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HJ 1101-2020: Technical specification for application and issuance of pollutant permit - Coal processing - Production of synthesis gas and liquid fuel
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Basic data

Standard ID HJ 1101-2020 (HJ1101-2020)
Description (Translated English) Technical specification for application and issuance of pollutant permit - Coal processing - Production of synthesis gas and liquid fuel
Sector / Industry Environmental Protection Industry Standard
Word Count Estimation 49,417
Date of Issue 2020-02-28
Date of Implementation 2020-02-28
Issuing agency(ies) Ministry of Ecology and Environment

HJ 1101-2020: Technical specification for application and issuance of pollutant permit - Coal processing - Production of synthesis gas and liquid fuel


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Technical specification for application and issuance of pollutant permit - Coal processing - Production of synthesis gas and liquid fuel National Environmental Protection Standards of the People's Republic of China Technical specifications for pollutant discharge permit application and issuance Coal processing-synthesis gas and liquid fuel production 2020-02-28 release 2020-02-28 Implementation Issued by the Ministry of Ecology and Environment

Table of contents

Foreword...ii 1.Scope of application...1 2.Normative references...1 3.Terms and definitions...2 4.Filling requirements for basic information of pollutant discharge units...2 5.Corresponding discharge outlets in the production and discharge process and the determination method of the permitted discharge limit...13 6.Feasible technologies for pollution prevention...16 7.Self-monitoring management requirements...18 8.Requirements for the preparation of environmental management ledger and pollution discharge permit execution report...22 9.Accounting method of actual emissions...24 10.Compliance Judgment Method...28 Appendix A (Informative Appendix) Reference Table of Pollution Prevention and Control Feasible Technologies...31 Appendix B (Informative Appendix) Environmental Management Ledger Record Reference Table...33 Appendix C (Informative Appendix) Form of Annual Report on Pollution Discharge Permit...36

Foreword

In order to implement the Environmental Protection Law of the People’s Republic of China, the Air Pollution Prevention and Control Law of the People’s Republic of China, and the Law of the People’s Republic of China on the Prevention and Control of Water Pollution, the Law of the People’s Republic of China on the Prevention and Control of Soil Pollution, etc. Notice on the Implementation Plan of the Pollutant Discharge Permit System (Guobanfa [2016] No. 81) and the "Administrative Measures for Pollution Discharge Permits (Trial)" (Ministry of Environmental Protection Order No. 48), improve the technical support system for pollutant discharge permits, guide and standardize the production of synthetic gas and coal in the coal processing industry This standard is formulated for the application and issuance of pollutant discharge permits for liquid fuel pollutants. This standard stipulates the basic conditions for the application and issuance of pollutant discharge permits by units producing synthetic gas and liquid fuels in the coal processing industry. Reporting requirements, determination of permitted emission limits, calculation of actual emissions, methods of compliance determination, self-monitoring, and environmental management accounts Environmental management requirements such as the implementation report of pollution discharge permits, and proposed feasible technical requirements for pollution prevention and control. Appendix A to Appendix C of this standard are informative appendices. This standard is issued for the first time. This standard is formulated by the Department of Environmental Impact Assessment and Emission Management and the Department of Regulations and Standards of the Ministry of Ecology and Environment. Drafting organizations of this standard. Environmental Engineering Evaluation Center of the Ministry of Ecology and Environment, Qingdao Ossay Environmental and Safety Technology Co., Ltd., China Huanqiu Engineering Co., Ltd., China Coal Processing and Utilization Association, Beijing Feiyan Petrochemical Environmental Technology Development Co., Ltd. This standard was approved by the Ministry of Ecology and Environment on February 28, 2020. This standard will be implemented on February 28, 2020. This standard is interpreted by the Ministry of Ecology and Environment.

1 Technical specifications for pollutant discharge permit application and issuance

Coal processing-synthesis gas and liquid fuel production 1.Scope of application This standard stipulates the basic conditions for the application and issuance of pollutant discharge permits by units producing synthetic gas and liquid fuels in the coal processing industry. Reporting requirements, determination of permitted emission limits, actual emission accounting, technical methods for compliance determination, self-monitoring, environmental management Environmental management requirements such as the ledger and the implementation report of the pollution discharge permit put forward feasible technical requirements for pollution prevention and control. This standard is applicable to guide the management information of the national emission permits for the production of synthetic gas and liquid fuel in the coal processing industry The platform fills in relevant information, which is suitable for guiding the issuing authority to review and determine the requirements of the pollutant discharge permit. This standard is applicable to the emissions of air pollutants and water pollutants from the coal processing industry that produces syngas and liquid fuels. Pollution permit management. In the coal processing industry that produces synthetic gas and liquid fuel emissions, the "Synthetic Resin Industry Pollutant Emission Standard" (GB 31572) pollution-producing facilities and discharge outlets shall be applicable to the "Pollution Discharge Permit Application and Issuance Technical Specification Petrochemical Industry" (HJ 853); implementation The "Emission Standard of Air Pollutants for Thermal Power Plants" (GB 13223) is applicable to the "Pollution Permit Application for Thermal Power Industry" And issuance of technical specifications; implementation of the “Boiler Air Pollutant Emission Standard” (GB 13271) for pollution-producing facilities and discharge outlets shall be applicable to the “Emission Application for Pollution Permit and Issuance of Technical Specifications for Boilers (HJ 953). This standard does not make provisions but discharges industrial waste water, waste gas or other toxic and harmful air pollutants specified by the state. Pollution facilities and discharge outlets shall be implemented in accordance with the "General Rules for the Application and Issuance of Pollution Permits" (HJ 942). 2.Normative references This standard quotes the following documents or their clauses. For undated reference documents, the effective version is applicable to this standard. GB 8978 Integrated Wastewater Discharge Standard GB 9078 Emission Standard of Air Pollutants for Industrial Furnaces GB 13223 Emission Standard of Air Pollutants for Thermal Power Plants GB 13271 Boiler Air Pollutant Emission Standard GB 14554 Emission Standard of Odor Pollutants GB 16297 Comprehensive Emission Standard of Air Pollutants GB 18484 pollution control standard for hazardous waste incineration GB 18597 Pollution Control Standard for Hazardous Waste Storage GB 18599 Pollution control standard for general industrial solid waste storage and disposal sites GB 31572 Pollutant Emission Standard for Synthetic Resin Industry GB 37822 Unorganized emission control standard of volatile organic compounds GB/T 4754 Classification of National Economic Industries GB/T 16157 Determination of particulate matter in exhaust from stationary sources and sampling method for gaseous pollutants GB/T 50934 Petrochemical Engineering Anti-seepage Technical Code HJ/T 55 Technical Guidelines for Monitoring Unorganized Emissions of Air Pollutants HJ 75 Technical specification for continuous monitoring of emission of stationary pollution source flue gas (SO2, NOX, particulate matter) HJ 76 Technical requirements and testing methods for continuous monitoring system for emission of stationary pollution source flue gas (SO2, NOX, particulate matter) HJ 91.1 Technical Specification for Wastewater Monitoring 2HJ 212 Data transmission standard for online automatic monitoring (monitoring) system of pollution sources HJ 353 Water Pollution Source Online Monitoring System (CODCr, NH3-N, etc.) Installation Technical Specification HJ 354 Technical Specification for Acceptance of Online Water Pollution Source Monitoring System (CODCr, NH3-N, etc.) HJ 355 water pollution source online monitoring system (CODCr, NH3-N, etc.) operation technical specifications HJ 356 Water pollution source online monitoring system (CODCr, NH3-N, etc.) data validity judgment technical specification HJ/T 397 Fixed source exhaust gas monitoring technical specification HJ 493 Technical Regulations for Storage and Management of Water Quality Samples HJ 494 Technical Guide for Water Quality Sampling HJ 495 Technical Regulations for Water Quality Sampling Scheme Design HJ 521 Wastewater Discharge Law Code (Trial) HJ 608 Code Rules for Pollutant Discharge Units HJ 819 General Rules of Technical Guidelines for Self-monitoring of Pollutant Discharge Unit HJ 853 Pollutant Discharge Permit Application and Issuance Technical Specification Petrochemical Industry HJ 942 General Rules of Technical Specifications for Pollution Discharge Permit Application and Issuance HJ 944 Technical Specification for Environmental Management Ledger and Pollution Permit Implementation Report of Pollutant Discharge Units (Trial) "List of Classification Management of Discharge Permits for Fixed Pollution Sources" "Administrative Measures for Pollution Discharge Permits (Trial)" (Ministry of Environmental Protection Order No. 48) "Technical Requirements for Standardized Remediation of Sewage Outlets (Trial)" (Environmental Supervision [1996] No. 470) 3.Terms and definitions The following terms and definitions apply to this standard. 3.1 Pollutant emission unit of coal-based synthesis gas Refers to the use of coal or coke as raw materials, oxygen (air, oxygen-enriched or pure oxygen), water vapor, etc. as gasification agent, passing under high temperature conditions The chemical reaction converts the combustible part of coal or coke into a gas pollutant discharge unit. The effective components of the gas include carbon monoxide, hydrogen and methane. The synthesis gas is used in industrial production or as a raw material for chemical production. 3.2 Pollutant emission unit of coal-based liquid fuel Refers to the conversion of solid coal into liquid fuels, chemical raw materials and products (such as coal to methanol, coal to dimethyl Ether, coal-to-glycol, coal-to-oil, coal-to-olefin, etc.) 3.3 permitted emission limits Refers to the maximum discharge concentration (rate) and discharge volume of pollutants that are allowed by the pollutant discharge unit as specified in the pollution discharge permit. 3.4 special period Refers to the specific requirements for pollutant discharge of pollutants in accordance with national and local plans for meeting standards and other relevant environmental management regulations. Periods of special requirements, including the period of response to heavy pollution weather. 3.5 Abnomal condition Refers to working conditions such as start-up, shutdown, or equipment maintenance of production equipment or facilities. 4.Requirements for the basic information of the pollutant discharge unit 4.1 General principles The pollutant discharge unit shall fill in the corresponding information form on the national pollution discharge permit management information platform in accordance with the requirements of this standard. Pollution permit platform Those that are not included in the drop-down menu, are required by the local ecological and environmental authorities, or the pollutant discharge unit thinks they need to 3 Increase content. The local ecological and environmental authorities at or above the municipal level with districts may, in accordance with local regulations, add The content, and fill in the column of “management content added by local ecological and environmental authorities with the right to issue approval” in the pollution discharge permit platform. 4.2 Basic information of pollutants The basic information of the pollutant discharge unit should be filled in with the name of the unit, whether it needs to be corrected, the category of pollution discharge permit management, postal code, and industry category (Select the coal-to-syngas C 2522 and coal-to-liquid fuel C 2523 in the coal processing industry C 252 in GB/T 4754 for reporting), yes Whether it is put into operation, the date of putting into operation, the latitude and longitude of the center of the production and operation site, and whether the location is an environmentally sensitive area (such as a key atmospheric control area Etc.), whether it is located in an industrial park/zone, the name of the industrial park/zone to which it belongs, the environmental impact assessment approval comment number (record number), and the place The document number of the government’s identification or filing of illegal projects, the document number of the total distribution plan of major pollutants, and the total particulate matter indicators (tons/ Year), total sulfur dioxide indicator (ton/year), total nitrogen oxide indicator (ton/year), total chemical oxygen demand indicator (ton/year), Total ammonia nitrogen indicators (tons/year), total other pollutants indicators (if any), etc. 4.3 Main products and production capacity 4.3.1 Main production units, production facilities and facility parameters The main production units are divided according to products. The main production units of coal-to-syngas include coal preparation, gasification, shifting, acid gas removal, sulfur recovery, air separation, and public works. The main production units of coal-to-methanol include coal preparation, gasification, shifting, acid gas removal, sulfur recovery, methanol synthesis, air separation, and utility Engineering etc. The main production units of coal-to-dimethyl ether include coal preparation, gasification, shifting, acid gas removal, sulfur recovery, methanol synthesis, and dimethyl ether synthesis. Production, air separation, public works, etc. The main production units of coal to olefins include coal preparation, gasification, shifting, acid gas removal, sulfur recovery, methanol synthesis, and methanol to olefins (MTO)/Methanol to Propylene (MTP), air separation, public works, etc. The main production units of coal-to-natural gas include coal preparation, gasification, shifting, acid gas removal, sulfur recovery, methanation, air separation, and utility Engineering etc. The main production units of coal-to-ethylene glycol include coal preparation, gasification, shifting, acid gas removal, sulfur recovery, glycol synthesis, air separation, Public works, etc. The main production units of coal-to-liquid (indirect liquefaction method) include coal preparation, gasification, shifting, acid gas removal, sulfur recovery, oil synthesis, Hydrogen production from exhaust gas, oil processing, air separation, public works, etc. The main production units of coal-to-liquid (direct liquefaction method) include coal preparation, catalyst preparation, pulverized coal preparation, coal liquefaction, coal liquefaction Hydrogen stabilization, hydrogenation upgrading, coal hydrogen production (gasification, conversion, acid gas removal), sulfur-containing sewage stripping, gas desulfurization, sulfur recovery, oil Slag forming, air separation, public works, etc. For production facilities, report the facilities that characterize production capacity, waste gas or wastewater, and the facility parameters are storage capacity, processing capacity, etc. row The number of sealing points of equipment and pipeline components containing volatile organic materials in the entire plant of the polluting unit is ≥2000, and the entire plant shall be reported as having volatile organic compounds. Number of sealing points of equipment and pipeline components for organic materials. 4.3.2 Production facility number The pollutant discharge unit can fill in the internal production facility number. If the pollutant discharge unit does not have an internal production facility number, it shall be reported in accordance with HJ 608. 4.3.3 Product name Fill in the name of the main product, including synthesis gas (calculated as H2CO), natural gas, methanol, hydrogen, sulfur, gasoline, diesel, Aviation fuel, ethylene, propylene, ethylene glycol, etc. 4.3.4 Production capacity and measurement units Fill in the design production capacity, and indicate the unit of measurement, excluding the production capacity eliminated or banned by the state or local government. 4.3.5 Design year production time Fill in the environmental impact assessment documents and their approval opinions, or the local government’s identification of non-compliance projects or the annual production volume determined by the filing documents. 7 hours. If there is no relevant document or the production time is not specified in the document, the report shall be based on the average of the actual operating time in the past 3 years. 4.3.6 Other If the pollutant discharge unit needs to explain, it can fill in the report. 4.4 Main raw and auxiliary materials and fuels 4.4.1 General principles Fill in the names of raw materials, auxiliary materials and fuels, design usage and measurement unit, composition and proportion. 4.4.2 Name The raw materials are mainly coal and coke, among which coal is divided into lignite, bituminous coal, and anthracite. For auxiliary materials, fill in the main auxiliary materials added in the production process, wastewater treatment and waste gas treatment, including catalysts, desulfurizers (stone Limestone, lime, calcium carbide slag, magnesium oxide, magnesium hydroxide, etc.), denitration agents (liquid ammonia, urea, ammonia, etc.), common water treatment chemicals (Hydrochloric acid, caustic soda, coagulant, coagulant, flocculant, scale inhibitor, etc.), others. Fuels include fuel oil, fuel gas, natural gas, fuel coal, etc. 4.4.3 Designed annual usage Report the designed annual usage that matches the production (processing) capacity. If there is no designed annual usage, according to the actual usage in the past 3 years Report the average value. 4.4.4 Composition Raw coal should report sulfur, ash, nitrogen, mercury, arsenic, lead, etc., and coke should report sulfur, ash, etc. Fill in the content of ash, sulfur, volatile, low calorific value and mercury for fuel coal, and fill in sulfur and low content for fuel oil and gas fuel Heat etc. 4.4.5 Other If the pollutant discharge unit needs to explain, it can fill in the report. 4.5 Production and discharge links, pollutants and pollution control facilities 4.5.1 General principles Exhaust gas includes the name of the corresponding pollution link, the type of pollutant, the form of discharge (organized or unorganized), pollution control facilities and participation Number, whether it is a feasible technology, organized discharge port number, whether the discharge port is set up in a standardized way, and the type of discharge port, etc. Wastewater includes waste water category, pollutant type, discharge destination, discharge law, pollution control facilities and parameters, and whether it is a feasible technology Technology, discharge port number, whether discharge port setting is standardized and discharge port type, etc. 4.5.2 Exhaust gas 4.5.2.1 Main production and discharge links of waste gas, pollutant items, emission forms and pollution control facilities See Table 2 for waste gas production and discharge links, pollutant items, discharge forms and pollution control facilities. Others not listed in Table 2 The production and discharge links, pollutant items, discharge forms, and pollution control facilities shall be filled in by the pollutant discharge unit. The pollutant items in Table 2 depend on According to GB 16297, GB 14554, GB 18484, GB 37822, etc., the regulations will be followed after the industry pollutant emission standards are released. Where local pollutant discharge standards have stricter requirements, follow their regulations. 4.5.2.2 Pollution control facilities and discharge port numbers The parameters of pollution control facilities include parameter names, design values, and measurement units. The parameter names include exhaust gas emissions, annual operation time. The serial number of the pollution control facility can be reported as the internal serial number of the pollutant discharge unit. If the sewage unit has no internal serial number, it shall be serialized according to HJ 608 And fill in. The number of the organized discharge outlet can be filled in with the existing number of the local ecological environment management department, or compiled by the pollutant discharge unit according to HJ 608 Number and fill in. 4.5.2.3 Discharge port setting According to the "Technical Requirements for Standardized Remediation of Sewage Outlets (Trial)", relevant local management requirements, and discharges implemented by pollutants Regarding the regulations on the standardized setting of exhaust outlets in the standard, report whether the setting of exhaust gas outlets meets the standardized requirements. Local pollutant discharge If the standard has stricter requirements, follow its regulations. 4.5.2.4 Type of discharge port The exhaust gas discharge ports are divided into main discharge ports, general discharge ports and other discharge ports, as shown in Table 2. 4.5.3 Wastewater 4.5.3.1 Wastewater category, pollutant items and pollution control facilities The waste water category, pollutant items, discharge destination and pollution control facilities of the pollutant discharge unit are shown in Table 3.Pollutants in Table 3 The project is determined according to GB 8978, and the regulations will be followed after the release of the industry pollutant emission standards. Local pollutant discharge standards are stricter If required, follow its regulations. 4.5.3.2 Wastewater destination, discharge destination and discharge law The pollutant discharge unit shall clarify the destination, discharge destination and discharge rules of wastewater. The destination of wastewater includes entering pretreatment facilities, integrated sewage biochemical and reuse treatment facilities in the plant, and concentrated brine treatment facilities. The discharge destination includes direct entry into rivers, lakes, reservoirs, sea areas and other environmental water bodies; into urban sewers and then into rivers, lakes, reservoirs, Coastal waters; entering public sewage treatment facilities such as urban sewage treatment facilities, industrial wastewater treatment facilities, etc.; entering other orders Position; no discharge (entering evaporation pond or evaporation crystallization); others. When wastewater enters the environmental water body directly or indirectly, report the discharge rule, and report it when it is not discharged. See the category of wastewater discharge rules HJ 521. 4.5.3.3 Pollution treatment facility and discharge port number The parameters of pollution treatment facilities include parameter names, design values and measurement units. See Table 3 for specific parameters. The serial number of the pollution control facility can be reported as the internal serial number of the pollutant discharge unit. If the sewage unit has no internal serial number, it shall be serialized according to HJ 608 And fill in. The number of the waste water discharge outlet can be filled in with the existing number of the local ecological environment management department, or the pollutant discharge unit shall be numbered according to HJ 608 And fill in. 4.5.3.4 Discharge port setting According to the "Technical Requirements for Standardized Remediation of Sewage Outlets (Trial)", relevant local management requirements, and discharges implemented by pollutants Regarding the regulations on the standardized setting of discharge outlets in the standard, report whether the setting of wastewater discharge outlets meets the standardized requirements. Local pollutant discharge If the standard has stricter requirements, follow its regulations. 4.5.3.5 Type of discharge port Wastewater discharge outlets are divided into general discharge outlets, workshop or workshop treatment facility discharge outlets, and the specific discharge outlet types are shown in Table 3. 4.6 Drawing requirements a) General layout of the plant Give the general layout plan of the factory area, which should indicate the name and location of the main production equipment, public facilities, etc., and organize exhaust gas emissions Source and waste water outlet location. b) The layout of rainwater and sewage pipelines of the whole plant The direction and discharge destination of rainwater and sewage pipelines in ...