GB 6675.13-2014 English PDFUS$2009.00 · In stock
Delivery: <= 13 days. True-PDF full-copy in English will be manually translated and delivered via email. GB 6675.13-2014: Safety of toys -- Part 13: Chemical toys (sets) other than experimental sets Status: Valid
Basic dataStandard ID: GB 6675.13-2014 (GB6675.13-2014)Description (Translated English): Safety of toys -- Part 13: Chemical toys (sets) other than experimental sets Sector / Industry: National Standard Classification of Chinese Standard: Y57 Classification of International Standard: 97.200.50 Word Count Estimation: 91,998 Date of Issue: 12/5/2014 Date of Implementation: 1/1/2016 Regulation (derived from): Announcement of Newly Approved National Standards 2014 No. 27 Issuing agency(ies): General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China GB 6675.13-2014: Safety of toys -- Part 13: Chemical toys (sets) other than experimental sets---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.Safety of toys - Part 13. Chemical toys (sets) other than experimental sets ICS 97.200.50 Y57 National Standards of People's Republic of China Toy Safety Part 13. In addition to outside chemical experiments toy playset Issued on. 2014-12-05 2016-01-01 implementation Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China Standardization Administration of China released Table of ContentsPreface Ⅰ Introduction Ⅳ 1 Scope 1 2 Normative references 1 3 Terms and definitions 4 plaster (plaster) Mould Set 3 Ceramic and vitreous glazing material 5 small workshop kit provided 3 6 oven cured plastic PVC modeling clay Set 4 7 5 plastic mold suit 8 photographic developing sets 6 9 model kit provided or recommended adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) 7 10 identifies 13 Instructions for use 11 14 12 Test Method 16 Appendix A (informative) solvent content of different matrix and the maximum allowable concentration of 77 Annex B (informative) Measurement and pre-tested on a ceramic vitreous glazing material element 78 Confirm Annex C (informative) Test Method 79 Annex D (informative) relevant EU directives 80 Annex E (informative) of this section and EN71-5.1993 A1.2006 technical differences and their causes 81 References 84ForewordAll technical content in this section is mandatory. GB 6675 toy safety series of standards, including the following sections. --- Basic specification (GB 6675.1); --- General requirements, including but not limited to mechanical and physical properties (GB 6675.2), flammability (GB 6675.3), migration of certain elements (GB 6675.4); --- Specific requirements, requirements for specific products. This is Part 13 GB 6675's. This part is a series of toy safety standards in addition to the specific requirements of experiments outside the toy chemistry sets toys (GB 6675.13), used in conjunction with GB 6675.1, GB 6675.2, GB 6675.3, GB 6675.4, GB 19865 (applicable to electric toys). This section drafted in accordance with GB/T 1.1-2009 given rules. This section uses redrafted Law Amendment uses EN71-5.1993 A1.2006 "Safety of toys - Part 5. In addition to outside chemical experiments toy playset" (English). Taking into account China's national conditions, in the use of EN71-5.1993 A1.2006 when this part has made several modifications. About the technical differences have been incorporated into the text, given a list of these technical differences and their causes in Appendix E for reference. For ease of use, this section also made the following editorial changes. a) table footnote with a, b, etc. instead of a), b); b) using the "part" instead of "EN71 this part of the standard" and "EN71-5"; c) with the "GB 6675" Toy Safety "" instead of "EN71-1, EN71-2 and EN71-3" and with "GB 6675" instead of "EN71-3"; d) Remove the EN71-5.1993 A1.2006's "title page", "foreword", "A1 revision preface" and "Annex ZA", modify the EN71-5.1993 A1.2006's "Introduction"; e) title to the original standard segment 7.2,9.2.1,9.2.1.1,9.2.1.2,9.2.2,9.3,9.4,10,12.6.3 suspension were added under the following headings. General Requirements 7.2.1, 9.2 .1.1 general requirements 9.2.1.2.1 general requirements, general requirements 9.2.1.3.1, 9.2.2.1 general requirements, general requirements 9.3.1, 9.4.1 general requirements, 10.1 12.6.3.1 general requirements and general requirements; f) increase the informative "Appendix D" and "Appendix E"; g) to correct typographical errors in the following. --- Table 4 "N- (4- hydroxyphenyl) - amino - acid," the CAS number "2298-36-4" to "122-87-2"; EINECS number "218-947-5" replaced by "204-580-8"; "for aminophenol and its salts" to "on aminophenol sulphate"; --- 9.2.1 original standard third row "in Tables 6 and 8 in the special material" to "Tables 6 to 8 special material"; --- 9.2.1.2 Table 7 polymethyl methacrylate CAS number "25087-27-7" should read "25087-26-7"; Symbol --- 12.2.9.1 original standard formula (2) in the "Mm" and the original standard formula (1) is repeated, another symbol instead as "MM"; Equation (2) description "Mm the sample content of the metal, in% (by mass) means "to" MM is the content (mass fraction) compound in a sample,%. "; the last line" reduction coefficient of f in Table 19. the individual metal "in the" f "to" fm "; --- 12.3.2.1 Note the reference to "Table 17" to "Table 2"; --- 12.3.2.1 chemicals listed in Table 22 "ATBC" in CASNo "77-89-4" be replaced by "77-90-7."; Name --- 12.3.3.14 Figure 2, DEHP and BBP of the swap; --- 12.3.4.1 Table 25 "alkyl sulfonate" name after the leak of a "4"; --- 12.3.7.5 in the first line of "12.3.7.1" to "12.3.7.3"; --- 12.3.7.6 in the first line of "12.3.7.2" to "12.3.7.3"; --- Note 12.3.8.1.3 mentioned in the "Table 17" to "Table 2"; --- 12.3.8.2.1 of "record 12.3.7.5 and 12.3.7.6 identification of plasticizer." To "Record 12.3.7.5 identification of a plasticizer."; --- 12.3.8.2.2.1 original standard formula (19) in ce1 instructions "for the concentration of the solution was extracted with μg/mL represent;" to "phthalic Dimethyl ester concentration, in micrograms per milliliter (μg/mL); "; the original standard formula (20)" ce1 = (WA E) -WA "is superfluous, delete; --- 12.3.8.2.2.2 original standard formula (21) in ce2 instructions "for the concentration of the solution was extracted with μg/mL represent;" with "the concentration of citric acid esters, in micrograms per milliliter (μg/mL ); "; the original standard formula (22)" ce2 = (WB E) -WB "is superfluous, delete; The ce instructions --- 12.3.8.2.2.3 original standard formula (23) "is the concentration of the solution was extracted with μg/mL represent;" with "the concentration of alkyl sulfonate, in micrograms per milliliter (μg/mL); "; --- 12.5.7 penultimate line styrene concentration "(mg/mL)" to "(μg/mL)"; --- 12.5.8 The first line of the concentration of styrene "(mg/mL)" to "(μg/mL)"; --- 12.6.2.4.2.2 Table 40 Table title "Standards" to "agent"; --- 12.6.2.6.1 of "12.6.2.6 When performing the test" to "When performing the test 12.6.2.5"; --- 12.6.2.6.2.2 Table 44 in "concentration" to "requirements"; --- In 12.6.2.6.4 3 title "sodium metabisulfite Na2SO3 IR spectrum" is replaced by "of sodium metabisulfite Na2S2O5 IR spectrum "; --- 12.6.2.9 mentioned in the "Table 35" to "Table 32"; --- 12.6.3.6 12.6.3.5 original standard formula (26) Wc instructions "is called the quality crucible material, denoted by g." Instead, "said the quality of the crucible of salt in grams (g)."; --- 12.6.4.1 Table 49 "on aminophenol and its salts" is replaced by "For aminophenol sulphate"; formula "C7H9NO" changed "(C7H9NO) 2 · H2SO4"; --- X-axis value of 12.6.4.2.7 in FIG. 5 labeled "0,2,4,6,8,1" is replaced by. "0,2,4,6,8,10"; "Y area "change Into a "Y --- response"; --- 12.6.4.3 title "For aminophenol and its salts" is replaced by "For aminophenol sulphate"; --- 12.6.4.3.1.1 in Table 53 "on the A-aminophenyl sulfate" is replaced by "For aminophenol sulphate"; --- 12.6.4.3.3 in the "toluene aminophenol" to "on aminophenol sulphate"; --- X-axis value of 12.6.4.3.7 in Figure 6 is labeled "5,1,1,2,2" to. "5,10,15,20,25"; "Y area" to "Y --- response"; --- 12.6.4.4.6 of "chromatogram shown in Figure 6" to "chromatogram shown in Figure 5"; --- 12.6.4.4.7 Zhongyuan standard formula (28) is wrong, the denominator "10000 × d acid" is replaced by "100 × d acid × 2"; --- 12.7.3.1 Table 60 Table title "solvent" to "Standard"; --- 12.7.4.12 column name "50% phenyl methyl polysiloxane" is replaced by "50% phenyl 50% dimethylpolysiloxane"; --- 12.7.5.1 The original standard formula (29) "Vs = Vf × ds csst "To" Vs = Vf × csst 1000 × ds "; --- 12.7.5.1 in "ds --- density of the solvent, with mg/mL represents" with "density ds --- solvents in grams per milliliter L (g/mL) "; --- 12.7.5.4.4 title of "discrimination" to "quantitative"; --- Table 73 12.7.5.4.4 second list header "a working solution" to "stock solution"; --- 12.7.5.4.6 original standard first line "Table 76" to "Table 76 to Table 79"; the third line of the original standard "3-methyl-2,4 Pentanediol "to" 2-methyl-2,4-pentanediol "; Table 76 and Table 79 in the second column the last number" 0.005 "to" 0.050 "; Table 76, Table 77, Table 78 and Table 79 corresponds to a note in the cited provisions of resolution "12.7.5.4.1" to "12.7.7.4"; --- 12.7.5.4.7 table 80 corresponds to a note in the cited provisions of resolution "12.7.5.4.1" to "12.7.7.4"; --- 12.7.7.4 original standard third row "3-methyl-2,4-pentanediol" to "2-methyl-2,4-pentanediol"; --- 12.7.7.5 original standard second line "12.7.7.2" to "12.7.7.3"; --- 12.7.8.1 fifth column of table 82 the third row of the solvent name "3-methyl-2-butanol" to "3-methyl-2-butanone"; Clause No. --- 12.7.8.3 original standard fourth line referenced "12.7.5.4.5" to "12.7.5.4.4"; Clause No. --- 12.7.8.4 original standard fourth line referenced "12.7.5.4.5" to "12.7.5.4.6"; Solvent concentration "(mg/mL)" --- 12.7.9.1 The first line of the original standard was changed to "(mg/bottle)"; --- 12.7.9.2 original standard formula (31) in the Ws that "mass of the solvent, expressed in mg" with "the concentration of the solvent, the unit Milligram per milliliter (mg/mL); "; --- 12.8.4.1 the first row "a plasticizer measuring 12.3 GC-MS method to be described.", Delete the "GC-MS"; --- 12.8.4.5 original standard referenced in the second row Clause No. "12.8.2.6" to "12.8.2.5"; The abscissa in FIG. 11 --- 12.8.5.3.4.1 "Y" to "X"; The abscissa in FIG. 12 --- 12.8.5.3.4.2 "Y" to "X"; --- 12.8.5.7 "cstd --- the standard concentration was added, with in mg/L." Changed to "cstd --- change the concentration of the added standard Counted as volume after the concentration, in milligrams per milliliter (mg/mL). "; --- 12.8.5.7 original standard formula (35) "Mfa = cfa × 2 × 100 1000 × 1000 × W × rec "To" Mfa = cfa × 50 × 100 1000 × 1000 × W rec . " This part is proposed by the China National Light Industry Council. This part of the National Toy Standardization Technical Committee (SAC/TC253) centralized. This section is drafted. SZCIQ Toy Testing Center, Guangdong Entry-Exit Inspection and Quarantine Bureau Technology Toys Center Laboratory, Beijing Certification Center of Light, Ningbo CIQ light industrial products test center, Guangzhou CVC detection technology graduate School. The main drafters of this section. Dong Fu silver, Liu Binbin, Huang Li Na, ants Le Chau, Nguyen Jianmiao.IntroductionThis section is about the addition of chemical experiments toy playset outside national toy safety standards. Taking into account the normal behavior of children, when chemically playset by purpose or foreseeable manner prescribed use, this section attempts to reduce The health of children may cause injury. When using these chemicals playset by the addition of about possible hazards, dangers and other issues arising from particular attention will be Potential danger to a minimum. Toy Safety Part 13. In addition to outside chemical experiments toy playset1 ScopeGB 6675 specifies the requirements of this section in addition to the use of chemical experiments toy playset outside of substances and materials and tested party Law, provides. --- The highest content of dangerous substances and preparations; --- Children's excessive use may harm their health, maximum levels of substances and preparations; --- Toy comes with the highest content of other substances and products. In addition, it provides for identification, warning, safety rules, a list of items, instructions for use and first aid information requirements. This section applies to. --- Plaster mold kit; Ceramics and glassy --- small workshop kit provided in the glazing material; --- Oven cured plastic PVC modeling clay sets; --- Plastic mold package; --- Embedding sets; --- Photographic developing sets; --- Model kit provided or recommended adhesives, paint, lacquer, varnish, thinner and cleaning agent (solvent).2 Normative referencesThe following documents for the application of this document is essential. For dated references, only the dated version suitable for use herein Member. For undated references, the latest edition (including any amendments) applies to this document. GB 2760 national food safety standards of food additives using standard GB 5296.5 consumer use - Part 5. Toys GB 6675 National Safety Technical Code for Toys GB/T 6682-2008 analytical laboratory use specifications and test methods (ISO 3696. 1987, MOD) GB 13690-2009 chemical classification and hazard communication General EN14517.2004 Liquefied petroleum product petroleum hydrocarbons and oxides of measuring multidimensional gas chromatography (Liquid petroleumproducts-Determinationofhydrocarbontypesandoxygenatesinpetrol-Multidimensional gaschromatographymethod) "Hygienic Standard for Cosmetics" (People's Republic of China Ministry of Health, January 2007)3 Terms and DefinitionsThe following terms and definitions apply to this document. 3.1 Plaster of Paris (gypsum) mold sets PlasterofParis (gypsum) mouldingset Toys containing mold, the mold can be poured into water and gypsum (mainly calcium sulfate hemihydrate CaSO4 · 0.5H2O) was to make it hard Technology, such as graphics and used to make plates. 3.2 Ceramics and glassy small workshop kit provided glazing material ceramicandvitreousenamelingmaterialssup- pliedinminiatureworkshopset Toys containing ceramic and vitreous glazing material (transparent, opaque or colored), and these glazing materials after water was added and painted ceramics Metal objects on the surface to form a smooth coating, and then place them in more than 700 ℃ dried and fired. 3.3 Modeling clay oven cured plastic PVC suits ovenhardeningplasticizedPVC-modelingclayset It used to make various types of graphic, brooches, fashion jewelry and other toys, which is prepared by and at a temperature between 100 ℃ of 130 ℃ Oven curing between achieved. 3.4 Plastic mold suit plasticmouldingset Alternatively the ceramic material used to fabricate the toy or ornament model, which is prepared by the maximum temperature does not exceed 180 deg.] C oven for Heating the polymer to achieve the integration. 3.5 Set embedding embeddingset Transparent material is used in some products stored in toys. 3.6 Photographic developing sets photographicdevelopingset Containing chemicals (developer, stop bath, fixer) to deal with black and white photographic film and photos and is designed to teach the basic principles of photography toy. 3.7 Model kit provided or recommended adhesives, paints, lacquers, varnishes, thinners and cleaning agents adhesives, paints, lacquers, varnishes, thinnersandcleaningagentssuppliedorrecommendedinmodelsets Used to assemble and film models (such as cars, planes, houses, ships) products. 3.7.1 Adhesive adhesive To provide a kind surface bonding (adhesion), and the adhesive force has a certain internal forces (cohesion) of the material combined non-metal material. 3.7.2 Water-based paint water-basedpaint A process for the paint material, when in liquid form to the surface of the coating film, after a period of time to form a dried adhesive film. 3.7.3 Containing paints and paint solvents paintandlacquerscontainingsolvents With adhesives, solvents, dyes and pigments (coloring substances), fillers and modifiers for the coating material. 3.7.4 Varnish varnishes Low viscous paint. 3.7.5 Thinner and cleaning agent (solvent) thinnersandcleaningagents (solvents) For obtaining the desired viscosity of paint and paint, brushes and cleaning tools and products. 3.8 Formulation preparations It composed of two or more substances of the mixture or solution. 4 plaster (gypsum) mold suit Note. Generally plaster (gypsum) is not a hazardous material, but if inhaled or swallowed the powder, lumps can form in the lungs or the stomach. 4.1 Logo 10.2 In addition to the labeling requirements, the packaging should also have the following. Note that only children under 5 years of age or more. Used under adult supervision. To read the instructions before use, and strictly in accordance with the instructions, the instructions to save backup. 4.2 Safety Rules Instructions In addition to the requirements of Rule 11.4, but also has the following safety rules. --- Do not place material into the mouth; --- Do not inhale dust or powder; --- Do not use on the body. Ceramic and vitreous glazing material 5 small workshop kit provided 5.1 chemical preparations These ceramics and silicate glaze vitreous glazing material, for the mixed metal oxide plus given in Table 1 and other compounds Formulations. A suite of products, each with a maximum mass not exceed 50g. Note. The ceramic glaze is an inorganic silicate glass material. Ceramic frit is a glass of inorganic pigment is added silicate material. 5.2 Logo 10.2 In addition to the labeling requirements, the packaging but also the content of the following warning. Warnings are for children 5 years old or more. Used under adult supervision. Note To read the instructions before use, and strictly in accordance with the instructions, the instructions to save backup. 5.3 Security Rules Instructions In addition to the requirements of Rule 11.4, but also has the following safety rules. --- Do not breathe powder; --- Do not powder was put into the mouth; --- Do not apply to the supply of goods and food and beverage contact; --- The Set away from food and beverages; --- Firing process does not belong to the function of the toy section, so that children do not close in the firing process, do not inhale the gas emitted. Table 1 Chemical preparations Substances/products CAS Number EINECS Number Hydrated calcium silicate (clay) Kaolin (china clay) Slightly soluble silicate glazes, such as enamel and ceramic frit Use only the following in these pigment glaze. Copper oxide ≤0.25% Ferric oxide ≤5% Zirconium silicate iron ≤5% Tin dioxide ≤10% Vanadium, zirconium silicate ≤5% ≤3% cobalt aluminum oxide Zirconium silicate ≤15% Praseodymium zirconium silicate ≤5% 1344-96-3 1332-58-7 65997-18-4 1317-38-0 1309-37-1 68412-79-3 18282-10-5 68186-95-8 1333-88-6 10101-52-7 68187-15-5 266-047-6 215-269-1 215-168-2 270-210-7 242-159-0 269-057-9 269-075-76 oven cured plastic PVC modeling clay sets6.1 Chemical Substances These packages by modeling clay PVC (polyvinyl chloride), plasticizers, fillers (e.g. clay, aluminum hydroxide) and a coloring agent. Only the Table 2 gives a plasticizer. The highest content of plasticizer in the formulation does not exceed 30%. Vinyl chloride monomer content to less than 1mg/kg. Table 2 Plasticizer Chemical substances CAS No. EINECS No. Adipic acid polyester Alkyl phenol sulfonates (C12 ~ C20) A mixture of straight-chain fatty alcohols (C6 and above) phthalate esters and such ATBC Acetyl tributyl citrate (2-ethylhexyl) phthalate 77-90-7 144-15-0 201-067-0 205-617-0 6.2 Logo 10.2 In addition to the labeling requirements, the packaging but also the content of the following warning. Warnings are for children over 8 years. Used under adult supervision. Note To read the instructions before use, and strictly in accordance with the instructions, the instructions to save backup. 6.3 Safety Rules Instructions In addition to the requiremen......Tips & Frequently Asked Questions:Question 1: How long will the true-PDF of GB 6675.13-2014_English be delivered?Answer: Upon your order, we will start to translate GB 6675.13-2014_English as soon as possible, and keep you informed of the progress. The lead time is typically 9 ~ 13 working days. 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