are as follows.
4.1 Method A
The reagents used.
a) nitric acid, ρ about 1.42g/mL;
b) perchloric acid, the mass fraction of from 69% to 72%;
c) an alcohol or acetone;
d) ammonium sulfate.
4.2 Method B
The reagents used.
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