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US$229.00 · In stock Delivery: <= 3 days. True-PDF full-copy in English will be manually translated and delivered via email. HYT263-2018: Determination of dissolved nitrous oxide in seawater. Headspace equilibrium gas chromatography method Status: Valid
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| HY/T 263-2018 | English | 229 |
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Determination of dissolved nitrous oxide in seawater. Headspace equilibrium gas chromatography method
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HY/T 263-2018
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Basic data | Standard ID | HY/T 263-2018 (HY/T263-2018) | | Description (Translated English) | Determination of dissolved nitrous oxide in seawater. Headspace equilibrium gas chromatography method | | Sector / Industry | Marine Industry Standard (Recommended) | | Classification of Chinese Standard | Z17 | | Classification of International Standard | 07.060; 13.060 | | Word Count Estimation | 10,174 | | Date of Issue | 2018-07-30 | | Date of Implementation | 2018-11-01 | | Regulation (derived from) | Ministry of Natural Resources Announcement No. 30 of 2018 | | Issuing agency(ies) | Ministry of Natural Resources of the People's Republic of China | | Summary | This standard specifies the principle, analysis steps and calculation of the method for the determination of dissolved nitrous oxide (N2O) in seawater by headspace equilibrium-gas chromatography. This standard is applicable to the determination of dissolved N2O concentration in offshore, oceanic and polar seawater. The measurement range is 5 nmol��L^(-1)��300 nmol��L^(-1). |
HYT263-2018: Determination of dissolved nitrous oxide in seawater. Headspace equilibrium gas chromatography method ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Determination of dissolved nitrous oxide in seawater.Headspace equilibrium gas chromatography method
ICS 07.060; 13.060
Z17
People's Republic of China Marine Industry Standard
Determination of dissolved nitrous oxide in seawater
Headspace balance-gas chromatography
Published on.2018-07-30
2018-11-01 implementation
Ministry of Natural Resources of the People's Republic of China
Foreword
This standard was drafted in accordance with the rules given in GB/T 1.1-2009.
This standard was proposed by the Ministry of Natural Resources of the People's Republic of China
This standard is under the jurisdiction of the National Marine Standardization Technical Committee (SAC/TC283).
This standard was drafted. National Marine Environmental Monitoring Center, Yantai Marine Environmental Monitoring Center Station of the State Oceanic Administration.
Drafters of this standard. Zhao Huade, Yan Kunpeng, Wang Juying, Wang Qin, Zheng Nan, Xu Xuemei.
Determination of dissolved nitrous oxide in seawater
Headspace balance-gas chromatography
1 Scope
This standard specifies the principle, analysis steps and results of the determination of dissolved nitrous oxide (N2O) in seawater by headspace equilibrium-gas chromatography.
Calculation.
This standard applies to the determination of dissolved N2O concentration in offshore, ocean and polar seawater, the measurement range is 5nmol·L-1~
300 nmol·L-1.
2 Terms and definitions
The following terms and definitions apply to this document.
2.1
Dissolved nitrous oxide dissolvednitrousoxide
The amount of N2O gas dissolved per liter of seawater.
Note. The unit is nanomolar per liter (nmol·L-1).
2.2
Headspace balance headspaceequilibrium
In a closed container, a gas-liquid system consisting of a seawater sample and a gas that does not affect the measurement result is formed, and the gas to be tested is formed
A method of achieving equilibrium in the gas-liquid two phases.
2.3
Head air headheadspacegas
In a closed vessel, the gas-liquid two phases reach the equilibrium portion of the gas phase in the headspace.
3 Principle of the method
Based on Dalton's gas partial pressure law and Henry's law, at room temperature, a gas composed of seawater samples and gases that do not affect the measurement results are formed -
The liquid-tight system is allowed to stand after shaking, so that the dissolved N2O in seawater reaches the distribution equilibrium between the gas-liquid two phases, and then determined by gas chromatography.
The concentration of N2O in the headspace gas, and the concentration of dissolved N2O in the seawater sample is calculated according to the gas-liquid two-phase volume.
4 reagents and materials
Warning - mercury chloride (HgCl2) is highly toxic, should be handled carefully, avoid direct contact, waste liquid sulfur treatment
Only deionized water or equivalent pure water was used in the analysis unless otherwise stated.
4.1 Hydrochloric acid solution (2 mol·L-1)..200 mL of concentrated hydrochloric acid (analytical grade, ρ=1.19 g·mL-1) was dissolved in 1 L of water.
4.2 13× molecular sieve. first grade, spherical type, diameter 2.0mm~2.8mm.
4.3 Silica gel. analytically pure, spherical, 4mm~8mm in diameter.
4.4 Argon Methane Gas. A mixed gas containing 5% methane and 95% argon, purified and dried by 13× molecular sieve (4.2) and silica gel (4.3).
4.5 Nitrogen (purity greater than or equal to 99.999%). Bottled with high purity nitrogen, purified and dried by 13× molecular sieve (4.2) and silica gel (4.3).
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