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Organic geochemical analysis methods for geological samples -- Part 4: Determination of aromatic hydrocarbon group component in heavy fraction of oil -- Mass spectrometry
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Organic geochemical measurements of geological samples -- Method for aromatic types analysis of gas-oils aromatic fractions by mass spectrometry
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Basic data Standard ID | GB/T 18340.4-2010 (GB/T18340.4-2010) | Description (Translated English) | Organic geochemical analysis methods for geological samples -- Part 4: Determination of aromatic hydrocarbon group component in heavy fraction of oil -- Mass spectrometry | Sector / Industry | National Standard (Recommended) | Classification of Chinese Standard | D04 | Classification of International Standard | 73.010 | Word Count Estimation | 23,221 | Date of Issue | 2010-11-10 | Date of Implementation | 2011-02-01 | Older Standard (superseded by this standard) | GB/T 18340.4-2001 | Regulation (derived from) | National Standard Approval Announcement 2010 No.8 (Total No.163) | Issuing agency(ies) | General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China | Summary | This standard specifies the method of mass spectrometry heavy petroleum distillate aromatic group composition, quantitative calculation and analysis of quality requirements. This section applies to heavy petroleum fractions (boiling range 205��C ~ 540��C) aromatic fractions of 18 aromatic and three kinds of aromatic thiophene group composition of quantitative analysis, the samples should be free of olefins, the total sulfur content of less than 1% of the total weight of the non-aromatic compound content of less than 5%. |
GB/T 18340.4-2010: Organic geochemical analysis methods for geological samples -- Part 4: Determination of aromatic hydrocarbon group component in heavy fraction of oil -- Mass spectrometry ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
. Organic geochemical analysis methods for geological smples Part 4; Determination of aromatic hydrocarbon group component in heavy fraction of oil Mass spectrometry.
ICS 73.010
D04
National Standards of People's Republic of China
Replacing GB/T 18340.4-2001
Organic geochemical analysis of geological samples
Part 4. petroleum heavy aromatic hydrocarbon fraction Family
Component mass spectrometry
Part 4. Determinationofaromatichydrocarbongroupcomponent
Issued on. 2010-11-10 2011-02-01 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Foreword
GB/T 18340 "organic geochemistry in geological samples analysis methods," There are six sections.
--- Part 1. Light Crude Gas Chromatography;
--- Part 2. Determination of Organic Matter stable carbon isotope isotope mass spectrometry;
--- Part 3. Determination of heavy petroleum fractions Mass Spectrometry saturated aliphatic hydrocarbon component;
--- Part 4. heavy petroleum distillate aromatic aliphatic component mass spectrometry;
--- Part 5. rock and extract crude oil saturated hydrocarbon analysis by gas chromatography;
--- Part 6. Gasoline Hydrocarbon Mass Spectrometry.
This section GB/T Part of 418,340.
This section of the reference standard American Society for Testing Materials ASTMD3239-91 (2006) "gas oil distillate aromatic hydrocarbons high
Ionizing Voltage Mass Spectrometry. "
This Part replaces GB/T 18340.4-2001 "organic geochemical analysis of geological samples to test the heavy fraction of petroleum hydrocarbons Mass Group Composition
Method ", compared with the GB/T 18340.4-2001, the following changes.
--- By the name of the standard "Organic geochemical measurements of geological samples heavy fraction of petroleum hydrocarbons Mass Spectrometry Group Composition" to "geological
Organic geochemical sample analysis methods - Part 4. heavy petroleum distillate aromatic aliphatic components Mass Spectrometry ";
--- Increased caution, warning;
--- Chapter 1, the original standard range boiling range to 205 ℃ ~ 540 ℃;
--- Original standard has been adjusted the structure and content, and make appropriate editorial changes; sections of the reference ASTMD3239-91
(2006) made the relevant sections of major changes.
Appendix A of this section is an informative annex.
This section presents the People's Republic of China Ministry of Land Resources.
This part of the National Standardization Technical Committee under the jurisdiction of Land and Resources.
This standard is drafted by. National Geological Experimental Test Center.
This section is drafted. Wuxi Institute of Petroleum Geology Research Institute of Petroleum Exploration and Development Co., Ltd. China Petroleum & Chemical.
The main drafters of this section. Double channel, Song Xiaoying, Zhang Zhirong, money Zhihao.
This part of the standard replaces the previous editions are.
--- GB/T 18340.4-2001.
Organic geochemical analysis of geological samples
Part 4. petroleum heavy aromatic hydrocarbon fraction Family
Component mass spectrometry
Warning --- Use this section shall be a person experiences regular laboratory work. This section does not point out all possible security asked
question. Users have the responsibility to take appropriate safety and health practices and to ensure compliance with the conditions relevant national regulations.
1 Scope
GB/T 18340 provisions of this part of the mass spectrometry method of petroleum heavy fractions aromatic group composition quantitative calculation and qualitative analysis
Volume requirements.
This section applies to heavy petroleum fractions (boiling range 205 ℃ ~ 540 ℃) aromatic hydrocarbon fraction 18 aromatics and three kinds of aromatic thiophene
Quantitative analysis of thiophene group composition. Samples should be free of olefins, the total sulfur content should be less than 1% of the total weight of the non-aromatic compound content of less than 5%.
Principle 2
Crude oil is separated by column chromatography, an aromatic hydrocarbon fraction obtained by direct injection into the mass spectrometer system by electron bombardment to give the aromatic
Mixed hydrocarbon fraction mass chromatogram. The mass spectral data of the class Ⅰ ~ Ⅶ aromatic characteristic peak intensity group and add each characteristic mass peak group package
Including multi-isotopic molecular ion peak series and single isotope molecular ion minus 1 series, calculated according to the export of pure aromatic compounds inverse matrix 7 × 7
7 out of the relative content of aromatic hydrocarbons. According to the baseline and each aromatic family law is divided into nominal type (Type 0), overlapping the first type (type 1) and a second weight
Stack type (type 2). Finally, calculate the class type 3 7 Total 21 kinds of aromatic hydrocarbons (Table 1) relative content.
Table 1 aromatic oil category, type, name and molecular formula
Category Type Name Formula
Alkylbenzene
Benzothiophene
Naphthenic Philippines
CnH2n-6
CnH2n-10S
CnH2n-20
Alkyl benzene ring
Pyrene
Unidentified
CnH2n-8
CnH2n-22
Bicyclic alkyl benzene
Qu class
Unidentified
CnH2n-10
CnH2n-24
Naphthalenes
Dibenzothiophene
Unidentified
CnH2n-12
CnH2n-16S
Acenaphthene and dibenzofuran
North Class
Unidentified
CnH2n-14 and CnH2n-16O
CnH2n-28
Fluorene
Dibenzanthracene
Unidentified
CnH2n-16
CnH2n-30
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