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US$169.00 · In stock Delivery: <= 3 days. True-PDF full-copy in English will be manually translated and delivered via email. YS/T 536.8-2009: Methods for chemical analysis of bismuth. Determination of chlorine content. Mercuric thiocyanate photometric method Status: Valid YS/T 536.8: Evolution and historical versions
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| YS/T 536.8-2009 | English | 169 |
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Methods for chemical analysis of bismuth. Determination of chlorine content. Mercuric thiocyanate photometric method
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YS/T 536.8-2009
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| YS/T 536.8-2006 | English | 239 |
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Methods for chemical analysis of bismuth -- Determination of chlorine content -- Distillation-mercuric thiocyanate photometric method
| Obsolete |
YS/T 536.8-2006
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PDF similar to YS/T 536.8-2009
Basic data | Standard ID | YS/T 536.8-2009 (YS/T536.8-2009) | | Description (Translated English) | Methods for chemical analysis of bismuth. Determination of chlorine content. Mercuric thiocyanate photometric method | | Sector / Industry | Nonferrous Metallurgy Industry Standard (Recommended) | | Classification of Chinese Standard | H13 | | Classification of International Standard | 77.120.70 | | Word Count Estimation | 6,642 | | Date of Issue | 2009-12-04 | | Date of Implementation | 2010-06-01 | | Older Standard (superseded by this standard) | YS/T 536.8-2006 | | Regulation (derived from) | MIIT [2009] No. 66 | | Issuing agency(ies) | Ministry of Industry and Information Technology | | Summary | This standard specifies the amount of chlorine in the determination of bismuth. This standard applies to the determination of the amount of bismuth chloride. Measuring range (mass fraction): 0. 001% to 0. 006 % |
YS/T 536.8-2009: Methods for chemical analysis of bismuth. Determination of chlorine content. Mercuric thiocyanate photometric method ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Methods for chemical analysis of bismuth.Determination of chlorine content.Mercuric thiocyanate photometric method
ICS 77.120.70
H13
People's Republic of China Nonferrous Metals Industry Standard
Replacing YS/T 536.8-2006
Methods for chemical analysis of bismuth - Determination of chlorine content
Mercury thiocyanate spectrophotometric method
2009-12-04 released
2010-06-01 Implementation
Issued by the Ministry of Industry and Information Technology of the People's Republic of China
Foreword
YS/T 536-2009 "Bismuth chemical analysis method" is divided into 13 parts.
- Methods for chemical analysis of bismuth - Determination of copper content - Diacetaldehyde oxalyl dihydrazone spectrophotometric method;
- Methods for chemical analysis of bismuth - Determination of iron content - Electrothermal atomic absorption spectrometric method;
- Methods for chemical analysis of bismuth - Determination of antimony content - Malachite green spectrophotometric method;
- YS/T 536.4 Methods for chemical analysis of bismuth - Determination of silver content - Flame atomic absorption spectrometric method and electrothermal atomic absorption spectrometry;
- Methods for chemical analysis of bismuth - Determination of zinc content - Solid - liquid extraction - Flame atomic absorption spectrometry;
- Methods for chemical analysis of bismuth - Determination of lead content - Electrothermal atomic absorption spectrometric method;
- YS/T 536.7 Methods for chemical analysis of bismuth - Determination of arsenic content - Atomic fluorescence spectrometry;
- Methods for chemical analysis of bismuth - Determination of chlorine content - Mercury thiocyanate spectrophotometric method;
- Methods for chemical analysis of bismuth - Determination of tellurium - Arsenic coprecipitation - oscillopolarographic method;
- Methods for chemical analysis of bismuth - Determination of tin content - Beryllium coprecipitation - spectrophotometric method;
- Methods for chemical analysis of bismuth - Determination of mercury content - Atomic fluorescence spectrometry;
Methods for chemical analysis of bismuth - Determination of nickel content - Electrothermal atomic absorption spectrometric method;
Methods for chemical analysis of bismuth - Determination of cadmium content - Electrothermal atomic absorption spectrometric method YS/T 536.13.
This section is part 8.
This part replaces YS/T 536.8-2006 (formerly GB/T 8220.8-1998) "Bismuth chemical analysis method Mercury thiocyanate spectrophotometric
Method to determine the amount of chlorine. " Compared with YS/T 536.8-2006, this section mainly has the following changes.
--- the text format has been modified;
- complements the precision, quality assurance and control terms.
This part of the National Nonferrous Metals Standardization Technical Committee proposed and centralized.
This part is drafted by Zhuzhou Smelting Group Co., Ltd.
This part is drafted by Zhuzhou Smelting Group Co., Ltd.
This part of the Beijing Nonferrous Metals Research Institute, Hunan Shizhuyuan limited liability company to participate in the drafting.
This part of the main drafters. to Lei Lei, Jiang Qing.
This part of the main verifier. Zang Muwen, Liao Guobao.
This part of the previous version of the standard to replace the release of the situation.
YS/T 536.8-2006.
Methods for chemical analysis of bismuth - Determination of chlorine content
Mercury thiocyanate spectrophotometric method
1 Scope
This section specifies the determination of the amount of chlorine in bismuth.
This part is applicable to the determination of chlorine in bismuth. Determination range (mass fraction). 0.001% to 0.006%.
2 method summary
The sample was dissolved in nitric acid and distilled in a nitric acid medium at a temperature of 250 ° C ± 20 ° C. The escape was absorbed in a sodium hydroxide solution
in. Adding mercuric thiocyanate and ferric chloride, the formation of chloride and mercuric thiocyanate reaction, free thiocyanate and iron (Ⅲ) color. In the points
The photometer absorbs the absorbance at a wavelength of 460 nm.
3 reagent
Reagents preparation and determination of the process are added with a small amount of sodium hydroxide distillation of a water.
3.1 commercially available reagents
3.1.1 Reduction of iron powder.
3.1.2 nitric acid (ρ1.42g/mL), ultra-pure.
3.1.3 perchloric acid (ρ1.67g/mL), excellent grade pure.
3.1.4 nitrogen, high purity.
3.2 solution
3.2.1 Mercury thiocyanate - methanol solution (5g/L). Weigh 0.5g of mercuric thiocyanate in a 250mL beaker, add 100mL of methanol, dissolved
After the whole, move into a brown bottle and save it.
3.2.2 ferric chloride solution. Weigh 7g of reduced iron powder in 400mL beaker, add.200mL nitric acid (2 +1, ultra-pure), heating solution
solution. Add 60mL perchloric acid (3.1.3), heat until the perchloric acid smoke and continue heating to the solution reddish brown and cool. Diluted with water
500mL, mix well.
3.2.3 sodium hydroxide solution (0.2mol/L), excellent grade pure.
3.3 standard solution
3.3.1 Chlorine standard storage solution. Weigh at 500 ℃ for 30min, and placed in a dryer to room temperature 0.2102g potassium chloride
(Excellent grade pure), placed in 250mL beaker, dissolved in water, into the 1000mL volumetric flask, diluted with water to the mark, mix. This solution
Liquid 1mL containing 0.1mg chlorine.
3.3.2 Chlorine standard solution. Remove 50.00mL chlorine standard storage solution (3.3.1) in 500mL volumetric flask, diluted with water to the scale, mixed
uniform. 1 mL of this solution contains 10 g of chlorine.
4 instruments and devices
4.1 spectrophotometer.
4.2 chlorine distillation device (see Figure 1).
4.3 temperature control furnace.
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