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Labelling of chemicals based on GHS
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Basic data
| Standard ID | GB/T 22234-2008 (GB/T22234-2008) |
| Description (Translated English) | Labelling of chemicals based on GHS |
| Sector / Industry | National Standard (Recommended) |
| Classification of Chinese Standard | A80 |
| Classification of International Standard | 13.300 |
| Word Count Estimation | 24,280 |
| Date of Issue | 2008-06-19 |
| Date of Implementation | 2009-02-01 |
| Quoted Standard | JIS Z7250 |
| Adopted Standard | JIS Z7251-2006, IDT |
| Regulation (derived from) | Announcement of Newly Approved National Standards No. 10 of 2008 (total 123) |
| Issuing agency(ies) | General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China |
| Summary | This standard provides a basis for chemical substances GHS hazard categories and levels of label elements. This standard applies to chemicals based on GHS label specification. |
GB/T 22234-2008: Labelling of chemicals based on GHS
---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Labelling of chemicals based on GHS
ICS 13.300
A80
National Standards of People's Republic of China
GHS-based chemical labeling specification
Posted.2008-06-19
2009-02-01 implementation
General Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
China National Standardization Administration released
Foreword
This standard is identical with JIS Z7251..2006 "GHS-based chemical labeling" (Japanese version).
For your convenience, the following editorial changes were made.
a) delete the original standard title and foreword;
b) delete the original standard preamble;
c) Use the punctuation "," instead of the symbol in the original standard "•"
d) punctuation "," instead of the original standard "," said the comma.
Appendix A of this standard is normative appendix.
This standard by the National Standardization Technical Committee of hazardous chemicals management (SAC/TC251) and focal point.
Participated in the drafting of this standard. Sinochem Chemical Standardization Institute, Exit Inspection and Quarantine of Anhui Province, Shanghai Institute of Chemical Industry.
Drafters of this standard. Wen Jinsong, Fan Bin, Yao Jian, Wang Xiaobing, Mei Jian, Ji Ruwu, Zheng Ping, peak, South Korea
Ping, Sun Zheng.
GHS-based chemical labeling specification
1 Scope
This standard specifies the label elements (symbols, warnings, hazard statements, etc.) based on the type and level of GHS hazard of the chemical substance.
This standard applies to GHS-based chemical labeling regulations.
2 Normative references
The terms of the following documents, through the reference to the standard become the terms of this standard. All dated references, which are subsequently owned
Amendments (not including errata content) or revisions do not apply to this standard, however, encourage the parties to reach an agreement based on this standard research
Whether you can use the latest versions of these files. For undated references, the latest version applies to this standard.
JIS Z7250 Safety Data Sheet for Chemical Substances Part 1. Contents and Order of Items
3 Terms and definitions
The following terms and definitions apply to this standard.
3.1
Potential causes of harm.
3.2
Chemical elements and their compounds that exist naturally or by synthesis or the like.
3.3
A mixture of two or more chemicals (including solutions).
3.4
Chemical substance or mixture.
Note. "chemical substances" can be understood as "chemicals" or "products" synonymous.
3.5
Constitute a chemical substances and other elements.
3.6
With physical means is not easy to separate, by more than two elements together, looks like a homogeneous metal body.
Note. Alloys are considered as a mixture in the GHS classification.
3.7
International coordination organization on the classification of chemicals and their labeling.
3.8
After adjusting for the physical and chemical hazards of GHS-based chemicals and their mixtures, health hazards, and environmental hazards
The classification of judgment criteria.
3.9
Divided into such as flammable solid physical and chemical hazards, carcinogenic substances, such as oral toxicity of health and harmful, as well as aquatic ring
Harmful environmental harmfulness.
3.10
Classification based on judgment criteria within various hazard categories. For example. oral acute toxicity is divided into five levels, flammable liquid is divided into four
A dangerous level. These grading is within the hazard category and is based on the degree of harm to be relatively divided, should not be regarded as general
Harm classification comparison.
3.11
The label is a summary of the main information on the written, printed or graphic composition of the hazardous product, within the relevant department of choice
To put directly on the hazardous substances in the container or on the packaging, paste, print or add something.
3.12
The label provides users with internationally accepted information. For example. symbols, warnings, hazardous instructions and precautions.
3.13
Image elements created to convey information concisely and clearly. For example. flame, skull and so on.
3.14
It consists of symbols, border lines, background patterns and colors that convey specific information.
3.15
For hazardous chemicals and mixtures, state the ingredients, product name, supplier, hazardous and safety precautions, in case of accidents
Coping measures and other content of the text material.
Note. The Material Safety Data Sheet (MSDS) is called the SafetyDataSheet (SDS) in the GHS.
3.16
Accredited by the International Economic Cooperation Council, the UN Convention on the Transport of Dangerous Goods, annex "on the transport of dangerous goods regulations
The "title, the official publication of text material.
4 General Matters
A label on the record of a chemical substances and other information.
Note. If the object is a mixture, not a label for each component, you can make a label on the mixture.
5 The order in which the necessary information and content on the label appear
5.1 The necessary information on the label
The necessary information on the label is as follows.
a) a pictogram that indicates a hazard;
b) warnings
c) Hazard statements;
d) Precautions;
e) product name
f) Manufacturer/supplier.
5.2 Labeling the order of representation
According to the GHS classification results relative to a hazard category and grade, the use of the corresponding pictograms, warnings, harmful to say
Make labels. A variety of correspondence as Appendix A shows.
a) A pictogram that represents a hazard
The standard pictograms used in the GHS are shown in Tables 1 to 3 below. Pictograms on labels can not be used with standard icons in GHS
Chart significantly different.
Table 1
Name (symbol) The flame bomb on the flame circle explodes
Pictograms
Use this graphical table
Hazard category shown
Flammable gas, flammable
Flammable gas under pressure
Flammable liquids
Flammable solid
Self-reactive chemicals
Spontaneous liquid and solid
Self-heating chemicals
Release water with flammable gas chemicals
Organic peroxides
Flammability, oxidizing gases, oxidation
Liquid, solid
Gunpowder category
Self-reactive chemicals
Organic peroxides
Table 2
Name (symbol) corrosive gas tank skull
Pictograms
Use this graphical table
Hazard category shown
Metal corrosion
Skin corrosion/irritation
Serious eye damage, irritation
Acute toxicity/toxicity under pressure
Table 3
Name (Symbol) Exclamation Point Environmental Health Hazard
Pictograms
Use this graphical table
Hazard category shown
Acute toxicity/toxicity
Skin corrosive, irritating
Serious eye damage/eye irritation
Causes skin irritation
On the target organ, systemic toxicity
Harmful to aquatic environment Causes respiratory sensitization
Cause germ cell mutation
Carcinogenicity
Reproductive toxicity
On the target organ, systemic toxicity
Harmful to inhalational respiratory organs
The pictograms used in the labels are. a black symbol on a rhombus (square) white background and a bold red line on the white background
frame. Non-export packaging, the label can also use the black line border.
An example of a pictogram is shown in Figure 1.
Figure 1 Skin irritant pictograms
b) Warnings
The so-called warning is the relative degree that indicates the severity of the hazard, warning the user of potentially harmful words. GHS
The warnings used are Dangerous Danger and Warning Warning. "Danger" is used for more serious hazard levels,
"Warnings" are intended for less harmful levels and are not subject to warnings even at a lower risk. Corresponds to GHS levels
Hazard warnings are shown in Appendix A.
c) Hazard statements
Hazard statements correspond to the various hazard and grade standards and indicate the nature and extent of the product's hazard. With GHS
Hazard at all levels corresponding to the hazardous instructions as shown in Appendix A.
d) Precautions
In order to prevent contact with hazardous products or improper storage and handling of the hazards, or to reduce the risk of
Low to minimum, and should take the recommended measures, with text (or pictogram) said. The label contains appropriate precautions, however
And, the choice is judged by the representation to be made.
Note. The format of precautions is the same as GHSAnnex3Precautionarystatements.
e) the name of the product
The product name is as follows.
1) The name of the product or the generic name is recorded on the label. The name and product-specific name of the MSDS should be the same. The thing
Quality or mixture If the UN Manual for the Transport of Dangerous Goods meets the standards, the UN products should be marked on the package
name.
MSDS item, description contents and all the components may be based on JISZ7250.
2) The label should contain the name of the chemical substance.
3) The mixture or the label on the alloy, if it indicates acute toxicity (highly toxic), corrosive skin, serious eye damage
Injuries, causing germ cell mutations, carcinogenicity, reproductive toxicity, can cause skin allergies, can cause respiratory allergies or
For specific target organs, Toxicity (TOST) and other hazards, all of these components or alloying elements
The chemical name of the prime should be shown on the label.
Skin irritation, eye irritation related to all the ingredients or alloying elements can also be recorded on the label.
f) manufacturer's name
The name of the manufacturer or supplier of the substance or mixture must be indicated on the label. At the same time should be marked with the address and
telephone number. If possible, the contact person in case of emergency should also be recorded on the label.
5.3 on the variety of hazardous and hazardous information in the order of presentation
When there are several kinds of harmful substances, such as chemical substances, deal with as follows.
a) The order of the pictograms
In terms of health and harmfulness, usually in the following order.
1) You can use the "skeleton", it is best not to "exclamation point."
2) Can use "corrosive", best not to show on the skin, eye irritation "exclamation point."
3) It is best not to use a "health hazard" that indicates sensitization of respiratory organs to skin or skin,
Exciting "exclamation point."
b) The order of the warnings
It is best not to use the warning "warning" when "dangerous" can be used.
c) The order of the hazardous information
I hope all the harmful information will be included in the label.
6 This standard does not include the use of information or additional information
a) Although it is not included in this standard, there are other items that should be included in the label, such as precautions,
Add supplementary information. However, in order to prevent the increase of unnecessary information caused by the standard elements of the label
To ignore, hope the use of additional information is limited to the following two aspects.
1) Provide detailed information, but there is no contradiction between the validity of the relevant information of the hazard indicated by this standard,
Have questions.
2) Provide information on the hazards that are not yet listed in the GHS. In any case, supplementary information may not be lowered
Health and environmental protection level.
b) Supplementary information on the status of the physical state, the route of exposure, etc., is not indicated in the Supplementary Information section of the label,
Hazard information together.
Appendix A.
(Normative)
Hazard Classification (Hazard Category and Grading) and Label Elements
Label elements (pictograms, warnings, hazard information) corresponding to the various hazard classes and their grading of the GHS are as follows.
A. 1 Physical and chemical hazards
A. 1.1 Explosives See Table A 1.
Table A. 1
Hazard level Hazard communication elements
Unstable explosives
Pictograms
Warning danger
Hazard Statements Unstable explosives
Item 1.1
Pictograms
Warning danger
Hazard Statements Explosives. Overall risk of explosion
1.2 items
Pictograms
Warning danger
Hazard Statements Explosives. Intense fire hazard
1.3
Pictograms
Warning danger
Hazard statements Explosives. fire, detonation, projection risk
1.4 items
Pictograms
Warnings
Hazard Description fire, projection risk
Table A. 1 (continued)
Hazard level Hazard communication elements
1.5 items
Pictogram 1.5 (orange background)
Warning danger
Hazard note A large number of explosions can occur in the event of a fire
1.6
Pictogram 1.6 (orange background)
No warnings
Hazard statements No dangerous instructions
A. 1.2 combustible, flammable gas in Table A. 2.
Table A. 2
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard Description Extremely flammable gas
No pictograms
Warnings
Hazard Statements Combustible, flammable gas
A. 1.3 combustible, flammable compressed gas in Table A. 3.
Table A. 3
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard Statements Flammable gas under extreme pressure
Pictograms
Warnings
Hazard Statements Combustible, flammable under pressure gas
A. 1.4 combustion, oxidizing gas in Table A. 4.
Table A. 4
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard statements May cause or exacerbate fire. oxidizers
A. 1.5 Gas pressure in Table A 5.
Table A. 5
Hazard level Hazard communication elements
compressed gas
Pictograms
Warnings
Hazard Statements Gas under pressure. Heating may explode
Liquefied gas
Pictograms
Warnings
Hazard Statements Gas under pressure. Heating may explode
Refrigerated liquefied gas
Pictograms
warning
Hazard notes Refrigerated liquefied gas. May cause burns or damage from low temperatures
Dissolved gas
Pictograms
Warnings
Hazard Statements Gas under pressure. Heating may explode
A. 1.6 flammable liquids in Table A. 6.
Table A. 6
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard statements Flammable liquids and vapors
Pictograms
Warning danger
Hazard statements Flammable liquids and vapors
Pictograms
Warnings
Hazard statements Flammable liquid and vapor
No pictograms
Warnings
Hazard Statements Flammable gas
A. 1.7 flammable solids in Table A 7.
Table A. 7
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard Statements Flammable solid
Pictograms
Warnings
Hazard Statements Flammable solid
A. 1.8 Self-reactive chemicals in Table A. 8.
Table A. 8
Hazard level Hazard communication elements
A type
Pictograms
Warning danger
Hazard Statements Heating may cause an explosion
B type
Pictograms
Warning danger
Hazard Statements Heating may cause a fire or explosion
C-type and D-type
Pictograms
Warning danger
Hazard Statements Heating may cause a fire
E-type and F-type
Pictograms
Warnings
Hazard Statements Heating may cause a fire
G type
Pictograms
warning
Hazard statement
There are no label elements at this level
A. 1.9 spontaneous combustion liquid see table A. 9.
Table A. 9
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard Description Spontaneous combustion occurs in the face of air
A. 1.10 See Table A for spontaneous combustion solids. 10.
Table A. 10
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard Description Spontaneous combustion occurs in the face of air
A. 1.11 Self-heating chemicals in Table A. 11.
Table A. 11
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard statements Self-heating, may cause a fire
Pictograms
Warnings
Hazard statements A large number of self-heating may cause a fire
A. 1.12 release water combustible gas chemical see table A. 12.
Table A. 12
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard statement
When exposed to water, it may cause flammability and flammability that may cause spontaneous combustion
gas
Pictograms
Warning danger
Hazard Statements When exposed to water, flammable, flammable gases are produced
Table A. 12 (continued)
Hazard level Hazard communication elements
Pictograms
Warnings
Hazard Statements When exposed to water, flammable, flammable gases are produced
A. 1.13 oxidizing liquid see table A. 13.
Table A. 13
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard statements May cause fire or explosion. Strong oxides
Pictograms
Warning danger
Hazard statements may help increase combustion. Oxides
Pictograms
Warnings
Hazard statements may exacerbate combustion. Oxides
A. 1.14 Oxidizing solids See Table A 14.
Table A. 14
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard statements May cause fire or explosion. Strong oxides
Table A. 14 (continued)
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard statements may exacerbate combustion. Oxides
Pictograms
Warnings
Hazard statements may exacerbate combustion. Oxides
A. 1.15 Organic Peroxide See Table A 15.
Table A. 15
Hazard level Hazard communication elements
A type
Pictograms
Warning danger
Hazard Description Explosion may occur after the heat
B type
Pictograms
Warning danger
Hazard statements Burning and explosion may occur after the heat
C-type and D-type
Pictograms
Warning danger
Hazard Statements May be burned when exposed to heat
E-type and F-type
Pictograms
Warnings
Hazard Statements May be burned when exposed to heat
Table A. 15 (continued)
Hazard level Hazard communication elements
G type
Pictograms
warning
Hazard statement
There are no label elements at this level
A. 1.16 metal corrosion in Table A 16.
Table A. 16
Hazard level Hazard communication elements
Pictograms
Warnings
Hazard statements may corrode the metal
A. 2 harmful to human health
A. 2.1 Acute toxicity in Table A. 17.
Table A. 17
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard statement
Fatal (oral)
Deadly skin contact (skin)
Inhalation fatal (gas, vapor, dust, smoke)
Pictograms
Warning danger
Hazard statement
Fatal (oral)
Deadly skin contact (skin)
Inhalation fatal (gas, vapor, dust, smoke)
Pictograms
Warning danger
Hazard statement
Toxic if swallowed (oral)
Toxicity to the skin (skin)
Inhalation poisoning (gas, vapor, dust, smoke)
Table A. 17 (continued)
Hazard level Hazard communication elements
Pictograms
Warnings
Hazard statement
Harmful if swallowed (oral)
Harmful to the skin (skin)
Harmful if inhaled (gases, vapors, dust, fumes)
No pictograms
Warnings
Hazard statement
May be harmful if swallowed (oral)
Contact with skin may be harmful (skin)
Inhalation may be harmful (gases, vapors, dust, fumes)
A. 2.2 on the skin corrosion, stimulation in Table A. 18.
Table A. 18
Hazard level Hazard communication elements
(Including A, B, C)
Pictograms
Warning danger
Hazard statements Severe burns on the skin, damaging the eyes
Pictograms
Warnings
Hazard statements Skin irritation
No pictograms
Warnings
Hazard statements Skin mild irritation
A. 2.3 serious eye damage, stimulation in Table A. 19.
Table A. 19
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard statements cause serious eye damage
Table A. 19 (continued)
Hazard level Hazard communication elements
2A
Pictograms
Warnings
Hazard statements have a strong eye irritation
2B
No symbol
Warnings
Hazard statements stimulate the eyes
A. 2.4 respiratory allergies, skin allergies
A. 2.4.1 Respiratory allergy in Table A 20.
Table A. 20
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard statements May cause allergy, asthma, breathing difficulties if inhaled
A. 2.4.2 skin allergy in Table A. 21.
Table A. 21
Hazard level Hazard communication elements
Pictograms
Warnings
Hazard statements may cause skin irritation
A. 2.5 germ cell mutation in Table A. 22.
Table A. 22
Hazard level Hazard communication elements
(1A and 1B)
Pictograms
Warning danger
Hazard statement
May cause genetic disease (if it is conclusively proven that there is no other access
Touch the path will have this danger, then it should explain the harm
Way of exposure)
Table A. 22 (continued)
Hazard level Hazard communication elements
Pictograms
Warnings
Hazard statement
Suspected of causing a genetic disorder (if not proven with certainty
Other routes of exposure give rise to this danger, so it should be stated that this will happen
A hazardous route of exposure)
A. 2.6 carcinogenicity in Table A 23.
Table A. 23
Hazard level Hazard communication elements
(1A and 1B)
Pictograms
Warning danger
Hazard statement
May cause cancer (if it is conclusively proven that no other routes of exposure will produce
The danger of birth, then it should explain the ways in which this hazard will occur)
Pictograms
Warnings
Hazard statement
Suspected of causing cancer (if there is definite evidence of no other routes of contact
If this path leads to this danger, then it should be stated that the hazard would have occurred
Touch the way)
A. 2.7 pairs of reproductive toxicity, affecting breastfeeding
a) Reproductive toxicity in Table A 24a.
Table A. 24 犪
Hazard level Hazard communication elements
(1A and 1B)
Pictograms
Warning danger
Hazard statement
May affect fertility or damage to the fetus (if clear, yes
Describe the specifics of the impact) or (if it is fairly certain that there is no such thing
This exposure to the danger of his exposure should be demonstrated
Harmful routes of exposure
Table A. 24 犪 (continued)
Hazard level Hazard communication elements
Pictograms
Warnings
Hazard statement
Suspected of affecting fertility or damage to the fetus (if already clear, want
Describe the specifics of the impact) or (if it is fairly certain that there is no such thing
This exposure to the danger of his exposure should be demonstrated
Harmful routes of exposure
b) Breastfeeding See Table A 24b.
Table A. 24 犫
Hazard level Hazard communication elements
Additional level
No pictograms
Warnings
Hazard statements cause harm to lactating infants
A. 2.8 pairs of target organs, systemic toxicity (single exposure) in Table A. 25.
Table A. 25
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard statement
Causes damage to organs (If specified, state all affected devices
Official) or (if it is conclusively proven that no other route of exposure will result in this
A dangerous, then it should explain the ways in which this hazard will occur)
Pictograms
Warnings
Hazard statement
May cause damage to organs (if clear, indicate affected
All organs) or (if it is conclusively proven that there is no other route of exposure
If this danger arises, then the contact that gave rise to this danger should be described
way)
Table A. 25 (continued)
Hazard level Hazard communication elements
Pictograms
Warnings
Hazard statement
(Stimulate the trachea)
May cause respiratory irritation
(Anesthetic effect)
May cause drowsiness or dizziness
A. 2.9 pairs of target organs, systemic toxicity (multiple/repeated exposure) in Table A. 26.
Table A. 26
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard statement
Organ damage caused by prolonged or repeated exposure if present
Describe all affected organs) (if it is surely not proven)
This exposure to the danger of his exposure should be demonstrated
Harmful routes of exposure
Pictograms
Warnings
Hazard statement
May cause damage to organs if prolonged or repeated
Clearly indicate all organs affected (if confirmed with certainty)
No other route of exposure would give rise to this danger, then the conference should produce
The path of exposure to this hazard)
A. 2.10 inhalation Respiratory organ toxicity in Table A 27.
Table A. 27
Hazard level Hazard communication elements
Pictograms
Warning danger
Hazard statements May be fatal if swallowed and inhaled
Table A. 27 (Continued)
Hazard level Hazard communication elements
Pictograms
Warnings
Hazard statements May be toxic if swallowed and aspiration into trachea
A. 3 environmental hazards
A. 3.1 Acute Hazard Aquatic Environment See Table A. 28.
Table A. 28
Hazard level Hazard communication elements
Pictograms
Warnings
Hazard statements Very toxic to aquatic life
No pictograms
No warnings
Hazard statements Toxic to aquatic life
No pictograms
No warnings
Hazard statements Harmful to aquatic life
A. 3.2 Chronic hazards Aquatic environment is shown in Table A. 29.
Table A. 29
Hazard level Hazard communication elements
(1A and 1B)
Pictograms
Warnings
Hazard statements by the long-term effects of aquatic organi...
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