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Determination of carbon content in aluminum electrolyte - IR absorption spectrometry method
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YS/T 1035-2015
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Basic data Standard ID | YS/T 1035-2015 (YS/T1035-2015) | Description (Translated English) | Determination of carbon content in aluminum electrolyte - IR absorption spectrometry method | Sector / Industry | Nonferrous Metallurgy Industry Standard (Recommended) | Classification of Chinese Standard | H12 | Classification of International Standard | 71.100.10 | Word Count Estimation | 5,579 | Date of Issue | 2015-04-30 | Date of Implementation | 2015-10-01 | Regulation (derived from) | Ministry of Industry and Information Technology Announcement (2015 No. 28) | Issuing agency(ies) | Ministry of Industry and Information Technology | Summary | This Standard specifies the determination of the carbon content of aluminum electrolyte infrared absorption spectrometry. This Standard applies to the determination of aluminum in the carbon content of the electrolyte. Measuring range: 0.02% to 2.00%. |
YS/T 1035-2015: Determination of carbon content in aluminum electrolyte - IR absorption spectrometry method ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
(Aluminum electrolytic carbon content of infrared absorption spectroscopy)
ICS 71.100.10
H12
People's Republic of China Nonferrous Metals Industry Standard
Determination of aluminum electrolyte carbon content
Infrared absorption spectrometry
Issued on. 2015-04-30
2015-10-01 implementation
Ministry of Industry and Information Technology of the People's Republic of China released
Foreword
This standard was drafted in accordance with GB/T 1.1-2009 given rules.
This standard by the national non-ferrous metals Standardization Technical Committee (SAC/TC243) and focal points.
This standard is drafted by. Shandong Nanshan Aluminum Co., Ltd.
Participated in the drafting of this standard. aluminum and magnesium in the County Kam Ning New Materials Co., Qingtongxia Aluminum Corporation.
The main drafters of this standard. Cheng Ren policy, Liu Jianying, Cheng Jianguo, Liu Chuan, Wang Gang, Guo Hong, Cai Qing, Zhang Lingzhi.
Determination of aluminum electrolyte carbon content
Infrared absorption spectrometry
1 Scope
This standard specifies the determination of the carbon content of aluminum electrolyte infrared absorption spectrometry.
This standard applies to the determination of aluminum in the carbon content of the electrolyte. Measuring range. 0.02% to 2.00%.
2 Method summary
This standard by adding a certain amount of flux in the sample, using high frequency induction heating a sample, the sample carbon oxygen OXYGEN
Into carbon dioxide gas, the gas is absorbed into the treated cell, absorption of infrared radiation, the detector signal is forwarded by the computer
Processing output.
3 Process Analysis
3.1 Reagents and configuration
3.1.1 Sodium fluoride (excellent pure). Before using placed under conditions of 300 ℃ drying 2h, placed in a desiccator to cool.
3.1.2 aluminum fluoride (excellent pure). Before using placed under conditions of 300 ℃ drying 2h, placed in a desiccator to cool.
3.1.3 alumina (excellent pure). Before using placed under conditions of 300 ℃ drying 2h, placed in a desiccator to cool.
3.1.4 magnesium fluoride (excellent pure). Before using placed under conditions of 300 ℃ drying 2h, placed in a desiccator to cool.
3.1.5 Calcium carbonate (reference reagents). Before using placed under conditions of 110 ℃ drying 2h, placed in a desiccator to cool.
3.1.6 pure iron flux. carbon content of less than 0.0005% (mass fraction), particle size < 1.25mm.
3.1.7 pure tungsten flux. carbon content of less than 0.0003% (mass fraction).
3.1.8 ethanol. AR.
3.1.9 carbon-free electrolyte formulation shown in Table 1.
Table 1
Name of the reagent NaF AlF3 Al2O3 MgF2
Mass fraction /% 533 944
The above proportions formulated as aluminum electrolyte composition similar to carbon-free electrolyte, the prepared reagent mix into the zirconia ceramic crucible
, Placed in 850 ℃ high temperature furnace temperature was raised to 980 ℃ 20min to burning molten. After cooling crushed ground, particle size of 75μm, again
Mix placed in oven, 105 ℃ ~ 110 ℃ drying 4h, put the dryer set aside.
3.1.10 standard sample preparation. Weigh accurately carbon-free electrolyte (3.1.9), calcium carbonate is added (3.1.5), were formulated as carbon content
0.02%, 0.05%, 0.10%, 0.30%, 0.50%, 1.00%, 2.00% of the standard electrolyte sample, sample preparation should be stored in dry conditions.
3.1.11 porcelain crucible. High-frequency infrared carbon and sulfur analyzer dedicated low-carbon low-sulfur crucible before use with air or oxygen in a high temperature (1100 ℃) burning
At least 2h, store in a desiccator.
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