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GB 30485-2013: Standard for pollution control on co-processing of solid wastes in cement kiln
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GB 30485-2013: Standard for pollution control on co-processing of solid wastes in cement kiln

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GB NATIONAL STANDARD Standard for pollution control on co-processing of solid wastes in cement kiln Issued on. DECEMBER 27, 2013 Implemented on. MARCH 1, 2014 Issued by. Ministry of Environmental Protection State Administration for Quality Supervision and Inspection and Quarantine Ministry of Environmental Protection of the People’s Republic of China 2013 No. 80 In order to carry out Environmental Protection Law of the People's Republic of China, Law of the People's Republic of China on Prevention and Control of Atmospheric Pollution and Law of the People's Republic of China on Prevention and Control of Water Pollution, prevent and control pollution, protect environment, and protect human health, we hereby approve the 4 standards including Emission Standard of Atmospheric Pollutants for Cement Industry as the national standards for emission (control) of pollutants. They are jointly issued by the Ministry of Environmental Protection and State Administration for Quality Supervision and Inspection and Quarantine. Standard names and standard numbers are as follows. 1.Emission standard of atmospheric pollutants for cement industry (GB 4915-2013); 2.Standard for pollution control on co-processing of solid wastes in cement kiln (GB 30485-2013); 3.Emission standard of pollutants for battery industry (GB 30484-2013); 4.Emission standard of water pollutants for leather and fur making industry (GB 30486-2013). In accordance with the provisions of relevant laws, above standards are compulsory. The above standards are effective since March 1, 2014. The above standards have been published by the China Environmental Press and the standards’ contents can be searched from the website of the Ministry of Environmental Protection (bz.mep.gov.cn). Newly established enterprises shall stop to execute GB 4915‐2004 Emission Standard of Air Pollutants for Cement Industry from March 1, 2014.And existing enterprises shall stop to execute GB 4915-2004 from July 1, 2015. Hereby it is noticed. Ministry of Environmental Protection December 27, 2013

Table of Contents

Foreword... 4 1 Scope of application... 6 2 Normative references... 7 3 Terms and definitions... 8 4 Co-processing facilities... 10 5 Characteristics of kiln co-processed solid waste... 12 6 Operation technical requirements... 12 7 Pollutants emission limits... 13 8 Pollution control of cement products... 14 9 Monitoring requirements... 15 10 Implementation and monitoring... 16

Foreword

This Standard is hereby prepared to carry out Environmental Protection Law of the People's Republic of China, Law of the People's Republic of China on Prevention of Environmental Pollution Caused by Solid Waste, Law of the People's Republic of China on Prevention and Control of Atmospheric Pollution, Circular Economy Promotion Law of the People's Republic of China, Law of the People's Republic of China on Product Quality, and other laws and regulations to protect the environment, prevent and control the pollution caused during the process of co-processing solid wastes in the cement kiln, and to improve the production process and pollution control technology. This Standard specifies the technical requirements for cement kiln facilities for co-processing solid wastes, property requirements of wastes entering the kiln, technical requirements for operation, emission limits of pollutants, control requirements, monitoring, supervision and management requirements for pollutants caused by cement products manufactured. This Standard is first-time issued. Emission of water pollutants, environment noises caused during the process of co-processing solid wastes in cement kiln is subject to relevant national emission standards for pollutants. And the identification, treatment and disposal of solids wastes caused are subject to relevant national control standards for solid waste pollution. Emission limits of the pollutants specified in this Standard are the basic requirements. Local provincial governments may develop local emission standard of pollutants for pollutant items that are not covered in this Standard. It may develop local emission standard of pollutants stricter than this Standard for pollutant items that are already covered in this Standard. If the limit values approved by the environmental influence assessment are stricter than that of this Standard or local standard, the limit values approved by the environmental influence assessment shall prevail. This Standard was organized and formulated by Department of Science, Technology and Standards, Ministry of Environmental Protection of the People’s Republic of China. Drafting organizations of this Standard. Chinese Research Academy of Environmental Sciences, China Building Materials Academy, Beijing Jinyu Mangrove Environmental Protection Technology Co., Ltd., and Foreign Economic Cooperation Office, Ministry of Environmental Protection. The Standard was approved by Ministry of Environmental Protection on December 16, 2013. This Standard will be implemented on March 1, 2014. The Ministry of Environmental Protection is responsible for the interpretation of this Standard. Standard for pollution control on co-processing of solid wastes in cement kiln

1 Scope of application

This Standard specifies the technical requirements for cement kiln facilities for co-processing solid wastes, property requirements of wastes entering the kiln, technical requirements for operation, emission limit of pollutants, control requirements, monitoring, supervision and management requirements for pollutants caused by cement products manufactured. This Standard is applicable to the pollution control, supervision and management during the process of co-processing hazardous wastes, household wastes (including waste plastics, waste rubbers, waste paper, waste tire, etc.), sludge caused by urban and industrial wastewater treatment, processing waste of animals and plants, polluted soil, emergency wastes and other solid wastes using cement kiln. When using cement kiln to co-process household wastes, if the mass of household wastes added exceeds 30% of the total mass of kiln (furnace) materials, the Standard for Pollution Control on the Municipal Solid Waste Incineration shall be executed. This Standard applies to the behavior of pollutants emission allowed by law. Site selection of newly established pollution source and management of existing pollution source within the special protection zone shall be executed in accordance with relevant provisions of Law of the Peoples Republic of China on the Prevention and Control of Atmospheric Pollution, Law of the Peoples Republic of China on the Prevention and Control of Water Pollution, Marine Environment Protection Law of the Peoples Republic of China, Law of the People's Republic of China on Prevention of Environmental Pollution Caused by Solid Waste, Law of the Peoples Republic of China on Prevention and Control of Radioactive Pollution, Law of the People's Republic of China on Appraising of Environment Impacts and other laws, regulations and rules.

2 Normative references

The articles contained in the following documents have become part of this Standard when they are quoted herein. For the undated documents so quoted, the latest editions shall be applicable to this Standard. GB 4915 Emission standard of air pollutants for cement industry GB 14554 Emission standard for odor pollutants GB 18597 Standard for pollution control on hazardous waste storage GB/T 16157 The determination of particulates and sampling methods of gaseous pollutants emitted from exhaust gas of stationary source HJ 77.2 Ambient air and waste gas Determination of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) HJ 543 Stationary source emission. Determination of mercury. Cold atomic absorption spectrophotometry (Provisional) HJ 657 Ambient air and stationary source emission - Determination of metals in ambient particulate matter – Inductively coupled plasma/mass spectrometry (ICP-MS)

3 Terms and definitions

For the purpose of this Standard, the following terms and definitions apply. 3.1 Co-processing in cement kiln It refers to the harmless treatment process. Solid wastes that meet the requirements or meet the requirements after pre-treatment for entering the kiln are put into the cement kiln, so that the harmless treatment process of solid wastes is achieved while the cement clinker is being manufactured. 3.2 Solid wastes It refers to the solid, semi-solid goods and substances, and gaseous ones in containers that have lost original value in use, or have not lost original value in use but have been abandoned in production, life and other activities; as well as the goods and substance incorporated into solid waste management by provisions of laws and administrative regulations, including liquid waste (except for the wastewater discharged into water). 3.3 Hazardous wastes It refers to the solid wastes included in national catalogue of hazardous wastes; or solid wastes identified to have one or more hazardous characteristics of corrosive, toxicity, ignitability, reactivity and infectivity, etc., according to national identification standards and methods for hazardous wastes; and the solid wastes that can not be excluded from the above hazardous characteristics. 3.4 Emergency wastes It refers to the solid wastes caused by pollution accident, safety accident, major disaster, and other events; as well as the solid wastes caused during the specific project of environment protection in a centralized manner. 3.5 New dry process cement kiln It refers to the rotary cement kiln that is additionally equipped with suspension pre-heater and discomposing furnace. 4 Co‐processing facilities 4.1 Cement kiln used for co-processing solid wastes shall meet the following conditions. 4.2 The location of cement kiln used for co-processing solid wastes shall meet the following conditions. 4.3 Special solid waste storage facilities shall be provided. Hazardous waste storage facilities shall meet the requirements of GB 18597 and HJ/T 176. 4.4 Special solid waste dosing facilities shall be provided based on properties of solid wastes to be co-processed. Solid waste dosing facilities shall meet the requirements of HJ662. 4.5 Co-processing of solid wastes shall ensure that it will not cause adverse effects on the production of cement and control of pollution. 5 Characteristics of kiln co‐processed solid waste 5.1 The following solid wastes are prohibited from kiln co-processing. 5.2 Solid waste into kiln shall be of relatively stable chemical composition and physical properties. The containing and dosing quantity of the heavy metals and harmful elements such as chlorine, fluorine, and sulfur shall meet the requirements of HJ 662.

6 Operation technical requirements

6.1 In the process of operation, it shall be based on solid waste characteristics and in accordance with the requirements of HJ 662, when choosing the correct way of adding and place of adding for solid waste. 6.2 Dosing process of solid waste and cement kiln co-process shall not affect the normal production of cement. 6.4 When cement kiln is of malfunction or abnormal operating conditions by accident, such as kiln temperature obviously decreasing, the concentration of the pollutants in flue gas increasing, then it must immediately stop adding the solid waste. 6.5 When co-processing solid waste, the INCREASED concentration of total organic carbon (TOC) concentration in cement kiln and kiln-tail heat utilization system exhaust funnel shall not exceed 10 mg/m3 because of co-processing solid waste.

7 Pollutants emission limits

7.1 For co-processing of solid waste in cement kiln, emissions limits of particulate matter, sulfur dioxide, nitrogen oxide and ammonia in the cement kiln and kiln-tail heat utilization system exhaust funnel shall be in accordance with the requirements of GB 4915. 7.3 Under the condition of article 6.4 of this Standard, the monitoring data obtained is not used as monitoring data for gas emissions upper limits of this Standard. Every failure or accident discharge pollutants duration shall not be more than 4 h. And the yearly accumulative total time must not exceed 60 h. 7.4 Exhaust gas from solid waste storage and pretreatment facilities shall be imported into cement kiln temperature area for incineration; or discharged after meeting the limits specified in GB 14554 by processing. 7.6 Odorous pollutants limits of solid waste co-processing of cement production enterprise shall comply with GB 14554. 7.7 Air pollutants emissions limits of cement kiln bypass fresh air vent shall comply with articles 7.1 and 7.2 of this Standard. 7.8 For cement production enterprises of solid waste co-processing - except for cement kiln, kiln-tail heat utilization system, bypass fresh air, solid waste storage and pretreatment facilities, and exhaust funnel – the atmospheric pollutant emissions, unorganized emissions and the surrounding environment quality of other raw materials, product processing, storage, and production facilities vent air pollutants emission shall comply with GB 4915. 7.9 If kiln ash from cement kiln circulatory system and the dust collected from the bypass snort are directly added into cement clinker, the adding proportion shall be strictly controlled, so as to meet the requirements of Chapter 8 of this Standard.

8 Pollution control of cement products

8.1 Quality of cement products of solid waste co-processing cement kiln shall comply with the relevant national standards. 8.3 The cement product taking general industrial solid waste such as coal ash, slag, pyrite cinder, blast furnace slag, gangue as replaced raw materials (including mixed materials) shall refer to Article 8.2 of this Standard.

9 Monitoring requirements

9.1 Flue gas monitoring 9.1.1 The enterprise shall build enterprise monitoring system and formulate monitoring scheme to carry out its own monitoring on waste emission and its influence on surrounding environment quality. It shall maintain the original monitoring records and publish monitoring results according to relevant laws and Environment Monitoring Management Regulations. 9.1.2 New enterprises and existing enterprises shall install automatic monitoring equipment of pollutant emissions. The requirements are according to relevant laws and Source of Pollution Automatic Monitoring Regulations. 9.2 Test performance of cement kiln co-processing dangerous waste facilities 9.2.1 Cement production enterprises shall conduct performance test on cement kiln co-processing facilities according to the requirements of HJ 662, before the first time of carrying out waste co-processing. 9.2.2 It shall regularly test the performance of cement kiln co-processing dangerous waster facilities with the frequency of once every 5 years at least.

10 Implementation and monitoring

10.1 This Standard shall be supervised and executed by the people's government above the county level’s administrative department of environmental protection together with relevant departments. 10.2 In any case, the cement production enterprises co-processing solid waste shall conform to waster control requirements of this Standard. And it shall take necessary measures to ensure that pollution prevention facility operates normally. ......

Source: Above contents are excerpted from the full-copy PDF -- translated/reviewed by: www.ChineseStandard.net / Wayne Zheng et al.
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