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Determination of imidazolinone herbicide residues in soybean
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GB/T 23818-2009
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Basic data Standard ID | GB/T 23818-2009 (GB/T23818-2009) | Description (Translated English) | Determination of imidazolinone herbicide residues in soybean | Sector / Industry | National Standard (Recommended) | Classification of Chinese Standard | X04 | Classification of International Standard | 67.060 | Word Count Estimation | 10,111 | Date of Issue | 2009-05-25 | Date of Implementation | 2009-09-01 | Regulation (derived from) | National Standard Approval Announcement 2009 No.7 (Total No.147) | Issuing agency(ies) | General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China | Summary | This standard specifies the soybean seeds imazapyr, Imazapic, imazethapyr methyl, imazethapyr, HPLC liquid chromatography imazaquin residues and-mass spectrometry/mass spectrometry. This standard applies to soybean seeds imazapyr, determination imazaquin residues, Imazapic, imazethapyr methyl, imazethapyr. |
GB/T 23818-2009: Determination of imidazolinone herbicide residues in soybean---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Determination of imidazolinone herbicide residues in soybean
ICS 67.060
X04
National Standards of People's Republic of China
Determination of soybean imidazolinone herbicide residues
Posted 2009-05-25
2009-09-01 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Foreword
The Standard Appendix A, Appendix B are informative appendices.
This standard is proposed and managed by the National Certification and Accreditation Administration Committee.
This standard was drafted. China Inspection and Quarantine Science Research Institute, Jiangxi People's Republic of China Exit Inspection and Quarantine.
The main drafters of this standard. Li Xiaojuan, Qi Yan, Zhang Xinzhong, accounted Chunrui, Chen Dongdong, on behalf of the Chinese Hui, Peng Tao, Ran Jia, Li Jianzhong, Yang Qiang,
LI Shu-juan, Chu Xiaogang.
Determination of soybean imidazolinone herbicide residues
1 Scope
This standard specifies the soybean seeds imazapyr, imazethapyr methyl, imazethapyr methyl, imazethapyr, imazaquin residues in high
Performance liquid chromatography and liquid chromatography - mass spectrometry/mass spectrometry.
This standard applies to soybean seeds imazapyr, imazethapyr methyl, imazethapyr methyl, imazethapyr, imazaquin residues
Determination.
2 Normative references
The following documents contain provisions which, through reference in this standard and become the standard terms. For dated references, subsequent
Amendments (not including errata content) or revisions do not apply to this standard, however, encourage the parties to the agreement are based on research
Whether the latest versions of these documents. For undated reference documents, the latest versions apply to this standard.
GB/T 6682 analytical laboratory use specifications and test methods (GB/T 6682-2008, ISO 3696. 1987, MOD)
Principle 3
The sample was extracted with dichloromethane, gel permeation chromatography and liquid-liquid distribution method purified by high performance liquid chromatography and liquid chromatography - mass spectrometry/mass spectrometry
Determination, external standard.
4 Reagents and materials
Unless otherwise noted, all reagents were of analytical grade water as a water GB/T 6682 regulations.
4.1 acetonitrile. chromatography.
4.2 hexane. chromatographically pure.
4.3 dichloromethane.
4.4 phosphoric acid.
4.5 filter. 0.22μm, organic phase.
4.6 Standards
4.6.1 imazapyr (imazapyr, CASNo.81334-34-1). purity greater than or equal to 99%.
4.6.2 imazapic (imazapic, CASNo.104098-48-8). purity greater than or equal to 99%.
4.6.3 imazethapyr acid methyl ester (imazamethabenz-methyl, CASNo.81405-85-8). not less than 99.5% purity.
4.6.4 imazethapyr (imazethapyr, CASNo.81335-77-5). purity greater than or equal to 99%.
4.6.5 imazaquin (imazaquin, CASNo.81335-37-7). not less than 99.5% purity.
4.7 standard stock solution. accurately weighed separately each standard 10mg (accurate to 0.1mg), dissolved in acetonitrile and set the volume to 100mL,
Preparation of a concentration of 100μg/mL standard stock solution of each standard stock solution at 0 ℃ ~ 4 ℃ stored.
5. Apparatus
5.1 High performance liquid chromatograph. equipped with a UV detector.
5.2 Liquid chromatography - mass spectrometry/mass spectrometer. with an electrospray ionization source.
5.3 mill.
5.4 Sample sieve. mesh size 0.425mm.
5.5 Analysis of balance. a sense of 0.1mg and 1mg.
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