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GB 25467-2010 English PDF

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GB 25467-2010: Emission standard of pollutants for copper, nickel, cobalt industry
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GB 25467-2010349 Add to Cart 3 days Emission standard of pollutants for copper, nickel, cobalt industry Valid

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Basic data

Standard ID: GB 25467-2010 (GB25467-2010)
Description (Translated English): Emission standard of pollutants for copper, nickel, cobalt industry
Sector / Industry: National Standard
Classification of Chinese Standard: Z70
Word Count Estimation: 15,178
Date of Issue: 2010-09-27
Date of Implementation: 2010-10-01
Older Standard (superseded by this standard): GB 8978-1996; GB 9078-1996; GB 16297-1996
Quoted Standard: GB/T 6920-1986; GB/T 7468-1987; GB/T 7475-1987; GB/T 7484-1987; GB/T 7485-1987; GB/T 11893-1989; GB/T 11894-1989; GB/T 11901-1989; GB/T 11912-1989; GB/T 11914-1989; GB/T 15432-1995; GB/T 16157-1996; GB/T 16489-1996; GB/T 16488-1996; HJ/T 27-1999; HJ/T 30-1999; HJ/T 55-2000; HJ/T 56-2000; HJ/T 57-2000; HJ/T 60-2000; HJ/T 63.1-2001; HJ/T 63.2-2001; HJ/T 67-2001; HJ/T 195-2005; HJ/T 199-2005; HJ/T 399-2007; HJ 480-2009; HJ 481-2009; HJ 482-2009; HJ 483 - 2009; HJ 487-2009; HJ 488-2009; HJ 535-2009; HJ 536-2009; HJ 537-2009; HJ 538-2009; HJ 539-2009; HJ 542-2009; HJ 543-2009; HJ 544 - 2009; HJ 547-2009; HJ 548-2009; HJ 549-2009; HJ 550-2009; " automatic monitoring pollution management approach" (State Environmental Protection Administration Order No. 28); "Environmental monitoring and Management Measures" (national Environmental Protection General Order No. 39); HJ 540-2009
Regulation (derived from): Department of Environmental Protection Notice 2010 No. 71 Announcement of Newly Approved National Standards 2010 No. 8 (No. 163 overall)
Issuing agency(ies): Ministry of Environmental Protection, General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China
Summary: This Chinese standard specifies the copper, nickel, cobalt, industrial enterprises and atmospheric water pollutant emission limits, surveillance and monitoring requirements, and standards for the implementation and supervision and other relevant provisions of blue. This standard applies to copper, nickel, cobalt, industrial enterprises of water pollutants and air pollution emissions management, as well as copper, nickel, cobalt, industrial enterprises to build the project's environmental impact assessment, environmental protection, facility design, completion and acceptance of environmental protection and water after commissioning pollutants and air pollutant emissions management.

GB 25467-2010: Emission standard of pollutants for copper, nickel, cobalt industry

---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Emission standard of pollutants for copper, nickel, cobalt industry National Standards of People's Republic of China Copper, nickel and cobalt industrial pollutant discharge standards Released on.2010-09-27 2010-10-01 Implementation Ministry of Environmental Protection State Administration of Quality Supervision, Inspection and Quarantine release Ministry of Environmental Protection announcement No. 71 of.2010 To implement the "Environmental Protection Law of the People's Republic of China", "Water Pollution Prevention and Control Law of the People's Republic of China" Pollution Prevention and Control Law, prevention and control of pollution, protection and improvement of the ecological environment, and protection of human health, the approval of the "Starch Industry Water Pollutant Emission Standard" The eight standards are the national pollutant discharge standards, and jointly issued by the Ministry and the General Administration of Quality Supervision, Inspection and Quarantine. The standard name and number are as follows. I. Emission standards for water pollutants in starch industry (GB 25461-2010) Second, the yeast industrial water pollutant discharge standards (GB 25462-2010) Third, the ink industry water pollutant discharge standards (GB 25463-2010) 4. Ceramic industry pollutant discharge standards (GB 25464-2010) V. Emission standards for aluminum industry pollutants (GB 25465-2010) 6. Lead and zinc industrial pollutant discharge standards (GB 25466-2010) 8. Magnesium and titanium industrial pollutant discharge standards (GB 25468-2010) According to the relevant laws, the above standards have the effect of enforcement. The above standards have been implemented since October 1,.2010. Special announcement. (This announcement was signed by Ji Zhengkun of the General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China) September 27,.2010

Content

Foreword..iv 1 Scope..1 2 Normative references..1 3 Terms and definitions. 2 4 Pollutant emission control requirements 4 5 Pollutant monitoring requirements..8 6 Implementation and supervision..10 Iv

Foreword

To implement the "Environmental Protection Law of the People's Republic of China", "Water Pollution Prevention and Control Law of the People's Republic of China" Dyeing Prevention and Control Law, the Marine Environmental Protection Law of the People's Republic of China, and the State Council's Decision on Implementing the Scientific Outlook on Development and Strengthening Environmental Protection And other laws, regulations and the "Opinions of the State Council on the preparation of national main functional area planning" to protect the environment, prevent pollution, promote copper, nickel, This standard is formulated for the advancement of cobalt industrial production processes and pollution control technologies. This standard specifies the limits, monitoring and monitoring requirements for water pollutants and atmospheric pollutants in the production process of copper, nickel and cobalt industrial enterprises. It is applicable to the prevention and management of water pollution and air pollution in copper, nickel and cobalt industrial enterprises. Promote the coordinated development of regional economy and environment and promote the economy Structural adjustment and transformation of economic growth mode, guiding the development direction of copper, nickel and cobalt industrial production processes and pollution control technologies, this standard The special emission limits for water pollutants are specified. The pollutant discharge concentrations in this standard are all mass concentrations. Copper, nickel, and cobalt industrial enterprises emit odorous pollutants and environmental noises, and apply corresponding national pollutant discharge standards to produce solid waste. Identification, treatment and disposal of national solid waste pollution control standards. This standard is the first release. Since the implementation of this standard, the discharge of water and air pollutants from copper, nickel and cobalt industrial enterprises has implemented this standard, and the implementation of sewage comprehensive Emission Standards (GB 8978-1996), "Integrated Emission Standards for Air Pollutants" (GB 16297-1996) and "Industrial Kiln Air Pollution" Relevant provisions in the Emission Standards (GB 9078-1996). Local provincial people's governments may formulate local pollutant discharge standards for pollutants not specified in this standard; For the specified pollutants, local pollutant discharge standards that are stricter than this standard can be formulated. This standard was formulated by the Science and Technology Standards Department of the Ministry of Environmental Protection. This standard is mainly drafted by. China Ruilin Engineering Technology Co., Ltd. (formerly Nanchang Nonferrous Metallurgy Design and Research Institute), Ministry of Environmental Protection Institute of Environmental Standards. This standard was approved by the Ministry of Environmental Protection on September 10,.2010. This standard has been implemented since October 1,.2010. This standard is explained by the Ministry of Environmental Protection. Copper, nickel and cobalt industrial pollutant discharge standards

1 Scope of application

This standard specifies the limits, monitoring and monitoring requirements for water pollutants and atmospheric pollutants in copper, nickel and cobalt industrial enterprises, as well as standard Implementation and supervision and other relevant regulations. This standard applies to the management of water pollutants and atmospheric pollutants in copper, nickel and cobalt industrial enterprises, as well as the construction of copper, nickel and cobalt industrial enterprises. Set environmental impact assessment, environmental protection facility design, environmental protection acceptance and completion of water pollutants and atmospheric pollutants after commissioning Put management. This standard does not apply to industries such as copper, nickel, cobalt regeneration and calendering; nor does it apply to non-characteristics attached to the copper, nickel and cobalt industries. Production process and equipment. This standard applies to the discharge of pollutants permitted by law; the location of newly established sources of pollution and the existing sources of pollution in special protected areas Li, in accordance with the Law of the People's Republic of China on the Prevention and Control of Air Pollution, the Law of the People's Republic of China on the Prevention and Control of Water Pollution, Environmental Protection Law, Law of the People's Republic of China on the Prevention and Control of Environmental Pollution by Solid Wastes, Law of the People's Republic of China on Prevention and Control of Radioactive Pollution, The relevant provisions of laws, regulations and rules such as the Environmental Impact Assessment Law of the People's Republic of China shall be implemented. The water pollutant emission control requirements specified in this standard are applicable to enterprises directly or indirectly discharging water pollutants outside their legal boundaries. behavior.

2 Normative references

The contents of this standard refer to the following documents or their terms. GB/T 6920-1986 Determination of pH value of water-based glass electrode method GB/T 7468-1987 Determination of total mercury in water -- Cold atomic absorption spectrophotometric method GB/T 7475-1987 Determination of copper, zinc, lead and cadmium - Atomic absorption spectrophotometric method GB/T 7484-1987 Determination of fluoride in water quality - Ion selective electrode method GB/T 7485-1987 Determination of total arsenic in water - Spectrophotometric method GB/T 11893-1989 Determination of total phosphorus in water - Ammonium molybdate spectrophotometric method GB/T 11894-1989 Determination of total nitrogen in water - Alkaline potassium persulfate digestion - UV spectrophotometric method GB/T 11901-1989 Determination of suspended solids by weight method GB/T 11912-1989 Determination of nickel in water quality - Flame atomic absorption spectrophotometric method GB/T 11914-1989 Determination of chemical oxygen demand in water - Dichromate method GB/T 15432-1995 Determination of total suspended particulate matter in ambient air GB/T 16157-1996 Determination of particulate matter in fixed pollution source exhaust gas and sampling method of gaseous pollutants Water quality -- Determination of petroleum and animal and vegetable oils - Infrared photometric method GB/T 16489-1996 Determination of sulphide content -- methylene blue spectrophotometric method HJ/T 27-1999 Determination of hydrogen chloride in fixed source emissions - Mercury thiocyanate spectrophotometric method HJ/T 30-1999 Determination of chlorine in fixed source exhaust gases - methyl orange spectrophotometric method HJ/T 55-2000 Technical Guidelines for the Monitoring of Unorganized Emissions of Air Pollutants HJ/T 56-2000 Determination of sulphur dioxide in fixed source s HJ/T 57-2000 Determination of sulfur dioxide in fixed source exhaust gases HJ/T 60-2000 Determination of water quality sulfides - Iodometric method HJ/T 63.1-2001 Determination of Nickel in Fixed Atmospheric Sources by Flame Atomic Absorption Spectrophotometry HJ/T 63.2-2001 Determination of Nickel in Fixed Atmospheres - Atomic Absorption Spectrophotometric Method HJ/T 67-2001 Determination of Fluoride in Fixed Atmospheric Sources Ion Selective Electrode Method HJ/T 195-2005 Determination of ammonia nitrogen in water quality HJ/T.199-2005 Determination of total nitrogen in water -- Gas phase molecular absorption spectroscopy HJ/T 399-2007 Determination of chemical oxygen demand in water quality - Rapid digestion spectrophotometric method HJ 480-2009 Determination of ambient air fluoride - Filter membrane sampling fluoride ion selective electrode method HJ 481-2009 Determination of ambient air fluoride - Lime filter paper sampling fluoride ion selective electrode method HJ 482-2009 Determination of sulphur dioxide in ambient air - Formaldehyde absorption - Para-elyl aniline spectrophotometric method HJ 483-2009 Determination of sulphur dioxide in ambient air - Tetrachlorohydroxide absorption - Pararosaniline spectrophotometric method HJ 487-2009 Determination of fluoride in water quality - Zirconium sulphonate Water quality - Determination of fluoride - Fluorescence spectrophotometric method HJ 535-2009 Determination of ammonia nitrogen in water quality - Nexus reagent spectrophotometric method HJ 536-2009 Determination of ammonia nitrogen in water quality - Salicylic acid spectrophotometric method HJ 537-2009 Determination of ammonia nitrogen in water quality - Distillation - Neutralometric titration HJ 538-2009 Determination of lead in fixed pollution sources - Flame atomic absorption spectrophotometric method (provisional) HJ 539-2009 Determination of lead in ambient air - Graphite furnace atomic absorption spectrophotometric method (provisional) HJ 540-2009 Determination of arsenic in air and waste gases - Spectrophotometric method for silver diethyldithiocarbamate (interim) HJ 542-2009 Determination of Mercury in Ambient Air - Enrichment of Sulfhydryl Cotton - Cold Atomic Fluorescence Spectrophotometry (Provisional) HJ 543-2009 Determination of mercury in fixed source emissions - Cold atomic absorption spectrophotometric method (provisional) HJ 544-2009 Determination of sulfuric acid mist of fixed pollution sources - Ion chromatography (interim) HJ 547-2009 Determination of chlorine in fixed source pollution - Iodometric method (provisional) HJ 548-2009 Determination of Hydrogen Chloride from Fixed Pollution Sources - Silver Nitrate Capacity Method (Provisional) HJ 549-2009 Determination of hydrogen chloride in air and exhaust gases - Chromatography (interim) HJ 550-2009 Determination of total cobalt in water - 5-chloro-2-(pyridylazo)-1,3-diaminobenzene spectrophotometric method (interim) Measures for the Automatic Monitoring and Control of Pollution Sources (Order No. 28 of the State Environmental Protection Administration) Measures for the Administration of Environmental Monitoring (Order No. 39 of the State Environmental Protection Administration)

3 Terms and definitions

The following terms and definitions apply to this standard. 3.1 Copper, nickel, cobalt industrial copper, nickel and cobalt industry Refers to the mining, mineral processing and smelting industries that produce copper, nickel and cobalt metals, excluding the recycling of scrap copper, nickel and cobalt materials. Smelting industry. 3.2 Characteristic production process and device Refers to the mining, mineral processing, smelting production processes of copper, nickel and cobalt metals and the devices associated with these processes. 3.3 Existing enterprise existing facility Refers to the copper, nickel or cobalt industrial enterprises or production facilities that have been completed and put into operation before the date of implementation of this standard. 3.4 New enterprise new facility Refers to the construction, construction and expansion of copper, nickel and cobalt production facilities approved by the environmental impact assessment document from the date of implementation of this standard. Head. 3.5 Effluent volume Refers to the amount of wastewater discharged by a production facility or enterprise outside the legal boundaries of the enterprise, including various effluxes that are directly or indirectly related to production. Waste water (such as domestic sewage, cooling wastewater, plant boilers and power station drainage). 3.6 Benchmark effluent volume per unit product Refers to the upper limit of wastewater discharge of copper, nickel and cobalt products produced by the production unit for the purpose of verifying the concentration of water pollutants. 3.7 Exhaust height Refers to the height from the ground level where the exhaust cylinder (or its main building construction) is located to the outlet of the exhaust. 3.8 Standard condition It refers to the state when the temperature is 273.15 K and the pressure is 101 325 Pa. The limits of atmospheric pollutant emission concentrations specified in this standard are based on standards. The dry gas in the state is the standard. 3.9 Excess air coefficient Refers to the ratio of the actual air volume to the theoretical air demand during the operation of the industrial furnace. 3.10 Exhaust volume Refers to the amount of waste gas discharged into the ambient air by the industrial production process and equipment of copper, nickel and cobalt, including direct or indirect contact with the production process and equipment. Various exhaust gases (such as environmental smoke collection, etc.). 3.11 Benchmark exhaust volume per unit product Refers to the upper limit of the displacement of copper, nickel and cobalt products produced by the production unit for the purpose of verifying the concentration of atmospheric pollutants. 3.12 Enterprise boundary Refers to the legal boundary of industrial enterprises of copper, nickel and cobalt. If the boundary cannot be determined, it means the actual boundary. 3.13 Public wastewater treatment system Refers to collecting waste water through sewage pipelines, providing wastewater treatment services for more than two sewage disposal units and draining can reach relevant rows Enterprises or institutions required by the standards, including urban sewage treatment plants of various scales and types, areas (including various industrial parks, development zones, Industrial gathering places, etc.) Wastewater treatment plants, etc., should have a wastewater treatment level of two or more. 3.14 Direct discharge Refers to the behavior of pollutant discharge units directly discharging water pollutants into the environment. 3.15 Indirect discharge Refers to the behavior of sewage units discharging water pollutants to public sewage treatment systems.

4 Pollutant emission control requirements

4.1 Water pollutant emission control requirements 4.1.1 From January 1,.2011 to December 31,.2011, existing enterprises implement the water pollutant discharge limits specified in Table 1. Table 1 Limits of water pollutant discharge concentration of existing enterprises and base product displacement of unit products Unit. mg/L (except pH) No. Pollutant project limit pollutant discharge monitoring position direct emission indirect discharge 1 pH value 6~9 6~9 Corporate wastewater discharge 2 Suspended matter 100 (optional).200 (selection) 70 (other) 140 (other) 3 Chemical Oxygen Demand (CODCr) 120 (wet smelting) 300 (wet smelting) 100 (other).200 (other) 4 Fluoride (in F) 8 15 5 total nitrogen 20 40 6 total phosphorus 1.5 2.0 7 ammonia nitrogen 15 20 8 total zinc 2.0 4.0 9 Petroleum 8 15 10 total copper 1.0 (mine and wet smelting) 2.0 (mine and wet smelting) 0.5 (other) 1.0 (other) 11 sulfide 1.0 1.0 12 total lead 1.0 Workshop or production facility wastewater discharge 13 total cadmium 0.1 14 total nickel 1.0 15 total arsenic 0.5 16 total mercury 0.05 17 total cobalt 1.0 Unit product benchmark Displacement Mineral processing (original ore)/(m3/t) 1.65 Displacement measurement position and pollutant discharge Consistent monitoring position Copper smelting/(m3/t) 25 Nickel smelting/(m3/t) 35 Cobalt smelting/(m3/t) 70 4.1.2 As of January 1,.2012, existing enterprises implement the water pollutant discharge limits specified in Table 2. 4.1.3 From October 1,.2010, the newly-built enterprise shall implement the water pollutant discharge limit specified in Table 2. Table 2 Limits of water pollutant discharge concentration of new enterprises and base product displacement Unit. mg/L (except pH) No. Pollutant project limit pollutant discharge monitoring position direct emission indirect discharge 1 pH value 6~9 6~9 Corporate wastewater discharge 2 Suspended matter 80 (selection).200 (selection) 30 (other) 140 (other) Continued No. Pollutant project limit pollutant discharge monitoring position direct emission indirect discharge 3 Chemical Oxygen Demand (CODCr) 100 (wet smelting) 300 (wet smelting) Corporate wastewater discharge 60 (other).200 (other) 4 Fluoride (in F) 5 15 5 total nitrogen 15 40 6 total phosphorus 1.0 2.0 7 ammonia nitrogen 8 20 8 total zinc 1.5 4.0 9 Petroleum 3.0 15 10 total copper 0.5 1.0 11 sulfide 1.0 1.0 12 total lead 0.5 Workshop or production facility wastewater discharge 13 total cadmium 0.1 14 total nickel 0.5 15 total arsenic 0.5 16 total mercury 0.05 17 total cobalt 1.0 Unit product benchmark Displacement Mineral processing (original ore)/(m3/t) 1.0 Displacement measurement position and pollutant discharge Consistent monitoring position Copper smelting/(m3/t) 10 Nickel smelting/(m3/t) 15 Cobalt smelting/(m3/t) 30 4.1.4 According to the requirements of environmental protection work, the density of land development has been higher, the environmental carrying capacity has begun to weaken, or the environmental capacity is relatively Areas that are small, ecologically fragile, prone to serious environmental pollution, and require special protection measures should be strictly controlled by enterprises. For pollutant discharge behavior, enterprises in the ab......
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