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Determination of silicon oxide, Iron oxide, Sodium oxide content of Aluminum Hydroxide by X-ray fluorescence spectrometric method
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YS/T 702-2009
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Basic data | Standard ID | YS/T 702-2009 (YS/T702-2009) | | Description (Translated English) | Determination of silicon oxide, Iron oxide, Sodium oxide content of Aluminum Hydroxide by X-ray fluorescence spectrometric method | | Sector / Industry | Nonferrous Metallurgy Industry Standard (Recommended) | | Classification of Chinese Standard | H30 | | Classification of International Standard | 71.120.10 | | Word Count Estimation | 6,632 | | Date of Issue | 2009-12-04 | | Date of Implementation | 2010-06-01 | | Regulation (derived from) | MIIT [2009] No. 66 | | Issuing agency(ies) | Ministry of Industry and Information Technology | | Summary | This standard specifies the aluminum hydroxide SiO (2), Fe (2) O (3), Na (2) O content determination. This standard applies to aluminum hydroxide SiO (2), Fe (2) O (3), Na (2) O content. Measuring range in Table 1. |
YS/T 702-2009: Determination of silicon oxide, Iron oxide, Sodium oxide content of Aluminum Hydroxide by X-ray fluorescence spectrometric method ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Determination of silicon oxide, Iron oxide, Sodium oxide content of Aluminum Hydroxide by X-ray fluorescence spectrometric method
ICS 77.120.10
H30
People's Republic of China Nonferrous Metals Industry Standard
X-ray fluorescence spectrometry
Posted 2009-12-04
2010-06-01 implementation
Ministry of Industry and Information Technology of the People's Republic of China released
Foreword
This standard by the National Standardization Technical Committee of non-ferrous metals and centralized.
Appendix A of this standard is an informative annex.
This standard by the Aluminum Corporation of China Guangxi Branch is responsible for drafting.
Participated in the drafting of this standard. Aluminum Corporation of China Research Institute of Zhengzhou, Luoyang Xiangjiang Wanji Aluminum Co., Ltd., China Aluminum
Ltd. Henan Branch.
The main drafters of this standard. Qin Wenzhong, Deng Wenjun, Yang Yun screen, the more Liang Bin, where unicorn, Zhang Aifen, Mahui Xia, Jiang Wei, Tang Fei, Sun Hongbin.
X-ray fluorescence spectrometry
1 Scope
This standard specifies the aluminum hydroxide SiO2, Fe2O3, Na2O content determination.
This standard applies to aluminum hydroxide SiO2, Fe2O3, Na2O content was measured, the measurement range shown in Table 1.
Table 1
Component measuring range (mass fraction) /%
SiO2 0.005 ~ 0.08
Fe2O3 0.004 ~ 0.07
Na2O 0.20 ~ 0.80
2 principle of the method
Mixing the molten sample flux anhydrous lithium tetraborate and lithium metaborate, plus a small amount of bromide (or iodide) as a release agent. In the fusion machine
Melted at a temperature of 1100 ℃, after cooling made of glass samples, measured by X-ray fluorescence spectrometer.
3 Reagents
3.1 Flux. anhydrous lithium tetraborate and lithium metaborate mixed flux, pure class distinctions. Flux contains some water, one of the following two methods should be adopted
Compensate.
3.1.1 Burning 2h at 700 ℃, cooling backup in the dryer;
3.1.2 per kg sufficiently mixed flux to take 2 parts, according to a predetermined melting temperature of the molten 10min, a predetermined melt melting time
Financial, loss on ignition to take greater amount of flux calibration. Flux should be sealed, weekly or once the determination of loss on ignition per kilogram. LOI L
Expressed as a percentage, according to equation (1) calculate the correction factor F, mixed melt dosage dose = F × 2 is not pillow melting.
F = 100100-L
(1)
3.2 release agent. Ammonium bromide solution (250g/L).
4 Equipment
Platinum 4.1 - crucible (95% Pt + 5% Au).
Platinum 4.2 - metal mold (95% Pt + 5% Au). Bottom mold material thickness of about 1mm, its deformation.
NOTE. melting and casting mold sample containers can be combined. If the sample in the crucible directly after melt molding, the bottom surface of the inner wall of the crucible is required smooth. Recommended Specifications.
The upper end of an inner diameter of 45mm, an inner diameter of the lower end of 33mm, high 25mm.
4.3 fusion machine
Automatic flame fusion machine or high-frequency inductors fusion machine. If other types of prototype melting temperature not lower than 1100 ℃, and temperature controlled.
4.4 wavelength dispersive X-ray fluorescence spectrometer. end window rhodium anode X-ray tube.
5 Sample
Sample Preparation. The sample was pulverized aluminum hydroxide, all through a pore size of 125μm sieve. Drying in an oven at 105 ℃ ± 5 ℃ in 1h, take
Placed in the dryer to cool to room temperature.
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