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Self-monitoring technology guidelines for pollution sources Chemical fertilizer industry - nitrogenous fertilizer
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HJ 948.1-2018
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Standard similar to HJ 948.1-2018 HJ 947 HJ 953 HJ 946
Basic data Standard ID | HJ 948.1-2018 (HJ948.1-2018) | Description (Translated English) | Self-monitoring technology guidelines for pollution sources Chemical fertilizer industry - nitrogenous fertilizer | Sector / Industry | Environmental Protection Industry Standard | Classification of Chinese Standard | HJ | Word Count Estimation | 9,963 | Date of Issue | 2018-07-31 | Date of Implementation | 2018-10-01 | Regulation (derived from) | Ministry of Ecology and Environment Announcement No. 25 of 2018 | Issuing agency(ies) | Ministry of Ecology and Environment |
HJ 948.1-2018: Self-monitoring technology guidelines for pollution sources Chemical fertilizer industry - nitrogenous fertilizer ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Self-monitoring technology guidelines for pollution sources Chemical fertilizer industry - nitrogenous fertilizer
National Environmental Protection Standard of the People's Republic
Sewage unit self-monitoring technical guide
Fertilizer Industry - Nitrogen Fertilizer
Self-monitoring technology guidelines for pollution sources
Chemical fertilizer industry-nitrogenous fertilizer
Published on.2018-07-31
2018-10-01 implementation
Department of Ecology and Environment
Content
Foreword..ii
1 Scope 1
2 Normative references 1
3 Terms and Definitions..1
4 General requirements for self-monitoring.1
5 Monitoring plan development. 2
6 Information records and reports 5
7 other..6
Foreword
To implement the "Environmental Protection Law of the People's Republic of China", "Water Pollution Prevention and Control Law of the People's Republic of China"
The National Air Pollution Prevention and Control Law, which guides and regulates the self-monitoring work of the nitrogen fertilizer industrial pollutant discharge units, and formulates this standard.
This standard proposes the general requirements for the self-monitoring of nitrogen fertilizer industrial sewage units, the development of monitoring plans, information records and reports.
The basic content and requirements.
This standard is the first release.
This standard was proposed and organized by the Ministry of Ecology and Environment.
This standard is mainly drafted by. China Environmental Monitoring Center, Chongqing Ecological Environment Monitoring Center.
This standard is approved by the Ministry of Ecology and Environment on July 31,.2018.
This standard has been implemented since October 1,.2018.
This standard is explained by the Ministry of Ecology and Environment.
Sewage unit self-monitoring technology guide fertilizer industry - nitrogen fertilizer
1 Scope of application
This standard proposes the general requirements for the self-monitoring of nitrogen fertilizer industrial sewage units, the development of monitoring plans, information records and reports.
The basic content and requirements.
This standard is applicable to water, gas pollutants, noise and weekly emissions of nitrogen fertilizer industrial sewage disposal units during production and operation.
Monitor the impact of environmental quality.
Self-monitoring requirements for self-contained thermal power generating units (plants) and supporting power boilers shall be carried out in accordance with HJ 820.
2 Normative references
The contents of this standard refer to the following documents or their terms. For undated references, the valid version is appropriate.
Used in this standard.
GB 13458 Synthetic ammonia industrial water pollutant discharge standard
HJ 2.2 Technical Guidelines for Environmental Impact Assessment Atmospheric Environment
HJ/T 2.3 Technical Guidelines for Environmental Impact Assessment Surface Water Environment
HJ/T 91 Surface Water and Wastewater Monitoring Technical Specifications
HJ/T 194 Technical Specifications for Manual Air Quality Monitoring
HJ 442 Code for Environmental Monitoring of Coastal Waters
HJ 819 General Guidelines for Self-Monitoring Technical Units of Sewage Units
HJ 820 sewage unit self-monitoring technical guide thermal power generation and boiler
National Directory of Hazardous Wastes (Ministry of Environmental Protection, National Development and Reform Commission, Ministry of Public Security Order No. 39)
3 Terms and definitions
The following terms and definitions defined in GB 13458 apply to this standard.
Nitrogenous fertilizer industry
The nitrogen fertilizer industry includes the production of synthetic ammonia and the production of urea, ammonium nitrate, ammonium hydrogencarbonate and alcohol ammonia from synthetic ammonia.
Production enterprise or production facility.
4 General requirements for self-monitoring
The pollutant discharge unit shall check the pollution source, pollutant index and potential environmental impact of the unit, formulate a monitoring plan, and set up
And maintenance monitoring facilities, carry out self-monitoring according to the monitoring plan, do quality assurance and quality control, record and save monitoring
Data, publicly monitor the results to the public according to law.
5 Monitoring plan development
5.1 Wastewater discharge monitoring
All nitrogen fertilizer industrial sewage units must set monitoring points in their wastewater discharge outlets and rainwater discharge ports, monitoring indicators and
The minimum monitoring frequency is performed according to Table 1.
Table 1 Monitoring indicators and minimum monitoring frequency of wastewater discharge port
Monitoring point monitoring indicator
Frequency of monitoring
Direct emission indirect emissions
Waste water discharge
Flow rate, pH value, chemical oxygen demand, automatic monitoring of ammonia nitrogen
Total nitrogen day (automatic monitoring a)
Suspended matter, total phosphorus b weeks
Petroleum, sulfide c, cyanide c, volatile phenol c
Rainwater discharge pH, chemical oxygen demand, ammonia nitrogen, suspended matter day d
Note. The municipal and above-level environmental protection authorities in the district expressly require the installation of automatic pollutant monitoring equipment pollutant indicators, which must be automatically monitored.
a After the release of the technical specification for automatic nitrogen monitoring, automatic monitoring is required.
b The area where total phosphorus is controlled by total phosphorus, and the minimum monitoring frequency of total phosphorus is performed on a daily basis.
c The monitoring frequency of sulfide, cyanide and volatile phenol in sewage unit with natural gas as raw material is carried out year by year.
d During the discharge period, it is monitored daily.
5.2 Exhaust emission monitoring
5.2.1 Organized exhaust emission monitoring
The monitoring points, monitoring indicators and monitoring frequency of organized exhaust emissions in each production process are carried out according to Table 2.
Table 2 Organized exhaust gas discharge monitoring indicators and minimum monitoring frequency
Production process monitoring point monitoring indicators monitoring frequency
Taking coal
For the original
Preparation of coal dusty exhaust gas exhaust particles for half a year
fixed
Bed often
Coal
gasification
Process
raw material
Gas system
Hair dryer waste heat recovery system or
Three waste co-firing system exhaust pipe
Automatic monitoring of particulate matter, sulfur dioxide and nitrogen oxides
Mercury and its compounds a for half a year
Smoke blackness
Gasification wastewater sedimentation tank
Set processing facility exhaust
Ammonia, hydrogen sulfide, non-methane total hydrocarbons, phenols,
Hydrogen cyanide
Quarter
Benzo(a) ่ half a year
Gas furnace vent tube
Particulate matter, ammonia, hydrogen sulfide, non-methane total hydrocarbons,
Benzo(a)pyrene
Venting period
raw material
Gas net
Decarbonization stripping tower exhaust ammonia, hydrogen sulfide, non-methane total hydrocarbon quarter
Dry coal
Powder gas
Flow bed
gasification
Process
raw material
Gas system
Coal and drying system exhaust cylinder particulate matter, nitrogen oxides quarter
Pulverized coal conveying and pressurized feed system
Powder coal warehouse exhaust
Particulate matter quarter
Methanol b, hydrogen sulfide b years
raw material
Gas net
Low temperature methanol washing tail gas scrubber
Exhaust
Methanol, hydrogen sulfide quarter
Sulfur recovery exhaust gas exhaust
Automatic monitoring of sulfur dioxide
Sulfuric acid mist c for half a year
Water coal
Slurry
raw material
Gas net
Low temperature methanol washing tail gas scrubber
Exhaust
Methanol, hydrogen sulfide quarter
Production process monitoring point monitoring indicators monitoring frequency
Flow bed
gasification
Process
Sulfur recovery exhaust gas exhaust
Automatic monitoring of sulfur dioxide
Sulfuric acid mist c for half a year
Crushed coal
fixed
Bed plus
Pressure
Chemical industry
raw material
Gas net
Acid gas removal facility exhaust
Methanol, non-methane total hydrocarbons, sulfur dioxide, nitrogen
Oxide
Quarter
Sulfur recovery exhaust gas exhaust
Automatic monitoring of sulfur dioxide
Sulfuric acid mist c for half a year
Day
Gas
For the original
steam
Conversion
raw material
Gas system
a reformer exhaust pipe particulate matter, NOx quarter
Focus
Furnace gas
For the original
section
Conversion
raw material
Gas system
Desulfurization regeneration tank exhaust gas exhaust cylinder hydrogen sulfide, ammonia month
a reformer exhaust pipe particulate matter, NOx quarter
Oil
For the original
heavy oil
section
Oxidation
raw material
Gas net
Low temperature methanol washing tail gas scrubber
Exhaust
Methanol, hydrogen sulfide quarter
Sulfur recovery exhaust gas exhaust
Automatic monitoring of sulfur dioxide
Sulfuric acid mist c for half a year
Urea
Air scrubber (or absorption)
Tower) exhaust pipe
Ammonia quarter
Pelletizing tower or granulator exhaust cylinder particulate matter, ammonia, formaldehyde d quarter
Packaging machine exhaust pipe particulate matter year
Ammonium nitrate
Pelletizing tower exhaust cylinder particulate matter, ammonia quarter
Packaging machine exhaust pipe particulate matter year
Sewage treatment and environmental protection facilities
Sewage treatment site exhaust collection
Equipment exhaust pipe
Hydrogen sulfide, ammonia, phenols e for half a year
Non-methane total hydrocarbons e quarter
Note. Exhaust gas monitoring shall be synchronized to monitor flue gas parameters in accordance with the corresponding standard analytical methods and technical specifications. (Except gas venting tube). Nitrogen fertilizer industry granulation
If the tail gas exhaust pipe cannot monitor the exhaust gas flow, the material balance can be used to estimate the pollutant discharge.
a When using a three-waste co-firing system, mercury and its compounds should be monitored.
b dry coal powder entrained flow gasification device pulverized coal transport carrier gas using carbon dioxide gas from low temperature methanol elution sulfur decarbonization facility, should be determined vulcanization
Hydrogen, methanol.
c Applicable to the sewage unit that produces sulfuric acid for sulfur recovery.
When formaldehyde is used in the granulation process, formaldehyde should be monitored.
e Sewage units using a fixed bed atmospheric pressure coal gasification process shall monitor phenolic and non-methane total hydrocarbons.
5.2.2 Unorganized exhaust emission monitoring
The monitoring points, monitoring indicators and monitoring frequency of unorganized exhaust emission are implemented according to Table 3.
Table 3 Unorganized exhaust gas monitoring indicators and minimum monitoring frequency
Frequency of monitoring monitoring indicators
Sewage unit boundary
Ammonia, non-methane total hydrocarbons, odor concentration, hydrogen sulfide a quarter
Particulate matter a, methanol b, benzo(a)pyrene, phenol c
Note. a Sewage unit with natural gas as raw material and fuel may not monitor hydrogen sulfide and particulate matter.
b. The unit that produces methanol by-product or uses a low-temperature methanol washing process should monitor methanol.
c The sewage unit in the fixed bed atmospheric pressure coal gasification process shall monitor phenols and benzo(a) pyrene.
5.3 Environmental noise monitoring at the boundary of the plant
The site noise monitoring point setting should follow the principle of HJ 819, mainly considering crushing equipment, screening equipment, wind
The distribution of noise sources such as air compressors, air compressors, various compressors and water pumps in the plant area.
The noise at the boundary of the plant is monitored at least once a day, and the monitoring index is equivalent continuous A sound level. Sensitive around
For sensitive points, sensitive point noise monitoring should be added.
5.4 Surrounding environment quality impact monitoring
5.4.1 Other environmental management policies, or environmental impact assessment documents and their approvals (only after January 1,.2015 (inclusive)
If the pollutant discharge unit that has obtained the approval of the environmental impact assessment has clear requirements, it shall be implemented as required.
5.4.2 If there is no specific requirement, if the pollutant discharge unit considers it necessary, it can monitor the surrounding water and air quality. can
Refer to HJ 2.2, HJ/T 2.3, HJ/T 91, HJ/T 194, HJ 442 for the setting of surface water and seawater monitoring
Surface and ambient air monitoring points, monitoring indicators and frequency are carried out according to Table 4. The ambient air monitoring time should be no group around the plant boundary.
Weaving exhaust emission monitoring time synchronization.
Table 4 Monitoring indicators and minimum monitoring frequency of surrounding environment quality impact
Frequency of monitoring of target environmental monitoring indicators
Surface water
pH, suspended solids, chemical oxygen demand, ammonia nitrogen, total phosphorus, total nitrogen,
Petroleum, cyanide, volatile phenol, sulfide
Quarter
seawater
pH, chemical oxygen demand, dissolved oxygen, total nitrogen, total phosphorus, active phosphorus
Acid salts, inorganic nitrogen, petroleum, cyanide, volatile phenols, sulfides
Half a year
Ambient air sulfur dioxide, nitrogen dioxide, particulate matter, benzo(a)่a, ammonia for half a year
Note. A sewage unit using a fixed bed atmospheric pressure coal gasification process should monitor benzo(a)pyrene in ambient air.
5.5 Other requirements
5.5.1 In addition to the pollutant indicators in Tables 1 to 3, the pollutant indicators in 5.5.1.1 and 5.5.1.2 should also be included in the monitoring indicators.
Range, and refer to Tables 1 to 3 and HJ 819 to determine the frequency of monitoring.
5.5.1.1 Drainage permit, pollutant discharge (control) standards implemented, environmental impact assessment documents and their approvals
It is limited to the pollutant discharge unit approved by the environmental impact assessment after January 1,.2015 (including), and the relevant management regulations clearly require
Pollutant indicator.
5.5.1.2 According to the raw materials and auxiliary materials used in the production process, the production process, the intermediate and final product types, and the monitoring results
Contaminant indicators in the relevant list of toxic, hazardous or preferentially controlled pollutants, or other toxic pollutants
index.
5.5.2 The frequency of monitoring of each indicator can be determined according to the requirements according to the frequency of monitoring in HJ 819.
The principle is to increase the frequency of monitoring.
5.5.3 Sampling methods, monitoring and analysis methods, monitoring quality assurance and quality control shall be performed in accordance with HJ 819.
5.5.4 The description and changes of the monitoring plan shall be implemented in accordance with HJ 819.
6 Information records and reports
6.1 Information Record
6.1.1 Monitoring information record
Manual monitoring records and automatic monitoring of operation and maintenance records are performed in accordance with HJ 819. The sewage disposal unit shall record the manual monitoring period as it is.
The working conditions (including production load, operation of pollution control facilities, etc.) ensure that the monitoring data is representative.
6.1.2 Record of operation status of production and pollution control facilities
The sewage disposal unit shall record the operation status of the production and pollution control facilities in detail, and the daily production shall also refer to the following contents.
Relevant information, and consolidated into a ledger for future reference, the retention period of the account is not less than three years.
6.1.2.1 Production Health Record
Record the operating status, production load and main product output of each production facility of each major production unit under normal working conditions according to shifts
Volume, raw materials and fuel use (including type, name, dosage, composition analysis), flare system and cooling tower work
Status and other data.
6.1.2.2 Record of the operation of pollution control facilities
The operational management records of pollution control facilities shall include at least the following. organized, unorganized emissions and wastewater
Name and process of dyeing treatment facilities, pollution control facility number, corresponding production facility name and number, pollution factor, and management design
Design parameters, air volume, production load corresponding to production facilities, and operating parameters.
6.1.3 General industrial solid waste and hazardous waste information records
Record the amount of general industrial solid waste generated, comprehensive utilization, disposal amount, storage amount; in accordance with hazardous waste management
Relevant requirements, record the amount of hazardous waste generated, comprehensive utilization, disposal, storage and its specific destination. raw material
The condition of other hazardous wastes generated in the auxiliary process or in the auxiliary process shall also be recorded. General industrial solid waste and hazardous waste generation
See Table 5.
Table 5 General industrial solid waste and hazardous waste sources
Category waste name
General industrial solid waste gasification furnace slag, boiler slag, dust collector ash, sludge generated during sewage treatment, domestic garbage
Hazardous waste copper mud, spent catalyst, waste activated carbon, etc.
Note. Other hazardous wastes may be identified according to the National Hazardous Waste List or the national hazardous waste identification standards and identification methods.
6.2 Information report, emergency report and information disclosure
Executed according to HJ 819.
7 other
Except as provided in this standard, it is implemented in accordance with HJ 819.
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