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National Food Safety Standard -- Food Additives -- Calcium stearate
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GB 1886.102-2016
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Basic data Standard ID | GB 1886.102-2016 (GB1886.102-2016) | Description (Translated English) | National Food Safety Standard -- Food Additives -- Calcium stearate | Sector / Industry | National Standard | Classification of Chinese Standard | X40 | Word Count Estimation | 6,692 | Date of Issue | 2016-08-31 | Date of Implementation | 2017-01-01 | Regulation (derived from) | Announcement of the State Administration of Public Health and Family Planning 2016 No.11 | Issuing agency(ies) | National Health and Family Planning Commission of the People's Republic of China, State Food and Drug Administration |
GB 1886.102-2016: National Food Safety Standard -- Food Additives -- Calcium stearate---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
(Food safety national standard - Food additive - Calcium stearate)
National Standards of People's Republic of China
National standards for food safety
Food Additives Calcium stearate
2016-08-31 released
2017-01-01 Implementation
People's Republic of China
National Health and Family Planning Commission released
National standards for food safety
Food Additives Calcium stearate
1 Scope
This standard applies to sodium stearate and calcium chloride solution after the interaction of refined and refined food additives from calcium stearate.
2 technical requirements
2.1 sensory requirements
Sensory requirements shall comply with the requirements of Table 1.
Table 1 sensory requirements
The project requires a test method
Color white to yellow and white
State loose powder, delicate, lubricity, no sand grain
Place the sample in a clean, dry white porcelain dish in nature
Under light, observe the color and state
2.2 physical and chemical indicators
Physical and chemical indicators should be consistent with the provisions of Table 2.
Table 2 Physical and chemical indicators
Item Index Test Method
Calcium stearate content (calculated as CaO on a dry basis), w /% 9.0 to 10.5 A.3 in Appendix A
Dry reduction, w /% ≤ 4.0 GB 5009.3 direct drying method a
Free acid (in stearic acid), w /% ≤ 3.0 Appendix A A.4
Lead (Pb)/(mg/kg) ≤ 2.0 GB 5009.12
a drying temperature of 105 ℃, drying time of 2h.
Appendix A
Testing method
A.1 General provisions
Unless otherwise stated, only the reagents identified as analytical reagents and the water specified in GB/T 6682 are used in the analysis. The criteria used in the analysis
Titration solution, standard solution for the determination of impurities, preparations and products, in the absence of other requirements, according to GB/T 601, GB/T 602 and
GB/T 603. The solution used in this test does not specify what kind of solvent preparation, refers to the aqueous solution.
A.2 Identification test
A.2.1 Take the sample 1g, mix with water 25mL and hydrochloric acid 5mL, heating, fatty acid is released, so that the oil layer of liquid surface. Water layer
Calcium test should be positive.
A.2.2 Take the sample 25g, mixed with hot water.200mL, plus 1mol/L sulfuric acid solution 60mL, heating and stirring to the fatty acid precipitation
And was transparent liquid. Wash the fatty acids with boiling water, until the sulphate is removed, collected in a small beaker, warm in the steam bath to fatty acids
Completely separate from the water layer and transparent. Cooling, discarding the water layer, melting the fatty acid into a dry beaker and drying at 105 ° C for 20 min.
The freezing point of the refined fatty acid should not be lower than 54 ° C. The freezing point is determined by conventional methods.
A.3 Calcium stearate content (calculated as CaO on a dry basis)
Accurately weighing about 1.2g sample, adding 50mL concentration of 0.1mol/L hydrochloric acid solution, boiling 10min, or to the fatty acid layer to clarify,
If necessary, add water to keep the original volume. Cooling, filtering, thoroughly washing the filtrate and the flask with water, until the final lotion is no longer acidic to litmus.
The filtrate was neutralized with 1 mol/L sodium hydroxide test solution and to litmus. Was added with a 50 mL burette with sufficient stirring with a magnetic stirrer
0.05mol/L ethylenediamine tetraacetic acid disodium solution of about 30mL, plus 1mol/L sodium hydroxide test solution 15mL and hydroxy naphthol blue indicator
300mg, and continue titration to the blue finish. 0.05mol/L of ethylenediamine tetraacetic acid disodium solution per ml is equivalent to CaO2.804mg.
A.4 Determination of free acid (measured as stearic acid)
Accurately weighed 2g sample, placed in 50mL acetone filled with 125mL dry conical flask, the bottle filled with air reflux condensation
, Boiled in a steam bath for 10 min and then cooled. Filtered through two layers of filter paper, washed with 50 mL of acetone, filter and filter. In the filtrate
Plus a few drops of phenolphthalein and 5 mL of water, titrated with 0.1 mol/L sodium hydroxide solution. While empty with 100 mL of acetone and 5 mL of water
White test. 0.1mol/L sodium hydroxide solution per milliliter equivalent to 28.45mg stearic acid (C18H36O2).
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