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Determination of rare earth in ink-stone by inductively coupled plasma mass spectrometry
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GB/T 30714-2014
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Basic data | Standard ID | GB/T 30714-2014 (GB/T30714-2014) | | Description (Translated English) | Determination of rare earth in ink-stone by inductively coupled plasma mass spectrometry | | Sector / Industry | National Standard (Recommended) | | Classification of Chinese Standard | D59 | | Classification of International Standard | 73.080 | | Word Count Estimation | 7,714 | | Date of Issue | 6/9/2014 | | Date of Implementation | 10/1/2014 | | Quoted Standard | GB/T 6682; GB/T 14505-2010; DZ/T 0130.2 | | Regulation (derived from) | National Standards Bulletin No. 11 of 2014 | | Issuing agency(ies) | General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China | | Summary | This Standard specifies the inductively coupled plasma mass spectrometry (ICP-MS) method Yanshitai method for the determination of rare earth elements. This Standard applies to Yanshitai rare earth elements scandium (Sc), yttrium (Y), lanthanum (La), ceri |
GB/T 30714-2014: Determination of rare earth in ink-stone by inductively coupled plasma mass spectrometry ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Determination of rare earth in ink-stone by inductively coupled plasma mass spectrometry
ICS 73.080
D59
National Standards of People's Republic of China
Inductively coupled plasma mass spectrometry
Yanshi Rare Earth Elements
Issued on. 2014-06-09
2014-10-01 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Foreword
This standard was drafted in accordance with GB/T 1.1-2009 given rules.
The standard proposed by the People's Republic of China Ministry of Land Resources.
This standard by the National Standardization Technical Committee jewelery (SAC/TC298) centralized.
This standard was drafted. Shenzhen Academy of Metrology and Quality Inspection.
The main drafters of this standard. the United States and Romania, Chen Zhiqiang, blue Yan, He Xiaoqing, Huang Xiaolong, Zhengyan Jie, Hu Shuyu, Yang Wanying.
Inductively coupled plasma mass spectrometry
Yanshi Rare Earth Elements
1 Scope
This standard specifies the inductively coupled plasma mass spectrometry (ICP-MS) method Yanshi method for the determination of rare earth elements.
This standard applies to Yanshitai rare earth elements scandium (Sc), yttrium (Y), lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), samarium (Sm), europium (Eu),
Gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu) measurement.
The standard methods of each rare earth element detection limit (mg/kg) were. Sc is 0.05; Y, La, Pr, Sm, Eu, Gd, Tb, Dy,
Ho, Er, Tm, Yb, Lu were 0.005; Ce is 0.1; Nd 0.025.
2 Normative references
The following documents for the application of this document is essential. For dated references, only the dated version suitable for use herein
Member. For undated references, the latest edition (including any amendments) applies to this document.
Laboratory use specifications and test methods GB/T 6682 Analysis
GB/T 14505-2010 Methods for chemical analysis of rocks and ores General rules and regulations
DZ/T 0130.2 Geology and Mineral Resources Laboratory Testing Quality Management specification - Part 2. Analysis of rock and mineral sample preparation
Principle 3
After acid digestion of the sample injection inductively coupled plasma mass spectrometer, under high temperature plasma by desolvation atom
, Post ionization enter the mass spectrometer. In a certain concentration range, the response is proportional to the intensity and measured REE contents with standard series
Quantitative comparison.
4 Reagents
4.1 Nitric acid. pure class distinctions.
4.2 nitrate solution (2% volume fraction). Take 20mL of nitric acid (4.1), diluted to 1000mL.
4.3 hydrochloride. pure class distinctions.
4.4 aqua regia. hydrochloric acid, nitric acid (31).
4.5 HF. pure class distinctions.
4.6 perchloric acid. pure class distinctions.
4.7 boric acid. pure class distinctions.
4.8 boric acid. 30g/L. 30g of boric acid (4.7), dissolved in 1L of water.
4.9 16 kinds of rare earth elements (Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) mixed standard stock solution
(10.0mg/L), the choice of the appropriate concentrations of certified reference material.
4.10 16 kinds of rare earth element standard solution (1.00mg/L); absorb 10.0mL rare earth elements mixed standard stock solution (4.9), placed
100mL flask with 2% nitric acid solution (4.2) diluted to the mark.
4.11 indium (In) standard solution (1000mg/L), the choice of the appropriate concentrations of certified reference material.
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