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Determination of phosphonic and amino acid group-containing herbicides residues in foodstuffs for export - LC-MS/MS method
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SN/T 3983-2014
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PDF similar to SN/T 3983-2014
Basic data Standard ID | SN/T 3983-2014 (SN/T3983-2014) | Description (Translated English) | Determination of phosphonic and amino acid group-containing herbicides residues in foodstuffs for export - LC-MS/MS method | Sector / Industry | Commodity Inspection Standard (Recommended) | Classification of Chinese Standard | X04 | Classification of International Standard | 67.050 | Word Count Estimation | 28,220 | Date of Issue | 12/1/2014 | Date of Implementation | 5/1/2015 | Quoted Standard | GB/T 6682 | Regulation (derived from) | State-Quality-Inspection-accreditation [2014] 614 | Issuing agency(ies) | General Administration of Customs | Summary | This standard specifies the rice, wheat, soybeans, corn, milk, cabbage, grapes, oranges, potatoes, garlic, tea, shrimp, fish and honey and other foods glyphosate (glyphosate) and its metabolite aminomethylphosphonic acid (aminomethyl phosphonic acid, AMPA |
SN/T 3983-2014: Determination of phosphonic and amino acid group-containing herbicides residues in foodstuffs for export - LC-MS/MS method ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
(Amino Acids food exports organophosphate herbicide residues measured by liquid chromatography - mass spectrometry/mass spectrometry)
People's Republic of China Entry-Exit Inspection and Quarantine Standards
Amino acids in food for export of organic phosphorus herbicide
Determination of residues of liquid chromatography - mass spectrometry/mass spectrometry
Issued on. 2014-11-19
2015-05-01 implementation
People's Republic of China
The State Administration of Quality Supervision, Inspection and Quarantine released
Foreword
This standard was drafted in accordance with GB/T 1.1-2009 given rules.
Please note that some of the content of this document may involve patents. Distribution of this document
Institutions do not assume the responsibility to identify these patents.
This standard is proposed and managed by the National Certification and Accreditation Administration Committee.
This standard was drafted. People's Republic of China, Shenzhen CIQ, Shenzhen Inspection and Quarantine Science Research Institute.
The main drafters. Zhang Jianying, Hu Yuan, Wu Fengqi, Chang, Loyola, Weidong, Yue Zhenfeng.
Amino acids in food for export of organic phosphorus herbicide
Determination of residues of liquid chromatography - mass spectrometry/mass spectrometry
1 Scope
This standard specifies the rice, wheat, soybeans, corn, milk, cabbage, grapes, oranges, potatoes, garlic, tea, shrimp, fish and honey
Food glyphosate (glyphosate) and its metabolite aminomethylphosphonic acid (aminomethylphosphonicacid, AMPA) and glufosinate
(Glufosinate) amino acids and other organic phosphine herbicide residues in liquid chromatography - mass spectrometry/mass spectrometry.
This standard applies to rice, wheat, soybeans, corn, milk, cabbage, grapes, oranges, potatoes, garlic, tea, shrimp, fish and honey
Glyphosate, aminomethylphosphonic acid (AMPA) and glufosinate residues measured and confirmed.
2 Normative references
The following documents for the application of this document is essential. For dated references, only the dated version suitable for use herein
Member. For undated references, the latest edition (including any amendments) applies to this document.
Laboratory use specifications and test methods GB/T 6682 Analysis
3 Method summary
Sample extraction with water (rice, milk, cabbage, grapes, oranges) amino acid residues of organic phosphine herbicide drugs, methylene chloride net
, Post and 9-fluorenylmethyl chloroformate derivatization, liquid chromatography - mass spectrometry/mass spectrometry and validation, internal standard.
Using a mixed solution of water and dichloromethane extract sample (wheat, soybeans, corn, garlic and potatoes) amino acid residues in organic phosphine
Herbicides drugs, extract protein by TCA, methylene chloride purification, after the 9-fluorenylmethyl chloroformate derivatization reaction solution
Chromatography - mass spectrometry/mass spectrometry and validation, internal standard.
Shrimp, fish, honey and tea amino acids organic phosphine herbicide drug residues using a mixed solution of water and methylene chloride extraction,
Extract by cation exchange column (CAX) purification, after the 9-fluorenylmethyl chloroformate derivatization, liquid chromatography - mass spectrometry/mass spectrometry and
Confirmed, internal standard.
4 Reagents and materials
Unless otherwise indicated, the reagents used were of analytical grade, test water to comply with a water GB/T 6682 regulations.
4.1 dichloromethane. high performance liquid chromatography.
4.2 acetone. chromatography.
4.3 Methanol. chromatographically pure.
4.4 acetonitrile. chromatography.
4.5 TCA.
4.6 hydrochloric acid.
4.7 sodium borate (Na2B4O7 · 10H2O).
Ammonium acetate 4.8. HPLC grade.
4.9 formic acid. Chromatographic pure.
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