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Methods for chemical analysis of antimony-doped tin oxide. Part 1: Determination od tin content. Potassium iodate titrimetric method
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YS/T 997.1-2014
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Basic data | Standard ID | YS/T 997.1-2014 (YS/T997.1-2014) | | Description (Translated English) | Methods for chemical analysis of antimony-doped tin oxide. Part 1: Determination od tin content. Potassium iodate titrimetric method | | Sector / Industry | Nonferrous Metallurgy Industry Standard (Recommended) | | Classification of Chinese Standard | H13 | | Classification of International Standard | 77.120.60 | | Word Count Estimation | 7,774 | | Date of Issue | 10/14/2014 | | Date of Implementation | 4/1/2015 | | Regulation (derived from) | People's Republic of China Ministry of Industry and Information Technology Notice 2014 No. 63; Industry Standard Filing Notice 2014 No. 12 (Overall No. 180) | | Issuing agency(ies) | Ministry of Industry and Information Technology | | Summary | This Standard specifies the method for determination of antimony-doped tin oxide in the amount of tin. This section applies to the determination of the amount of antimony tin oxide doped tin measuring range (mass fraction) of 55.00% - 78.50%. |
YS/T 997.1-2014: Methods for chemical analysis of antimony-doped tin oxide. Part 1: Determination od tin content. Potassium iodate titrimetric method ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Methods for chemical analysis of antimony-doped tin oxide Part 1. Determination od tin content Potassium iodate titrimetric method.
ICS 77.120.60
H13
People's Republic of China Nonferrous Metals Industry Standard
Antimony-doped tin oxide chemical analysis
Part 1. Determination of tin content potassium iodate titration
Part 1. Determinationoftincontent-
Issued on. 2014-10-14
2015-04-01 implementation
Ministry of Industry and Information Technology of the People's Republic of China released
Foreword
YS/T 997 "Methods for chemical analysis of antimony-doped tin dioxide," is divided into three parts.
--- Part 1. Determination of tin content potassium iodate titration;
--- Part 2. Determination of antimony content cerium sulfate titration;
--- Part 3. Determination of chlorine content of thiocyanate mercury spectrophotometry.
This section YS/T Part 1 997.
This section drafted in accordance with GB/T 1.1-2009 given rules.
The non-ferrous metal part by the National Standardization Technical Committee (SAC/TC243) centralized.
This section is drafted. Guangxi metallurgical products Quality Supervision, Inspection Station, Liuzhou one hundred tough special Advanced Materials Co., Ltd., Guangxi
Analysis and Testing Center Zhuang Autonomous Region, Guilin University of Technology, Nanning Abacus detection technology limited liability company.
The main drafters of this section. Zhang Hongyun, Hu Yongmei, Yangyu Bing, Ye Kaifu, Liu Yongqiang, Zhang, Huangzhao Min, Lung Chi Cheung, Zhou Sulian, Huang He,
Mao Xiangen.
Antimony-doped tin oxide chemical analysis
Part 1. Determination of tin content potassium iodate titration
1 Scope
YS/T of the provisions of the section 997 determination of antimony doped tin oxide in the amount of tin.
This section applies to the determination of antimony tin oxide doped with tin in the amount of measurement range (mass fraction) 55.00% - 78.50%.
2 Method summary
After sodium oxide sample melted in hydrochloric acid solution was added reduced iron, antimony reduced to elemental separated and removed, with aluminum tin reduced to two
Price, starch as the indicator for the end of bluish titration with potassium iodate standard solution titration test solution.
3 Reagents
Unless otherwise indicated, this part of the reagents were analytical reagent, the water of GB/T 6682 in the secondary water.
3.1 sodium peroxide.
3.2 reduced iron.
3.3 metal tin (Sn mass fraction ≥99.99%).
3.4 aluminum (Al mass fraction ≥99.5%), thickness of less than 0.1mm.
3.5 Sodium hydroxide solution (25g/L).
3.6 hydrochloride (11).
3.7 potassium iodate standard titration solution.
--- Preparation. Weigh 3.6g of potassium iodate dissolved in 500mL of water, add 18g potassium iodide and 2g of anhydrous sodium carbonate was dissolved, diluted with water
To 2000mL, shake.
--- Calibration. Weigh 0.1200g metal tin (3.3) placed in 300mL conical flask, 2g ~ 3g reduced iron (3.2),
100mL of hydrochloric acid (3.6), the flask was connected to the reduction apparatus (FIG. 1). Low-temperature heating tin dissolved, add 20mL water, add
2.0g ~ 2.5g folded into small pieces of aluminum foil (3.4), continuous shaking the flask to dissolve most of the aluminum, and heating was continued to boil test solution
To produce large bubbles 1min. Under the protection of carbon dioxide gas, the flasks were placed in cold water to cool to room temperature. Remove the cone
Vial, immediately join 5mL starch solution (3.8), titration with potassium iodate standard solution (3.7) titration test solution was light blue as the end point.
While doing the blank test.
The actual concentration of potassium iodate standard solution titration according to formula (1).
c =
m0
59.355 × (V1-V0) × 10-3
(1)
Where.
C --- the actual concentration of potassium iodate standard titration solution, expressed in moles per liter (mol/L);
m0 --- metal tin in grams (g);
When V1 --- calibration standard solution titration tin volume of potassium iodate standard titration solution consumption in milliliters (mL);
V0 --- the calibration, the volume of potassium iodate titration reagent blank standard titration solution consumption in milliliters (mL);
59.355 --- tin (1/2Sn) molar mass in grams per mole (g/mol).
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