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Plastics -- Polypropylene (PP) and propylene copolymer thermoplastics -- Determination of isotactic index
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GB/T 2412-2008
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GB/T 2412-1980 | English | 239 |
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Polypropylene--Method of determination of normal indices
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PDF similar to GB/T 2412-2008
Basic data Standard ID | GB/T 2412-2008 (GB/T2412-2008) | Description (Translated English) | Plastics -- Polypropylene (PP) and propylene copolymer thermoplastics -- Determination of isotactic index | Sector / Industry | National Standard (Recommended) | Classification of Chinese Standard | G31 | Classification of International Standard | 83.080.20 | Word Count Estimation | 9,938 | Date of Issue | 2008-06-19 | Date of Implementation | 2009-02-01 | Older Standard (superseded by this standard) | GB/T 2412-1980 | Quoted Standard | GB/T 2546.1-2006 | Adopted Standard | ISO 9113-1986, MOD | Regulation (derived from) | National Standard Approval Announcement 2008 No.10 (Total No.123) | Issuing agency(ies) | General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China | Summary | This standard specifies the method of percentage of n-heptane polypropylene quality of the determination of the quality of the sample is not soluble in boiling under standard test conditions. This standard applies to GB/T 2546. 1-2006 described propylene homopolymer (PP-H), propylene impact copolymer (PP-B), propylene random copolymer (PP-R). This standard is applicable to conventional powder, granules or crushed granular polypropylene material. This standard does not apply to a colorant, fillers modified polypropylene material. |
GB/T 2412-2008: Plastics -- Polypropylene (PP) and propylene copolymer thermoplastics -- Determination of isotactic index ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Plastics. Polypropylene (PP) and propylene copolymer thermoplastics. Determination of isotactic index
ICS 83.080.20
G31
National Standards of People's Republic of China
Replacing GB/T 2412-1980
Plastic polypropylene (PP) and propylene copolymer thermoplastic
Plastics - Determination of isotactic index
(ISO 9113. 1986, MOD)
Posted 2008-06-19
2009-02-01 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Foreword
This revised standard adopts ISO 9113. 1986 "--- plastic polypropylene (PP) and propylene copolymer thermoplastics --- isotactic index measurement
Fixed "(in English).
This standard is based on ISO 9113. 1986 re-drafted. The standard lists the reg number and ISO 9113 in Appendix A. 1986 reg
Control list numbered. In Appendix B gives a list of these technical differences for reference.
This standard replaces GB/T 2412-1980 "polypropylene isotactic index test method."
This standard compared with GB/T 2412-1980 The main changes are as follows.
a) scope of application has been modified;
b) increase the "Normative references" chapter;
c) increase the "principle" chapter;
d) test procedure, when the sample preparation, the "approximately 2 times the amount of dry ice placed in enamel pan and mix" to "an appropriate amount of dry ice or liquid nitrogen mixed
Together "and increase" for films, fibers or films, such as the sample at least one dimension less than 0.6mm, you do not have to grind and sift. thin
The film should be cut into small pieces, small pieces of ribbon or by melt becomes friable form ";
e) test procedure, drying and annealing the sample, it will be "more than nitrogen pressure was kept at 180 mm Hg at 140 ℃ ± 2 ℃ dried
2h; for powder, vacuum and pressure 50 mm Hg, ± 2 ℃ dried 2h at 70 ℃ "to" make the nitrogen pressure was kept at more than
25kPa or less than the nitrogen pressure in at 2 ℃ ± 140 ℃ drying 2h, powder samples available at 70 ℃ ± 2 ℃ under dry ";
f) the test procedure, after the end of the extraction, "residual polymer containing nitrogen funnel placed in a vacuum oven at 100 ℃ ~
105 ℃, more than 50 mm Hg pressure drying 2h "to" residual polymer containing nitrogen funnel placed in a vacuum oven at
100 ℃ ~ 105 ℃, nitrogen residual pressure maintained in a dry 2h 25kPa or less condition ";
g) the results of the calculation, the changes are made to the formula symbol.
Appendix A of this standard and Appendix B is an informative annex.
The standard proposed by China Petroleum and Chemical Corporation.
This standard by the National Standardization Technical Committee plastic plastic resins and petrochemical products Club (SAC/TC15/SC1) centralized.
This standard was drafted. China Sinopec Yangzi Petrochemical Co., Ltd., China Petroleum Daqing Petrochemical Research Institute of Chemical Research Center.
This standard was drafted. Beijing Yanshan Branch Institute of Applied resin China Petrochemical, China Petrochemical Jiujiang Company, China Sinopec Zhenhai
Refinery subsidiary, China Sinopec Zhongyuan Petroleum Chemical Co., Ltd., China PetroChina Lanzhou Petrochemical Company.
The main drafters of this standard. Wu Shibin, Wangqi Kun, Xu Dejun, Lijing Qing.
This standard was first published in 1980, this is the first revision.
Plastic polypropylene (PP) and propylene copolymer thermoplastic
Plastics - Determination of isotactic index
1 Scope
1.1 standard specifies the determination under standard test conditions boiling n-heptane-insoluble polypropylene quality of the percentage of the sample mass
method.
1.2 This standard applies to the GB/T 2546.1-2006 described propylene homopolymer (PP-H), a propylene impact copolymer (PP-B), propionic
Butene random copolymer (PP-R).
1.3 This standard applies to conventional powdery, granular or crushed granular polypropylene material.
1.4 This standard does not apply to colorants, fillers such as modified polypropylene material.
2 Normative references
The following documents contain provisions which, through reference in this standard and become the standard terms. For dated references, subsequently
Some amendments (not including errata content) or revisions do not apply to this standard, however, encourage the parties to the agreement are based on research
Study whether the latest versions of these documents. For undated reference documents, the latest versions apply to this standard.
GB/T 2546.1-2006 Plastics - Polypropylene (PP) molding and extrusion materials - Part 1. Designation system and basis
(ISO 1873-1.1995, MOD)
Principle 3
The amount of sample is placed in a Soxhlet extractor, refluxed with boiling n-heptane extraction, the quality of the sample before and after extraction, the insoluble in the calculation
The mass fraction of n-heptane, is the isotactic index.
4 Reagents and materials
4.1 n-heptane. AR, no aromatic components.
4.2 acetone. AR.
4.3 dry ice or liquid nitrogen.
5 Instruments
5.1 Disposal. can crushed into pellets or 0.3mm ~ 0.6mm diameter equally effective device.
5.2 sieve. aperture of 0.3mm and 0.6mm each.
5.3 extraction means shown in Figure 1.
5.3.1 Soxhlet extractor (with round bottom flask), shown in Figure 2.
5.3.2 condenser, shown in Figure 3.
5.3.3 glass sand funnel. filled with distilled water at room temperature, it flows through the time of 45s ~ 90s, shown in Figure 4.
5.3.4 perforated glass funnel, shown in Figure 5.
Electric sets with 5.4 regulator device. Volume 250mL.
5.5 vacuum oven. the temperature can be maintained separately at 70 ℃ ± 2 ℃ and 140 ℃ ± 2 ℃, and pressure is maintained at 25kPa or less.
5.6 Analytical balance. accuracy 0.1mg.
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