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GB/T 37866-2019 PDF English

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GB/T 37866-2019: Green Product Assessment - Plastic Products
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GB/T 37866-2019: Green Product Assessment - Plastic Products

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NATIONAL STANDARD OF THE PEOPLE’S REPUBLIC OF CHINA ICS 13.020.20 Z 04 Green Product Assessment - Plastic Products ISSUED ON: AUGUST 30, 2019 IMPLEMENTED ON: MARCH 1, 2020 Issued by: State Administration for Market Regulation; Standardization Administration of the People’s Republic of China.

Table of Contents

Foreword ... 3 1 Scope ... 4 2 Normative References ... 4 3 Terms and Definitions ... 5 4 Requirements of Product Assessment ... 5 5 Assessment Methods ... 8 Appendix A (normative) Volatile Organic Compounds (VOC) Content Determination Method ... 9 Green Product Assessment - Plastic Products

1 Scope

This Standard stipulates the requirements and methods for green product assessment of plastic products. This Standard is applicable to all the plastic products.

2 Normative References

The following documents are indispensable to the application of this document. In terms of references with a specified date, only versions with a specified date are applicable to this document. In terms of references without a specified date, the latest version (including all the modifications) is applicable to this document. GB/T 2408 Plastics - Determination of Burning Characteristics - Horizontal and Vertical Test; GB 4806.7 National Food Safety Standard - Food Contact Plastic Materials and Articles; GB/T 7119 Evaluating Guide for Water Saving Enterprises; GB 8978 Integrated Wastewater Discharge Standard; GB/T 9345.5 Plastics - Determination of Ash - Part 5: Poly (vinyl chloride); GB/T 16288 Marking of Plastics Products; GB 16297 Comprehensive Emission Standard of Air Pollutants; GB/T 17592 Textiles - Determination of the Banned Azo Colorants; GB/T 19001 Quality Management Systems - Requirements; GB/T 19277.1 Determination of the Ultimate Aerobic Biodegradability of Plastic Materials under Controlled Compositing Conditions - Method by Analysis of Evolved Carbon Dioxide - Part 1: General Method; GB/T 22048 Determination of Certain Phthalate Esters in Toys and Children’s Products; GB/T 23331 Energy Management Systems - Requirements; GB/T 24001 Environmental Management Systems - Requirements with Guidance for Use; GB/T 28001 Occupational Health and Safety Management Systems - Requirements; GB/T 28206 Specification for Compostable Plastic; GB/T 33284 Indoor Decorating and Refurbishing Materials - Limit of Harmful Substances of Un-plasticized Polyvinyl Chloride (PVC-U) Profiles for the Doors and Windows; HJ/T 400-2007 Determination of Volatile Organic Compounds and Carbonyl Compounds in Cabin of Vehicles; QB/T 5158 Test Method of Artificial Leather and Synthetic Leather - Test of Quantitatively Determine Dimethylformamide

3 Terms and Definitions

The following terms and definitions are applicable to this document. 3.1 Green Plastic Product Green plastic product refers to plastic product which has no harm or little harm to the ecological environment and human health, and has less energy consumption and a high quality, and can comply with the requirements of environmental protection in the full life cycle.

4 Requirements of Product Assessment

4.1 Basic Requirements Green requirements that production enterprises shall satisfy include, but shall not be limited to: ---Production enterprises’ pollutant discharge condition: production enterprises shall be requested to comply with relevant laws and regulations on environmental protection; reach the requirements of national or local pollutant discharge standards (GB 8978 and GB 16297). There shall be no major safety accidents and major environmental pollutant incidents in the past three years; ---Production enterprises’ total pollutant control: production enterprises shall be requested to reach the national and local total pollutant discharge control indicators; ---Production enterprises’ management: production enterprises shall be requested to respectively establish and operate environmental management system, analysis equipment may also adopt other equipment other than what is stipulated in HJ/T 400-2007. However, it shall be guaranteed that quantitative relative standard deviation (RSD) within the dynamic range is not more than 10%, and the quantitative repeatability relative standard deviation (RSD) in 5 successive sample injection is not more than 10%. A.3 Sample Sample dimension shall be: 100 mm  100 mm  2 mm. A.4 Handling of Sample Bag Firstly, seal up the sample bag, then, pump out air in the sample bag. Then, fill in the sample bag with pure nitrogen (purity: above 99.99%), which occupies around 50% of its volume. In 60 °C incubator, place it for 2 h. Then, use a vacuum pump to promptly pump out air in the sample bag. A.5 Sealing and Packaging of Sample Sealing and packaging of sample shall comply with the following steps: a) Measure and record the dimensions of sample (mm); b) Inject sample into the sample bag, which is already processed in accordance with the requirements in A.4, then, seal it up; c) Fill in the sample bag with pure nitrogen, which occupies around 30% of the volume of the sample bag, then, use a pump to pump out the air; d) In accordance with c), conduct repeated operation twice, then, at 25 °C, fill in pure nitrogen, which is around 50% of the volume of the sample bag. A.6 Gas Trapping Before conducting gas trapping, place the sample, which is sealed and packed in A.5, into 60 °C incubator for 2 h. Maintain the sample at 60 °C for 2 h, then, in accordance with the tubing demonstrated in Figure A.1 and the following steps, conduct the sampling: a) Lightly rub the sample bag, which is loaded with components, so that the gas inside the bag can be homogenized. Slightly open the valve to squeeze out residual gas in the tube; b) On Conduit 1, install TENAX tube; on Conduit 2, install DNPH tube; c) Open the valve on Conduit 1 and Conduit 2, then, start the sampling; d) After the sampling of TENAX tube on Conduit 1 is completed, close the valve If the analysis cannot be conducted immediately, use aluminum foil to properly pack the trapping tube, then, store it in a cool and dark place (below 10 °C); the storage period shall be 7 d at the maximum. Under the above-mentioned conditions, use DNPH trapping tube to conduct the sampling once. If the analysis cannot be conducted immediately, use aluminum foil to properly pack the trapping tube, then, store it in a cool and dark place (below 10 °C); the storage period shall be 7 d at the maximum. A.7 Analysis A.7.1 Analysis of benzene series Conduct the measurement in accordance with the stipulations in 5.1 in HJ/T 400-2007, namely, thermal desorption/capillary gas chromatography/mass spectrometry. Prepare 2 TENAX for measurement, one of which shall be reserved for later usage. When the first TENAX is adopted in the measurement of benzene series, if quantitative substance exceeds the linear range, highest point of standard solution may be added, or, sampling amount may be reduced, or, the split ratio may be altered for a re- measurement. Conduct parallel sampling (not less than 2 parallel samples), the relative deviation between the measured value and the average value shall not exceed 20%. A.7.2 Analysis of aldehyde ketone Conduct the measurement in accordance with the stipulations in 5.2 in HJ/T 400-2007, namely, solid phase adsorption/high performance liquid chromatography. In the analysis of each batch of samples, at least retain 2 sampling tubes (1 TENAX and 1 DNPH) to conduct gas trapping and analysis of an empty bag (does not seal or pack sample; but contains nitrogen and goes through heating treatment). This shall be considered as on-site blank test during the sampling process. Compare the zero concentration value of the analysis result and the calibration curve. If this turns out to be abnormal, then, this batch of samples shall become invalid. A.8 Data Processing and Test Report A.8.1 Data processing Volatile concentration shall be calculated in accordance with Formula (A.1): Where, C---sample volatile amount, expressed in (μg/m3); W---compound amount measured through trapping tube, expressed in (μg); ......

Source: Above contents are excerpted from the full-copy PDF -- translated/reviewed by: www.ChineseStandard.net / Wayne Zheng et al.
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