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GB 15580-2011 English PDF

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GB 15580-2011: Discharge standard of water pollutants for phosphate fertilizer industry
Status: Valid

GB 15580: Historical versions

Standard IDUSDBUY PDFLead-DaysStandard Title (Description)Status
GB 15580-2011279 Add to Cart 3 days Discharge standard of water pollutants for phosphate fertilizer industry Valid
GB 15580-1995319 Add to Cart 3 days Discharge standard of water pollutants for phosphate fertilizer industry Obsolete

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Basic data

Standard ID: GB 15580-2011 (GB15580-2011)
Description (Translated English): Discharge standard of water pollutants for phosphate fertilizer industry
Sector / Industry: National Standard
Classification of Chinese Standard: Z61
Classification of International Standard: 13.020.40
Word Count Estimation: 12,191
Date of Issue: 2011-04-02
Date of Implementation: 2011-10-01
Older Standard (superseded by this standard): GB 15580-1995
Quoted Standard: HJ/T 199-2005; HJ/T 399-2007; HJ 487-2009; HJ 488-2009; HJ 535-2009; HJ 536-2009; HJ 537-2009; " automatic monitoring pollution management approach" SEPA Order No. 28; "Environmental monitoring and Management Measures" State Environmental Protection Administration Order No. 39; GB/T 6920-1986; GB/T 7484-1987; GB/T 7485-1987; GB/T 11893-1989; GB/T 11894-1989; GB/T 11901-1989; GB/T 11914-1989; HJ/T 84-2001; HJ/T 195-2005
Regulation (derived from): Announcement of Newly Approved National Standards No. 6 of 2011 Environment Department Notice No. 30 of 2011
Issuing agency(ies): General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China
Summary: This Chinese standard specifies the phosphate fertilizer industry enterprises or production facilities of water pollutant discharge limits. This standard applies to existing industrial enterprises phosphate fertilizer production facilities or water pollutant emissions management. This standard applies to the phosphate fertilizer industry construction project environmental impact assessment, environmental protection facilities design, environmental acceptance and commissioning completed water pollutant emissions management. This standard applies to legally permissible emission behavior. The location and the newly established sources of existing pollution sources in special protected areas management, according to"The People's Republic of China Air Pollution Prevention Law", "PRC Water Pollution Prevention Law, "Marine Environmental Protection Law, "China people's Republic of solid Waste Pollution prevention Law", "people's Republic of radioactive pollution Prevention Law", "PRC environmental Impact Assessment Law"and other laws, regulations and rules of the relevant regulations. This standard specifies a water pollutant emission control requirements apply to companies directly or indirectly, to its discharge water pollutants outside the legal boundaries of behavior.

GB 15580-2011: Discharge standard of water pollutants for phosphate fertilizer industry

---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Discharge standard of water pollutants for phosphate fertilizer industry National Standards of People's Republic of China Replace GB 15580-95 Phosphate fertilizer industry water pollutant discharge standard Published on.2011-04-02 2011-10-01 Implementation Ministry of Environmental Protection State Administration of Quality Supervision, Inspection and Quarantine release Ministry of Environmental Protection announcement No. 30 of.2011 To implement the "Environmental Protection Law of the People's Republic of China", "Water Pollution Prevention and Control Law of the People's Republic of China" Pollution Prevention and Control Law, prevention and control of pollution, protection and improvement of the ecological environment, and protection of human health, is now approved "vanadium industrial pollutant discharge standards", etc. The three standards are national pollutant discharge standards, and are jointly issued by the Ministry and the General Administration of Quality Supervision, Inspection and Quarantine. The standard name and number are as follows. I. Vapor industry industrial pollutant discharge standard (GB 26452-2011) Third, flat glass industry air pollutant discharge standards (GB 26453-2011) According to the relevant laws, the above standards have the effect of enforcement. The above standards have been implemented since October 1,.2011. From the date of implementation of the above standards, the following national pollutant discharge standards are abolished. Phosphate fertilizer industry water pollutant discharge standard (GB 15580-95). Special announcement. (This announcement was signed by Ji Zhengkun of the General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China) April 2,.2011

Content

Foreword..iv 1 Scope..1 2 Normative references..1 3 Terms and Definitions.1 4 Water pollutant emission control requirements..2 5 Water pollutant monitoring requirements.4 6 Implementation and supervision.5 Iv

Foreword

To implement the "Environmental Protection Law of the People's Republic of China", "Water Pollution Prevention and Control Law of the People's Republic of China" Laws and Regulations, "State Council's Decision on Implementing the Scientific Outlook on Development and Strengthening Environmental Protection", etc. Opinions on the planning of the main functional area of the country, protect the environment, prevent pollution, strengthen the control and management of wastewater discharge from phosphate fertilizer enterprises, and develop this standard quasi. This standard specifies the limits, monitoring and monitoring requirements for water pollutant discharge in phosphate fertilizer industrial enterprises. To promote the coordinated development of the regional economy and the environment, Promote the adjustment of economic structure and the transformation of economic growth mode, and guide the development direction of industrial production technology and pollution control technology, this standard Specific emission limits for water pollutants have been established. The concentration of pollutants discharged in this standard is the mass concentration. Phosphate fertilizer industrial enterprises and production facilities emit atmospheric pollutants (including odorous pollutants), and environmental noise is applied to corresponding national pollutant discharges. Standards, the identification, treatment and disposal of solid wastes are subject to national solid waste pollution control standards. This standard was first published in.1995 and this is the first revision. The main contents of this revision are. -- Adjusted the pollutant discharge control project according to the needs of implementing national environmental protection planning, environmental protection management and law enforcement work. Increased pollutant emission control requirements; - Increased special discharge limits and indirect emission limits for water pollutants; - Cancellation of the classification management according to the direction of sewage; -- Pollutant emission limits are no longer regulated by firm size. From the date of implementation of this standard, the "Phosphorus Industry Water Pollutant Discharge Standard" (GB 15580-95) shall be abolished at the same time. Local provincial people's governments may formulate local pollutant discharge standards for pollutants not specified in this standard; For the specified pollutants, local pollutant discharge standards that are stricter than this standard can be formulated. This standard was formulated by the Science and Technology Standards Department of the Ministry of Environmental Protection. This standard is mainly drafted by. China Academy of Environmental Sciences, Sinopec Nanjing Design Institute. This standard was approved by the Ministry of Environmental Protection on April 2,.2011. This standard has been implemented since October 1,.2011. This standard is explained by the Ministry of Environmental Protection. Phosphate fertilizer industry water pollutant discharge standard

1 Scope of application

This standard specifies the limits for the discharge of water pollutants from phosphate fertilizer industrial enterprises or production facilities. This standard applies to the management of water pollutant discharge in existing phosphate fertilizer industrial enterprises or production facilities. This standard applies to the environmental impact assessment of the phosphate fertilizer industry construction project, the design of environmental protection facilities, the completion of environmental protection acceptance and its investment Post-production water pollutant discharge management. This standard applies to the discharge of pollutants permitted by law. Sites for newly established pollution sources and tubes for existing pollution sources in special protection areas Li, in accordance with the Law of the People's Republic of China on the Prevention and Control of Air Pollution, the Law of the People's Republic of China on the Prevention and Control of Water Pollution, Environmental Protection Law, Law of the People's Republic of China on the Prevention and Control of Environmental Pollution by Solid Wastes, Law of the People's Republic of China on Prevention and Control of Radioactive Pollution, The relevant provisions of laws, regulations and rules such as the Environmental Impact Assessment Law of the People's Republic of China shall be implemented. The water pollutant discharge control requirements specified in this standard are applicable to the behavior of enterprises directly or indirectly discharging water pollutants outside their legal boundaries.

2 Normative references

The contents of this standard refer to the following documents or their terms. GB/T 6920-86 Determination of pH of water - Glass electrode method GB/T 7484-87 Determination of fluoride in water quality - Ion selective electrode method GB/T 7485-87 Determination of total arsenic in water - Diethyldithiocarbamate spectrophotometric method GB/T 11893-89 Determination of total phosphorus in water - Ammonium molybdate spectrophotometric method GB/T 11894-89 Determination of total nitrogen in water -- Basic potassium persulfate digestion spectrophotometric method GB/T 11901-89 Determination of suspended solids by weight method GB/T 11914-89 Determination of chemical oxygen demand in water - Dichromate method HJ/T 84-2001 Determination of inorganic anions in water - Ion chromatography HJ/T 195-2005 Determination of ammonia nitrogen in water quality HJ/T.199-2005 Determination of total nitrogen in water -- Gas phase molecular absorption spectroscopy HJ/T 399-2007 Determination of chemical oxygen demand in water quality - Rapid digestion spectrophotometric method HJ 487-2009 Determination of fluoride in water quality - Zirconium sulphonate Water quality - Determination of fluoride - Fluorescence spectrophotometric method HJ 535-2009 Determination of ammonia nitrogen in water quality - Nexus reagent spectrophotometric method HJ 536-2009 Determination of ammonia nitrogen in water quality - Salicylic acid spectrophotometric method HJ 537-2009 Determination of ammonia nitrogen in water quality - Distillation - Neutralometric titration Measures for the Automatic Monitoring and Control of Pollution Sources (Order No. 28 of the State Environmental Protection Administration) Measures for the Administration of Environmental Monitoring (Order No. 39 of the State Environmental Protection Administration)

3 Terms and definitions

The following terms and definitions apply to this standard. 3.1 Phosphate fertilizer industry The industry that produces phosphate fertilizer products. Phosphate fertilizer products include. superphosphate (referred to as calcium), calcium magnesium phosphate, ammonium phosphate, heavy superphosphate (simplified Weighing calcium), compound fertilizers (including compound fertilizers and fertilizers), nitrophosphate and other by-products (such as fluorine processing products), and the production of phosphate fertilizer The intermediate product required is phosphoric acid (wet method). 3.2 Existing enterprise existing facility Phosphate fertilizer enterprises or production facilities that have been approved for production or environmental impact assessment documents have been completed by the date of implementation of this standard. 3.3 New enterprise new facility From the date of implementation of this standard, the environmental impact assessment document approved the construction, reconstruction and expansion of the phosphate fertilizer industry construction project. 3.4 Direct discharge The behavior of pollutant discharge units directly discharging pollutants into environmental water bodies. 3.5 Indirect discharge The discharge of pollutants by the pollutant discharge unit to the public sewage treatment system. 3.6 Public sewage treatment system Collect wastewater through sewage pipelines, provide wastewater treatment services for more than two sewage disposal units, and discharge to achieve relevant emissions Enterprises or institutions required by the standard, including urban sewage treatment plants of various scales and types, areas (including various industrial parks, development zones, Industrial gathering places, etc.) Wastewater treatment plants, etc., should have a wastewater treatment level of two or more. 3.7 Effluent volume The amount of wastewater discharged by a production facility or enterprise outside the legal boundaries of the enterprise, including various external wastes that are directly or indirectly related to production. Water (such as domestic sewage, cooling wastewater, plant boilers and power station drainage). 3.8 Benchmark effluent volume per unit product The upper limit of the wastewater discharge amount of the production unit phosphate fertilizer product specified for the approval of the discharge concentration of water pollutants.

4 Water pollutant emission control requirements

4.1 From October 1,.2011 to March 31,.2013, existing companies implement the water pollution emission limits specified in Table 1. Table 1 Limits of existing enterprise water pollutants Unit. mg/L (except pH) Serial number of pollutants Direct emission limit indirect discharge Limit pollutant discharge monitoring position, superphosphate, calcium, magnesium phosphate, ammonium phosphate, a heavy superphosphate, compound fertilizer 1 pH value 6~9 6~9 6~9 6~9 6~9 6~9 Corporate wastewater discharge 2 Chemical oxygen demand (CODCr) 80 80 80 80 80 150 3 Suspension 80 80 50 50 50 100 4 Fluoride (in F) 20 20 15 15 15 20 5 Total phosphorus (in P) 20 20 20 20 20 20 Continued Serial number of pollutants Direct emission limit indirect discharge Limit pollutant discharge monitoring position, superphosphate, calcium, magnesium phosphate, ammonium phosphate, a heavy superphosphate, compound fertilizer 6 total nitrogen 15 15 20 15 20 60 Corporate wastewater discharge 7 Ammonia nitrogen 10 10 15 10 15 30 8 Total arsenic 0.5 0.5 0.5 0.5 0.5 0.5 Waste water discharge port of workshop or production facility Unit product basis displacement / (m3/t product) 0.3 0.4 0.3 0.2 0.2 with direct discharge the same Displacement measurement position and pollution The emission monitoring position is consistent 15b a Phosphate fertilizer is implemented in accordance with the limits of ammonium phosphate emissions. b Applicable to enterprises with fluorine processing products (products are based on sodium fluorosilicate), the unit is m3/t. 4.2 As of April 1,.2013, existing companies implement the water pollution emission limits specified in Table 2. 4.3 Since October 1,.2011, new enterprises have implemented the water pollution emission limits specified in Table 2. Table 2 New enterprise water pollutant emission limit Unit. mg/L (except pH) Serial number of pollutants direct emission limit indirect emission limit pollutant discharge monitoring position superphosphate calcium magnesium magnesium phosphate ammonium phosphate a heavy superphosphate super compound fertilizer 1 pH value 6~9 6~9 6~9 6~9 6~9 6~9 Corporate wastewater discharge 2 Chemical oxygen demand (CODCr) 70 70 70 70 70 150 3 Suspension 30 30 30 30 30 100 4 Fluoride (in F) 15 15 15 15 15 20 5 Total phosphorus (in P) 10 10 15 15 10 20 6 total nitrogen 15 15 20 15 20 60 7 Ammonia nitrogen 10 10 15 10 15 30 8 Total arsenic 0.3 0.3 0.3 0.3 0.3 0.3 Wastewater discharge port of workshop or production facility Unit product basis displacement / (m3/t) 0.3 0.4 0.2 0.15 0.15 with direct emissions the same Displacement measurement position and pollution Material emission monitoring position consistent 12b a Phosphate fertilizer is implemented in accordance with the limits of ammonium phosphate emissions. b Applicable to enterprises with fluorine processing products (products are based on sodium fluorosilicate), the unit is m3/t. 4.4 According to the requirements of environmental protection work, the density of land development has been high, the environmental carrying capacity has begun to weaken, or the environmental capacity is small. In areas where the ecological environment is fragile and prone to serious environmental pollution problems and special protection measures are required, the pollutants of enterprises should be strictly controlled. In the discharge behavior, the phosphate fertilizer enterprises in the above-mentioned areas implement the special discharge limit of water pollutants specified in Table 3. Table 3 Special limits for water pollutants Unit. mg/L (except pH) Serial number of pollutants direct emission limit indirect emission limit pollutant discharge monitoring position superphosphate calcium magnesium magnesium phosphate ammonium phosphate a heavy superphosphate super compound fertilizer 1 pH value 6~9 6~9 6~9 6~9 6~9 6~9 Corporate wastewater discharge 2 Chemical oxygen demand (CODCr) 50 50 50 50 50 100 3 suspended solids 20 20 20 20 20 40 4 Fluoride (in F) 10 10 10 10 10 15 5 Total phosphorus (in P) 0.5 0.5 0.5 0.5 0.5 1.0 Continued Serial number of pollutants direct emission limit indirect emission limit pollutant discharge monitoring position superphosphate calcium magnesium magnesium phosphate ammonium phosphate a heavy superphosphate super compound fertilizer 6 Total nitrogen 10 10 15 10 15 20 Total discharge of enterprise wastewater 7 ammonia nitrogen 5 5 10 5 10 15 8 Total arsenic 0.1 0.1 0.1 0.1 0.1 0.1 Wastewater discharge port of workshop or production facility Unit product basis displacement / (m3/t product) 0.2 0.2 0.1 0.1 0.1 With direct emissions the same Displacement measurement position and pollution Material emission monitoring position is consistent a Phosphate fertilizer is implemented in accordance with the limits of ammonium phosphate emissions. The geographical scope and time for the implementation of special discharge limits for water pollutants shall be governed by the environmental protection administrative department of the State Council or the provincial people's government. set. 4.5 The concentration limit of water pollutant discharge is applicable to the case where the actual displacement of the unit product is not higher than the unit discharge of the unit product. If the unit is produced If the actual displacement of the product exceeds the standard discharge of the unit product, the measured water pollutant concentration shall be converted into the reference discharge of the water pollutant according to formula (1). Emission concentration, and the discharge concentration of water pollutants as the basis for determining whether the emission is up to standard. Product Production and Discharge Statistics Week The period is one working day. Production of two or more products at the same time in the production facilities of the enterprise, applicable to different emission control requirements or national pollutant discharge standards in different industries In the case of quasi-mixed wastewater from production facilities, the most stringent concentration limits specified in the emission standards shall be implemented and Equation (1) Converts the discharge concentration of water pollutants from the baseline. YQ ρ ρ= ×∑ total base (1) Where. ρ base - water pollutant baseline discharge concentration, mg/L; Q total - measured total drainage, m3; iY--the output of a certain product, t; iQ base - the base product displacement of a product, m3/t; ρ实--Measured water pollutant concentration, mg/L. If the ratio of Q to is less than 1, the measured concentration of water pollutants is used as the basis for determining whether the discharge meets the standard. Total i iY Q∑ base

5 Water pollutant monitoring requirements

5.1 Sampling of wastewater discharged by enterprises shall be carried out according to the type of pollutants to be monitored and at the monitoring location of the specified pollutant discharge. Waste water The treatment facilities shall be monitored after the treatment facility. A permanent drain outlet sign shall be provided at the pollutant discharge monitoring location. 5.2 Requirements for the installation of automatic monitoring equipment for pollutant discharge in newly-built enterprises and existing enterprises, in accordance with relevant laws and “Automatic Monitoring and Management of Pollution Sources” The provisions of the Measures are implemented. 5.3 Frequency, sampling time, quality assurance and quality control requirements for monitoring the discharge of pollutants from enterprises, according to relevant national pollution Implementation of the technical specifications for dye source monitoring. 5.4 The verification of the output of the enterprise products shall be based on the statutory statements. 5.5 The enterprise shall monitor the discharge status and preserve the original monitoring in accordance with the relevant laws and the Measures for the Administration of Environmental Monitoring. recording. 5.6 The method standards listed in Table 4 are used to determine the concentration of pollutants discharged from enterprises. Table 4 Standards for determination of water pollutant concentration No. Contaminant Project Method Standard Name Method Standard Number 1 pH value water quality determination of glass electrode method GB/T 6920-86 2 Chemical oxygen demand water quality Determination of che......
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