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GB/T 33056-2016 English PDF

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GB/T 33056-2016: Technical specification for fluorine waste gas treatment and disposal
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Basic data

Standard ID GB/T 33056-2016 (GB/T33056-2016)
Description (Translated English) Technical specification for fluorine waste gas treatment and disposal
Sector / Industry National Standard (Recommended)
Classification of Chinese Standard Z05
Classification of International Standard 13.030.30
Word Count Estimation 10,147
Date of Issue 2016-10-13
Date of Implementation 2017-05-01
Regulation (derived from) National Standard Notice No.1716 of 2016
Issuing agency(ies) General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China

GB/T 33056-2016: Technical specification for fluorine waste gas treatment and disposal

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Technical specification for fluorine waste gas treatment and disposal ICS 13.030.30 Z05 National Standards of People's Republic of China Technical specification for disposal of fluorine - containing waste gas 2016-10-13 released 2017-05-01 implementation General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China China National Standardization Management Committee released

Foreword

This standard is drafted in accordance with the rules given in GB/T 1.1-2009. This standard is proposed by the China Petroleum and Chemical Industry Association. This standard is under the jurisdiction of the National Standardization Technical Committee on Disposal of Waste Chemicals (SAC/TC294). The drafting unit of this standard. Yunnan Fenye Environmental Protection Technology Co., Ltd., Weifang Daoyao New Material Co., Ltd., Xiamen Gao Puer Automation Equipment Co., Ltd., Sinochem Chongqing Fuling Chemical Co., Ltd., Quanzhou Yunshang Sanwei Technology Co., Ltd., Guizhou Wengfu Blue Sky Fluorine Chemical Co., Ltd. Co., Ltd., Zhejiang Chemical Industry Research Institute Co., Ltd., Guizhou Province Product Quality Supervision and Inspection Institute, CNOOC Tianjin Chemical Research and Design Institute. The main drafters of this standard. Lin Minghui, Wang Qiang, Feng Jianping, Li Bing, Xu Huagang, Meng Wenxiang, Fang Lu, Chen Jianmin, Zhong Hongbo, Shi Wanjun, Zhao Meijing. Technical specification for disposal of fluorine - containing waste gas

1 Scope

This standard specifies the main components of fluorine-containing waste gas, treatment and disposal methods and environmental protection requirements. This standard applies to wet phosphoric acid and phosphate fertilizer produced in the process of production of fluorine.

2 normative reference documents

The following documents are indispensable for the application of this document. For dated references, only the dated edition applies to this article Pieces. For undated references, the latest edition (including all modifications) applies to this document. GB 7744 Industrial hydrofluoric acid GB 7746 Industrial anhydrous hydrogen fluoride Emission standard for odorous pollutants GB 14554 GB 16297 Integrated Emission Standard for Air Pollutants HG/T 4692 Industrial ammonium fluorosilicate

3 fluorine containing the main components of waste gas

The main components of fluorine-containing waste gas are silicon tetrafluoride (SiF4) gas and hydrogen fluoride (HF) gas.

4 Dispose of disposal methods

4.1 Production of ammonium fluorosilicate 4.1.1 Principle Ammonium fluoride solution is used to absorb the fluorine-containing waste gas to obtain the ammonium fluorosilicate solution, crystallized by cooling, centrifuged and dried to obtain the finished product. Its reaction The equation is as follows. SiF4 2NH4F → (NH4) 2SiF6 The ammonium dilute ammonium silicate reacts with ammonia to give a lower concentration of ammonium fluoride solution, which can be used to absorb fluorine-containing waste gas The reaction equation is as follows. (NH4) 2SiF6 4NH3 2H2O → 6NH4F SiO2 Ammonium fluoride solution can also be used to absorb fluorine-containing waste gas to obtain ammonium fluoride solution, without cooling crystallization and direct access to ammonia, can be concentrated High ammonium fluoride solution, ammonium fluoride solution can be used for the preparation of such as ammonium fluoride, ammonium hydrogen fluoride, aluminum fluoride and other inorganic fluoride. At the same time can be added Water diluted part of the higher concentration of ammonium fluoride solution, diluted for the absorption of fluorine-containing waste gas. 4.1.2 Process flow A tower and two towers with a concentration of 15% to 25% of the ammonium fluoride solution as the absorption medium, the three towers of water as the absorption medium, A tower and two towers absorb the formation of ammonium fluorosilicate, at this time the basic absorption of fluoride exhaust gas is completely complete, and the absorption of a tower with three towers and two towers are not completely absorbed The amount of fluorine-containing waste gas, while a tower and the two tower ammonium fluoride solution volatile ammonium fluoride, ammonium fluorosilicate and free ammonia for washing absorption. A tower of suction