GB 13690-2009_English: PDF (GB13690-2009)
| Standard ID | Contents [version] | USD | STEP2 | [PDF] delivered in | Standard Title (Description) | Status | PDF |
| GB 13690-2009 | English | 579 |
Add to Cart
|
4 days [Need to translate]
|
General rule for classification and hazard communication of chemicals
| Valid |
GB 13690-2009
|
Standards related to: GB 13690-2009
| Standard ID | GB 13690-2009 (GB13690-2009) | | Description (Translated English) | General rule for classification and hazard communication of chemicals | | Sector / Industry | National Standard | | Classification of Chinese Standard | A80 | | Classification of International Standard | 13.300 | | Word Count Estimation | 25,286 | | Date of Issue | 2009-06-21 | | Date of Implementation | 2010-05-01 | | Older Standard (superseded by this standard) | GB 13690-1992 | | Quoted Standard | GB/T 16483; GB 20576; GB 20577; GB 20578; GB 20579; GB 20580; GB 20581; GB 20582; GB 20583; GB 20584; GB 20585; GB 20586; GB 20587; GB 20588; GB 20589; GB 20590; GB 20591; GB 20592; GB 20593; GB 20594; GB 20595; GB 20596; GB 20597; GB 20598; GB 20599; GB 20601; GB 20602; GB/T 22272 ~ GB/T 22278; ISO 11683-1997 | | Drafting Organization | In the chemical industry institute | | Administrative Organization | National management of hazardous chemicals Standardization Technical Committee | | Regulation (derived from) | Announcement of Newly Approved National Standards No. 8, 2009 (No. 148 overall) | | Proposing organization | National Chemicals Management Standardization Technical Committee dangerous (SAC/TC 251) | | Issuing agency(ies) | Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China; Standardization Administration of China | | Summary | This Chinese standard provides for the GHS classification and hazard communication of chemicals. This standard applies to classification and hazard communication of chemicals. This standard applies to chemicals production sites and consumer logo. | GB 13690-2009
General rule for classification and hazard communication of chemicals
ICS 13.300
A80
National Standards of People's Republic of China
Replacing GB 13690-1992
Chemical classification and hazard communication General
Posted 2009-06-21
2010-05-01 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Foreword
The standard Chapter 4, Chapter 5 are mandatory, the rest are recommended.
This corresponds to the standard of the United Nations "Classification and Labeling of Chemicals Globally Harmonized System" (GHS) Second revised edition (ST/SG/AC.10/30 /
Rev. 2), with its non-equivalent, its technical content consistent with the GHS, in a standard text format according to GB/T 1.1-
Do a 2000 editorial changes.
This standard replaces GB 13690-1992 "commonly used classification of dangerous chemicals and signs."
This standard compared with GB 13690-1992 main changes are as follows.
--- Standard name changed to "chemical classification and hazard communication of Law";
--- The standard in accordance with the requirements of the GHS hazard chemicals are classified;
--- The standard in accordance with GHS requirements for chemical hazard communication has been stipulated.
The Standard Appendix A, Appendix B, Appendix C, Appendix D is an informative annex.
This standard is managed by the National Standardization Technical Committee chemicals dangerous (SAC/TC251) and focal points.
Participated in the drafting of this standard. the Chemical Institute of Standardization, Shandong CIQ, Shanghai Chemical Research Institute, Jiangsu access
Habitat Inspection and Quarantine Bureau, Hubei Exit Inspection and Quarantine.
Drafters of this standard. Zhang Shao Yan, Cui Hairong, Yang, Wang Xiaobing, Mei Jian, Tang Lijun, courtesy car East Falls Apart, Zhou Wei.
This standard replaces the standards previously issued as follows.
--- GB 13690-1992.
Chemical classification and hazard communication General
1 Scope
This standard specifies the classification of chemicals related to GHS and hazard communication.
This standard applies to chemical classification and hazard communication. This standard applies to chemical production sites and consumer logo.
2 Normative references
The following documents contain provisions which, through reference in this standard and become the standard terms. For dated references, subsequent
Amendments (not including errata content) or revisions do not apply to this standard, however, encourage the parties to the agreement are based on research
Whether the latest versions of these documents. For undated reference documents, the latest versions apply to this standard.
GB/T 16483 MSDS Content and Order
GB 20576 chemical classification, precautionary labeling and precautionary statements Explosives Safety rules
GB 20577 chemical classification, precautionary labeling and precautionary statements of specification flammable gases
GB 20578 chemical classification, precautionary labeling and precautionary statements of norms Flammable
GB 20579 chemical classification, precautionary labeling and precautionary statements of normative oxidizing gas
GB 20580 chemical classification, precautionary labeling and precautionary statements under pressure gas safety regulations
GB 20581 chemical classification, precautionary labeling and precautionary statements of specification flammable liquids
GB 20582 chemical classification, precautionary labeling and precautionary statements Flammable solid Specification
GB 20583 chemical classification, precautionary labeling and precautionary statements of self-reactive substances Specification
GB 20584 chemical classification, precautionary labeling and precautionary statements of self-heating substance specification
GB 20585 chemical classification, precautionary labeling and precautionary statements of spontaneous combustion of liquid Specification
GB 20586 chemical classification, precautionary labeling and precautionary statements of spontaneous combustion of solid Specification
GB 20587 chemical classification, precautionary labeling and precautionary statements of specification contact with water emit flammable gases
GB 20588 Chemicals classification, precautionary labeling and precautionary statements of specification metal corrosion
GB 20589 chemical classification, precautionary labeling and precautionary statements of normative oxidizing liquid
GB 20590 chemical classification, precautionary labeling and precautionary statements of normative oxidizing solid
GB 20591 chemical classification, precautionary labeling and precautionary statements of norms organic peroxides
GB 20592 Chemicals classification, precautionary labeling and precautionary statements of norms acute toxicity
GB 20593 chemical classification, precautionary labeling and precautionary statements of norms skin corrosion/irritation
GB 20594 chemical classification, precautionary labeling and precautionary statements of norms serious eye damage/eye irritation
GB 20595 chemical classification, precautionary labeling and precautionary statements of norms Respiratory or skin sensitization
GB 20596 chemical classification, precautionary labeling and precautionary statements of norms Germ cell mutagenicity
GB 20597 chemical classification, precautionary labeling and precautionary statements of normative carcinogenicity
GB 20598 chemical classification, precautionary labeling and precautionary statements of reproductive toxicity Specification
GB 20599 chemical classification, precautionary labeling and precautionary statements Specific target organ toxicity - single exposure
GB 20601 chemical classification, precautionary labeling and precautionary statements Specific target organ toxicity - Repeated exposure
GB 20602 chemical classification, precautionary labeling and precautionary statements of norms on water environment hazards
GB/T 22272 ~ GB/T 22278 Good Laboratory Practice (GLP) standards series
ISO 11683.1997 packaging requirements Tactile danger warning
IPCS/EHC No. 225 document "Assessment of the principle of reproductive health risks caused by exposure to chemicals used"
3 Terms and Definitions
GHS conversion of the national standards (GB 20576 ~ GB 20599, GB 20601, GB 20602) and the following terms and definitions apply
To this standard.
3.1
One description to uniquely identify chemicals. The name may be in line with the International Union of Pure and Applied Chemistry (IUPAC) or chemical
Title Abstracts Service (CAS) naming system, it may be a technical name.
3.2
When packaged under pressure is entirely at -50 ℃ when a gas gaseous; including critical temperature ≤-50 ℃ for all gases.
3.3
Administered under certain specified test conditions ignition source causing ignition of liquid vaporization lowest temperature (corrected to standard atmospheric pressure 101.3kPa).
3.4
Each hazard class standard division, such as oral acute toxicity includes five hazard categories and flammable liquids includes four hazard categories.
These hazard categories within a hazard more dangerous kind of severity, should not treat them as more general hazard category comparison.
3.5
Hazard class means the physical, health or environmental hazard properties, such as flammable solids, carcinogenicity, acute oral toxicity.
3.6
A description of the hazard class or category, they illustrate the dangers of a dangerous nature of the product, in the case for a statement in which dangerous
degree.
3.7
One kind is equal to the vapor pressure of the liquid standard pressure (101.3kPa), the temperature of the first bubble appears.
3.8
About a dangerous product of an appropriate set of written, printed or graphic information elements, because the target is selected and relevant departments, they
Attached to or printed on the immediate container of a dangerous product or its external packaging.
3.9
One class of unified information on the label, such as pictograms, signal words.
3.10
Recognized by the United Nations Economic and Trade Council, the United Nations Recommendations on the Transport of Dangerous Goods Regulations Annex "on the transport of dangerous goods
Template "in the title, the official publication of the written word.
3.11
A graphical structure, which may include a symbol plus other graphic elements, such as borders, background pattern or color that is intended to convey specific
Information.
3.12
A phrase/and (or) pictograms, the measures recommended to minimize or prevent exposure to a hazardous substance or
Arising from the adverse effects of improper storage or handling of produce.
3.13
Label or safety data sheets for hazardous product name or number. It provides a unique means for users to make products in special
Given the use of the background to identify the substance or mixture under, for example, transport, consumption or in the workplace.
3.14
On the label used to indicate the relative severity of the hazard and alert the reader to a potential hazard. GHS using the "dangerous" and "police
Advertisement "as a signal word.
3.15
Graphic element intended to succinctly convey information.
Category 4
4.1 Physical and chemical hazard
4.1.1 Explosives
Explosives classification, precautionary labeling and precautionary statements, see GB 20576.
4.1.1.1 explosive substance (or mixture) is such a solid (or mixture of substances) or liquid substance, which in itself through a chemical reaction
It should produce gas, and produce gas temperature, pressure and speed as to cause damage to the surroundings. Including pyrophoric substances, even if they
Do not evolve gases.
Pyrophoric substance (or mixture) is a substance or a mixture of such substances, it is designed to self-sustaining exothermic chemical reactions through non-explosive
Heat, light, sound, gas or smoke or a combination of these generated to produce an effect.
Explosive articles containing one or more explosive substances or mixtures items.
Pyrotechnic articles containing one or more pyrotechnic substances or mixtures items.
4.1.1.2 explosives comprises.
a) explosive substances and mixtures;
b) Explosive articles, but does not include the following devices. which contains explosive substances or mixtures in such quantity or characteristics, or in an accident
After the accidental ignition or initiation, not by projection, fire, smoke, heat or loud noise producing any effect external to the device.
c) a) and b) it is not mentioned in the produce substances, mixtures and articles practical explosive or pyrotechnic effect produced.
4.1.2 flammable gas
Flammable gas classification, precautionary labeling and precautionary statements, see GB 20577.
Flammable gas is at 20 ℃ and 101.3kPa standard pressure, a flammable range of gas and air.
4.1.3 Flammable aerosol
Flammable aerosol classification, precautionary labeling and precautionary statements, see GB 20578.
Aerosols means aerosol spray cans, the Department of any non-refillable container made of metal, glass or plastic, built mandatory
Compressed, liquefied or dissolved gases, with or without a liquid, paste or powder, fitted with a release device allowing the contents to be ejected form
Gas suspended solid or liquid particles or a foam, paste or powder or in a liquid or gaseous.
4.1.4 oxidizing gas
Oxidizing gas classification, precautionary labeling and precautionary statements, see GB 20579.
Oxidizing gas is generally by providing oxygen, cause or contribute to air than any other material gas combustion.
4.1.5 gas under pressure
Under pressure of the gas classification, precautionary labeling and precautionary statements, see GB 20580.
The gas pressure is a gas under high pressure gas contained in a receptacle at a pressure of 200 kPa greater than or equal to (gauge pressure), or liquefied gas or
Refrigerated liquefied gases.
Under pressure of the gas include compressed gases, liquefied gases, dissolved gases, refrigerated liquefied gases.
4.1.6 flammable liquids
Flammable liquid classification, precautionary labeling and precautionary statements, see GB 20581.
Flammable liquid means a flash point of not higher than 93 ℃ of liquid.
4.1.7 Flammable solids
Flammable solid classification, precautionary labeling and precautionary statements, see GB 20582.
Flammable solids are readily combustible or may cause or by rubbing the solid combustion.
Readily combustible solids are powdered, granular, or pasty substances which can be ignited and the fire in brief contact with burning matches and other ignition sources
The case of the rapid spread of flame, are very dangerous.
4.1.8 Self-reactive substances or mixtures
Self-reactive substances classification, precautionary labeling and precautionary statements, see GB 20583.
4.1.8.1 Self-reactive substances or mixtures are even without oxygen (air) is also prone to heat strongly exothermic decomposition unstable liquid or solid
Substance or mixture. This definition does not include classified under the GHS as explosives, organic peroxides or oxidation of a substance and
mixture.
When self-reactive substances or mixtures 4.1.8.2 If the laboratory testing the formulation is liable to detonate, to deflagrate rapidly or heated under confinement
Show a violent effect, it should be regarded as possessing explosive properties.
4.1.9 Spontaneous liquid
Spontaneous liquid classification, precautionary labeling and precautionary statements, see GB 20585.
Spontaneous liquid is even in small quantities within 5min of energy upon contact with air to ignite the liquid.
4.1.10 Spontaneous solid
Spontaneous solid classification, precautionary labeling and precautionary statements, see GB 20586.
Spontaneous is solid even in small quantities within 5min of energy upon contact with air to ignite the solid.
4.1.11 Self-heating substances and mixtures
Self-heating substances classification, precautionary labeling and precautionary statements, see GB 20584.
Self-heating substances other than a pyrophoric liquid or solid, the reaction with air without energy supply will be able to own heat solid or liquid substances
Or mixtures thereof; or a mixture of such materials with different pyrophoric liquid or solid, because only the large number of such materials (kilograms) and after long
Room (hours or days) will burn.
NOTE. Self-heating substance or mixture result in spontaneous combustion is the heat due to the substance or mixture with oxygen (oxygen in the air) and the resulting reaction is not
Conducted away rapidly enough to the outside caused. When the rate of heat production exceeds the rate of heat loss to achieve auto-ignition temperature, spontaneous combustion will occur.
4.1.12 substance or mixture with water, emit flammable gases
In contact with water, emit flammable gases of classification, precautionary labeling and precautionary statements, see GB 20587.
In contact with water, emit flammable gases are substances or mixtures with the water, are liable to become spontaneously flammable or emit flammable gases in dangerous quantities
Solid or liquid substance or mixture.
4.1.13 oxidizing liquid
Oxidizing liquid classification, precautionary labeling and precautionary statements, see GB 20589.
Oxidizing liquid is itself not necessarily combustible, may, generally by yielding oxygen, cause or contribute to combustion of other substances in the liquid.
4.1.14 oxidizing solid
Oxidizing solids classification, precautionary labeling and precautionary statements, see GB 20590.
Solid oxide itself is not necessarily combustible, may, generally by yielding oxygen, cause or contribute to the combustion of other substances.
4.1.15 Organic peroxides
Organic peroxides classification, precautionary labeling and precautionary statements, see GB 20591.
4.1.15.1 Organic peroxides are liquid or solid organic substances containing bivalent -0-0- structure and may be considered one or two hydrogen atoms
Group is replaced by an organic peroxide derivatives. The term also includes organic peroxide formulations (mixtures). Organic peroxides are thermally unstable
Given substance or mixture undergo exothermic self-accelerating decomposition. In addition, they may have the following one or several properties.
a) be liable to explosive decomposition;
b) burn rapidly;
c) sensitive to impact or friction;
d) the occurrence of dangerous reactions with other substances.
4.1.15.2 If the organic peroxide in laboratory testing, when heated under confinement component liable to detonate, to deflagrate rapidly or exhibit
Dramatic effect, is regarded as possessing explosive properties.
4.1.16 corrosive metal
Metal corrosion classification, precautionary labeling and precautionary statements, see GB 20588.
Substance or mixture corrosive to metals by chemical action of significant damage or destruction of the substance or mixture of metals.
4.2 Health hazard
4.2.1 Acute toxicity
Acute toxicity classification, warning labels and warning instructions see GB 20592.
Acute toxicity refers to a single dose or multiple doses within 24h oral or dermal administration of a substance, or inhalation exposure after 4h
Harmful effects.
4.2.2 Skin corrosion/irritation
Skin corrosion/irritation classification, precautionary labeling and precautionary statements, see GB 20593.
Skin corrosion is the production of irreversible damage to the skin; namely application of a test substance reached 4h, observed the epidermis and dermis necrosis.
Corrosive reactions are typified by ulcers, bleeding, bloody scabs, and 14d at the end of the observation period, the skin, complete areas of alopecia and crusting
Fade due to blanching. It should be considered to evaluate questionable lesions by histopathology.
Skin irritation is the application of a test substance reached after 4h of reversible damage to the skin.
4.2.3 Serious eye damage/eye irritation
Serious eye damage/eye irritation classification, precautionary labeling and precautionary statements, see GB 20594.
Serious eye damage after application of a test substance to the anterior surface of the eye resulting in the administration of 21d is not entirely irreversible tissue damage
Injury, or serious physical decay of vision.
Eye irritation after application of a test substance to the anterior surface, resulting in the administration of 21d fully reversible changes in the eye.
4.2.4 Respiratory or skin sensitization
Respiratory or skin sensitization classification, precautionary labeling and precautionary statements, see GB 20595.
4.2.4.1 Respiratory allergy substance that will cause an allergic reaction tube over substance after inhalation. Skin allergens after skin contact may cause allergies
Substance reactions.
4.2.4.2 allergy consists of two phases. the first stage is an individual by exposure to an allergen and cause-specific immunological memory. The second stage is
Initiation, that of a sensitized individual by exposure to an allergen to produce a cell-mediated or antibody-mediated allergic reactions.
4.2.4.3 For respiratory allergies, the induction followed by elicitation phase, which is the same shape and skin allergies. For skin allergies, there is a need
So that the immune system learns to react induction phase; thereafter, the clinical symptoms, exposure is sufficient to elicit a visible skin reactions
It should be (elicitation phase). Thus, predictive tests usually follow this pattern in which there is an induction phase, the response phase is marked by
Quasi elicitation phase, typically involving the use of a patch test. Directly measuring the induction response local lymph node assay is the exception to do
law. Evidence of human skin allergy usually assessed by a diagnostic patch test plaques.
4.2.4.4 on skin allergies and respiratory allergies, with respect to induce the desired value is generally lower than the desired value initiator.
4.2.5 Germ cell mutagenicity
4.2.5.1 Germ cell mutagenicity classification, warning labels and warning statements, see GB 20596.
4.2.5.2 This hazard class is mainly involved may lead to human reproductive cells can spread to future generations of mutations chemicals. but,
When in this hazard class for substances and mixtures are classified, but also consider in vitro mutagenicity/genotoxicity tests and in vivo mammalian
Somatic cells in mutagenicity/genotoxicity tests.
4.2.5.3 The standard used to cause mutations, mutagen, mutations and reproductive toxicity is defined as the common definition of the word. A mutation is defined as fine
The number of cell structure or a permanent change in the genetic material.
The term 4.2.5.4 "mutation" is used may be manifested at the phenotypic level and heritable genetic changes underlying DNA modifications when known (for example,
Including specific base pair changes and chromosomal translocations). Mutagenic and mutagen two words used in the cell and/or communities of organisms produce
Mutation increased breaking agent.
Structure 4.2.5.5 reproductive toxicity and reproductive toxicity of these two relatively general terms for changing the DNA, the amount of information, separating agent
Or process, including those caused by interfering with normal replication process of DNA damage or non-physiological manner (temporarily) alter DNA replication agent
Or process. Reproductive toxicity test results are usually used as indicators for mutagenic effects.
4.2.6 carcinogenicity
4.2.6.1 carcinogenicity classification, precautionary labeling and precautionary statements, see GB 20597.
4.2.6.2 refers carcinogens can cause cancer or increase the chemical substance or mixture of substances chemically cancer incidence. In a good implementation
Benign and malignant tumors of the substance induced in experimental studies on animals are considered to be presumed or suspected human carcinogens unless there is strong
Evidence that the mechanism of tumor formation has nothing to do with humans.
4.2.6.3 produce carcinogenic hazard classification of chemicals based on the inherent properties of the substance is not provided on the use of chemicals may yield
Health and human cancer risk level information.
Reproductive toxicity 4.2.7
Reproductive toxicity classification, precautionary labeling and precautionary statements, see GB 20598.
4.2.7.1 Reproductive Toxicity
Reproductive toxicity includes adverse effects on adult male and female sexual function and fertility, as well as developmental toxicity in the offspring. the following
Is defined IPCS/EHC No. 225 document given.
In this standard, reproductive toxicity is subdivided under two main headings.
a) harmful effects on sexual function and fertility;
b) The development of the offspring harmful effects.
Some reproductive toxic effects can not be clearly attributed to sexual function and fertility damage or developmental toxicity. Nevertheless, with this
Some effects of chemicals will be classified as reproductive toxicants with a general hazard statement.
4.2.7.2 harmful effects on sexual function and fertility
Chemicals interfere with any effect reproductive capacity. This may include (but are not limited to) alterations to the female and male reproductive system, for youth
Start period, gamete production and transport, reproductive cycle normality, sexual behavior, fertility, parturition pregnancy outcomes, premature reproductive
Aging, or change other features depend on the integrity of the reproductive system.
Adverse effects on lactation harmful effects arising from or via lactation are also included in reproductive toxicity, but for classification purposes, these
Kind of effects are treated separately. This is because the adverse effects of chemicals on lactation of the best specialized classification, so that you can
Lactating mothers about the effect of this particular hazard warning.
4.2.7.3 harmful effects on development of the offspring
In its widest sense, developmental toxicity includes any effect before or after birth interfering with normal development, and this effect
It should occur because of contact with a parent before conception or developing offspring before birth or after birth before the sexual maturity
The contact period. However, the main developmental toxicity classified under the heading order for pregnant women and reproductive capacity of men and women raised risk
Risk warning. Therefore, to pragmatic purposes of classification, developmental toxicity essentially means the harmful effects induced during pregnancy, or parental exposure
The harmful effects. These effects can be manifested at any time of the life cycle of the organism.
The main manifestations of developmental toxicity include.......
...
|