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Determination of chloroform, benzene, carbon tetrachloride, chloropicrine, nitrobenzene and dichlorotolnene in cosmetics
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Basic data
| Standard ID | SN/T 2933-2011 (SN/T2933-2011) |
| Description (Translated English) | Determination of chloroform, benzene, carbon tetrachloride, chloropicrine, nitrobenzene and dichlorotolnene in cosmetics |
| Sector / Industry | Commodity Inspection Standard (Recommended) |
| Classification of Chinese Standard | Y42 |
| Classification of International Standard | 71.100.70 |
| Word Count Estimation | 14,163 |
| Date of Issue | 2011-05-31 |
| Date of Implementation | 2011-12-01 |
| Regulation (derived from) | National-Quality-Inspection-accreditation (2011) 291 |
| Issuing agency(ies) | General Administration of Customs |
| Summary | This standard specifies the cosmetics chloroform, benzene, carbon tetrachloride, chloropicrin, nitrobenzene and dichlorotoluene gas chromatography-mass spectrometry and headspace gas chromatographic method. This standard gas chromatography-mass spectrometry applied lotion, moisturizing creams and toothpaste, cosmetics in chloroform, benzene, carbon tetrachloride, chloropicrin, nitrobenzene and dichlorotoluene determination and confirmation. This standard headspace gas chromatography method applies lotion, moisturizing creams and toothpaste, cosmetics in chloroform, carbon tetrachloride, determination of chloropicrin and Dichlorotoluene. |
SN/T 2933-2011: Determination of chloroform, benzene, carbon tetrachloride, chloropicrine, nitrobenzene and dichlorotolnene in cosmetics
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Determination of chloroform, benzene, carbon tetrachloride, chloropicrine, nitrobenzene and dichlorotolnene in cosmetics
People's Republic of China Entry-Exit Inspection and Quarantine Standards
Cosmetics chloroform, benzene, carbon tetrachloride, trichlorosilane Glass
Detection methane, dichloro-nitrobenzene and toluene
Determinationofchloroform, benzene, carbontetrachloride,
chloropicrine, nitrobenzeneanddichlorotolueneincosmetics
Issued on. 2011-05-31
2011-12-01 implementation
People's Republic of China
The State Administration of Quality Supervision, Inspection and Quarantine released
Foreword
This standard was drafted in accordance with GB/T 1.1-2009 given rules.
This standard is proposed and managed by the National Certification and Accreditation Administration Committee.
This standard by the People's Republic of China Shanghai Entry-Exit Inspection and Quarantine Bureau, Chinese Academy of Inspection and Quarantine, Beijing People's Republic of China
Entry-Exit Inspection and Quarantine of Jiangsu People's Republic of China is responsible for drafting.
The main drafters of this standard. Li Bo, Yang Huiqin, birch, Zhang community, a Xu Chao, Joe Jian Huai, Hai Hung Yi, Zheng Li.
Cosmetics chloroform, benzene, carbon tetrachloride, trichlorosilane Glass
Detection methane, dichloro-nitrobenzene and toluene
1 Scope
This standard specifies the cosmetics chloroform, benzene, carbon tetrachloride, chloropicrin, nitrobenzene and Dichlorotoluene gas chromatography - mass
Spectroscopy and headspace gas chromatographic method.
The standard gas chromatography - mass spectrometry applied to toner, moisturizing creams and toothpaste, cosmetics in chloroform, benzene, carbon tetrachloride, tri
Chlorine nitromethane, nitrobenzene and dichlorotoluene determination and confirmation.
This standard headspace gas chromatography is suitable for toner, moisturizing creams and toothpaste Cosmetics chloroform, carbon tetrachloride, trichlorosilane Glass
Group determination of methane and dichlorotoluene.
The first method
2 Gas Chromatography - Mass Spectrometry
2.1 Method summary
After the sample was extracted with methanol, ultrasonic, gas chromatography - mass spectrometry, selected ion monitoring MS scan mode (SIM), with a compound
Abundance retention times and mass spectral fragmentation than qualitative, quantitative internal standard.
2.2 Reagents and materials
2.2.1 Methanol. liquid chromatography.
2.2.2 1,1,1-trichloroethane (CAS Number. 71-55-6, molecular formula. C2H3Cl3). purity greater than or equal to 99%.
2.2.3 1,2-dichlorobenzene (CAS Number. 95-50-1, molecular formula. C6H4Cl2). not less than 99% purity.
2.2.4 chloroform Standards (CAS Number. 67-66-3, molecular formula. CHCl3). purity greater than or equal to 99%.
2.2.5 Benzene Standards (CAS Number. 71-43-2, molecular formula. C6H6). purity greater than or equal to 99%.
2.2.6 CTC Standards (CAS Number. 56-23-5, Formula. CCl4). purity greater than or equal to 99%.
2.2.7 chloropicrin Standards (CAS Number. 76-06-2, molecular formula. CCl3NO2). purity greater than or equal to 99%.
2.2.8 nitrobenzene Standards (CAS Number. 98-95-3, molecular formula. C6H5NO2). purity greater than or equal to 99%.
2.2.9 α, α- dichlorotoluene standards (CAS Number. 98-87-3, molecular formula. C7H6Cl2). not less than 99% purity.
2.2.10 each standard stock solution. accurately weighed amount of each standard (2.2.4 - 2.2.9), were prepared in methanol at a concentration of 10mg/mL
Standard stock solution stored in the dark at 4 ℃, valid for six months.
2.2.11 1,1,1-trichloroethane internal standard solution. methanol preparation of 1,1,1-trichloroethane concentration of 1.0mg/mL, the dark at 4 ℃
save.
2.2.12 1,2-dichlorobenzene internal standard solution. methanol preparation of 1,2-dichlorobenzene concentration of 1.0mg/mL, stored in the dark at 4 ℃.
2.2.13 internal standard mix solution. accurate Pipette the appropriate amount of internal standard solution (2.2.11 and 2.2.12), respectively, diluted with methanol concentrations were approximately
Was 2.0μg/mL, stored in the dark at 4 ℃.
2.3 instruments and equipment
2.3.1 Gas chromatography - mass spectrometry. quadrupole mass spectrometer with EI ion source and having a select function.
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