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GB/T 42513.6-2024 English PDF

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GB/T 42513.6-2024: Methods for chemical analysis of nickel alloys - Part 6: Determination of molybdenum content - Inductively coupled plasma atomic emission spectrometric method
Status: Valid
Standard IDUSDBUY PDFLead-DaysStandard Title (Description)Status
GB/T 42513.6-2024519 Add to Cart 5 days Methods for chemical analysis of nickel alloys - Part 6: Determination of molybdenum content - Inductively coupled plasma atomic emission spectrometric method Valid

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Basic data

Standard ID: GB/T 42513.6-2024 (GB/T42513.6-2024)
Description (Translated English): Methods for chemical analysis of nickel alloys - Part 6: Determination of molybdenum content - Inductively coupled plasma atomic emission spectrometric method
Sector / Industry: National Standard (Recommended)
Classification of Chinese Standard: H13
Classification of International Standard: 77.120.40
Word Count Estimation: 26,241
Date of Issue: 2024-04-25
Date of Implementation: 2024-11-01
Issuing agency(ies): State Administration for Market Regulation, China National Standardization Administration

GB/T 42513.6-2024: Methods for chemical analysis of nickel alloys - Part 6: Determination of molybdenum content - Inductively coupled plasma atomic emission spectrometric method


---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
ICS 77:120:40 CCSH13 National Standards of People's Republic of China Chemical analysis methods for nickel alloys Part 6: Determination of molybdenum content Inductively coupled plasma atomic emission spectrometry spectrometric method, MOD) Published on April 25, 2024, implemented on November 1, 2024 State Administration for Market Regulation The National Standardization Administration issued

Foreword

This document is in accordance with the provisions of GB/T 1:1-2020 "Guidelines for standardization work Part 1: Structure and drafting rules for standardization documents" Drafting: This document is part 6 of GB/T 42513 "Chemical analysis methods for nickel alloys": GB/T 42513 has been published in the following parts: --- Part 1: Determination of chromium content by ammonium ferrous sulfate potentiometric titration method; --- Part 2: Determination of phosphorus content-Molybdenum blue spectrophotometric method; --- Part 3: Determination of aluminum content by nitrous oxide-flame atomic absorption spectrometry and inductively coupled plasma atomic emission spectrometry Spectrum; --- Part 4: Determination of silicon content by nitrous oxide-flame atomic absorption spectrometry and molybdenum blue spectrophotometry; --- Part 5: Determination of vanadium content by nitrous oxide-flame atomic absorption spectrometry and inductively coupled plasma atomic emission spectrometry Spectrum; --- Part 6: Determination of molybdenum content - Inductively coupled plasma atomic emission spectrometry; --- Part 7: Determination of cobalt, chromium, copper, iron and manganese content: Flame atomic absorption spectrometry: This document is modified to adopt ISO 11435:2011 "Nickel alloys - Determination of molybdenum content - Inductively coupled plasma atomic emission spectrometry": Compared with ISO 11435:2011, this document has many structural adjustments: The structural number changes between the two documents are shown in the table below: See Appendix A: This document has many technical differences compared to ISO 11435:2011: A single line (|) is used to indicate these technical differences: A list of these technical differences and their reasons is given in Appendix B: The following editorial changes were made to this document: --- In order to coordinate with the existing standards, the name of the standard is changed to "Chemical Analysis Methods for Nickel Alloys Part 6: Determination of Molybdenum Content Coupled Plasma Atomic Emission Spectrometry"; --- Added Appendix F (informative) "Original data of method 1 verification test"; --- Added Appendix G (informative) "Sample information for method 2 test and raw data of precision test": Please note that some of the contents of this document may involve patents: The issuing organization of this document does not assume the responsibility for identifying patents: This document was proposed by China Nonferrous Metals Industry Association: This document is under the jurisdiction of the National Technical Committee on Standardization of Nonferrous Metals (SAC/TC243): This document was drafted by: Guangxi Zhuang Autonomous Region Metallurgical Products Quality Inspection Station, Guangxi Zhuang Autonomous Region Analysis and Testing Research Center, Guangxi Zhuang Autonomous Region Food and Drug Inspection Institute, Guilin University of Technology, Shenzhen Zhongjin Lingnan Nonferrous Metals Co:, Ltd:, China Certification and Inspection Group Guangxi Co:, Ltd:, Shanxi Taigang Stainless Steel Co:, Ltd:, Jiuquan Iron and Steel (Group) Co:, Ltd:, Zhejiang Huayou Cobalt Co:, Ltd: Co:, Ltd:, Zijin Mining Group Co:, Ltd:, and Shenzhen Wanze Central South Research Institute Co:, Ltd: The main drafters of this document are: Zhang Tao, Wei Li, Huang Yifan, Luo Yi, Huang Jining, Huang Zhaomin, Chen Guiluan, Zhu Xueyan, Lin Yuting, Lu Zhongxin, Zhang Ruilin, Wei Jing, Xia Xiujuan, Zhou Liang, Chen Fang, Hu Yongmei, Wu Zishun, Huang Wenhe, Huang Yizhong, Huang Junyi, Lin Yijun, Yang Julei, Yang Caixia, Chen Zhuhai, Gao Juanya, and Li Feng:

Introduction

Nickel alloys are commonly used in instruments, electronic communications, pressure vessels, corrosion-resistant devices, aerospace and high-end special-purpose It is one of the important metal raw materials for industrial development: International standards for chemical analysis methods of nickel alloys have been published for dozens of years: In:2008, with the progress of my country's industry, the demand for the production and import and export of high-end nickel alloy materials increased: To this end, the international standards were converted into national standards: GB/T 42513 "Chemical Analysis Methods for Nickel Alloys" is a standard for the development and upgrading of the non-ferrous industry and the development of the domestic manufacturing industry: In establishing a complete and feasible set of standard methods for testing chromium, phosphorus, niobium, molybdenum, aluminum, vanadium, silicon, cobalt, copper and other elements in nickel alloys, the conversion The following international standards: ---ISO 7592:2017 Nickel alloys - Determination of chromium content - Ammonium ferrous sulfate potentiometric titration method; ---ISO 9388:1992 Nickel alloys - Determination of phosphorus content - Molybdenum blue spectrophotometric method; ---ISO 7530-7:1992 Nickel alloys - Flame atomic absorption spectrometric analysis - Part 7: Determination of aluminium content; ---ISO 7530-8:1992 Nickel alloys - Flame atomic absorption spectrometric analysis - Part 8: Determination of silicon content; ---ISO 7530-9:1993 Nickel alloys - Flame atomic absorption spectrometric analysis - Part 9: Determination of vanadium content; ---ISO 11435:2011 Nickel alloys - Determination of molybdenum content - Inductively coupled plasma atomic emission spectrometry; ---ISO 7530-1:2015 Nickel alloys - Flame atomic absorption spectrometric analysis - Part 1: Determination of cobalt, chromium, copper, iron and manganese contents; ---ISO 22033:2011 Nickel alloys - Determination of niobium content - Inductively coupled plasma atomic emission spectrometry; ---ISO 11436:1993 Nickel and nickel alloys - Determination of total boron content - Curcumin spectrophotometric method; ---ISO 23166:2018 Nickel alloys - Determination of tantalum content - Inductively coupled plasma atomic emission spectrometry: GB/T 42513 is proposed to consist of 13 parts: --- Part 1: Determination of chromium content by ammonium ferrous sulfate potentiometric titration method; --- Part 2: Determination of phosphorus content-Molybdenum blue spectrophotometric method; --- Part 3: Determination of aluminum content by nitrous oxide-flame atomic absorption spectrometry and inductively coupled plasma atomic emission spectrometry Spectrum; --- Part 4: Determination of silicon content by nitrous oxide-flame atomic absorption spectrometry and molybdenum blue spectrophotometry; --- Part 5: Determination of vanadium content by nitrous oxide-flame atomic absorption spectrometry and inductively coupled plasma atomic emission spectrometry Spectrum; --- Part 6: Determination of molybdenum content - Inductively coupled plasma atomic emission spectrometry; --- Part 7: Determination of cobalt, chromium, copper, iron and manganese content by flame atomic absorption spectrometry; --- Part 8: Determination of niobium content by inductively coupled plasma atomic emission spectrometry; --- Part 9: Determination of total boron content Curcumin spectrophotometric method; --- Part 10: Determination of trace element content by glow discharge mass spectrometry; --- Part 11: Determination of silicon, manganese, phosphorus, chromium, nickel, copper, molybdenum, cobalt, iron, aluminum, vanadium, titanium, tungsten and niobium contents by X-ray fluorescence Spectrum; --- Part 12: Determination of tantalum content by inductively coupled plasma atomic emission spectrometry; --- Part 13: Determination of oxygen, nitrogen and hydrogen content - Inert gas fusion - thermal conductivity method/infrared absorption method: Molybdenum is an important alloying element in nickel alloys: The content of molybdenum can significantly affect the performance and life of nickel alloys: GB/T 42513:6 will promote the progress of nickel alloy testing technology in my country and ensure that the industry Industry personnel have standards to follow during production, application, scientific research and testing: Chemical analysis methods for nickel alloys Part 6: Determination of molybdenum content Inductively coupled plasma atomic emission spectrometry Warning---People who use this document need to have practical experience in formal laboratory work: This document does not address all possible safety issues: The user is responsible for taking appropriate safety and health measures and ensuring that the conditions stipulated by relevant national laws and regulations are met:

1 Scope

This document describes a method for the determination of molybdenum in nickel alloys using inductively coupled plasma atomic emission spectrometry: This document is applicable to the determination of molybdenum content in nickel alloys: Method 1 determines the content of 0:05%~20%, and method 2 determines the content of 0:05%~30:00%:

2 Normative references

The contents of the following documents constitute the essential clauses of this document through normative references in this document: For referenced documents without a date, only the version corresponding to that date applies to this document; for referenced documents without a date, the latest version (including all amendments) applies to This document: GB/T 6682 Specifications and test methods for laboratory water (GB/T 6682-2008, ISO 3696:1987, MOD) GB/T 12806 Laboratory glassware - Single-line volumetric flasks (GB/T 12806-2011, ISO 1042:1998, NEQ) GB/T 12808 Laboratory glassware single-line pipettes

3 Terms and definitions

There are no terms or definitions that require definition in this document: 4 Method 1 4:1 Principle Dissolve the sample with hydrochloric acid, nitric acid and phosphoric acid, add perchloric acid and phosphoric acid, and heat until smoke appears: Add hydrofluoric acid and internal standard element (if necessary): The emission intensity of molybdenum was measured directly or by internal standard method on an inductively coupled plasma atomic emission spectrometer: Examples of molybdenum element analysis lines are shown in Table 1: Table 1 Analysis lines and interference element examples element Analysis Line nm Interference elements 202:03 Thallium (Ta) 281:61 Aluminum (Al), Hafnium (Hf)
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