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GB/T 29773-2013 English PDF

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GB/T 29773-2013: The technical specification of waste water recycle for copper mineral processing plant
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Basic data

Standard ID GB/T 29773-2013 (GB/T29773-2013)
Description (Translated English) The technical specification of waste water recycle for copper mineral processing plant
Sector / Industry National Standard (Recommended)
Classification of Chinese Standard Z60
Classification of International Standard 77.120.01
Word Count Estimation 9,911
Quoted Standard GB/T 6920; GB/T 7470; GB/T 7475; GB/T 7477; GB/T 7485; GB 8978; GB/T 11901; GB 24789; GB 50013; HJ/T 195; HJ/T 341; HJ 484; HJ 485; HJ 486; HJ 535; HJ 537; HJ 597; HJ 637
Regulation (derived from) National Standards Bulletin 2013 No. 23
Issuing agency(ies) General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China
Summary This standard specifies the copper concentrator wastewater treatment principles, methods, processes and indicators of water quality requirements and analysis methods. This standard applies to the use of copper flotation process plant wastewater recycling

GB/T 29773-2013: The technical specification of waste water recycle for copper mineral processing plant


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The technical specification of waste water recycle for copper mineral processing plant ICS 77.120.01 Z60 National Standards of People's Republic of China Wastewater recycling copper concentrator Specification Issued on. 2013-11-27 2014-08-01 implementation Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China Standardization Administration of China released

Foreword

This standard was drafted in accordance with GB/T 1.1-2009 given rules. This standard by the national non-ferrous metals Standardization Technical Committee (SAC/TC243) centralized. This standard is drafted by. Yunnan Copper Industry (Group) Co., Ltd. Yuxi Mining. Participated in the drafting of this standard. Beijing General Research Institute of Mining and Metallurgy, Zijin Mining Group, Tongling Nonferrous Metals Group Holdings Co., Ltd., Jiangsu Western Copper Corporation, Zhongtiaoshan Nonferrous Metals Group Co., Ltd. The main drafters of this standard. Su Yaohua, Wujin Fu, Wang, Li Donglin, Wu Dongxu, Li, He cocoa, Chen Chuen, accounting Liao Pi, Wubing Zhi, Zhang Guanghua, Pan Bin, Jin Shangyong. Wastewater recycling copper concentrator Specification

1 Scope

This standard specifies the copper concentrator wastewater treatment principles, methods, processes and water quality objectives and requirements analysis methods. This standard applies to the use of a copper concentrator flotation process wastewater recycling system design, construction and operation management.

2 Normative references

The following documents for the application of this document is essential. For dated references, only the dated version suitable for use herein Member. For undated references, the latest edition (including any amendments) applies to this document. GB/T 6920 Water quality pH glass electrode method of measurement Determination of GB/T 7470 Water quality dithizone spectrophotometry GB/T 7475 Water quality copper, zinc, lead, and cadmium - Atomic absorption spectrophotometry GB/T 7477 Water quality - Determination of the total amount of calcium and magnesium EDTA titration Determination of GB/T 7485 Water Quality total arsenic diethyl dithiocarbamate spectrophotometry silver GB 8978 Integrated Wastewater Discharge Standard Determination of GB/T 11901 Quality of suspended solids - Gravimetric method GB 24789 units of water management and water measuring instruments General GB 50013 outdoor water supply engineering HJ/T 195 Water quality - Determination of ammonia gas phase molecular absorption spectrometry Determination of HJ/T 341 Quality of mercury by cold vapor atomic fluorescence spectrometry Water quality was measured HJ484 cyanide capacity and spectrophotometric methods Determination HJ485 water quality copper diethyl dithiocarbamate spectrophotometry Determination of Copper in Water HJ486 2,9-dimethyl-1,10-phenanthroline spectrophotometry HJ535 Water quality - Determination of ammonia Nessler reagent spectrophotometric HJ537 water quality ammonia by Distillation - neutralization titration method HJ597 Water quality Determination of mercury by cold vapor atomic absorption spectrophotometry By infrared spectrophotometry HJ637 water quality oil and animal and vegetable oils

3 Terms and Definitions

The following terms and definitions apply to this document. 3.1 Beneficiation Wastewater mineralprocessingwastewater In the dressing production process generated do not meet water quality objectives backwater wastewater, including tailings waste water, waste water and other waste concentrates Water. 3.2 Beneficiation backwater returnwaterofMineralprocessing Beneficiation waste water after appropriate treatment, backwater achieve water quality objectives, and the water can be reused. 3.3 Beneficiation backwater use returnwaterusing Beneficiation waste water is treated to achieve water quality objectives and then take advantage of backwater process. 3.4 Beneficiation wastewater reuse rate reusingrateofmineralprocessingwastewater After beneficiation wastewater treatment and reuse of the total (Vcy)% of total production water (V) is.

4 copper beneficiation wastewater treatment and reuse system for use with the principle of

4.1 General requirements Copper beneficiation wastewater treatment and reuse system should follow economically viable, energy conservation, stepped configuration, multi-purpose back early, efficient and environmentally friendly principles. in Concentrator designs have backwater system should be carried out backwater system demonstration program, beneficiation wastewater treatment and reuse system should be designed with the main project, Constructed and put into use. Copper beneficiation wastewater treatment and reuse system generally includes. thickener backwater system, tailings backwater system. 4.2 thickener backwater system Thickener backwater system from the tailings (concentrate) concentration system, pump station and pipeline components. By concentrating backwater pond system, as soon as possible beneficiation wastewater treatment and reuse, help to improve efficiency and save energy. 4.3 tailings backwater system To improve the efficiency of water use, environmental protection, water treatment tailings recovery system should be established tailings, tailings water through water to reach students Production quality requirements, return concentrator re-use. 4.3.1 library artesian water Tailings backwater design should make full use of the library of potential energy of water to save energy. For high dam, it should adopt the artesian water. 4.3.2 library pontoon water When the library tailings clarification zones meeting the requirements of Table 1, the library can set floating boat backwater system in the tailings. Pontoon type intake structures installed by the pump pontoons, laid on a slope of the return pipe and connection pipes and pipe pontoons liaison group to make. Pontoon arrangement is mainly used to pump unit and some auxiliary equipment, floating boat shall meet the requirements related to the balance and stability. 4.3.3 water pumping station outside the library There should be drainage installations of tailings dam is located downstream of the dam to collect water seepage discharge pumping station, all will discharge water seepage collection, reuse or disposal. 4.3.4 tailings return water should be designed to take full advantage of the potential energy of water in the library to save energy. For the high dam, the rate of return and return balance Higher and shorter ice surface tailings, should adopt the library cable car or boat-store backwater backwater pumping station. 4.3.5 backwater pumping station design should leave rich capabilities in order to increase the water back. 4.3.6 tailings from the tailings deposition library backwater pool of water abstraction pitch sideline during the use of tailings shall meet not less than all of clarification Distance requirements. Clarification from the tailings may refer to similar or measured data determined by calculation. 4.3.7 backwater volume of tailings pond, for medium and small concentrator should not be less than the return water supply 4h ~ 6h, and should not be large-scale concentrator Less than the return of the water supply 1h ~ 3h.

5 ways beneficiation wastewater treatment and recycling

5.1 copper beneficiation wastewater treatment Beneficiation wastewater treatment depends on the composition of harmful substances, quantity and quality requirements of the backwater. Commonly used methods are the following Several. a) Natural degradation. the use of tailings settling ponds or other forms of degradation will remove mineral beneficiation waste water, or other solid impurities. b) physical purification method. the use of the filter medium beneficiation wastewater harmful substances removed by filtration. c) chemical purification method. adding an appropriate amount of water in the dressing chemicals, prompting harmful substances into harmless substances. General Information 5.2 beneficiation wastewater reuse 5.2.1 thickener backwater In or near the construction of the concentrator tailings (concentrate) dehydration enrichment pool and other facilities, to clarify the water is returned to the production process and then dressing. 5.2.2 tailings backwater After the tailings slurry into the tailings, most of the solid-liquid separation, the formation of water in the Tail Mineral Processing then returns. 5.2.3 sedimentation tank backwater Production of non-beneficiation process water and wastewater generated (such as cleaning water, dust water, cooling water, etc.) by sedimentation process after returning beneficiation Production process for reuse.

6 copper beneficiation wastewater reuse test

6.1 backwater beneficiation test Carrying copper ore optional test should be carried out wastewater reuse test conditions, the test results to assess wastewater reuse for beneficiation indicators Movies Ring, presented to beneficiation backwater water quality requirements. 6.2 backwater depth treatment test When beneficiation wastewater by clarifying, back into the water on chemical substances in large beneficiation indicators, reach the corresponding quality requirements, should be open Experimental Study on Advanced Treatment exhibition backwater proposed process, pharmaceutical backwater conditions and facilities requires advanced treatment, and demonstrated the depth of processing backwater Feasibility and economic rationality of technology.

7 beneficiation wastewater treatment process

7.1 copper concentrator mild wastewater treatment process Copper ore beneficiation wastewater treatment process should be mildly meet the requirements of Figure 1.

1 mild copper beneficiation wastewater treatment process diagram

7.2 copper concentrator wastewater treatment process After precipitation method for purifying water still can not reach reuse requirements adopted generally need treatment process using FIG. 2. Figure 2 copper beneficiation wastewater treatment process General requirements 8 backwater water quality index and analysis 8.1 General requirements backwater WQO Table 1. Table 1 backwater WQO No. Process Water Control Project Equipment cooling water DC-type circulation Green plant, dust, Cleaning water 1 pH value of 6 ~ 96 ~ 96 ~ 96 ~ 9 2 suspended solids (SS)/(mg/L) ≤ 300 100 70 - 3 Total Hardness (as CaCO3)/(mg/L) ≤ 450 450 450 - 4 ammonia (in N gauge)/(mg/L) ≤ 25 - 25 25 5 petroleum/(mg/L) ≤ 10 10 10 10 Cyanide 6/(mg/L) ≤ 0.5 0.5 - 0.5 7 Cu/(mg/L) ≤ 1.0 - - - 8 Pb/(mg/L) ≤ 1.0 - - - 9 Cd/(mg/L) ≤ 0.1 - - - 10 As/(mg/L) ≤ 0.5 - - 0.5 11 Hg/(mg/L) ≤ 0.05 0.05 - 0.05 8.2 Water Quality Analysis Detection and Analysis Methods Table 2 or alternative method recognized by the national equivalent method. Table 2 backwater water analysis method No. Name Standard Control Project Determination Analysis 1 pH value measured water quality pH glass electrode method GB/T 6920 2 Determination of suspended solids (SS) Water suspension Gravimetric method GB/T 11901 3 Total Hardness (as CaCO3)/(mg/L) - EDTA titration GB of total quality calcium and magnesium/T 7477 4 ammonia (in N gauge)/(mg/L) Water quality - Determination of ammonia Nessler reagent spectrophotometric Water quality - Determination of ammonia distillation - and titration HJ535 HJ537 5 petroleum/(mg/L) was measured infrared water quality oil and animal and vegetable oils spectrophotometry HJ637 6 cyanide/(mg/L) ≤ Water quality - Determination of cyanide - Volumetric and spectrophotometric HJ484

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