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HJ 993-2018: Technical guidelines of accounting method for pollution source intensity - Pesticide industry
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Technical guidelines of accounting method for pollution source intensity - Pesticide industry
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HJ 993-2018
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Standard similar to HJ 993-2018 HJ 511 HJ 945.3 HJ 943 Basic data | Standard ID | HJ 993-2018 (HJ993-2018) | | Description (Translated English) | Technical guidelines of accounting method for pollution source intensity - Pesticide industry | | Sector / Industry | Environmental Protection Industry Standard | | Word Count Estimation | 27,290 | | Date of Issue | 2018-12-25 | | Date of Implementation | 2019-03-01 | | Regulation (derived from) | Ministry of Ecology and Environment Announcement No. 69 of 2018 | | Issuing agency(ies) | Ministry of Ecology and Environment | HJ 993-2018: Technical guidelines of accounting method for pollution source intensity - Pesticide industry
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Technical guidelines of accounting method for pollution source intensity - Pesticide industry
National Environmental Protection Standard of the People's Republic
Technical Guidelines for Strong Sources of Pollution Sources Pesticide Manufacturing Industry
Technical guidelines of accounting method for pollution source intensity
Pesticide industry
Published on.2018-12-25
2019-03-01 implementation
release
Content
Foreword...ii
1 Scope...1
2 Normative references...1
3 Terms and Definitions...2
4 source strong accounting program...3
5 Strong source method for waste gas pollution sources...7
6 Wastewater pollution source and source strong accounting method...16
7 Noise source strong accounting method...18
8 Solid waste source strength accounting method...19
9 other...20
Appendix A (informative appendix) Pesticide manufacturing industry source strength accounting results and related parameters...21
Foreword
To implement the Environmental Protection Law of the People's Republic of China, the Environmental Impact Assessment Law of the People's Republic of China
Law on Prevention and Control of Atmospheric Pollution, Law of the People's Republic of China on Prevention and Control of Water Pollution, Law of the People's Republic of China on Prevention and Control of Environmental Noise Pollution
Law of the People's Republic of China on the Prevention and Control of Environmental Pollution by Solid Wastes, etc., to improve the system of strong accounting methods for fixed sources of pollution, guidance and
This standard is formulated to regulate the strong accounting of pollution sources in the pesticide manufacturing industry.
This standard stipulates the procedures, contents and accounting for the strong accounting of waste gas, wastewater, noise and solid waste pollution sources in pesticide manufacturing industry.
Methods and requirements, etc.
Appendix A of this standard is an informative annex.
This standard is the first release.
This standard is formulated by the Department of Environmental Impact Assessment and Emission Management of the Ministry of Ecology and Environment, and the Department of Regulations and Standards.
This standard is mainly drafted by. Environmental Engineering Evaluation Center of the Ministry of Environmental Protection, Shanghai Research Institute of Chemical Industry, Shenyang Chemical Research Institute
Research Institute Co., Ltd., China Pesticide Industry Association.
This standard is approved by the Ministry of Ecology and Environment on December 25,.2018.
This standard has been implemented since March 1,.2019.
This standard is explained by the Ministry of Ecology and Environment.
Technical Guidelines for Strong Sources of Pollution Sources Pesticide Manufacturing Industry
1 Scope of application
This standard stipulates the procedures, contents, methods and requirements for the strong accounting of pollution sources in the pesticide manufacturing industry.
This standard is applicable to the source strength accounting of new (reconstruction, expansion) construction projects and existing engineering pollution sources in the pesticide manufacturing industry.
This standard is applicable to the strong accounting of pollution sources during normal and abnormal discharge of pesticide manufacturing industry, and is not applicable to sudden leakage, fire, explosion.
Strong source of pollution sources in case of accidents.
This standard is applicable to the source strength accounting of waste gas, waste water, noise and solid waste pollution sources in the production process of pesticide manufacturing industry. Implementation of GB 13223
The boiler source is strongly calculated according to HJ 888, and the boiler source source of GB 13271 is calculated according to HJ 991.
2 Normative references
This standard refers to the terms of the following documents. For undated references, the valid version applies to this standard.
GB 8978 Integrated Wastewater Discharge Standard
GB 12348 industrial enterprise boundary environmental noise emission standards
GB 13223 Standard for emission of atmospheric pollutants from thermal power plants
GB 13271 Boiler Air Pollutant Emission Standard
GB 14554 Odor Pollutant Emission Standard
GB 16297 Integrated emission standards for atmospheric pollutants
GB 18484 Hazardous Waste Incineration Pollution Control Standard
GB 18597 Hazardous Waste Storage Pollution Control Standard
GB 18599 General industrial solid waste storage and disposal site pollution control standards
GB 21523 Heterogeneous pesticide industrial water pollutant discharge standard
GB 50015 Building Water Supply and Drainage Design Code
GB/T 16157 Method for sampling particulate matter and gaseous pollutants in fixed pollution source exhaust
HJ 2.1 General Outline of Technical Guidelines for Environmental Impact Assessment of Construction Projects
HJ 2.2 Technical Guidelines for Environmental Impact Assessment Atmospheric Environment
HJ 2.3 Environmental Impact Assessment Technical Guidelines Surface Water Environment
HJ 2.4 Environmental Impact Assessment Technical Guidelines Acoustic Environment
HJ 75 Fixed Pollution Source Flue Gas (SO2, NOx, Particulate Matter) Emissions Continuous Monitoring Technical Specification
HJ 76 Technical requirements and test methods for continuous monitoring system for stationary pollution source flue gas (SO2, NOx, particulate matter)
HJ/T 91 Surface Water and Wastewater Monitoring Technical Specifications
HJ/T 92 Water Pollutant Total Monitoring Technical Specification
HJ/T 353 Water Pollution Source Online Monitoring System Installation Technical Specification (Trial)
HJ/T 354 Water Pollution Source Online Monitoring System Acceptance Technical Specification (Trial)
Technical Specifications for Operation and Assessment of HJ/T 355 Water Pollution Source Online Monitoring System (Trial)
HJ/T 356 Water Pollution Source Online Monitoring System Data Validity Discrimination Technical Specification (Trial)
HJ/T 373 Technical Specifications for Quality Assurance and Quality Control of Fixed Pollution Source Monitoring (Trial)
HJ/T 397 Fixed Source Exhaust Gas Monitoring Technical Specification
HJ 582 Technical Guidelines for Environmental Impact Assessment Pesticide Construction Project
HJ 630 Environmental Monitoring Quality Management Technical Guidelines
HJ 862 Sewage Permit Application and Issuance Technical Specification Pesticide Manufacturing Industry
HJ 884 Guidelines for the Guidelines for Sources of Pollution Sources
HJ 888 Pollution Source Power Accounting Technical Guide
HJ 991 Pollution Source Power Accounting Technical Guide Boiler
HJ 2045-2014 Technical specification for petroleum refining industrial wastewater treatment engineering
3 Terms and definitions
The following terms and definitions apply to this standard.
3.1
Pesticide manufacturing industry
Refers to diseases, insects, grasses, rats and other harmful organisms used to control agricultural and forestry crops, and various chemical pesticides and micro-organisms that regulate plant growth.
Biological pesticides, biochemical pesticides, and anti-corrosion of warehousing, agricultural and forestry products, river dams, railways, airports, buildings and other places
Production activities of the original drug and preparation of the drug.
3.2
Volatile organic compounds (VOCs)
The organic compound involved in the atmospheric photochemical reaction, or the determined organic compound is measured or calculated according to the relevant regulations. according to
Industry characteristics and environmental management requirements, the method of quantitative addition of major VOCs can be selected to measure total organic compounds (to TOC)
Indicates), or by measuring the reference material, the detector measures the comprehensive response of VOCs in the mixed injection to measure non-methane organic compounds.
(in NMOC, in terms of carbon). This standard is characterized by non-methane total hydrocarbons.
3.3
Non-methane hydrocarbon
The general name of the gaseous organic compounds other than methane (in terms of carbon) using the specified monitoring method.
3.4
Abnormal discharge
Refers to the discharge of pollutants under abnormal conditions of production facilities or pollution prevention (control) measures. For example. hazardous waste incinerator start and stop
When the flue gas treatment system is abnormally discharged, or other process equipment is abnormally operated, the pollution prevention and control facilities fail to achieve the proper treatment efficiency and operate synchronously.
Emissions under abnormal conditions such as rate.
4 source strong accounting procedures
4.1 General principles
The strong source accounting procedures include pollution source identification and pollutant determination, accounting methods and parameter selection, source strength accounting, and accounting results.
For details, see HJ 884 for details.
4.2 Identification of pollution sources
The identification of pollution sources in pesticide manufacturing industry shall comply with the technical guidelines for environmental impact assessment such as HJ 2.1, HJ 2.2, HJ 2.3, HJ 2.4 and HJ 582.
Requirements and covers all sites, equipment or equipment that may generate waste gas, wastewater, noise, solid waste.
4.3 Determination of pollutants
The determination of pollutants in pesticide manufacturing industry shall include GB 8978, GB 14554, GB 16297, GB 18484, GB 21523 and other countries.
And pollutants included in local emission standards. Contaminants that may be produced in the production process but not included in national or local emission standards,
According to environmental quality standards, other industry standards, other national emission standards, local people's governments or environmental protection departments
Good demand, based on the analysis of raw and auxiliary materials and fuel use and production process.
4.4 Accounting methods and selection
Strong accounting methods for pesticide production industry pollution sources include material balance algorithm, analogy method, actual measurement method and pollution coefficient method, etc. Source strong accounting method
It should be selected in order of priority, as shown in Table 1. If the priority method cannot be used, reasonable reasons should be given.
Table 1 source strength accounting method selection order table
Element pollution source pollutant
Accounting method and priority order
New (reform, expansion) construction
Process pollution source
Existing engineering pollution source b
Exhaust gas
Group
Weaving
Source
Original drug production waste gas
Sulfur dioxide
Material balance algorithm
2. Analogy
3. Pollution coefficient method
Measured method
Hydrogen chloride, hydrogen fluoride, hydrogen cyanide, hydrogen sulfide,
Ammonia, sulfuric acid mist, phosgene, chlorine, volatile
Organic matter, characteristic pollutants, etc.
Material balance algorithm
2. Analogy
3. Pollution coefficient method
Measured method
Particulate matter, nitrogen oxides
Analogy method
2. Pollution coefficient method
Measured method
Preparation processing, packaging waste
Volatile organic compounds, characteristic pollutants, etc.
Material balance algorithm
2. Analogy
3. Pollution coefficient method
Measured method c
Particle analog method
Incinerator tail gas
Soot, nitrogen oxide analog method
Carbon monoxide, hydrogen chloride, hydrogen fluoride, two evil
British class
Analogy method
Mercury and its compounds, cadmium and its compounds, lead
And its compounds, arsenic, nickel and their compounds,
Chromium, tin, antimony, copper, manganese and their compounds
Material balance algorithm
2. Analogy
3. Pollution coefficient method
Measured method
Sulfur dioxide material balance algorithm measurement method
Wastewater treatment station has a group
Weaving exhaust
Analogue method for hydrogen sulfide, ammonia, volatile organic compounds, etc.
Analogous method for measuring volatile organic compounds in waste gas during temporary storage
No group
Weaving
Source
Process unorganized
Emissions
Particulate matter, hydrogen chloride, hydrogen fluoride, hydrogen cyanide,
Hydrogen sulfide, ammonia, sulfuric acid mist, chlorine, volatilization
Sexual organic matter, characteristic pollutants, etc.
Material balance algorithm
2. Pollution coefficient method
Material balance algorithm
2. Pollution coefficient method
Equipment static sealing point
exhaust
Volatile organic compounds
Pollution coefficient method
2. Analogy
Actual measurement method
2. Pollution coefficient method
Volatile organic liquid
Storage of exhaust gas
Volatile organic compounds, characteristic pollutants, a material balance algorithm, material balance algorithm
Volatile organic liquid
Loading and unloading exhaust
Volatile organic compounds, characteristic pollutants, a material balance algorithm, material balance algorithm
Wastewater collection, storage, storage,
No treatment process
Tissue exhaust
Volatile organic compounds
Material balance algorithm
2. Pollution coefficient method
Material balance algorithm
2. Pollution coefficient method
Other unorganized
Emissions
Volatile organic compounds, characteristic pollutants, etc.
Material balance algorithm
2. Pollution coefficient method
3. Analogy
Material balance algorithm
2. Pollution coefficient method
3. Analogy
Abnormal operating conditions
Particle and NOx analog method
Sulfur dioxide, hydrogen chloride, hydrogen fluoride, cyanide
Hydrogen, hydrogen sulfide, ammonia, sulfuric acid mist, chlorine,
Volatile organic compounds, characteristic pollutants, etc.
Material balance algorithm
2. Analogy
Actual measurement method
2. Material balance algorithm
Waste water
Process wastewater from various facilities and production facilities
Characteristic pollutant a
Material balance algorithm
2. Analogy
3. Pollution coefficient method
Measured method c
Suspended matter, chemical oxygen demand, five-day biochemical needs
Oxygen, total organic carbon, ammonia nitrogen, total nitrogen, total
Analogy method
2. Pollution coefficient method
Measured method c
Workshop or production facility wastewater discharge
Total mercury, alkyl mercury, total cadmium, total chromium, hexavalent
Chromium, total arsenic, total lead, total nickel, benzo[a]pyrene,
Total 总, total silver
Material balance algorithm
2. Analogy
3. Pollution coefficient method
Measured method c
Continued
Element pollution source pollutant
Accounting method and priority order
New (reform, expansion) construction
Process pollution source
Existing engineering pollution source b
Waste water
Ground and equipment flushing water
Initial pollution rain
Suspended matter, chemical oxygen demand, five-day biochemical needs
Oxygen, total organic carbon, ammonia nitrogen, total nitrogen, total
Phosphorus, characteristic pollutants, etc.
Analogy method
2. Pollution coefficient method
Measured method c
Auxiliary facilities such as circulating cooling system
Water, domestic sewage
Suspended matter, chemical oxygen demand, five-day biochemical needs
Oxygen, ammonia nitrogen, total nitrogen, animal and vegetable oil
Analogy method
2. Pollution coefficient method
Measured method c
Waste water discharge
Characteristic pollutant a, total mercury, alkyl mercury, total cadmium,
Total chromium, hexavalent chromium, total arsenic, total lead, total nickel,
Benzo[a]pyrene, total strontium, total silver
Material balance algorithm
2. Analogy
3. Pollution coefficient method
Measured method
Suspended matter, chemical oxygen demand, five-day biochemical oxygen demand
Amount, total organic carbon, ammonia nitrogen, total nitrogen, total phosphorus
Analogy method
2. Pollution coefficient method
Measured method
Noise production equipment and facilities noise level analogy method
solid
waste
Production equipment and facilities
General industrial solid waste 1. Material balance algorithm
2. Analogy
3. Pollution coefficient method
Actual measurement method
2. Material balance algorithm hazardous waste
a Characteristic pollutants and their control shall comply with national, industrial or local pollutant discharge standards and HJ 582 requirements. The place has strict management requirements, from which it is required.
b Existing project pollution sources are not manually monitored according to relevant management requirements, automatic monitoring equipment for installation of pollutants or automatic monitoring equipment does not meet the requirements, the environment
In the process of impact evaluation and management, it shall be calculated according to the method in this table after rectification according to law; in the process of management of sewage discharge permit, the nuclear shall be carried out in accordance with the relevant provisions of the discharge permit.
Count.
c When the existing project pollution sources are strongly accounted for, when there are multiple sources of the same type of pollution for the same enterprise, other sources of pollution can be compared with the same type of pollution source.
The calculation source is strong.
4.4.1 Exhaust gas
4.4.1.1 New (reconstruction, expansion) construction project pollution source
Under normal working conditions, the original drug production waste gas, preparation processing and packaging waste gas source strong accounting, in addition to particulate matter, nitrogen oxides should be analogous and pollution
In addition to the coefficient method, other pollutants are calculated with the material balance algorithm first, followed by the analogy method and the pollution coefficient method;
Accounting, sulfur dioxide should be based on the material balance algorithm, soot, nitrogen oxides, carbon monoxide, hydrogen chloride, hydrogen fluoride, dioxins should be used
Analogy, other heavy metal pollutants can be preferentially used in the material balance algorithm, followed by the analogy method and the pollution coefficient method. Wastewater treatment station, dangerous
The analogy method should be adopted for the strong accounting of organized waste gas sources such as waste temporary storage.
The strong accounting of unorganized exhaust gas sources can be calculated by means of material balance algorithm, pollution coefficient method and analogy method. Process unorganized exhaust gas source
Strong balance calculation should adopt the material balance algorithm and the pollution yield coefficient method. The strong calculation of the exhaust gas source of the equipment static and dynamic sealing point should adopt the pollution production coefficient method and the analogy method. Swing
The material balance algorithm should be used for the strong accounting of the storage and handling of the organic liquid. Wastewater collection, storage, treatment and disposal process
The source strength calculation should use the material balance algorithm and the pollution yield coefficient method.
Under the normal working conditions, the source of exhaust gas pollution is strongly accounted for, the particulate matter and nitrogen oxides are analogous, and other pollutants are preferentially used for material balance.
Law, followed by analogy.
4.4.1.2 Existing engineering pollution sources
The actual calculation method for the strong source of organized exhaust gas pollution in existing projects should be measured. When the actual emission is calculated by the actual measurement method, the pesticide is manufactured.
Technical specifications such as self-monitoring technical guidelines for industrial pollutant discharge units require the use of automatically monitored pollutants, and only effective automatic monitoring data can be used.
Carry out accounting. For the technical specifications such as the self-monitoring technical guide of the pollutant discharge unit, the automatic monitoring of pollutants is not required, and the automatic supervision is preferred.
The measured data is followed by manual monitoring data, including supervisory monitoring data and self-monitoring data by the pollutant discharge unit. If at the same time
The manual monitoring data is inconsistent with the supervisory monitoring data, which is subject to the monitoring data.
The strong calculation of the sources of unorganized exhaust gas pollution in existing projects can be carried out by means of material balance algorithm, pollution yield coefficient method and analogy method. Process unorganized
The material balance algorithm and the pollution yield coefficient method should be adopted for the strong accounting of the exhaust gas source. The dynamic calculation of the exhaust gas source of the equipment static and dynamic sealing point should adopt the actual measurement method and the pollution generation.
Coefficient method. The material balance algorithm should be used for the strong accounting of volatile organic liquid storage and handling. Wastewater gathering, storage, treatment and disposal process
The material balance algorithm and the pollution yield coefficient method should be adopted for the strong calculation of unorganized exhaust gas source.
In the existing engineering, the exhaust gas source is strongly accounted for under abnormal conditions, and the actual measurement method is preferred, followed by the material balance algorithm and the analogy method.
4.4.2 Waste water
4.4.2.1 New (reconstruction, expansion) construction project pollution source
Under normal and abnormal conditions, the new source (reconstruction, expansion) construction wastewater pollution source source is usually preferred to use the material balance algorithm.
Secondly, the analogy method and the pollution coefficient method are adopted. Suspended matter, chemical oxygen demand, five-day biochemical oxygen demand, ammonia nitrogen, total nitrogen, total phosphorus and plants and animals
Contaminants such as oil can be preferentially used, followed by the pollution coefficient method.
4.4.2.2 Existing engineering pollution sources
The actual calculation of the source of existing engineering wastewater pollution should be based on the actual measurement method. When using the actual measurement method, the self-monitoring unit for the pesticide manufacturing industry
Technical specifications such as technical guidelines require the use of automatically monitored contaminants, which can only be accounted for using effective automated monitoring data. For sewage orders
Technical specifications such as self-monitoring technical guidelines do not require the use of automatically monitored pollutants, priority is given to automatic monitoring data, followed by manual
Monitoring data, including supervisory monitoring data and self-monitoring data by the emitters themselves. If the manual monitoring data and supervision of the same period
Sexual monitoring data is inconsistent, subject to monitoring data.
4.4.3 Noise
4.4.3.1 New (reconstruction, expansion) construction of pollution sources
The strong source of noise pollution is calculated by analogy.
4.4.3.2 Existing sources of pollution
The strong source of noise pollution is measured by the actual method.
4.4.4 Solid waste
4.4.4.1 New (reformed, expanded) pollution sources
The industrial solid waste source strength calculation adopts the material balance algorithm first, followed by the analogy method and the pollution production coefficient method.
4.4.4.2 Existing sources of pollution
The industrial solid waste source strength calculation takes precedence over the actual measurement method, followed by the material balance algorithm.
4.5 Parameter selection
The engineering design data can be selected for the strong accounting parameters of the new (reconstruction and expansion) construction equipment or facility pollution sources. Existing engineering production equipment
Or the strong accounting parameters of the facility pollution sources can take effective monitoring data during the accounting period.
4.6 Source strength accounting
According to the accounting result of pollutant production, combined with the effect of the treatment measures adopted (considering the collection rate and removal rate), adopt the formula (1)
Calculate pollutant emissions.
1E D 去除 Remove emissions to generate collection ( )
(1)
Where. E emissions - pollutant emissions, t;
D produces - the amount of pollutants produced, t;
η collection - collection efficiency of pollutants, %;
η removal - removal efficiency of pollutants, %.
The sum of emissions or emissions of waste gas, waste water and solid waste, the sum of emissions or emissions, and the source o...
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