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GB/T 36421-2018 English PDF

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GB/T 36421-2018: Restricted substances concerning printing inks for packaging materials
Status: Valid

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GB/T 36421-2018	919	Add to Cart	6 days	Restricted substances concerning printing inks for packaging materials	Valid

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Basic data

Standard ID: GB/T 36421-2018 (GB/T36421-2018)
Description (Translated English): Restricted substances concerning printing inks for packaging materials
Sector / Industry: National Standard (Recommended)
Classification of Chinese Standard: Y44
Classification of International Standard: 87.080
Word Count Estimation: 46,428
Date of Issue: 2018-06-07
Date of Implementation: 2019-01-01
Issuing agency(ies): State Administration for Market Regulation, China National Standardization Administration

GB/T 36421-2018: Restricted substances concerning printing inks for packaging materials

---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Restricted substances concerning printing inks for packaging materials ICS 87.080 Y44 National Standards of People's Republic of China Packaging materials use ink to limit the use of substances Published on.2018-06-07 2019-01-01 implementation State market supervision and administration China National Standardization Administration issued

Foreword

This standard was drafted in accordance with the rules given in GB/T 1.1-2009. Please note that some of the contents of this document may involve patents. The issuing organization of this document is not responsible for identifying these patents. This standard was proposed by the China National Light Industry Council. This standard is under the jurisdiction of the National Ink Standardization Technical Committee (SAC/TC127). This standard was drafted. Shanghai Peony Ink Co., Ltd., Bauhinia Ink (Zhejiang) Co., Ltd., Changshu Guohe New Materials Co., Ltd. Chengdu Tuozhan New Materials Co., Ltd., Hanghua Ink Co., Ltd., Zhejiang Yongzai Ink Co., Ltd., Guangdong Tianlong Ink Group Co., Ltd., Suzhou Coswood Ink Co., Ltd., Foshan Huihong Plastic Mould Co., Ltd., Beijing Technology and Business University. The main drafters of this standard. Chen Aijun, Wu Shaoqi, Li Guangming, Wang Qiang, Liu Guowen, Gong Zhangshui, Wu Min, Wang Datian, Xiao Xuejun, Peng Kaizhen, Xin Xiulan.

Introduction

In order to minimize the safety and environmental problems of inks for packaging materials in recent years, and the development of the packaging and printing industry, the ecological environment will be brought The adverse effects of combing the raw materials used in ink production, and it is not allowed to use some raw materials that are not suitable as packaging materials. Chemical substances make the packaging materials more safe and environmentally friendly. The substances listed in this standard that are not suitable as raw materials for packaging materials are highly toxic or allergenic, carcinogenic, mutagenic, and Distortion characteristics, persistent environmental pollution, serious harm to human safety, health and the environment. This standard encourages the manufacture and use of safer and more environmentally friendly The packaging materials use ink to ensure the printing safety of packaging materials. Packaging materials use ink to limit the use of substances

1 Scope

This standard specifies the management requirements and types of materials used for packaging materials. This standard applies to the production, sale and use of packaging printing inks. Other inks for non-packaging materials can also be referred to. 2 Terms and definitions, abbreviations 2.1 Terms and definitions The following terms and definitions apply to this document. 2.1.1 Printing ink printingink Ink A dispersion system composed of a colorant, a binder, an auxiliary agent, and the like, which is transferred to a colored substance on a substrate during printing. [GB/T 15962-2018, definition 2.1] 2.1.2 Restricted use of restrictedsubstances Substances used in the formulation of the ink are not permitted. 2.1.3 Packaging package Containers, materials and auxiliary materials used to protect products, facilitate transportation, and promote consumption in accordance with certain technical methods. General name. Note. Rewrite GB/T 4122.1-2008, definition 2.1. 2.1.4 Packaging container packagingcontainers A general term for a package or package used for storage, transportation, or sale, referred to as a container. Examples. boxes, boxes, buckets, cans, bottles, bags, baskets, and the like. 2.1.5 Packaging materials A general term for the materials used to make packaging containers (2.1.4) and the packaging that makes up the product. Examples. paper or cardboard, metal, plastic, glass, ceramic, wood, etc. Note. Rewrite GB/T 4122.1-2008, definition 5.1. 2.1.6 Package printing packageprinting The graphic information is printed on the packaging material (2.1.5) or the packaging container (2.1.4) for the surface decoration and/or molding process. Note. Rewrite GB/T 4122.1-2008, definition 7.2. 2.1.7 Good practice specification goodmanufacturingpractice; GMP An operation specification that guarantees the quality and safety of products in the production process involving people, raw materials, equipment, and processes. 2.2 Abbreviations The following abbreviations are used in this document. CAS. Chemical Abstracts Registration Number (chemicalabstractservice)

3 Management requirements

3.1 Restricted substances that seriously endanger human safety, health and the environment should not be used as raw materials for packaging materials. Packaging material See Appendix A for restrictions on the use of inks in the production, sale and use. 3.2 Ink for packaging materials should be used in daily production management with good operating practices and effective measures to reduce restrictions on use as impurities. Substance to prevent the incorporation of substances or contamination. Note. Due to the purity of industrial raw materials, there may be unintended use of restricted substances as impurities. 3.3 Ink raw material manufacturers (or distributors), ink manufacturers and printing companies should ensure the timely delivery of information, packaging materials Impurities carried by raw materials such as resins, pigments and functional additives used in ink production may be restricted substances in Table A.1. because However, if a material is expected to be used as a raw material for the production of packaging materials, whether the material exists in the design, production and packaging transportation. Table A.1 information on restricted substances should be notified and explained to the ink manufacturer. 3.4 Ink and its raw materials for packaging materials, the control of harmful substances shall meet the following requirements. --- Restrict the use of POPs, persist in the environment, have a long half-life, and can pass the bio-chain (food Network) organic chemicals that accumulate damage (adverse effects) to the environment and human health; --- Limit the use of harmful substances such as carcinogenicity, teratogenicity, and mutagenicity. 3.5 The date of production, production status and relevant records of raw materials used for packaging materials shall be kept for 3 years, and the storage period of product samples shall be kept. Should not be shorter than the shelf life of the product. 3.6 In order to avoid possible contact between the ink printed layer and the contents of the package, there should be a corresponding barrier function between the two, which should not be in the package. The contents have any effect.

Appendix A

(normative appendix) Limit the type of substance used The chemical substances listed in Table A.1 are ink-restricted substances for packaging materials. The substances in Table A.1 are subject to the CAS number for the CAS number and the chemical substance name for the absence of the CAS number. Table A.1 Packaging materials use ink to limit the use of substances Serial number chemical substance name or category alias, example substance, other CAS number 1 Polychlorinated biphenyl PCB 1336-36-3 2 Polychlorinated naphthalenes (three or more substances containing chlorine) Octachlorinated 2234-13-1 Tetrachlorinated naphthalene 1335-88-2 Trichlorinated naphthalene 1321-65-9 Hexachloronaphthalene 1335-87-1 Heptachlorinated naphthalene 32241-08-0 Pentachlorinated 1321-64-8 3 Hexachlorobenzene HCB 118-74-1 1,2,3,4,10,10-hexachloro-1,4,4a,5,8,8a- Hexahydro-1,4.5,8-bridge, hanging-dimethylnaphthalene Hexachloro-hexahydro-dimethylnaphthalene; aldrin 309-00-2 (1R, 4S, 4aS, 5R, 6R, 7S, 8S, 8aR)-1, 2, 3, 4,10,10-hexachloro-1,4,4a,5,6,7,8,8a-octahydro-6, 7-epoxy-1,4,5,8-dimethylene naphthalene Dield agent 60-57-1 (1R, 4S, 5R, 8S)-1,2,3,4,10,10-hexachloro-1,4, 4a,5,6,7,8,8a-octahydro-6,7-epoxy-1,4;5,8-two Methylene naphthalene Endrin 72-20-8 7 1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane DDT (DDT) 50-29-3 1,2,4,5,6,7,8,8-octachloro-2,3,3a,4,7,7a-six Hydrogen-4,7-anthracene; 1,4,5,6,7,8,8-heptachloro-4,7-Asia Mixture of methyl bridge-3a, 4,7,7a-tetrahydroanthracene and its analogues Compound Chlordane, cesium chloride 57-74-9 Heptachloride antimony 76-44-8 Cis-chlordane 5103-71-9 Trans-chlordane 5103-74-2 Trans-Nine chloride 39965-80-5 N,N'-bis(tolyl)-p-phenylenediamine; N-tolyl- N'-xylyl-p-phenylenediamine; N,N'-bis(xylene P-phenylenediamine 620-91-7 10 2,4,6-tri-tert-butylphenol 732-26-3 11 polychlorinated toxaphene; octadecene 8001-35-5 12 dodecachloropentacyclohexane mirex 2385-85-5 13 2,2,2-trichloro-1,1-bis(4-chlorophenyl)ethanol dicofol 115-32-2 14 hexachloro-1,3-butadiene perchlorobutadiene 87-68-3 Table A.1 (continued) Serial number chemical substance name or category alias, example substance, other CAS number 2-(2H)-benzotriazol-2-yl)-4,6-bis(tert-butyl) phenol 2-(2'-hydroxy-3',5'-di-tert-butylphenyl)-benzo Triazole UV absorber UV-320 3846-71-7 16 PFOS and its salt perfluorooctane sulfonate (PFOS) 1763-23-1 17 perfluorooctane sulfonyl fluoride PFOSF 307-35-7 18 pentachlorobenzene 608-93-5 19 α-HCH 319-84-6 20 β-HCH 319-85-7 21 γ-HCH lindane 58-89-9 22 Chlordecone Decachloro octahydro-methylene-cyclobutan[CD]pentene-2- Ketone 143-50-0 23 tetrabromodiphenyl ether 40088-47-9 24 pentabromodiphenyl ether 32534-81-9 25 hexabromodiphenyl ether 36383-60-0 26 heptabromodiphenyl ether 68928-80-3 (1,4,5,6,7,7-hexachloro-8,9,10-three norborn-5-ene- 2,3-subunit bismethylene)sulfite Endosulfan; 1,2,3,4,7,7-hexachlorobicyclo[2,2,1]heptene- (2)-bishydroxymethyl-5,6-sulfite 115-29-7 --endosulfan 959-98-8 --endosulfan 33213-65-9 28 Hexabromocyclododecane (HBCCD) 25637-99-4 4736-49-6 65701-47-5 138257-17-7 138257-18-8 138527-19-9 169102-57-2 678970-15-5 678970-16-6 678970-17-7 1,2,5,6,9,10-hexabromocyclododecane 3194-55-6 --HBCD 134237-50-6 --HBCD 134237-51-7 γ-HBCD 134237-52-8 29 trichloroethylene 79-01-6 30 tetrachloroethylene perchloroethylene 127-18-4 Table A.1 (continued) Serial number chemical substance name or category alias, example substance, other CAS number 31 carbon tetrachloride tetrachloromethane 56-23-5 32 triphenyltin N,N-dimethyldithiocarbamic acid 1803-12-9 33 triphenyltin fluoride 379-52-2 34 triphenyltin acetate triphenyltin acetate 900-95-8 35 triphenyltin chloride triphenyltin chloride 639-58-7 36 triphenyltin hydroxide hydroxide triphenyltin 76-87-9 Triphenyltin fatty acid (the fatty acid has a carbon number of 9, 10, 11) Triphenyl 2,2,4,4-tetramethylpentanoate 18380-71-7 Triphenyl 2-isopropyl-2.3-dimethylbutyrate tin 18380-72-8 Triphenyl phthalate 47672-31-1 Tin triphenylphosphonate 94850-90-5 38 triphenyltin chloroacetate chloroacetyl triphenyltin 7094-94-2 39 bis(tributyltin) fumaric acid Bis(tri-n-butyltin) fumaric acid 6454-35-9 Bis(tri-n-butyltin) 2-butenedioic acid 24291-45-0 40 bis(tributyltin)-2,3-dibromosuccinic acid bis(tributyltin)-2,3-dibromosuccinic acid 31732-71-5 41 Tributyltin acetate tributyltin acetate 56-36-0 42 Tributyltin lauric acid lauric acid butyltin 3090-36-6 43 bis(tributyltin)phthalic acid 4782-29-0 Acrylate-methyl methacrylate-tributyltin methyl propyl Acrylic acid copolymer (the alkyl group of the acrylate has 8 carbon atoms) N-octyl acrylate-methyl methacrylate-tributyltin Acrylic acid copolymer 67772-01-4 45 Tributyltin sulfonate 6517-25-5 46 bis(tributyltin) maleate 14275-57-1 Tributyltin 1,2,3,4,4a,4b,5,6,10,10a-decahydro- 7-isopropyl-1,4a-dimethyl-1-phenanthrenecarboxylic acid and the like mixture Tributyltin rosin 26239-64-5 48 yellow phosphorus tetraphosphorus; white phosphorus 12185-10-3 49 benzidine and its salts Benzidine 92-87-5 Benzidine acetate 36341-27-2 Benzidine sulfate 21136-70-9 Benzidine dihydrochloride 531-85-1 Biphenyl sulfonate 531-86-2 50 4-aminobiphenyl and its salt 4-aminobiphenyl 92-67-1 51 4-nitrobiphenyl and its salt 4-nitrobiphenyl 92-93-3 52 dichloromethyl ether 542-88-1 Table A.1 (continued) Serial number chemical substance name or category alias, example substance, other CAS number Naphthylamine salt 553-00-4 2-naphthylamine hydrochloride 612-52-2 --naphthylamine and its salt β-naphthylamine, 2-naphthylamine 91-59-8 54 Rubber glue containing benzene (more than 5%) - 55 dichlorobenzidine and its salts Dichlorobenzidine 1331-47-1 2,2'-dichlorobenzidine 84-68-4 3,3'-dichlorobenzidine 91-94-1 3,3'-dichlorobenzidine dihydrochloride 612-83-9 56 α-naphthylamine and its salt α-naphthylamine 134-32-7 57 o-toluidine and its salt o-toluidine 119-93-7 58 anisidine and its salt anisidine 119-90-4 59 铍 and its compounds Barium chloride 7787-47-5 Alkaline strontium carbonate 13106-47-3 Zinc silicate 铍39413-47-3 Barium silicate 15191-85-2 Yttrium silicate 25638-88-4 Barium aluminum silicate 1302-52-9 Yttrium oxide 1304-56-9 Lanthanum nitrate 13597-99-4 Barium hydroxide 13327-32-7 Bismuth difluoride 7787-49-7 铍7440-41-7 Barium acetate 543-81-7 Fluoride oxyfluoride 63990-88-5 Barium sulfate 13510-49-1 Barium sulfate tetrahydrate 7787-56-6 Hydroquinone phosphate 13598-15-7 60 benzyl trichloride α,α,α-trichlorotoluene 98-07-7 61 Indium Compounds - 62 ethylbenzene 100-41-4 63 aziridine ethylene imine; hypoethylene imine 151-156-4 64 ethylene oxide ethylene oxide 75-21-8 65 vinyl chloride (monomer) 75-01-4 66 gold amine bis(dimethylaminophenyl)-methylimine hydrochloride; alkaline 槐 yellow 492-80-8 Table A.1 (continued) Serial number chemical substance name or category alias, example substance, other CAS number 67 Chromic acid and its salts Calcium Chromate (1.1) 13765-19-0 Zinc chromate (1.1) 13530-65-9 Copper chromate (1.1) 13548-42-0 Barium chromate (1.1) 10294-40-3 CI Pigment Red 104; molybdate chrome red; molybdenum chrome orange; molybdenum orange; molybdenum red 12656-85-8 Chromic acid 7738-94-5 Sodium chromate 7775-11-3 Potassium chromate 7789-00-6 Ammonium dichromate 7789-09-5 Chromium trioxide 1333-82-0 Sodium dichromate dihydrate 7789-12-0 Lead chromate 7758-97-6 Pigment Yellow 34 1344-37-2 Basic lead chromate 18454-12-1 Dichromic 13530-68-2 Potassium dichromate (1.2) 7778-50-9 Zinc chromate containing zinc potassium chromate - Sodium dichromate 10588-01-9 68 chloroform chloroform 67-66-3 69 chloromethyl methyl ether methyl oxychloromethane 107-30-2 70 cobalt and its inorganic compound cobalt sulfate (1.1) 10124-43-3 71 coal tar 8007-45-2 72 propylene oxide methyl oxirane 75-56-9 73 二英123-91-1 74 1,2-dichloroethane 107-06-2 75 3,3'-Dichloro-4,4'-diaminodiphenylmethane 4,4'-methylenebis(2-chloroaniline) 101-14-4 76 dichloromethane 75-09-2 77 2,2-dichlorovinyl dimethyl phosphate dichlorvos 62-73-7 78 1,1-dimethylhydrazine 57-14-7 79 styrene 100-42-5 80 1,1,2,2-tetrachloroethane 79-34-5 81 nickel carbonyl nickel tetrahydride 13463-39-3 82-p-dimethylaminoazobenzene solvent yellow 2 60-11-7 83 β-propiolactone oxycyclobutanone 57-57-8 Table A.1 (continued) Serial number chemical substance name or category alias, example substance, other CAS number 84 benzene 71-43-2 85 Formaldehyde 50-00-0 86 Basic Fuchsine Alkaline Violet 14 632-99-5 87 1,2-dichloroethylene 156-59-2 88 carbon disulfide 75-15-0 89 lead oxide Lead dan (Pb3O4); lead tetraoxide 1314-41-6 Lead Oxide (PbO) 1317-36-8 Lead dioxide (PbO2) 1309-60-0 90 lead hydroxide 39345-91-0 91 lead chloride lead chloride II 7758-95-4 92 lead carbonate Lead carbonate (1.1) 598-63-0 Lead white; alkaline lead carbonate 1319-46-6 Basic lead carbonate 1344-36-1 93 lead silicate 11120-22-2 10099-76-0 94 lead sulfate Lead sulfate 7446-14-2 Basic lead sulfate 12036-76-9 95 lead titanate 12060-00-3 96 lead borate lead borate (II) · monohydrate 10214-39-8 97 lead nitrate 10099-74-8 98 lead acetate Lead sugar; lead acetate test paper 301-04-2 Alkaline lead acetate 1335-32-6 Lead (II) acetate trihydrate 6080-56-4 Lead tetraacetate 546-67-8 99 lead stearate Lead stearate 1072-35-1 Lead stearate (mixed) 7428-48-0 100 O-ethyl-O-(p-nitrophenyl)phenylphosphonate EPN, phenylphosphonate 2104-64-5 101 octachlorotetrahydromethylene bridge benzofuran carbofuran 297-78-9 102 octamethyl pyrophosphoramide-Hilden; octa-phosphorus 152-16-9 103 arrow poison 8063-06-7 104 tetraalkyl lead Tetramethyl lead 75-74-1 Tetraethyl lead 78-00-2 105 hydrogen cyanide hydrogen cyanide 74-90-8 106 sodium cyanide 143-33-9 Table A.1 (continued) Serial number chemical substance name or category alias, example substance, other CAS number 107 O,O-Diethyl-O-(4-nitrophenyl) phosphorothioate parathion; Barlason 56-38-2 Dimethylethylthioethyl thiophosphate methyl endophos 867-27-6 O,O-dimethyl-S-[2-(ethylthio)ethyl]thiophosphorus Acid ester Internally absorbed phosphorus-S-methyl 919-86-8 O,O-dimethyl-O-[2-(ethylthio)ethyl]thiophosphate Acid ester Methyl endophos 8022-00-2 O,O-dimethyl-O-[1-methyl-2chloro-2-(diethylammonium) Carbamoyl)vinyl]phosphate 2-chloro-3-(diethylamino)-1-methyl-3-oxo-1-propene Methyl phosphate 13171-21-6 110 O,O-dimethyl-O-(4-nitrophenyl) thiophosphate methyl parathion 298-00-0 111 Mercury 7439-97-6 112 Selenium 7782-49-2 113 thiosemicarbazide N-thiosemicarbazide 79-19-6 114 tetraethyl pyrophosphate TEPP, tetraethyl pyrophosphate 107-49-3 115 nicotine 1-methyl-2-(3-pyridyl)pyrrole 51-11-5 116 Hydrogen fluoride hydrofluoric acid 7664-39-3 117 monofluoroacetic acid fluoroacetic acid 144-49-0 118 fluoroacetamide diamide 640-19-7 119 phosphorus pentasulfide pentasulfide pentasulfide 1314-80-3 120 sodium azide 26628-22-8 121 isopropyl nitrite 541-42-4 122 n-butyl nitrite n-butyl nitrite 544-16-1 123 avermectin 71751-41-2 124 3-amino-1-propenylamine 107-11-9 125 propylene alcohol 2-propen-1-ol 107-18-6 126 2,4-Dinitro-6-(1-methylpropyl)phenol alkyl ammonium 2-sec-butyl-4,6-dinitrophenol hydroxyalkyl ammonium 8048-12-2 O-ethyl-O-(2-isopropoxycarbonylphenyl)-N-isopropyl Thiophosphoramide Iso-Phosphorus 25311-71-1 128 O-ethyl-S, S-dipropyl dithiophosphate, gram-free phosphorus; chlorophosphorus 13194-48-4 N-ethyl-methyl-(2-chloro-4-methylthiobenzene)-thiophos Amide 54381-26-9 130 benzenesulfonyl chloride 98-09-9 131 phosphorus oxychloride phosphorus oxychloride 10025-87-3 132 tetramethyl orthosilicate [Si(OCH3)4] 681-84-5 133 crotonaldehyde 2-butenal 4170-30-3 Cis-2-butenal 15798-64-8 Trans-2-butenal 123-73-9 134 chloroacetaldehyde monochloroacetaldehyde 107-20-0 Table A.1 (continued) Serial number chemical substance name or category alias, example substance, other CAS number 135 methyl chloroacetate 96-34-4 136 1-chloro-2,4-dinitrobenzene 97-00-7 137 phenyl chloroformate 1885-14-9 138 3-chloro-1,2-propanediol 96-24-2 139 phosphorus pentachloride pentachloride pentachloride 10026-13-8 140 boron trichloride boron chloride 10294-34-5 141 phosphorus trichloride phosphorus chloride 7719-12-2 142 boron trifluoride boron fluoride 7637-07-2 143 phosphorus trifluoride phosphorus trifluoride 7783-55-3 144 diacetoxyallyl allyl diacetate 869-29-4 Inorganic cyanide (excluding navy, ferricyanide, ferrocyanide) salt) Cyanogen chloride 506-77-4 Mercury oxyhydride 1335-31-5 Cyanide; dicyano 460-19-5 Zinc cyanide 557-21-1 Cadmium cyanide 542-83-6 Potassium cyanide 151-50-8 Calcium cyanide 592-01-8 Silver cyanide 506-64-9 Silver potassium cyanide 506-61-6 Potassium cobalt cyanide; cobalt potassium cyanide 13963-58-1 Bromo cyanide; cyanogen b......

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Question 2: Can I share the purchased PDF of GB/T 36421-2018_English with my colleagues?

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Question 3: Does the price include tax/VAT?

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