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HJ 1036-2019 English PDF

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HJ 1036-2019: Technical specifications for application and issuance of pollutant permit polyvinylchloride (PVC) industry
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Basic data

Standard ID HJ 1036-2019 (HJ1036-2019)
Description (Translated English) Technical specifications for application and issuance of pollutant permit polyvinylchloride (PVC) industry
Sector / Industry Environmental Protection Industry Standard
Word Count Estimation 65,697
Date of Issue 2019-08-13
Date of Implementation 2019-08-13
Issuing agency(ies) Ministry of Ecology and Environment

HJ 1036-2019: Technical specifications for application and issuance of pollutant permit polyvinylchloride (PVC) industry


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Technical specifications for application and issuance of pollutant permit polyvinylchloride (PVC) industry National Environmental Protection Standard of the People's Republic Sewage permit application and issuance technical specifications Polyvinyl chloride industry Technical specifications for application and issuance of pollutant permit Polyvinylchloride (PVC) industry Published on.2019-08-13 2019-08-13 Implementation Ministry of Ecology and Environment released

Content

Foreword ... ii 1 Scope ... 1 2 Normative references ... 1 3 Terms and Definitions ... 3 4 Basic requirements for reporting of sewage disposal units ... 3 5 How to determine the corresponding discharge port and the allowable emission limit for the production and discharge of pollutants... 13 6 Feasible technical requirements for pollution prevention and control ... 17 7 Self-monitoring management requirements ... 19 8 Environmental Management Accounting Record and Emission Permit Implementation Reporting Requirements ... 23 9 Actual emissions accounting method ... 27 10 Compliance Determination Method ... 31 Appendix A (informative appendix) Possible technical reference for pollution prevention and control ... 34 Appendix B (informative) Environmental Management Accounting Record Reference Table ... 37 Appendix C (informative appendix) implementation report preparation reference table ... 44

Foreword

To implement the Law of the People's Republic of China on Environmental Protection, the Law of the People's Republic of China on the Prevention and Control of Water Pollution, Law on Prevention and Control of Gas Pollution, Laws and Regulations on Soil Pollution Prevention and Control of the People's Republic of China, and the General Office of the State Council on Printing and Controlling Pollutants Notice of Implementation Plan for Emission Permit System (Guo Dang Fa [2016] No. 81) and "Measures for the Administration of Sewage Permits (Trial)" (Ministry of Environmental Protection) Order No. 48), improve the technical support system for pollutant discharge permits, and guide and standardize the application and issuance of pollutant discharge permits for PVC industrial units Work to develop this standard. This standard stipulates the requirements for the basic situation of the application of the PVC industrial discharge permit and the issued pollutant discharge unit, and the permitted emission limit. Determination, actual emissions accounting method, compliance determination method, and self-monitoring, environmental management ledger, and discharge permit execution report Management requirements, put forward the feasible technical requirements for the prevention and control of PVC industrial pollution. Appendix A, Appendix B and Appendix C of this standard are informative annexes. This standard is the first release. This standard is formulated by the Department of Environmental Impact Assessment and Emission Management of the Ministry of Ecology and Environment, and the Department of Regulations and Standards. This standard is mainly drafted by. Beijing Environmental and Environmental Engineering Design Institute, China Chlor-Alkali Industry Association, China University of Mining and Technology (Beijing), China Tianchen Engineering Co., Ltd., Environmental Engineering Evaluation Center of the Ministry of Ecology and Environment, and Foreign Cooperation and Exchange Center of the Ministry of Ecology and Environment. This standard was approved by the Ministry of Ecology and Environment on August 13,.2019. This standard has been implemented since August 13,.2019. This standard is explained by the Ministry of Ecology and Environment. Sewage permit application and issuance technical specifications Polyvinyl chloride industry

1 Scope of application

This standard stipulates the requirements for the basic conditions of the application and issuance of PVC industrial discharge permits, the determination of the allowable emission limits, and the actual Environmental management requirements for emissions accounting, compliance determination techniques, and self-monitoring, environmental management ledgers, and discharge permit execution reports, The feasible technical requirements for the prevention and control of PVC industrial pollution were put forward. This standard is applicable to guide the industrial discharge unit of PVC to report the “Application for Pollution Discharge Permit” and the management information of sewage discharge permit in the country. The platform shall fill in the relevant application information and shall be applicable to guide the issuing authority to review and determine the requirements for the discharge permit of the PVC industrial sewage unit. This standard is applicable to the discharge permit management of pollutants and atmospheric pollutants discharged from PVC industrial discharge units. In the PVC industrial sewage discharge unit, the production facilities and discharge ports of the "Fire Power Plant Air Pollutant Emission Standards" (GB 13223) shall be implemented. Applicable to the Notice on Carrying out the Management of Elevated Source Pollution Discharge Permits in Thermal Power, Papermaking Industry and Beijing-Tianjin-Hebei Pilot City (Circular Water Body [2016] No. 189) Annex 1 “Technical Specifications for Application and Issuance of Pollution Discharge Permits for Thermal Power Industry”; Implementation of “Boiler Air Pollutant Emission Standards” (GB) The production facilities and discharges of 13271) are applicable to the “Drainage Permit Application and Issuance Technical Specification Boiler” (HJ 953). PVC industrial platoons that are not specified in this standard but emit atmospheric pollutants, water pollutants and toxic and harmful pollutants specified by the state. Other pollution-producing facilities and discharge outlets of sewage units shall be implemented with reference to the General Rules for the Application and Issuance of Pollution Discharge Permits (HJ 942).

2 Normative references

The contents of this standard refer to the following documents or their terms. For undated references, the latest edition applies to this standard. GB 8978 Integrated Wastewater Discharge Standard GB 13223 Standard for emission of atmospheric pollutants from thermal power plants GB 13271 Boiler Air Pollutant Emission Standard GB 14554 Odor Pollutant Emission Standard GB 15581 caustic soda, polyvinyl chloride industrial pollutant discharge standards GB 18484 Hazardous Waste Incineration Pollution Control Standard GB 18597 Hazardous Waste Storage Pollution Control Standard GB 18599 General industrial solid waste storage and disposal site pollution control standards GB 37822 Volatile Organic Compounds Unorganized Emission Control Standard GB/T 15432 Determination of total airborne particulate matter - Gravimetric method GB/T 16157 Determination of particulate matter in fixed pollution source exhaust gas and sampling method of gaseous pollutants HJ/T 38 Determination of non-methane total hydrocarbons in fixed source s HJ/T 55 Technical Guidelines for the Monitoring of Unorganized Emissions of Air Pollutants HJ 75 Fixed Pollution Source Flue Gas (SO2, NOx, Particulate Matter) Emissions Continuous Monitoring Technical Specification HJ 76 Technical requirements and test methods for continuous monitoring system for stationary pollution source flue gas (SO2, NOx, particulate matter) HJ/T 91 Surface Water and Wastewater Monitoring Technical Specifications HJ/T 92 Water Pollutant Total Monitoring Technical Specification HJ 194 Technical Specifications for Manual Air Quality Monitoring HJ 212 pollution source online automatic monitoring (monitoring) system data transmission standard HJ/T 353 Water Pollution Source Online Monitoring System Installation Technical Specification (Trial) HJ/T 354 Water Pollution Source Online Monitoring System Acceptance Technical Specification (Trial) Technical Specifications for Operation and Assessment of HJ/T 355 Water Pollution Source Online Monitoring System (Trial) HJ/T 356 Water Pollution Source Online Monitoring System Data Validity Discrimination Technical Specification (Trial) HJ/T 373 Technical Specifications for Quality Assurance and Quality Control of Fixed Pollution Source Monitoring (Trial) HJ/T 397 Fixed Source Exhaust Gas Monitoring Technical Specification HJ 493 Water quality Sample preservation and management technical regulations HJ 494 Water Quality Sampling Technical Guidance HJ 495 water quality sampling plan design technical regulations HJ 608 sewage unit coding rules HJ 732 Fixed source pollution, sampling of volatile organic compounds HJ 819 Self-monitoring technical guide for sewage disposal units HJ 917 Fixed source pollution gas Determination of gaseous mercury Activated carbon adsorption/thermal cracking atomic absorption spectrophotometry HJ 942 Sewage Permit Application and Issuance Technical Specifications General Technical Specifications for HJ 944 Emissions Unit Environmental Management Account and Emission Permit Execution Report General (Trial) HJ 953 Sewage Permit Application and Issuance Technical Specification Boiler HJ 2051 Technical specification for caustic soda and polyvinyl chloride industrial wastewater treatment engineering "List of classified management of fixed pollution source discharge permits" Measures for the Management of Pollution Discharge Permits (Trial) (Order No. 48 of the Ministry of Environmental Protection) Technical Requirements for Standardized Remediation of Sewage Discharges (Trial) (National Environmental Protection Agency Environmental Supervision [1996] No. 470) Measures for the Operation and Management of Automatic Monitoring Facilities for Pollution Sources (Huanfa [2008] No. 6) Announcement on the Implementation of Special Emission Limits for Air Pollutants (Notified by the Ministry of Environmental Protection No. 14 of.2013) Notice of the General Office of the State Council on Strengthening Environmental Supervision and Enforcement (Guo Ban Fa [2014] No. 56) "Technical Policy on Prevention and Control of Mercury Pollution" (Organization of the Ministry of Environmental Protection No. 90 of.2015) "13th Five-Year Plan" Ecological Environmental Protection Plan (Guo Fa [2016] No. 65) Notice of the General Office of the State Council on Printing and Distributing the Implementation Plan for the Control of Pollutant Discharge Permit System (Guo Ban Fa [2016] No. 81) Circular on Carrying out the Management of Elevated Source Pollution Discharge Permits in Thermal Power, Papermaking Industry and Beijing-Tianjin-Hebei Pilot City (Circular Water Body [2016] No. 189) Notice on Strengthening the Relevant Issues Concerning the Automatic Monitoring of Elevated Pollutants in Beijing-Tianjin-Hebei Region (Circular Office of the Environmental Protection Agency [2016] No. 1488) Notice on Strengthening Prevention and Control of Nitrogen and Phosphorus Pollution from Fixed Pollution Sources (Circular Water Body [2018] No. 16) The Minamata Convention on Mercury Notice on Promulgating Samples of Emission Permits, Sewage Permit Application Forms and Emission Permit Formats (Circular Regulations [2018] No. 80)

3 Terms and definitions

The following terms and definitions apply to this standard. 3.1 PVC industrial sewage unit polyvinyl chloride (PVC) industry pollutant emission unit Refers to the industrial sewage unit that produces polyvinyl chloride by the acetylene method, the ethylene method and the monomer method. 3.2 Acetylene method acetylene method It refers to the production process of producing vinyl chloride by using acetylene and hydrogen chloride as raw materials and synthesizing polyvinyl chloride by polymerization. 3.3 ethylene method It refers to a production process for producing vinyl chloride by using ethylene, chlorine or the like or dichloroethane as a raw material to synthesize polyvinyl chloride by polymerization. 3.4 Monomer method It refers to the production process of directly synthesizing polyvinyl chloride as raw material and directly synthesizing polyvinyl chloride. 3.5 General Polyvinyl Chloride Resin Production Process production process of general PVC resin The production process of polymerizing vinyl chloride monomer into polyvinyl chloride resin by suspension polymerization and bulk polymerization. 3.6 Production process of paste polyvinyl chloride resin production process of paste PVC resin The production process of polymerizing vinyl chloride monomer into polyvinyl chloride resin by emulsion polymerization and microsuspension polymerization. 3.7 Permitted emission limits Refers to the maximum emission concentration and emissions of pollutants allowed by the discharge unit specified in the discharge permit. 3.8 Special time periods special periods Refers to the environmental quality deadlines and other relevant environmental management regulations formulated by the local people's government according to law, and for the sewage disposal units. Periods with special requirements for pollutant discharge, including heavy pollution weather response period and winter defense period. 3.9 abnormal situation Refers to the abnormal working conditions of the production facilities such as opening and closing furnaces (machines), equipment maintenance, and abnormal operation of process equipment or abnormal conditions of pollution control facilities.

4 Basic requirements for reporting the discharge unit

4.1 Basic principles The PVC industrial pollutant discharge unit shall, in accordance with the requirements of this standard, fill in the “discharge permit” in the national pollutant discharge permit management information platform declaration system. Corresponding information in the certifiable application form. The local ecological environment authorities not included in the drop-down menu of the filling system have regulations to fill in the report or If the sewage disposal unit thinks that it needs to fill in the report, it can increase the content by itself. The local ecological environment competent department at or above the municipal level in the district may increase the need for the pollutant discharge permit according to the local regulations on environmental protection. The contents stated in the report and filled in the national sewage permit management information platform declaration system "the local ecological environment competent authority with nuclear powers increased "Management content" column. The pollutant discharge unit that has not obtained the approval opinion for the environmental impact assessment document of the construction project in accordance with the law has not obtained the relevant The pollutant discharge control units or measures adopted in accordance with the law shall deal with and rectify the relevant certification materials issued by the regulations. The pollutant discharge unit required by the emission concentration, and the other pollutant discharge units that need to correct the behavior according to the regulations, apply for the discharge of the pollutant discharge permit for the first time. When requesting information, it should be in the “Correction Correction” column in the National Pollution Discharge License Management Information Platform Filing System, when the correction plan is proposed and clearly completed. limit. The PVC industrial discharge unit shall report in accordance with the actual situation and shall be negatively responsible for the authenticity, legality and integrity of the submitted application materials. Legal responsibility. 4.2 Basic information of sewage disposal units The basic information of the pollutant discharge unit should be filled in the name of the pollutant discharge unit, whether it needs to be corrected, the discharge permit management category, postal code, and industry No, whether it is put into production, the date of production, the latitude and longitude of the center of the production and operation site, and whether the location is a sensitive area of the environment (such as the key control of the atmosphere) System area, total phosphorus total nitrogen control area, etc.), whether it is located in the industrial park and its industrial park name, environmental impact assessment approval opinion number (prepared Case number), local government's identification of illegal projects or filing documents and document numbers, major pollutants distribution plan documents and document numbers, chemical needs Total oxygen index (t/a), total ammonia nitrogen index (t/a), total sulfur dioxide index (t/a), total nitrogen oxides index (t/a), Total particulate matter index (t/a), total volatile organic matter (in terms of non-methane total hydrocarbons, t/a), and other pollutants total indicators (if any) Wait. When reporting industry categories, PVC industrial sewage units should choose primary form plastics and synthetic resin manufacturing (national economic classification code) C2651). 4.3 Main products and production capacity 4.3.1 General principles The main product and capacity report the main production unit name, main process name, production facility name, production facility number, facility parameters, Product name, production capacity, unit of measurement, design year production time and others. The following “4.3.2-4.3.6” are required and “4.3.7” is optional. 4.3.2 Main production units, main processes, production facilities and facility parameters The acetylene-based polyvinyl chloride industrial sewage unit refers to Table 1 to fill in the main production unit, production process, production facilities and facility parameters. Rong. The ethylene-based polyvinyl chloride industrial sewage unit refers to Table 2 to fill in the main production unit, production process, production facilities and facility parameters. Rong. The ethylene method using ethylene as a raw material is started from the dichloroethane production unit, and the ethylene method using dichloroethane as a raw material is produced from vinyl chloride. The production unit begins to be filled in, and the monomer method is filled in from the polymerization unit. The unit that produces the PVC in combination with the ethylene method and the acetylene method shall also fill in the contents of Tables 1 and 2. Table 1 Table of main production units, main production processes, production facilities and facilities of acetylene-based polyvinyl chloride industrial sewage unit Main production unit Main production process Production facilities Facility parameters raw material system Calcium carbide crushing calcium carbide crusher crushing capacity (t/h) Calcium carbide conveying system conveying capacity (t/h) Acetylene Production unit Acetylene production Dry method Acetylene generator gas production (m3/h) Wet method Acetylene purification Clean tower Processing capacity (m3/h) Alkali washing tower Vinyl chloride synthesis unit Vinyl chloride synthesis Vinyl chloride converter Production capacity (m3/h) Syngas demercuration Processing capacity (m3/h) Vinyl chloride purification Falling film absorber/deacidification tower Washing tower Alkali washing tower Vinyl chloride distillation distillation column processing capacity (m3/h) Aggregation unit Vinyl chloride polymerization, polymerizer, production capacity (t/h) Vinyl chloride recovery slurry stripper treatment capacity (m3/h) Dry packaging unit PVC drying dryer (except the bulk method) Processing capacity (t/h) PVC storage silo PVC packaging machine Common unit Water supply and drainage system, circulating water cooling tower, circulating water volume (m3/h) Soft water preparation system ion exchange reactor/reverse osmosis unit treatment water volume (m3/h) Integrated sewage treatment system sewage treatment facility treatment water volume (m3/h) Table 2 Table of main production units, main production processes, production facilities and facilities of ethylene-based polyvinyl chloride industrial sewage unit Main production unit Main production process Production facilities Facility parameters Dichloroethane production unit Direct chlorination direct chlorination reactor Production capacity (t/h) Oxychlorination oxychlorination reactor Waste water stripping stripper treatment capacity (t/h) Dichloroethane purification Low boiler degassing tower Processing capacity (t/h) High boiler de-weighting tower Vinyl chloride production unit Dichloroethane cracking cracking furnace Processing capacity (t/h) Vinyl chloride distillation tower Aggregation unit Vinyl chloride polymerization, polymerizer, production capacity (t/h) Vinyl chloride recovery slurry stripper treatment capacity (m3/h) Table 2 Table of main production units, main production processes, production facilities and facilities of ethylene-based polyvinyl chloride industrial sewage unit (Continued) Main production unit Main production process Production facilities Facility parameters Dry packaging unit Polyvinyl chloride drying dryer Production capacity (t/h) PVC storage silo PVC packaging machine Common unit Water supply and drainage system, circulating water cooling tower, circulating water volume (m3/h) Soft water preparation system ion exchange reactor/reverse osmosis unit treatment water volume (m3/h) Exhaust gas incineration treatment system Incinerator treatment capacity (m3/h) Integrated sewage treatment system sewage treatment facility treatment water volume (m3/h) 4.3.3 Production Facility Number The sewage unit fills in the internal production facility number. If the sewage unit does not have an internal production facility number, it is numbered and filled according to HJ 608. Newspaper. 4.3.4 Product Name Polyvinyl chloride, including dichloroethane and vinyl chloride sold as commodities. 4.3.5 Production capacity and unit of measurement Production capacity is the main product design capacity, excluding production capacity that is eliminated or banned by the state or local government. The production capacity is measured in t/a. 4.3.6 Design annual production time Fill in the production time in the environmental impact assessment document and the approval opinion or the local government's identification of the illegal project or the filing document. If If the production time is not clear in the document, it will be reported according to the actual production time. 4.3.7 Other If you need to explain the contents of the PVC industrial sewage disposal unit, you can fill it out. 4.4 Main raw and auxiliary materials and fuel 4.4.1 General principles The main raw and auxiliary materials and fuels should be reported as raw and auxiliary materials and fuel types, components and proportions, design annual usage and units of measurement. Belonging to danger The raw materials, excipients and fuels of the Catalogue of Hazardous Chemicals should be fully reported. 4.4.2 Raw materials and auxiliary materials 4.4.2.1 Type The raw materials for the production of acetylene polyvinyl chloride include acetylene (or calcium carbide), hydrogen chloride, and others. The raw materials for the production of ethylene polyvinyl chloride include ethylene, oxygen, chlorine, dichloroethane, vinyl chloride, and others. Excipients fill in the main excipients in the production process, as well as the chemicals and consumables used in the wastewater treatment and waste gas treatment processes, including catalysts. Activated carbon, ion exchange resin, coagulant, etc. 4.4.2.2 Design annual usage and unit of measurement Report the annual usage of the design that matches the design production capacity. The unit of measure for design annual usage is t/a or Nm3/a. 4.4.2.3 Toxic and harmful components and proportion in raw and auxiliary materials According to the design annual usage or the actual use of the previous year, the toxic and harmful components and proportion of the main raw and auxiliary materials are reported. 4.4.3 Fuel 4.4.3.1 Type Fuels include coal, fuel oil, fuel gas, natural gas, liquefied petroleum gas, and others. In the remarks, it should be marked as self-produced or purchased. 4.4.3.2 Design annual usage and unit of measurement Report the annual usage that matches the production capacity. The unit of measure for design annual usage is t/a or Nm3/a. 4.4.3.3 Fuel ash, sulfur, volatile matter and calorific value The solid fuel is filled with ash, sulfur, volatile matter and calorific value (low calorific value). Liquid fuel and gaseous fuel to report sulfur (liquid fuel) According to the sulfur content, the gaseous fuel is based on hydrogen sulfide and the calorific value (low calorific value). The reported values...

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