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Methods for chemical analysis of tungsten ores and molybdenum ores -- Part 1: Determination of tungsten content
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GB/T 14352.1-2010
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GB/T 14352.1-1993 | English | 199 |
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Methods for chemical analysis of tungsten ores and molybdenum ores
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Basic data Standard ID | GB/T 14352.1-2010 (GB/T14352.1-2010) | Description (Translated English) | Methods for chemical analysis of tungsten ores and molybdenum ores -- Part 1: Determination of tungsten content | Sector / Industry | National Standard (Recommended) | Classification of Chinese Standard | D40 | Classification of International Standard | 73.060 | Word Count Estimation | 8,885 | Date of Issue | 2010-11-10 | Date of Implementation | 2011-02-01 | Older Standard (superseded by this standard) | GB/T 14352.1-1993 | Quoted Standard | GB/T 6682; GB/T 14505; GB/T 14352.2 | Regulation (derived from) | National Standard Approval Announcement 2010 No.8 (Total No.163) | Issuing agency(ies) | General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China | Summary | This standard specifies the tungsten ores, determination of the amount of tungsten molybdenum ore. This section applies to tungsten ores, determination of the amount of wood tungsten ore. |
GB/T 14352.1-2010: Methods for chemical analysis of tungsten ores and molybdenum ores -- Part 1: Determination of tungsten content ---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Methods for chemical analysis of tungsten ores and molybdenum ores Part 1. Determination of tungsten content
ICS 73.060
D40
National Standards of People's Republic of China
Replacing GB/T 14352.1-1993
Tungsten ores and molybdenum ores - Methods for chemical analysis
Part 1. Determination of the amount of tungsten
Part 1. Determinationoftungstencontent
Issued on. 2010-11-10
2011-02-01 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Foreword
GB/T 14352 "tungsten ores and molybdenum ores chemical analysis methods," a total of 18 parts.
--- Part 1. Determination of tungsten;
--- Part 2. Determination of molybdenum;
--- Part 3. Determination of copper content;
--- Part 4. Determination of lead content;
--- Part 5. Determination of the amount of zinc;
--- Part 6. Determination of cadmium content;
--- Part 7. Determination of cobalt content;
--- Part 8. Determination of nickel content;
--- Part 9. Determination of sulfur content;
--- Part 10. Determination of arsenic content;
--- Part 11. Determination of the amount of bismuth;
--- Part 12. determination of silver;
--- Part 13. Determination of tin;
--- Part 14. Determination of gallium;
--- Part 15. Determination of germanium content;
--- Part 16. Determination of the amount of selenium;
--- Part 17. Determination of tellurium content;
--- Part 18. Determination of the amount of rhenium.
This section GB/T 14352 Part 1.
This Part replaces GB/T 14352.1-1993 "tungsten ores and molybdenum ores - Methods for chemical analysis thiocyanate spectrophotometric determination of tungsten content."
Section compared with the GB/T 14352.1-1993, major changes in the following.
--- Increasing the content of the warning;
--- Modify the sample drying temperature.
Appendix A of this section is an informative annex.
This section presents the People's Republic of China Ministry of Land Resources.
This part of the National Standardization Technical Committee under the jurisdiction of Land and Resources.
This section is responsible for drafting. National geology test center.
This section is drafted. Jiangsu Provincial Institute of Geological Survey (Ministry of Land and Mineral Resources Supervision and Testing Center, Nanjing).
The main drafters of this section. CAI Yu Man, Zhang new.
This part of the standard replaces the previous editions are.
--- GB/T 14352.1-1993.
Tungsten ores and molybdenum ores - Methods for chemical analysis
Part 1. Determination of the amount of tungsten
Warning. Use of this section a person shall be regular laboratory work experience. This section does not indicate that all possible security issues.
Users have the responsibility to take appropriate safety and health practices and to ensure compliance with the conditions relevant national regulations.
1 Scope
This section GB/T 14352 specifies the method for the determination of tungsten content of tungsten ores and molybdenum ores.
This Part applies to tungsten ores and determination of tungsten content of molybdenum ore.
Measurement range. from 0.05% to 5% of tungsten trioxide.
2 Normative references
The following documents contain provisions which, through reference GB/T 14352 in this section constitute provisions of this section. For dated reference documents
Member, all subsequent amendments (not including errata content) or revisions do not apply to this section, however, encouraged to reach under this section
Parties to research agreement to use the latest versions of these documents. For undated reference documents, the latest versions apply to this
section.
Laboratory use specifications and test methods GB/T 6682 Analysis
GB/T 14505 method for chemical analysis of rocks and ores General rules and regulations
GB/T 14352.2 tungsten ores and molybdenum ores - Methods for chemical analysis - Part 2. Determination of molybdenum content
Principle 3
Sample molten sodium peroxide, hot water extraction, iron, titanium, manganese, nickel, cobalt, niobium, tantalum and tungsten to form a precipitate separated. An aliquot of the filtrate
In hydrochloric acid medium, titanium trichloride tungsten reducing pentavalent state thiocyanate forms a yellow complex on the spectrophotometer, at a wavelength
Absorbance was measured at 420nm, calculate the amount of tungsten.
Molybdenum can also be reduced to titanium trichloride is pentavalent and thiocyanate generated orange-red complexes affect the determination. If the concentration of hydrochloric acid is greater than 25%,
When adding an excess of the reducing agent can restore the trivalent molybdenum with thiocyanate complexes formed yellow, the color intensity much lower than tungsten thiocyanate yellow
Complex is weak, 0.2mg of molybdenum (50 mL chromogenic volume) had no effect on the determination, when exceeding this amount shall be calibrated, or decomposed with an acid
Sample of separation.
4 Reagents
Unless otherwise stated in this section are consistent with the use of analytical reagent and GB/T 6682 analytical laboratory use in the analysis.
4.1 sodium peroxide.
4.2 ethanol.
4.3 formaldehyde.
4.4 hydrochloride (ρ1.19g/mL).
4.5 solution of potassium thiocyanate (250g/L, the time is now equipped with).
4.6 sodium hypophosphite solution (100g/L).
Solution of aluminum chloride 4.7 [500g/L, with the preparation of aluminum chloride hexahydrate (AlCl3 · 6H2O)].
4.8 titanium trichloride solution (15g/L).
Pipette 10mL titanium trichloride solution (150g/L), placed in 100mL flask, diluted with hydrochloric acid (4.4) to the mark with a time of
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