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Measuring ratio of anatase to rutile in titanium dioxide pigments by X-ray diffraction
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GB/T 30793-2014
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Basic data Standard ID | GB/T 30793-2014 (GB/T30793-2014) | Description (Translated English) | Measuring ratio of anatase to rutile in titanium dioxide pigments by X-ray diffraction | Sector / Industry | National Standard (Recommended) | Classification of Chinese Standard | G53 | Classification of International Standard | 87.060.10 | Word Count Estimation | 10,195 | Date of Issue | 7/8/2014 | Date of Implementation | 12/1/2014 | Quoted Standard | GB/T 3186 | Adopted Standard | ASTM D3720-1990(2011), NEQ | Regulation (derived from) | 2014 National Standards Bulletin No. 18 | Issuing agency(ies) | General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China | Summary | This standard specifies the method for the determination by X- ray diffraction of titanium dioxide pigment in anatase and rutile ratio. This standard applies to the determination of titanium dioxide pigment in anatase and rutile ratio. This standard can a |
GB/T 30793-2014: Measuring ratio of anatase to rutile in titanium dioxide pigments by X-ray diffraction ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Measuring ratio of anatase to rutile in titanium dioxide pigments by X-ray diffraction
ICS 87.060.10
G53
National Standards of People's Republic of China
Determination of X- ray diffraction of titanium dioxide pigment
Anatase and rutile ratio
Issued on. 2014-07-08
2014-12-01 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Foreword
This standard was drafted in accordance with GB/T 1.1-2009 given rules.
A method of this standard reference is made to the American Society for Testing and Materials standard ASTMD3720-1990 (2011) "Determination of X- ray diffraction Act II
Anatase titanium dioxide pigment and test methods "rutile ratio.
The standard proposed by China Petroleum and Chemical Industry Association.
This standard by the National Standardization Technical Committee paint pigment (SAC/TC5) centralized.
This standard was drafted. CNOOC Changzhou coating Chemical Research Institute, Shandong Dong Jia Group Co., Ltd., Nanjing Titanium White Chemical limited liability
Any company, DuPont China Holding Co., Ltd., Shanghai Yipin Pigments Co., Ltd., Guangzhou Supe Chemical Co., Ltd., Shenzhen Hirota Decoration Set
Group Company.
The main drafters of this standard. Huang Ning, Wan snow period, the whole of Lee, Xujia Shun Zhou Chun, Wang Danying, Albert Lee, Li Shaojiang.
Determination of X- ray diffraction of titanium dioxide pigment
Anatase and rutile ratio
1 Scope
This standard specifies the method for the determination by X- ray diffraction of titanium dioxide pigment in anatase and rutile ratio.
This standard applies to the determination of titanium dioxide pigment in anatase and rutile ratio. The method may also be used containing titanium dioxide pigment
The mixture, dry coating, liquid paint and powder coating.
A method of this standard apply to be free of interferences or interferences can be removed (see Appendix A) of any sample; B method is suitable for the sample
In all phases of qualitative accurate, and that any data sample crystal structure of these phases can be obtained.
2 Normative references
The following documents for the application of this document is essential. For dated references, only the dated version suitable for use herein
Member. For undated references, the latest edition (including any amendments) applies to this document.
GB/T 3186 Paints, varnishes and raw materials for paints and varnishes - Sampling
Principle 3
3.1 A standard method using the intensity ratio method, as measured from anatase and maximum diffraction peak intensity with X- ray diffraction rutile will
Diffraction peak intensity of anatase is converted into rutile with respect to the content of anatase, rutile content is determined by the difference.
3.2 Standard B method using the Rietveld analysis lawful, that is based on the crystal structure and structural parameters of the model assumptions, combined with a
Species peak shape function to calculate the polycrystalline diffraction, adjust these structural parameters and peak shape parameters make computing spectrum consistent with the experimental determination of the spectrum obtained
Structural parameters and peak shape parameters, and thus the determination of titanium dioxide pigment in anatase and rutile ratio.
4 instruments and experimental conditions
4.1 X- ray diffractometer
Comprehensive diffractometer stability better than 1%.
NOTE. Integrated stability of this standard instrument refers to the same conditions on the same test the same diffraction surface of the sample, measured once every 10min diffraction intensity in
Diffraction line intensity values \u200b\u200bmeasured within 8h relative standard deviation σ-1 (see YB/T 5320-2006).
4.2 Test Conditions 1)
4.2.1 High Voltage Power Supply
Signal intensity select X- ray tube voltage, current, and other conditions, so 0.1% is anatase produced at least four times the noise
strength.
1) In the case to ensure accuracy, but also to choose the best test conditions depending on the X- ray diffraction performance and test sample of the actual situation.
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