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HJ 1186-2021 English PDF

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HJ 1186-2021: (Technical specification for pollution control of waste lithium-ion power battery treatment (for trial implementation))
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Basic data

Standard ID: HJ 1186-2021 (HJ1186-2021)
Description (Translated English): (Technical specification for pollution control of waste lithium-ion power battery treatment (for trial implementation))
Sector / Industry: Environmental Protection Industry Standard
Word Count Estimation: 10,151
Issuing agency(ies): Ministry of Ecology and Environment

HJ 1186-2021: (Technical specification for pollution control of waste lithium-ion power battery treatment (for trial implementation))


---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
(Technical specification for pollution control of waste lithium-ion power battery treatment (for trial implementation)) National Ecological Environment Standard of the People's Republic of China Pollution control of waste lithium-ion power battery disposal Technical Specifications (Trial) Technical specification of pollution control for treatment of waste power lithium-ion battery(Trial) This electronic version is the official standard text, which is reviewed and typeset by the Environmental Standards Institute of the Ministry of Ecology and Environment. Published on 2021-08-07 2022-01-01 Implementation Released by the Ministry of Ecology and Environment directory Foreword...ii 1 Scope...1 2 Normative references...1 3 Terms and Definitions...1 4 General requirements...2 5 Technical requirements for pollution control in the treatment process...3 6 Pollutant emission control and environmental monitoring requirements...3 7 Requirements for operating environment management...4 Appendix A (Informative Appendix) Monitoring Requirements for Main Pollutant Emissions During the Treatment of Waste Lithium-ion Power Batteries...6 Appendix B (informative appendix) Environmental monitoring requirements for waste lithium-ion power battery processing enterprises...7 Technical specification for pollution control of waste lithium-ion power battery disposal

1 Scope of application

This standard specifies the general requirements for the treatment of waste lithium-ion power batteries, the technical requirements for pollution control in the treatment process, and the control of pollutant emissions. and environmental monitoring requirements and operational environmental management requirements. This standard is applicable to the pollution control of waste lithium-ion power battery treatment process, and can be treated as waste lithium-ion power battery related construction Technical reference basis for project environmental impact assessment, construction and operation, environmental protection acceptance upon completion, and emission permit management. For other types of waste lithium-ion batteries such as energy storage and consumption, as well as the pollution control of the waste disposal process of lithium-ion battery production, please refer to Follow this standard. This standard does not apply to the fault detection, repair and refurbishment of lithium-ion power batteries during the warranty period.

2 Normative references

This standard refers to the following documents or clauses thereof. For dated references, only the dated version applies to this standard. For undated references, the latest edition (including all amendments) applies to this standard. GB 3095 Ambient Air Quality Standard GB 8978 Integrated Wastewater Discharge Standard GB 9078 Industrial Furnace Air Pollutant Emission Standard GB 12348 Industrial Enterprise Boundary Environmental Noise Emission Standard GB/T 14848 Groundwater Quality Standard GB 16297 Comprehensive Emission Standard of Air Pollutants GB 18484 Standard for Pollution Control of Hazardous Waste Incineration GB 18597 Hazardous Waste Storage Pollution Control Standard GB 18599 General Industrial Solid Waste Storage and Landfill Pollution Control Standard GB 31573 Inorganic Chemical Industry Pollutant Emission Standard GB 36600 Soil Environmental Quality Construction Land Soil Pollution Risk Control Standard (Trial) GB 37822 Volatile organic compound fugitive emission control standard HJ 819 General Principles of Technical Guidelines for Self-Monitoring of Pollutants

3 Terms and Definitions

The following terms and definitions apply to this standard. 3.1 power lithium-ion battery Lithium ions are used as conductive ions to move between the anode and the cathode, and charge and discharge are realized through the mutual conversion of chemical energy and electrical energy, providing new A battery that supplies energy to the energy vehicle powertrain. 3.2 battery cell The basic unit device that converts chemical energy and electrical energy into and out of, usually includes electrodes, separators, electrolytes, casings and terminals, and is Designed to be rechargeable. 3.3 battery module A combination of more than one battery cells in series, parallel or series-parallel, and used as a power source. 3.4 battery pack A unit that obtains electrical energy from the outside and can output electrical energy to the outside, usually including battery cells, battery management modules, battery boxes and corresponding Accessories (cooling components, connecting cables, etc.). 3.5 treatment Extract substances from waste lithium-ion power batteries through dismantling, roasting, crushing, sorting, leaching, purification, smelting and other processing procedures the process of. 3.6 dismantling dismantling The work of disassembling waste lithium-ion power battery packs and battery modules. 3.7 roasting The process of heating spent lithium-ion power batteries without melting them to change their chemical composition or physical properties. 3.8 material recycling The process of recovering waste electrode material powder or extracting metal materials from waste lithium-ion power batteries using a certain treatment process.

4 General requirements

4.1 The site selection of waste lithium-ion power battery treatment and construction projects should not be located in the State Council and relevant competent departments of the State Council, as well as provinces, autonomous regions, and direct Within the ecological protection red line area, permanent basic farmland and other areas that need special protection designated by the municipal people's government. 4.2 Waste lithium-ion power battery processing enterprises shall have environmental protection facilities that match the production scale. Construction and operation shall comply with the "Three Simultaneous" environmental management system. 4.3 The site of the waste lithium-ion power battery treatment enterprise shall be divided into areas by function, and the living area shall be separated from the production area. 4.4 The raw material storage area, processing operation area and product storage area of the waste lithium-ion power battery processing enterprise shall be set up in a windproof and rainproof workshop. The ground should be hardened and an anti-seepage layer should be constructed; the functional areas such as raw material storage area, processing operation area and product storage area should have clear boundaries and standards. Wastewater collection facilities should be set up in the treatment operation area, and the ground washing wastewater should be collected and treated separately, and should not be directly discharged into the rainwater collection pipe network. 4.5 Waste lithium-ion power battery processing enterprises should give priority to adopting processes and equipment with high resource utilization and low pollutant emissions; The waste lithium-ion power battery processing enterprise of the battery cell should at least have the ability to process the waste lithium-ion power battery into waste battery electrode material powder Ability. 4.6 The exhaust gas, waste water, noise and other emissions generated in the process of waste lithium-ion power battery treatment should meet the national and local pollutant emissions Standards and pollutant discharge permit requirements; solid waste generated shall be properly stored, utilized and disposed of in accordance with relevant national environmental protection regulations and standards. 4.7 In addition to meeting the relevant requirements for environmental protection, the treatment process of waste lithium-ion power batteries should also comply with national production safety, occupational health, Relevant requirements of laws and regulations such as transportation and fire protection.

5 Technical requirements for pollution control in the treatment process

5.1 Incoming 5.1.1 The waste lithium-ion power battery should be tested before entering the factory. If it is found that there is liquid leakage, smoke, electricity leakage, damage to the casing, etc., it should be used. Store it separately in a special container and dispose of it in time to avoid the environmental risk caused by the spontaneous combustion of the waste lithium-ion power battery. 5.1.2 When storing waste lithium-ion power batteries with liquid leakage, smoke, electricity leakage, shell damage, etc., the storage warehouse or container should use micro-negative Pressure design, and equipped with corresponding waste gas collection and treatment facilities. 5.2 Disassembly 5.2.1 The disassembly process should be reasonably formulated according to the battery product information, and the battery packs and battery modules should be disassembled by category to avoid electrolytes, organic solvents, etc. The leakage of the agent will cause environmental pollution. 5.2.2 When disassembling, remove battery packs, plastic connectors in battery modules, circuit boards, high-voltage wiring harnesses and other components, and collect and store them by category. Disassemble the product. 5.2.3 Before disassembling the battery pack equipped with liquid cooling device, special equipment should be used to collect the cooling liquid; the collected waste cooling liquid should be properly stored, Use disposal. 5.2.4 When dismantling the waste lithium-ion power battery with liquid leakage, smoke, electricity leakage, shell damage, etc., it should be Regional dismantling, waste gas should be collected and led to waste gas treatment facilities. 5.2.5 When the battery is discharged by the soaking method, the soaking tank shall be equipped with a gas collecting device, and the exhaust gas shall be collected and introduced into a centralized exhaust gas treatment facility; Bubble pool waste liquid should be properly stored, utilized and disposed of. 5.3 Roasting, crushing and sorting 5.3.1 One or more processes such as roasting, crushing and sorting can be used to remove electrolytes and organic solvents in battery cells. 5.3.2 Undisassembled waste lithium-ion power battery packs and battery modules should not be directly roasted. 5.3.3 The battery cells containing electrolytes and organic solvents shall be crushed and sorted by mechanized or automated equipment under negative pressure conditions. 5.3.4 The crushing and sorting process shall separate the waste battery electrode material powder, current collector and shell in subsequent steps. 5.3.5 Roasting, crushing, sorting and other processes should prevent waste gas from escaping, and the collected waste gas should be introduced into the waste gas centralized treatment facility. 5.4 Material Recovery 5.4.1 Before adopting the pyrotechnic process for material recovery, dismantling, crushing, sorting and other processes can be selectively carried out according to material conditions and equipment requirements. The alloy material is obtained after high temperature smelting. 5.4.2 The smelting equipment of the pyrotechnic process shall prevent waste gas from escaping and be equipped with waste gas treatment facilities. 5.4.3 Before using the wet process for material recovery, one or more processes such as dismantling, roasting, crushing and sorting shall be carried out to remove waste lithium. Electrolyte and organic solvent in ion power battery to obtain waste battery electrode material powder that can enter the leaching process. 5.4.4 The vents and sampling ports of reaction vessels such as leaching, separation and purification, and compound preparation during wet process treatment shall be equipped with gas collecting devices. After the exhaust gas is collected, it should be introduced into a centralized exhaust gas treatment facility.

6 Pollutant emission control and environmental monitoring requirements

6.1 Exhaust Gas Pollution Control 6.1.1 Dismantling, crushing, and sorting processes of waste lithium-ion power batteries, as well as wet process leaching, separation, purification and compound preparation processes Sequence exhaust emissions should meet the requirements of GB 16297; fugitive emissions of volatile organic compounds should meet the requirements of GB 37822.Monitoring factor package Including sulfur dioxide, particulate matter, non-methane total hydrocarbons, fluoride, nickel and its compounds, sulfuric acid mist, hydrogen chloride, etc. 6.1.2 Exhaust emissions from the roasting process and pyrotechnic smelting process of waste lithium-ion power batteries shall meet the requirements of GB 9078, among which nickel and The emission limits of its compounds and non-methane total hydrocarbons shall comply with the provisions of GB 16297; the fugitive emission of volatile organic compounds shall meet the requirements of GB 37822 Provisions. 6.1.3 The emission limits of cobalt and its compounds in the roasting, crushing, and sorting processes of waste lithium-ion power batteries, as well as the pyrotechnic smelting process, Refer to the implementation of the provisions of GB 31573. 6.1.4 The emission limits of dioxins produced in the roasting process and pyrotechnic smelting process of waste lithium-ion power batteries shall be implemented with reference to GB 18484 Provisions. 6.1.5 In the process of waste lithium-ion power battery treatment, the waste battery electrode material powder should be piped or other anti-leakage and anti-spray measures The waste gas generated in the production workshop should be collected and introduced into the waste gas centralized treatment facility. 6.2 Wastewater Pollution Control 6.2.1 Waste lithium-ion power battery processing enterprises shall have wastewater collection and treatment facilities for the collection and treatment of production wastewater and initial rainwater Wait. 6.2.2 The pollutant discharge concentration of the waste lithium-ion power battery treatment enterprise's total waste water discharge outlet, workshop or production facility waste water discharge outlet, Execute in accordance with the requirements of GB 8978.Monitoring factors include flow, pH value, chemical oxygen demand, five-day biochemical oxygen demand, suspended solids, ammonia nitrogen, Fluoride, total copper, total manganese, total nickel, total zinc, total phosphorus, etc. 6.2.3 The discharge limit of total cobalt at the total waste water outlet of waste lithium-ion power battery treatment enterprises shall refer to the provisions of GB 31573. 6.2.4 For waste lithium-ion power battery treatment enterprises using wet process, the workshop production wastewater should be collected, treated or reused separately to achieve a The total nickel discharge concentration of such pollutants meets the requirements of GB 8978; the workshop production wastewater should not be directly mixed with other wastewater for treatment. 6.2.5 The waste water collection and transportation in the waste lithium-ion power battery treatment enterprise should be separated from rainwater and sewage, and the initial rainwater in the production area should be collected separately and process it. 6.3 Solid Waste Pollution Control 6.3.1 Waste lithium-ion power battery disposal enterprises shall set up hazardous waste storage areas and general industrial solid waste in accordance with GB 18597 and GB 18599. Waste lithium-ion power batteries and their treatment products should not be stored in the open air. 6.3.2 Waste circuit boards, waste plastics, waste metals, waste coolants, pyrotechnic residues, Solid wastes such as waste activated carbon, waste gas purification ash, production wastewater treatment sludge, etc. shall be collected, stored, utilized and disposed of by classification; they are classified as hazardous wastes. If it is necessary to entrust an external unit to use and dispose of it, it shall be handed over to an enterprise with corresponding qualifications for use and disposal. 6.3.3 The particulate matter collected by the crushing, sorting and dust removal process shall be returned to the material recovery facility to extract metal components. 6.4 Noise pollution control 6.4.1 The main equipment that produces noise, such as crushers, pumps, fans, etc., should take basic vibration reduction and noise reduction and sound insulation measures. 6.4.2 Boundary noise should meet the requirements of GB 12348.

7 Requirements for operating environment management

7.1 Operating conditions 7.1.1 There are trained technical personnel, management personnel and corresponding number of operators. 7.1.2 There are rules and regulations for pollution control of waste lithium-ion power battery disposal. 7.1.3 Have the ability to monitor the main environmental pollutants discharged. 7.2 Personnel training 7.2.1 The laws and regulations related to environmental protection for operators, technicians and managers should be carried out by waste lithium-ion power battery processing enterprises Theoretical knowledge and operational skills training such as regulations, environmental emergency handling, etc. 7.2.2 The training content should include the following aspects. - Requirements of relevant environmental protection laws and regulations; -- Environmental hazard characteristics of waste lithium-ion power batteries; --The technological process and pollution prevention and control measures of the enterprise's production; - Emission limits for environmental pollutants emitted in the production process; - Operation and maintenance requirements for pollution prevention and control facilities and equipment; -- Measures for handling environmental emergencies, etc. 7.3 Monitoring and Evaluation System Requirements 7.3.1 Enterprises dealing with waste lithium-ion power batteries shall, in accordance with relevant laws and regulations and the requirements of HJ 819, establish an enterprise monitoring system, formulate Monitoring plan, carry out self-monitoring on the discharge status of major pollutants, keep original monitoring records, and publish monitoring results; industry self-monitoring Before the management requirements are issued, see Appendix A for the monitoring requirements for the main pollutants of waste lithium-ion power battery processing enterprises, and see Appendix A for the environmental monitoring requirements. See Appendix B. 7.3.2 The pollutant discharge of waste lithium-ion power batteries shall be regularly monitored and evaluated, and improvement measures shall be taken if necessary.
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