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Safety of toys -- Experimental sets for chemistry and related activities
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Basic dataStandard ID: GB 26387-2011 (GB26387-2011)
Description (Translated English): Safety of toys -- Experimental sets for chemistry and related activities
Sector / Industry: National Standard
Classification of Chinese Standard: Y57
Classification of International Standard: 97.200.50
Word Count Estimation: 14,111
Date of Issue: 2011-05-12
Date of Implementation: 2011-09-15
Quoted Standard: GB/T 531; GB 5296.5; GB 6675; GB 13690; ISO 868; ISO 8317
Adopted Standard: BS EN 71-4-2007, MOD
Regulation (derived from): National Standard Approval Announcement 2011 No.6
Issuing agency(ies): General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China
Summary: This standard specifies the specific substances and chemical products, toys and similar experimental activities can be used in their maximum amount and type of toys marked, instructions and requirements for the testing of equipment, contents of the list. This standard applies to toys and attachment chemistry experiment.
GB 26387-2011: Safety of toys -- Experimental sets for chemistry and related activities---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Safety of toys.Experimental sets for chemistry and related activities
ICS 97.200.50
Y57
National Standards of People's Republic of China
Toys Toys and chemical safety experiment similar activities
Issued on. 2011-05-12
2011-09-15 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Table of Contents
Preface Ⅰ
1 Scope 1
2 Normative references 1
3 Terms and definitions
4 1 chemicals
5 Equipment 4
6 6 labels
7 warning and emergency information with the contents of Listing 6
8 Owner's Manual 7
Density Appendix A (normative) borosilicate glass measuring identification methods 9
Cover testing methods Appendix B (normative) reagent containers 10
Foreword
All the technical contents of this standard is mandatory.
This standard is specific requirements and chemical experiments toy similar activities, and GB 6675 series of standards, GB 19865 (applies to Games
A) used in combination.
This revised standard adopts BSEN71-4.2007 "experiment toy toy safety chemistry and similar activities."
This standard BSEN71-4. Compared to 2007, the main technical differences are as follows.
--- Modify the risk of danger signs and symbols marking requirements;
--- Modify the labeling requirements;
--- Modified Goggle's impact test;
--- Adjustments to the original text of section 5.2.6 "borosilicate glass density determination method of identifying" as Appendix A.
This standard Annex A, Annex B normative appendix.
The standard proposed by China National Light Industry Council.
This standard by the National Toy Standardization Technical Committee (SAC/TC253) centralized.
This standard was drafted. Guangdong Entry-Exit Inspection and Quarantine Bureau Technology Center Toys Lab, SZCIQ play
With detection technology center, Ningbo CIQ light industrial products testing center, eastern Guangdong CIQ Toy Testing
Heart, Guangzhou CVC Testing Institute, Guangdong Alpha Animation and Culture Co., Ltd., Beijing Certification Center of Light.
The main drafters of this standard. Liuchong Hua, Han Fang, Jiang Liyuan, Ruan Jian Miao, Wang Yu, Fan Cen Liang, Wang Long.
Toys Toys and chemical safety experiment similar activities
1 Scope
This standard specifies the particular substances and preparations and chemical experiments toy similar activities can be used and the maximum amount, as well as the class
Labeling requirements for toys, the contents list, instructions for use and for testing equipment.
This standard applies to chemistry experiment toys and attachments.
2 Normative references
The following documents contain provisions which, through reference in this standard and become the standard terms. For dated references, subsequent
Amendments (not including errata content) or revisions do not apply to this standard, however, encourage the parties to the agreement are based on research
Whether the latest versions of these documents. For undated reference documents, the latest versions apply to this standard.
GB/T 531 pocket rubber hardness indentation hardness test methods
GB 5296.5 consumer use - Part 5. Toys
GB 6675 National Safety Technical Code for Toys
GB 13690 chemical classification and hazard communication General
ISO 868 plastics and hard rubber durometer using the indentation hardness [Plasticsandebonite-Determinationofin-
dentationhardnessbymeansofadurometer (shorehardness)]
Requirements and test methods ISO 8317 open child-resistant packaging reclosable package (Child-resistantpackaging-
Requirementsandtestingproceduresforreclosablepackages)
3 Terms and Definitions
The following terms and definitions apply to this standard.
3.1
Chemistry Experiment Toys chemistryset
Experimental toys containing one or more chemical substances and/or chemical preparations, whether or not with equipment for chemical testing.
Note. This definition also applies to test toys mineralogy, biology, physics, microscopy, environmental science and other fields, as long as they contain one or more
Chemical substances and chemical preparations.
3.2
Additional means supplementaryset
Chemical plants and chemical experiments toy sets used in conjunction.
4 chemicals
Only 4.1 Tables 1 and 2 chemical substances, chemical preparations and chemical indicator can be used to test toys, used in an amount not exceeding the
Limit specified in the table. Indicator provided in the form of a solution having a solid content should not exceed the limits specified in Table 2.
Table 1 chemical substances and products with limited risk category
Chemical substances and preparations of the maximum amount in each toy hazard class a CAS Registry Number
Aluminum potassium sulfate b 10g - 10043-67-1
Ammonium carbonate g 5g harmful 10361-29-2
Harmful 12125-02-9 ammonium chloride 30g
Table 1 (continued)
Chemical substances and preparations of the maximum amount in each toy hazard class a CAS Registry Number
Ammonium ferric sulfate 10138-04-2 irritating g 5g
Sodium ammonium hydrogen phosphate 5g - 13011-54-6
Calcium carbonate 471-34-1 irritating 100g
Calcium chloride 10043-52-4 irritating 10g
Calcium hydroxide, c, g 20g irritating 1305-62-0
Calcium nitrate g 5g irritating, oxidizing h 10124-37-5
Calcium oxide c, g 10g corrosive h 1305-78-8
Calcium sulfate 100g - 7778-18-9
Charcoal b 100g - 7440-44-0
Citric acid 77-92-9 irritating g 20g
Clove b, g, 10mL harmful 84961-50-2
Copper 100g - 7440-50-8
Copper oxide (Ⅱ) g 10g harmful 1317-38-0
Copper sulfate (Ⅱ) 15g harmful 7758-98-7
Sodium metabisulfite 10g harmful 7681-57-4
Glycerol (water content ≥15%) 25g - 56-81-5
Hexamethylene tetramine (solid fuel) 10g hazardous, flammable solids h 100-97-0
Iron/iron b, g 100g flammable solids h 7439-89-6
Ferric chloride g 10g harmful 7705-08-0
Ferric g 10g harmful 7720-78-7
Lactose 100g - 63-42-3
Lead-free solder b 100g - -
Article g 3g magnesium flammable solids h, h 7439-95-4 flammable when wet
Magnesium sulfate 25g - 7487-88-9
Manganese dioxide (Ⅳ) 5g harmful 1313-13-9
Manganese sulfate (Ⅱ) 15g harmful 7785-87-7
Ninhydrin g 1g harmful 485-47-2
Pepsin A 10g harmful 9001-75-6
G 15g Potassium bromide 7758-02-3 irritating
Ferricyanide b 10g - 13746-66-2
Potassium ferrocyanide b 10g - 13943-58-3
Potassium iodide 10g - 7681-11-0
D 15g potassium permanganate harmful oxidizing h 7722-64-7
Potassium permanganate. sodium sulfate mixture (1.2 mass fraction) 10g harmful oxidizing h -
Silver nitrate g [1% (mass concentration) solution] 10mL harmful 7761-88-8
Table 1 (continued)
Chemical substances and preparations of the maximum amount in each toy hazard class a CAS Registry Number
Sodium acetate 20g - 127-09-3
50g of sodium carbonate 497-19-8 irritating
Sodium chloride 100g - 7647-14-5
Sodium bicarbonate 50g - 144-55-8
Sodium bisulfate 30g irritating 7681-38-1
Sodium silicate solution g (SiO2.Na2O > 2) 100mL corrosive h -
Sodium 100g - 7757-82-6
Sodium thiosulfate 50g - 7772-98-7
Sulfur g 15g flammable solids h 7704-34-9
Tannins b 15g - 1401-55-4
G 20g tartaric acid irritation 87-69-4
Stannous g 15g corrosive h 7772-99-8
Iodine b [2.5% (mass concentration) ethanol] e 10mL harmful f, flammable liquid h -
Urea 10g - 57-13-6
Zinc dust and zinc particles 20g flammable when wet h 7440-66-6
Zinc sulfate (heptahydrate) 20g harmful 7446-20-0
a Chemical Abstracts Service (CAS) registration number only for data usage.
b In addition to labeling substances, other substances according to IUPAC rules.
c Each toy can only use one of these substances.
d only for toys intended for children over 12 years of use.
e denatured alcohol (ethanol).
f "bad" applies to iodine, which does not apply to ethanol.
G substance classification should be based on manufacturer data of the most rigorous self-consistent classification.
h danger signs referring to GB 13690.
i should give the following risk warnings and safety tips phrases.
Clove Risk Warning. may cause skin irritation;
Safety Tips. Avoid contact with skin.
Table 2 limit indicator and hazard class
Indicator name
Each toys
The maximum amount of
Risk category a CAS Registry Number
Eosin (eosin) b, d 1g irritating 17372-87-1
Iodine [2.5% (mass concentration)] of potassium iodide [2.5% (mass concentration
Degree)] solution
10mL harmful c 7553-56-2
Litmus blue b 1g - -
Red litmus b 1g - 1393-92-6
A mixture of luminol and sodium sulfate (5.95 mass fraction) b, d 3g harmful 521-31-3
TABLE 2 (cont.)
Indicator name
Each toys
The maximum amount of
Risk category a CAS Registry Number
Methyl orange b, d and sodium sulfate mixture (20.80, mass fraction) 3g toxic e 547-58-0
Methylene Blue b, d 1g harmful 67-73-4
D 1g irritating 143-74-8 phenol red
Thymol blue 1g - 76-61-9
General dispersion strip b 1 package - -
a Chemical Abstracts Service (CAS) registration number only for data usage.
b In addition to labeling substances, other substances according to IUPAC rules.
c "bad" applies to iodine, which does not apply to ethanol.
D material classification shall be carried out according to the manufacturer data the most rigorous self-consistent classification.
e danger signs referring to GB 13690.
If chemical toys containing dangerous substances and preparations in nature, should be the appropriate label on its container.
Note 1. The quality of the chemicals used to meet the requirements of the test, in particular does not contain a clear response and not cause dangerous impurities or components.
Note 2. Book, inks will not bleed or picture indicator far below the relevant toxicological criteria, the amount used in Table 2 are not limiting.
4.2 denatured methylated spirit and Table 3 lists the reagent can be used as specified, but should not be provided with the toy together.
Table 3 Chemical Experiment in toys may not be provided but allows maximum concentration of the reagents and hazard category
Name of the reagent maximum concentration/(mol/L) hazard class a CAS Registry Number
2 1336-21-6 irritating ammonia
2 7647-01-0 irritating hydrochloric acid
Hydrogen peroxide b 1 - 7722-84-0
1 c 1310-73-2 caustic sodium hydroxide solution
a Chemical Abstracts Service (CAS) registration number only for data usage.
b hydrogen peroxide concentration of 3% (volume fraction) solution.
c danger signs referring to GB 13690.
4.3 In addition to Tables 1 and 2 outside the other substances should not be provided together with the toy 1. However, the instructions may not require the use of a dangerous nature
Other substances or preparations of substances, such as sugar.
5 device
5.1 General Requirements
Toys should be attached to the use of chemical experiment instructions, instructions for use should be required to complete the description of the test vessel, eye protection, and the necessary test tube rack.
Additional means should be set out in clause 8 the contents of the list, according to 6.3.3 for the label.
All tests specified by the manufacturer to evaluate, in particular, the amount of material generated by the test should not be hazardous to health.
NOTE. For detailed description of known hazards during use toys especially produced during the test. For example. chemicals and glassware operation, boiling delay, condensed
Hot water return to the operating glassware, as well as changes in gas furnaces and other heating devices.
5.2 Containers and Glassware
5.2.1 tubes
5.2.1.1 tubes for heating
Instructions for use, such as a test tube containing a chemical heating experiments toy, in which all tubes used to make heating test applications heat resistance boron
Silicate glass. Borosilicate glass test in accordance with Appendix A of discrimination.
Length for heating the glass tube should be greater than 110mm, shall be greater than the inner diameter of 15mm.
5.2.1.2 test tube is not used for heating
Instructions contained in test tubes and glass tubes are not used to heat the chemical test is not made of borosilicate glass, in toys
Some 6.2 tube should be labeled.
Heating the glass tube is not used (for example. the use of non-chemical test tubes), the length should be less than 90mm, the inner diameter should be less than
12mm.
5.2.2 Other glassware
Instructions for use, such as glassware comprising heating chemical test toys where all the vessels for heating the heat-resistant borosilicate application
Salt glass. Borosilicate glass test in accordance with Appendix A of discrimination.
The above requirement does not apply to heat it for the purpose of bending the glass tube.
Other vessels for heating, if not in shape and appearance may be mistaken for a heatable container shall be labeled 6.2.
5.2.3 reagent container
Reagent container size and shape should be different from the test of glassware, to avoid being mistaken for trial testing glassware
use.
All containers should be shock, when tested by the following method there should be no breaks, cracks or leaks.
From (850 ± 50) mm in height in the most unfavorable position dropped to a level placed on a hard surface, 4mm thick stainless steel plate, the
2mm thick stainless steel plate coated with a coating having a Shore hardness hardness (75 ± 5) degrees (according to ISO 868 or GB/T 531 test). weight
Complex dropped a total of five times. Visual observation vessel for damage, cracks or leaks.
5.2.4 Cover
Shall cover one of the following requirements.
--- In line with the requirements of ISO 8317;
--- Need to open two separate actions. a vertical downward pressure and a clockwise or counterclockwise direction (dentate Interface)
Of torque. B.1 in Appendix B of the first chapter (cover Test Method A) test, the lid should not be opened;
--- Should contain an inner plug, you need to use external tools to open. With a special cover only special tools can be opened. Appendix Press
Section B, Chapter B.2 (cover Test Method B) test, the lid should not be opened.
In addition, the closure for a container for liquids in accordance with Appendix B of when the first chapter B.3 (cover Test Method C) for testing should not have broken, cracked
Seam or leakage.
NOTE. The purpose of this test is to prevent young children in contact with these products chemicals.
5.2.5 Empty containers
Maximum capacity for the storage of empty containers of reagents in accordance with the requirements of Table 4, respectively, should not exceed 50mL and 100mL.
Table 4 empty storage container with a maximum capacity of reagent
The maximum capacity of the reagent/mL
Ammonia water, 2mol/L 50
Hydrochloric acid, 2mol/L 100
Hydrogen peroxide, 1mol/L 100
Sodium hydroxide solution, 1mol/L 100
5.3 pipetting apparatus
Can not be used when pipetting liquid nozzle suction pipette. If you need pipetting liquids, should not be to provide a mechanical pipette suction mouth party
Type, for example. with fixed emitter of eyedropper.
5.4 tube rack and test tube holder
When a test tube containing 5mL of water is placed in a test tube rack outermost holes and tilted 15 °, tube racks can not be overturned.
When the test is in progress need to be heated, it should be equipped with suitable test tube holder.
5.5 eye protection device
Goggle from the function and should be designed to maximize the protection of the eyes.
Blinkers the transparent protective material according to GB 6675 imitation toys impact test should not rupture.
If the experiment toy without adult supervision for people with eye protection device, the packaging should be labeled according to 6.3.2.
6 labels
6.1 General Requirements
Label shall comply with the provisions of GB 5296.5.
6.2 single vessel label and glassware
6.2.1 for a single packaged chemical substance or product shall be labeled with the following information.
a) Table 1, Table 2, or the name of a chemical substance or preparation are listed in Table 3;
b) Table 1, is a dangerous substance chemical substance or preparation, application text Table 2 or Table 3 lists the labels respective hazard class
No, oxidation, corrosive, flammable solids, flammable when wet, flammable liquids, toxic and other dangerous category should be in accordance with GB 13690
Logo hazard labels.
Note. Chemical substances and preparations of common names can be marked on the container.
6.2.2 on the glassware is not used for heating should be marked. "Prohibition heating."
Marked on the outer packaging 6.3
6.3.1 External packaging shall GB 5296.5 label producer, the name and address of the distributor.
6.3.2 It should also be marked on the outside of the package the following warning.
--- "Warning. only for children over the age of 10; only familiar with the precautionary measures under the strict supervision of adult use."
--- "Note. Contains chemicals with safety hazards.
Please read the instructions before use, follow the instructions and keep the manual for reference.
Chemicals must not touch any part of the body, especially the eyes and mouth.
The test shall be away from children and animals.
Chemicals should be stored out of children's reach. "
If necessary (see 5.5) marked on the packaging.
"Does not include adult supervision for eye protection devices people use."
Containing potassium permanganate toy safety warning should be in the age group 12 years and above.
NOTE. If necessary, the manufacturer can determine the age group 10 years and older in the security alert.
6.3.3 In addition, the attachment on the outer packaging should indicate the following warning.
"Note. This does not include the additional means required to complete all the test equipment and chemicals.
Complete test requires a full set of chemical equipment. "
7 warning and emergency information with the contents of the list
The contents of the list should include the following information.
List of chemicals a) a copy of the offer, including at least its name and dosage.
b) Risk Warning adapted for each specific substance, safety tips phrases.
c) blank space provided by the manufacturer, to fill in for your local poison center (emergency center) or the hospital's phone number to prepare for Inhalation
Use of toxic substances.
d) the general emergency ambulance follows.
"If contact with eyes. Flush eyes with plenty of water, so that if necessary, rinse eyes open, and seek medical attention immediately.
If swallowed. Rinse mouth and drink some clean water, do not induce vomiting. Seek immediate medical attention.
If inhaled. The person transferred to fresh air.
If skin contact and burns. Flush with plenty of water injured area 5min.
When in doubt, seek immediate medical attention, carrying containers of chemicals and chemical loading time for medical treatment.
If the injured. Get medical attention immediately. "
NOTE. Emergency Ambulance test data can also be placed in the operating instructions.
e) the need to provide special emergency medical information when necessary.
8 Owner's Manual
8.1 General Description
Instructions should use standard Chinese characters.
6.3 packaging labeling provisions should be repeated on the operating instructions written on the cover.
Instructions on the first page should contain a list of the contents of this product. Inventory information should refer to the requirements of 8.2 and 8.3.
Each test procedure shall be described in detail.
When appropriate, should be adapted to increase the risk of each specific substance in the course of trial operation descriptions, phrases and......
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GB 26387-2011: Safety of toys -- Experimental sets for chemistry and related activities
Status: Valid
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