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GB/T 4103.4-2012 English PDF

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GB/T 4103.4-2012: Methods for chemical analysis of lead and lead alloys -- Part 4: Determination of iron content
Status: Valid

GB/T 4103.4: Historical versions

Standard IDUSDBUY PDFLead-DaysStandard Title (Description)Status
GB/T 4103.4-2012189 Add to Cart 3 days Methods for chemical analysis of lead and lead alloys -- Part 4: Determination of iron content Valid
GB/T 4103.4-2000199 Add to Cart 2 days Methods for chemical analysis of lead and lead alloys Determination of iron content Obsolete
GB/T 4103.4-1983RFQ ASK 3 days Methods for chemical analysis of lead-base alloys--The bromate volumetric method for the determination of antimony content Obsolete

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GB/T 3884.2   GB/T 3884.1   GB/T 4103.14   GB/T 4103.1   GB/T 4103.12   GB/T 4103.11   

Basic data

Standard ID: GB/T 4103.4-2012 (GB/T4103.4-2012)
Description (Translated English): Methods for chemical analysis of lead and lead alloys -- Part 4: Determination of iron content
Sector / Industry: National Standard (Recommended)
Classification of Chinese Standard: H13
Classification of International Standard: 77.120.60
Word Count Estimation: 8,850
Older Standard (superseded by this standard): GB/T 4103.4-2000
Quoted Standard: GB/T 6682; GB/T 12806; GB/T 12808; GB/T 12809; GB/T 12810
Regulation (derived from): National Standards Bulletin No. 41 of 2012
Issuing agency(ies): General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China
Summary: This standard specifies the lead and lead alloys Determination of iron content. This section applies to lead and lead alloys Determination of iron content.

GB/T 4103.4-2012: Methods for chemical analysis of lead and lead alloys -- Part 4: Determination of iron content


---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
ICS77.120.60 H13 National Standards of People's Republic of China Replacing GB/T 4103.4-2000 Lead and lead alloys - Analysis Part 4. Determination of iron content Part 4. Determinationofironcontent Issued on. 2013-10-01 2012-12-31 implementation Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China Standardization Administration of China released

Foreword

GB/T 4103 "Methods for chemical analysis of lead and lead alloys" is divided into 16 parts. --- Part 1. Determination of tin content; --- Part 2. Determination of antimony content; --- Part 3. Determination of copper content; --- Part 4. Determination of iron content; --- Part 5. Determination of bismuth content; --- Part 6. Determination of arsenic content; --- Part 7. Determination of the amount of selenium; --- Part 8. Determination of tellurium content; --- Part 9. Determination of calcium; --- Part 10. Determination of the amount of silver; --- Part 11. Determination of zinc content; --- Part 12. Determination of thallium content; --- Part 13. Determination of aluminum content; --- Part 14. Determination of cadmium content by flame atomic absorption spectrometry; --- Part 15. Determination of nickel content by flame atomic absorption spectrometry; --- Part 16. copper, silver, bismuth, arsenic, antimony, tin, zinc contents Optical emission spectroscopy. This is Part 4 GB/T 4103's. This Part replaces GB/T 4103.4-2000 "of lead and lead alloys - Determination of iron content", and GB/T 4103.4- Compared to 2000, the main changes are as follows. --- Determination of change. the abolition of 1,10 phenanthroline spectrophotometry using flame atomic absorption spectrometry; --- Measuring range. 0.0003% - extended from 0.012 to 0.0002% to 0.050%; --- Supplementary dissolution and method of processing a large number of antimony, tin-lead alloy sample of; --- Supplementary terms of precision. The non-ferrous metal part by the National Standardization Technical Committee (SAC/TC243) centralized. This section is responsible for drafting unit. Zhuzhou Smelter Group Co., Ltd., Beijing Mining Research Institute, Shaanxi Dongling Smelting Co., Ltd., White Silver colored copper Northwest Limited. This section was drafted by. People's Republic of China Liaoning Province Exit Inspection and Quarantine, Beijing Mining Research Institute, Zhuzhou Smelter Group Co., Ltd., MCC Huludao Nonferrous Metals Group Co., Ltd., Hubei Jinyang Metallurgical Company. The main drafters of this section. Li Yan, Dong Xiuwen, Zhang Ning, Feng advanced, Jiang Tao demand, Zhou Yi, Zhang Ying, Ye wear red, Jiang Li, Li Zunyi, often just silver. This part replaces the previous version of the standard distribution as follows. --- GB/T 4103.4-2000; --- GB/T 472.8-1984; --- GB/T 4103.6-1983. Lead and lead alloys - Analysis Part 4. Determination of iron content

1 Scope

This section GB/T 4013 provisions of the determination of lead and lead alloys in iron content. This section applies to the determination of lead and lead alloy iron content.

2 Normative references

The following documents for the application of this document is essential. For dated references, only the dated edition applies to this article Member. For undated references, the latest edition (including any amendments) applies to this document. GB/T 6682 analytical laboratory use specifications and test methods (ISO 3696) GB/T 12806 laboratory glassware single marking flask (ISO 1042) GB/T 12808 laboratory glassware single marking pipette (ISO 648) GB/T 12809 Laboratory glassware Glass Container design and construction principles (ISO 384) GB/T 12810 laboratory glassware gauge capacity calibration and use (ISO 4787)

3 General

3.1 Unless otherwise stated, the use of superior grade pure reagents identified only in the analysis; the water is distilled or deionized water or equivalent purity, Shall comply with the provisions of GB/T 6682's. 3.2 instruments shall be within the test cycle, the performance indicators should meet the technical parameters required for verification; glass containers GB/T 12808, GB/T 12809, GB/T 12806 specified in Class A, with reference to the specific use requirements GB/T 12810 in.

4 Flame Atomic Absorption Spectrometry

4.1 Determination of Range Determination of iron content in the range of 0.0002% to 0.050% (mass fraction). 4.2 Principle Sample dissolved in nitric acid (wFe < 0.001%, lead to form lead sulfate precipitation and separation of iron) in acid medium, with air - acetylene fire Flame atomic absorption spectrometer measured at a wavelength of 248.3nm iron absorbance when the sample contains a large amount of tin, antimony, plus Na2EDTA, lemon Lemon and ammonium tartrate solubilization and prevent hydrolysis. 4.3 Reagents 4.3.1 tartaric acid. 4.3.2 citric acid. 4.3.3 nitrate (ρ1.42g/mL).
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