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Chemical analysis methods of potassium fluoborate -- Part 5: Determination of calcium content -- Flame atomic absorption spectrometric method
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GB/T 22661.5-2008
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Basic data | Standard ID | GB/T 22661.5-2008 (GB/T22661.5-2008) | | Description (Translated English) | Chemical analysis methods of potassium fluoborate -- Part 5: Determination of calcium content -- Flame atomic absorption spectrometric method | | Sector / Industry | National Standard (Recommended) | | Classification of Chinese Standard | H61 | | Classification of International Standard | 77.120.10 | | Word Count Estimation | 6,664 | | Date of Issue | 2008-12-29 | | Date of Implementation | 2009-11-01 | | Quoted Standard | GB/T 22661.1-2008 | | Regulation (derived from) | National Standard Approval Announcement 2008 No.23 (Total No.136) | | Issuing agency(ies) | General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China | | Summary | This standard specifies the method for the determination of calcium fluoride, potassium borate content. This section applies to the determination of calcium fluoride, potassium borate content. Measuring range: �� 0. 5%. |
GB/T 22661.5-2008: Chemical analysis methods of potassium fluoborate -- Part 5: Determination of calcium content -- Flame atomic absorption spectrometric method ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Chemical analysis methods of potassium fluoborade Part 5. Determiantion of calcium content Flame atomic absorption spectrometric method
ICS 77.120.10
H61
National Standards of People's Republic of China
Chemical analysis methods of potassium fluoroborate
Part 5. Determination of calcium content
Flame Atomic Absorption Spectrometry
Posted 2008-12-29
2009-11-01 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Foreword
GB/T 22661 "potassium fluoroborate chemical analysis method" is divided into 10 parts.
--- Part 1. Preparation and storage of test samples;
--- Part 2. Determination of the weight of water in the wet method;
--- Part 3. Determination of potassium fluoride boric acid sodium hydroxide volumetric method;
--- Part 4. Determination of magnesium by flame atomic absorption spectrometry;
--- Part 5. Determination of calcium content by flame atomic absorption spectrometry;
--- Part 6. Determination of silicon content - Molybdenum blue spectrophotometric method;
--- Part 7. Determination of sodium content by flame atomic absorption spectrometry;
--- Part 8. Determination of the free boronic acid sodium volumetric method;
--- Part 9. Determination of the chlorine content of mercuric nitrate volumetric method;
--- Part 10. Determination of phosphorus pentoxide content - Molybdenum blue spectrophotometric method.
This section GB/T 22661 Part 5.
This part is proposed by the China Nonferrous Metals Industry Association.
The non-ferrous metal part by the National Standardization Technical Committee.
This section is drafted. Fluoride Chemicals Co., Ltd.
Participated in the drafting of this section. Hunan Nonferrous fluorine chemical limited liability company, Aluminum Corporation of China Zhengzhou Research Institute, Hengyang City
State Friends of Chemical Technology Co., Ltd.
The main drafters of this section. Xue Xu Jin, Shi Xiuhua, Li Yongqiang, Wang Jianping, Liu Tsz military, army Xu, Zhu Liang, Li Zhijian, Wang Chunxia,
Shin Ji flowers, Liu Zhihong Huang Ju in particular, Liu Min.
Chemical analysis methods of potassium fluoroborate
Part 5. Determination of calcium content
Flame Atomic Absorption Spectrometry
1 Scope
This section GB/T 22661 specifies the method for determination of potassium fluoroborate in calcium content.
This section applies to the determination of fluorine content of calcium, potassium borate. Measuring range. ≤0.5%.
2 Normative references
The following documents contain provisions which, through reference GB/T 22661 in this section constitute provisions of this section. For dated reference documents
Member, all subsequent amendments (not including errata content) or revisions do not apply to this section, however, encouraged to reach under this section
Parties to research agreement to use the latest versions of these documents. For undated reference documents, the latest versions apply to this
section.
GB/T 22661.1-2008 Chemical analysis methods of potassium fluoroborate Part 1. Preparation and storage of test samples
3 Method summary
Sample with perchloric catch fluorine, heated to high acid smokes do, dissolved in hydrochloric acid and water, in the presence of lanthanum chloride, atomic absorption spectrometer wave
Long 422.7nm at the air - acetylene flame measured calcium content.
4 Reagents
4.1 perchloric acid. ρ1.67g/mL.
4.2 HCl. 1 + 1.
4.3 lanthanum chloride. 100g/L.
Weigh 25.00g of lanthanum chloride heptahydrate in a beaker, add 150mL water, dissolved by heating and then diluted to 250mL flask, shake,
spare.
4.4 Calcium standard stock solution. Weigh accurately 1.2486g pre-drying at 110 ℃ and cooled in the dryer baseline calcium carbonate placed
250mL beaker, covered with a watch glass, was added 50mL of water, add 10mL of hydrochloric acid (4.2) micro heat, until the reaction is complete, cool, moved
500mL volumetric flask, dilute with water to volume, and mix. This solution 1mL containing 0.1000mg calcium.
4.5 Calcium standard solution. Pipette 25.00mL calcium standard stock solution (4.4) in 500mL volumetric flask, dilute to the mark, mix,
This solution 1mL containing 0.05mg calcium.
5. Apparatus
5.1 platinum dish. diameter 80mm, high 35mm.
5.2 Atomic absorption spectrometer, with a calcium hollow cathode lamp.
6 Sample
The specimen shall comply with GB/T 22661.1 requirements in 3.3.
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