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HJ 572-2010 English PDF

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HJ 572-2010: Technical requirement for enviromental labeling products. Stationery
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Q/CT 2299   QB/T 1337   QB/T 1655   

Basic data

Standard ID HJ 572-2010 (HJ572-2010)
Description (Translated English) Technical requirement for enviromental labeling products. Stationery
Sector / Industry Environmental Protection Industry Standard
Classification of Chinese Standard Y50
Classification of International Standard 35.260.20
Word Count Estimation 12,157
Date of Issue 2010-05-04
Date of Implementation 2010-07-01
Quoted Standard GB 6675-2003; GB 19601; GB 21027-2007; GB/T 1033.1-2008; GB/T 9758.4-1988; GB/T 17592-2006; GB/T 19942-2005; GB/T 22048-2008; GB/T 22788-2008; HJ/T 201-2005; HJ/T 220; HJ/T 370; HJ/T 371; SN/T 1877.2-2007; SN/T 1877.4-2007
Regulation (derived from) Department of Environmental Protection Notice No. 41 of 2010
Issuing agency(ies) Ministry of Ecology and Environment
Summary This standard specifies the greenhouse ventilation and cooling system definition, design and calculation methods, the main technical parameters determination method. This standard applies to greenhouse ventilation and cooling systems.

HJ 572-2010: Technical requirement for enviromental labeling products. Stationery

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Technical requirement for enviromental labeling products.Stationery National Environmental Protection Standard of the People's Republic Environmental Labeling Products Technical Requirements Stationery Technical requirement for environmental labeling products -Stationery Published on.2010-05-04 2010-07-01 Implementation Ministry of Environmental Protection released Ministry of Environmental Protection announcement No. 41 of.2010 In order to implement the "Environmental Protection Law of the People's Republic of China", protect the environment, and promote technological progress, the technology of environmental labeling products is now approved. Five standards such as “requesting bags” are national environmental protection standards and are released. The standard name and number are as follows. I. Environmental Labeling Products Technical Requirements Bags (HJ 569-2010) Second, environmental labeling products technical requirements toner cartridge (HJ 570-2010) Third, environmental labeling products technical requirements wood-based panels and their products (HJ 571-2010) V. Environmental Labeling Products Technical Requirements for Inkjet Cartridges (HJ 573-2010) The above standards have been implemented since July 1,.2010 and published by the China Environmental Science Press. The standard content can be found on the website of the Ministry of Environmental Protection. Special announcement. May 4,.2010

Content

Foreword..iv 1 Scope..1 2 Normative references..1 3 Terms and Definitions.1 4 Basic requirements..2 5 Technical content..2 6 Inspection method..3 Appendix A (Normative Appendix) Persistent Organic Pollutants..5 Appendix B (Normative Appendix) List of Decomposable Aromatic Amines..6 Appendix C (Normative Appendix) List of Specific Polycyclic Aromatic Hydrocarbons..7 Iv

Foreword

To implement the Environmental Protection Law of the People's Republic of China, reduce the environmental and human health of stationery products during production, use and disposal. The impact of Kang, the development of this standard. This standard puts forward some restrictions on the restriction and prohibition of toxic and hazardous substances in some raw materials, packaging materials and products used in the stationery production process. Requirements, at the same time for the transferable elements of the accessible materials in the product (including parts), total surface coating lead, total cadmium and phthalates, plastics And polycyclic aromatic hydrocarbons in rubber, textiles, leather, decomposable carcinogenic aromatic amine azo dyes, etc., set a limit requirement. This standard refers to the Japanese environmental labeling standard "Stationery/Office Supplies (1.7 version)" (Stationery/Office Supplies Version 1.7), National Toy Safety Technical Specification (GB 6675-2003), US Consumer Product Safety Improvement Act (CPSIA) and EU Directive.2005/84/EC And other relevant requirements are formulated. This standard applies to China Environmental Labeling Product Certification. This standard was formulated by the Science and Technology Standards Department of the Ministry of Environmental Protection. The main drafting units of this standard. Environmental Development Center of the Ministry of Environmental Protection, Shenzhen Institute of Metrology and Quality Inspection, Zhejiang Guangbo Group Co., Ltd., Shenzhen Qixin Stationery Co., Ltd., Deli Group Co., Ltd., China Culture and Education Sporting Goods Association, National Stationery Quality Supervision and Inspection Center, Ningbo Songhe Stationery Co., Ltd., Beijing Xueao Stationery Manufacturing Co., Ltd. This standard was approved by the Ministry of Environmental Protection on May 4,.2010. This standard has been implemented since July 1,.2010. This standard is explained by the Ministry of Environmental Protection. Environmental Labeling Products Technical Requirements Stationery

1 Scope of application

This standard specifies the terms and definitions, basic requirements, technical content and testing methods of stationery environmental labeling products. This standard applies to stationery and similar products for office, study, etc. This standard does not apply to Fujian and Taiwan stationery.

2 Normative references

The contents of this standard refer to the terms in the following documents. For undated references, the valid version applies to this standard. GB 6675-2003 National Toy Safety Technical Specification Limits and determination of 23 harmful aromatic amines in GB 19601 dye products GB 21027-2007 General requirements for the safety of student supplies Plastics -- Determination of density of non-foam plastics -- Part 1 . Dipping method, liquid pycnometer method and titration method Paints and varnishes -- Determination of the content of cadmium - Part 4. Determination of cadmium content Sub-absorption spectroscopy and polarography GB/T 17592-2006 Determination of banned azo dyes for textiles GB/T.19942-2005 Determination of banned azo dyes in leather and fur chemical tests GB/T 22048-2008 Determination of phthalate plasticizers in polyvinyl chloride plastics for toys and children's products GB/T 22788-2008 Determination of total lead content in toy surface coatings HJ/T 201-2005 Environmental Labeling Products Technical Requirements Waterborne Coatings HJ/T 220 Environmental Labeling Product Technical Requirements Adhesive HJ/T 370 Environmental Labeling Product Technical Requirements Offset Printing Ink HJ/T 371 environmental labeling product technical requirements gravure ink and flexo ink SN/T 1877.2-2007 Method for determination of polycyclic aromatic hydrocarbons in plastics and their products SN/T 1877.4-2007 Determination of polycyclic aromatic hydrocarbons in rubber and its products

3 Terms and definitions

The following terms and definitions apply to this standard. Stationery It refers to various items for the purpose of office, study, etc. The stationery in this standard mainly includes pencil case, stationery bag, folder and text. Box, desktop file cabinet, file box, file basket, file holder, word paper, book file, official seal holder, pen holder, pen tray, pen holder, letter insert, letter Clips, letterheads, index labels, binders, combination stationery and similar office supplies, staples, pushpins, pins, paper clips, pencil sharpeners, Pencil sharpener, pencil sharpener, stapler, puncher, stapler, numbering machine, utility knife, art blade, scissors, eraser, ruler, book, Photo album, business card book, correction fluid, correction tape, correction pen, color mud, rubber strip, solid glue, glue, stamp made by vegetable oil, ink, Stationery, ink and water-based stamps, ink, ink and other stationery products.

4 basic requirements

4.1 Product quality should meet the requirements of the corresponding product quality standards. 4.2 Product safety should comply with the requirements of relevant product safety standards. 4.3 Pollutant emissions from product manufacturing enterprises shall comply with the requirements of national or local pollutant discharge standards. 4.4 Product manufacturers should strengthen clean production in the production process.

5 Technical content

5.1 Environmental performance requirements for materials used in products (including raw materials) 5.1.1 Plastic materials (1) The plastic shall not contain the persistent organic pollutants specified in Appendix A; (2) Additives containing organotin (TBT) and its compounds shall not be used in plastics; (3) The content of vinyl chloride monomer in polyvinyl chloride raw materials and products thereof shall not exceed 1 mg/kg; (4) Enterprises should use recycled plastics in the design and production process. 5.1.2 Adhesive Adhesives shall comply with the requirements of HJ/T 220. 5.1.3 Ink (1) It is advisable to use water-based inks; (2) Offset printing inks shall comply with the requirements of HJ/T 370; (3) Gravure inks and flexo inks shall comply with the requirements of HJ/T 371. 5.1.4 Dyes The dye should meet the requirements of GB 19601. 5.1.5 Paper (1) Enterprises should use recycled paper in the design and production process; (2) The whiteness of the paper used by students in this book should be no more than 85%. The whiteness of paper in general office should not exceed 90%. 5.2 Environmental performance requirements for products (including components) 5.2.1 The substances listed in Table 1 shall not be artificially added to the product. Table 1 Prohibition of artificial addition of substances in products Type of substance Benzene benzene, toluene, ethylbenzene, xylene Glycol ether and its esters, ethylene glycol methyl ether, ethylene glycol methyl ether acetate, ethylene glycol ethyl ether, ethylene glycol ethyl ether acetate, diethylene glycol butyl ether acetate Phthalate dioctyl phthalate (DOP), dibutyl phthalate (DBP), di(2-ethylhexyl) phthalate (DEHP) Halogenated hydrocarbons methylene chloride, dichloroethane, chloroform, trichloroethane, carbon tetrachloride 5.2.2 The limit of harmful substances in the product should meet the requirements of Table 2. Table 2 Limits of hazardous substances in products Project limited application Migable element 锑(Sb)/(mg/kg) ≤25 All accessible materials and inks, stamps, stamps, Ink and other products Arsenic (As)/(mg/kg) ≤ 10 Cadmium (Cd)/(mg/kg) ≤ 40 Lead (Pb)/(mg/kg) ≤ 60 Mercury (Hg)/(mg/kg) ≤ 10 Selenium (Se)/(mg/kg) ≤.200 Chromium (Cr) Note 1/(mg/kg) ≤40 钡(Ba) Note 2/(mg/kg) ≤500 Total lead (Pb)/(mg/kg) ≤ 90 total surface coating cadmium (Cd)/(mg/kg) ≤ 40 Phthalate Acid ester /% Di(2-ethylhexyl) phthalate (DEHP), phthalic acid Dibutyl acrylate (DBP), butyl phthalate (BBP) total ≤ 0.1 surface coating, plastic diisodecyl phthalate (DINP), diisononyl phthalate (DIDP), the sum of di-n-octyl phthalate (DNOP) ≤ 0.1 Decomposable aromatic amine Note 3/(mg/kg) No textiles or leather should be detected Polycyclic aromatic hydrocarbons benzo[a]pyrene(B[a]P)/(mg/kg) ≤1 Plastics, rubber-specific polycyclic aromatic hydrocarbons Note 4/(mg/kg) ≤10 Free formaldehyde/(mg/kg) ≤ 900 liquid glue, solid glue and water-based ink, stamp pad, stamp, etc. Total volatile organic compounds/(g/L) ≤ 50 liquid glue, solid glue Benzene injection 5/(mg/kg) ≤20 liquid glue, solid glue, ink, stamp pad, stamp And toluene ethylbenzene xylene total sum/ink, correction supplies/(mg/kg) ≤ 40 Chlorinated hydrocarbon injection 6/(mg/kg) shall not detect the correction supplies Note 1. The chromium (Cr) limit in plasticine is ≤25 mg/kg; Note 2. The limit of barium (Ba) in plasticine is ≤250 mg/kg; Note 3. Decomposable aromatic amines are listed in Appendix B; Note 4. Specific polycyclic aromatic hydrocarbons are listed in Appendix C; Note 5. The limit of benzene in the modified product is ≤10 mg/kg; Note 6. The components of the chlorinated hydrocarbon project are dichloromethane, 1,1-dichloroethane, 1,2-dichloroethane, 1,1,1-trichloroethane, 1,1,2- Trichloroethane, chloroform and four Carbon chloride. 5.3 Environmental performance requirements for packaging materials 5.3.1 The total amount of lead (Pb), mercury (Hg), cadmium (Cd) and hexavalent chromium (Cr6) shall not exceed 100 mg/kg. 5.3.2 Recyclable materials should be used for packaging.

6 Test methods

6.1 Technical content 5.2.2 The detection of the migratable elements in Table 2 is carried out in accordance with the method specified in GB 6675-2003. 6.2 Technical content 5.2.2 The total lead content in Table 2 is tested according to the method specified in GB/T 22788-2008. 6.3 Technical content 5.2.2 Determination of total cadmium content in Table 2 Sample pretreatment according to the method specified in GB/T 22788-2008 The detection of cadmium in the test solution is carried out in accordance with the method specified in GB/T 9758.4-1988. Atomic emission spectrometer or other suitable instrument can also be used The device is tested, but it must be indicated in the test report. 6.4 Technical content 5.2.2 The detection of phthalates in Table 2 is carried out in accordance with the method specified in GB/T 22048-2008. 6.5 Technical content 5.2.2 The detection of decomposable aromatic amines in textiles in Table 2 shall be carried out in accordance with the method specified in GB/T 17592-2006. The detection of decomposable aromatic amines in leather is carried out in accordance with the method specified in GB/T.19942-2005. 6.6 Technical content 5.2.2 Detection of polycyclic aromatic hydrocarbons in Table 2, plastic materials in accordance with the method specified in SN/T 1877.2-2007; rubber The material was carried out in accordance with the method specified in SN/T 1877.4-2007. 6.7 Technical content 5.2.2 The detection of benzene in the altered articles in Table 2 shall be carried out in accordance with the method specified in 4.2 of GB 21027-2007. The detection of free formaldehyde, total volatile organic compounds, benzene, toluene ethylbenzene xylene and other items in the product according to GB 21027-2007 4.3 The corresponding method is prescribed. Among them, in the toluene ethylbenzene xylene summation project, the ethylbenzene component is detected in the same way as the toluene component. The method is tested, and when detecting the total volatile organic compounds in the solid glue, the determination of the density of the solid glue is determined by GB/T 1033.1-2008. The method is carried out. 6.8 Technical content 5.2.2 The detection of chlorinated hydrocarbons in Table 2 is carried out in accordance with the corresponding method specified in HJ/T 201-2005. 6.9 Other content in the technical content is verified by means of document review combined with on-site inspection.

Appendix A

(normative appendix) Persistent organic pollutants Chinese name English name chemical registration number Aldrin Aldrin 309-00-2 Dieldrin Dieldrin 60-57-1 Endrin Endrin 72-20-8 Chlordane Chlordane 57-74-9 Heptachlor Heptachlor 76-44-8 DDT Dichloro-diphenyl-trichloroethane 50-29-3 Mirex Mirex 2385-85-5 Toxaphene Toxaphene 8001-35-2 Hexachlorobenzene Hexachlorobenzene 118-74-1 Polychlorinated biphenyl polychlorobiphenyls 1336-36-3 Two evil English PCDD 1746-01-6 Furan PCDF 51207-31-9 --HCH (α-HCH) α-1,2,3,4,5,6-Hexachlorocyclohexane 319-84-6 --HCH (β-hexachlorocyclohexane) β-1,2,3,4,5,6-Hexachlorocyclohexane 319-85-7 PentaBromodiphenyl Ether 32534-81-9 OctaBromodiphenyl Ether 117964-21-3 Chlordecone Chlordecone 143-50-0 Hexabromobiphenyl Hexabromobiphenyl 59536-65-1 Lin Dan (六六六) Lindane 58-89-9 Pentachlorobenzene Pentachlorobenzene 608-93-5 Perfluorooctane sulfonate and its salts and perfluorooctane sulfonyl fluoride PFOS and PFOSF -

Appendix B

(normative appendix) Decomposable aromatic amine list Serial number Chinese name English name chemical registration number 1 4-aminobiphenyl 4-Aminodiphenyl 92-67-1 2 benzidine Benzidine 92-87-5 3 4-Chloro-o-toluidine 4-Chloro-o-toluidine 95-69-2 4 2-Naphthylamine 2-Naphthylamine 91-59-8 5 o-aminoazotoluene o-Amino-azotoluene 97-56-3 6 2-Amino-4-nitrotoluene 2-Amino-4-Nitrotoluene 99-55-8 7 p-chloroaniline p-Chloroaniline 106-47-8 8 2,4-diaminoanisole 2,4-Diaminoanisole 615-05-4 9 4,4'-diaminodiphenylmethane 4,4'-Diaminodiphenylmethane 101-77-9 10 3,3'-Dichlorobenzidine 3,3'-Dichlorobenzidine 91-94-1 11 3,3'-dimethoxybenzidine 3,3'-Dimethoxybenzidine 119-90-4 12 3,3'-Dimethylbenzidine 3,3'-Dimethylbenzidine 119-93-7 13 3,3'-Dimethyl-4,4'-diaminodiphenylmethane 3,3'-Dimethyl-4,4'-Diaminodipheylmethane 838-88-0 14 3-Amino-p-toluidine methyl p-Cresidine 120-71-8 15 4,4'-methine-bis-(2-chloroaniline) 4,4'-Methylene bis-(2-Chloroaniline) 101-14-4 16 4,4'-diaminodiphenyl ether 4,4'-Oxydianiline 101-80-4 17 4,4'-diaminodiphenyl sulfide 4,4'-Thiodianiline 139-65-1 18 o-toluidine (2-methylaniline) o-Toluidine 95-53-4 19 2,4-Diaminotoluene 2,4-Diaminotoluene 95-80-7 20 2,4,5-trimethylaniline 2,4,5-Trimethylaniline 137-17-7 21 o-methoxyaniline (o-aminoanisole) 2-Anisidine 90-04-0 22 2,4-dimethylaniline 2,4-Xylidine 95-68-1 23 2,6-dimethylaniline 2,6-Xylidine 87-62-7

Appendix C

(normative appendix) List of specific polycyclic aromatic hydrocarbons Compound English name abbreviation compound Chinese name chemical registration number Naphthalene Nap naphthalene 91-20-3 Acenaphthylene AcPy Terpene 208-96-8 Acenaphthene Acp 苊83-32-9 Fluorene Flu 芴86-73-7 Phenanthrene PA Philippine 85-01-8 Anthracene Ant 蒽120-12-7 Fluoranthene FL fluoranthene 206-44-0 Pyrene Pyr 芘129-00-0 Chrysene CHR 1,2-benzophenanthrene 218-01-9 Benzo[a]anthracen B[a]A benzo[a]蒽56-55-3 Benzo[b]fluoranthene B[b]F benzo[b]fluoranthene 205-99-2 Benzo[k]fluoranthene B[k]F benzo[k]fluoranthene 207-08-9 Benzo[a]pyrene B[a]P benzo[a]芘50-32-8 Dibenzo[a,h]anthracene DBA dibenzo[a,h]蒽53-70-3 Indeno[1,2,3-cd]pyrene IND 茚[1,2,3-cd]芘193-39-5 Benzo[g,h,i]perylene B[g,h,i]P benzo[g,h,i]苝[perylene] 191-24-2

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