GB 27834-2011 English PDFUS$279.00 · In stock
Delivery: <= 3 days. True-PDF full-copy in English will be manually translated and delivered via email. GB 27834-2011: Safety code for packaging of hazardous chemicals of self-reactive substances Status: Valid
Basic dataStandard ID: GB 27834-2011 (GB27834-2011)Description (Translated English): Safety code for packaging of hazardous chemicals of self-reactive substances Sector / Industry: National Standard Classification of Chinese Standard: A80 Classification of International Standard: 13.300 Word Count Estimation: 12,175 Date of Issue: 2011-12-30 Date of Implementation: 2012-08-01 Quoted Standard: GB 19432; GB 19433; GB 21178; United Nations ' Recommendations on the Transport of Dangerous Goods Model Regulations " sixteenth revised edition; United Nations ' Globally Harmonized System of Classification and Labelling " (GHS)third revised edition Regulation (derived from): Announcement of Newly Approved National Standards No. 23 of 2011 Issuing agency(ies): General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China Summary: This Chinese standard specifies the hazardous chemical classification of self-reactive substances packaging, requirements, marking and labeling. This standard applies to self-reactive substances hazardous chemicals packaging inspection. GB 27834-2011: Safety code for packaging of hazardous chemicals of self-reactive substances---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.Safety code for packaging of hazardous chemicals of self-reactive substances ICS 13.300 A80 National Standards of People's Republic of China Self-reactive substances hazardous chemicals Packaging Published 2011-12-30 2012-08-01 implementation Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China Standardization Administration of China issued ForewordThis standard Chapter 4, Chapter 5 and Chapter 6 are mandatory, the rest are recommended. This standard was drafted in accordance with rules GB/T 1.1-2009 given. This standard and the United Nations "on the Recommendations on the Transport of Dangerous Goods Model Regulations" (sixteenth revised edition) second, fourth, fifth and sixth chapters for Consistent with the technical content of 4.1 self-reactive substances packaging requirements. This standard is proposed and managed by the Dangerous Chemicals Management Standardization Technical Committee (SAC/TC251). This standard was drafted. Hunan Entry-Exit Inspection and Quarantine Technology Center, Tianjin Entry-Exit Inspection and Quarantine Bureau, Jiangnan University. The main drafters. Wang Libing, Chi Feng Jie, Zhao Lihua, Xiongzhong Jiang, Wang Hua, Zhao Haolibao. Self-reactive substances hazardous chemicals Packaging1 ScopeThis standard specifies the classification of dangerous chemicals self-reactive substances packaging requirements, tags and labels. This standard applies to self-reactive substances hazardous chemicals packaging inspection.2 Normative referencesThe following documents for the application of this document is essential. For dated references, only applies to the version dated paper Pieces. For undated references, the latest edition (including any amendments) applies to this document. GB 19432 Bulk Dangerous Goods Safety code for inspection GB 19433 Air Safety code for inspection of dangerous goods packaging GB 21178 self-reactive substances and organic peroxides categorizer UN "Recommendations on Transport of Dangerous Goods Model Regulations of" (sixteenth revised edition) The United Nations' Globally Harmonized System of Classification and Labeling "(GHS) (third revised edition)3 Terms and DefinitionsThe United Nations "on the Recommendations on the Transport of Dangerous Goods Model Regulations ·" (hereinafter referred to as "Model Regulations") and the following definition of terms and definitions Meaning applies to this document. 3.1 Self-reactive substances self-reactivesubstances Even without oxygen (air) is also prone to thermally unstable substances strongly exothermic decomposition, in the "Model Regulations" hazardous category 4.1 Self-reactive substances. The following materials should not be considered 4.1 self-reactive substances. --- according to the standard of Class 1 they are explosives; 5.1 --- The procedure of classification, which are oxidizing substances, but mixtures of oxidizing materials, such as combustible organic substances contained up To 5.0% or more, it should go through the classification procedure defined GB 21178; According to standard 5.2 --- they are organic peroxides; --- thermal decomposition of less than 300kJ/kg; --- which SADT 50kg package is larger than 75 ℃. 3.2 SADT self-acceleratingdecompositiontemperature (SADT) Packaged material self-accelerating decomposition of the lowest ambient temperature may occur. Category 4 4.1 self-reactive substances classification The degree of self-reactive substances according to their risk of A to G into seven types, see GB 21178. Since the packaging material is only suitable reaction Wherein BF for self-reactive substances. a) A self-reactive substances, any substance, such as to detonate or deflagrate rapidly transport package. Specific carried out in accordance with GB 21178 Determination, it is determined that A, shall be prohibited mounted in the container transported under the provisions of this Standard. b) B self-reactive substances, any substance having explosive properties, such as rapid deflagration neither detonates nor transport package but the The package may undergo a thermal explosion, it should be labeled "EXPLOSIVE" subsidiary risk label. Such materials in containers number The amount of up to 25kg, but in order to preclude detonation or rapid deflagration in the package and should limit the maximum amount in addition to the lower of outer. GB 21178 determines the specific basis, determined to B. c) C self-reactive substances, any substance having explosive properties, such as (up to 50kg) in a fast transport can not detonate or package Thermally speed deflagration or explosion, not "EXPLOSIVE" secondary risk label transport. GB 21178 determines the specific basis, Determined to C. d) D self-reactive substances, any substance, such as in laboratory testing. 1) partially detonation, deflagration not quickly, does not exhibit any dramatic effect when heated under confinement; or 2) does not detonate, a slow deflagration, does not exhibit any dramatic effect when heated under confinement; or 3) does not detonate or deflagrate exhibit moderate effect when heated in a closed condition; Acceptable mounted net does not exceed 50kg packages transported. GB 21178 determines the specific basis, determined as D. When e) E self-reactive substances, any substance, such as in laboratory testing, neither detonates deflagration never heated under confinement Exhibit low or no effect, not exceeding an acceptable means 400kg/450L packages transported, into specific basis GB 21178 Line determination, it is determined that E. f) F self-reactive substances, any substance, such as in laboratory testing, not only in cavitation and never detonation knocking state, closed Under conditions show weak or no effect only upon heating, weak or non-explosive and explosive, it may be considered for IBC or tank Transport of, in particular according to GB 21178 determines, determined is F; portable tank may be employed and the neutral bulk container transport. g) G self-reactive substances, any substance, such as in laboratory testing, both not detonate never empty state of knocking, the closing Show no effect when heated under a condition, and no explosive power, should be exempted from 4.1 classified as self-reactive substance, but the formulation should Is thermally stable (self accelerating decomposition temperature 50kg package 60 ℃ ~ 75 ℃), any diluent should follow the "Model Regulations" in Required, if the formulation is not thermally stable, or with a compatible diluent having a boiling point of less than 150 ℃ desensitization, the formulation should be set as F-type From the reaction of liquid/solid. GB 21178 determines the specific basis, determined as G. 4.2 self-reactive substances classification packaging method Self-reactive substances into the packaging OP1 ~ OP8 eight classes based on the maximum load capacity of each container and the package, shown in Table 1. with permission The following vessel. in line with GB 19432 GB 19433 and packaging requirements, while meeting the requirements of Chapter 5 of the package. "Model Regulations" is now regulated The method of packaging of self-reactive substances given in Appendix A. It allows the use of "Model Regulations" provides the following containers. --- outer container includes a box (4A, 4B, 4C1,4C2,4D, 4F, 4G, 4H1 and 4H2), a barrel (1A2,1B2,1G, 1H2 and 1D) and Tank (3A2,3B2 and 3H2) a combination of a container; --- comprising a barrel (1A1,1A2,1B1,1G, 1H1 and 1D) and a tank (3A1,3A2,3B1,3B2,3H1 and 3H2) a single vessel; Composite container (6HA1,6HA2,6HB1,6HB2,6HC, 6HD1,6HD2,6HG1,6HG2, --- with the plastic container 6HH1 and 6HH2). Table substance packaging method and the maximum loading of the reactor 1 from And a corresponding method of packaging the most Large loading capacity OP1 OP2a OP3 OP4a OP5 OP6 OP7 OP8 A container for solids and combinations (Liquids and solids) most Large mass/kg 0.5 0.5/10 5 5/25 25 50 50 400b Maximum capacity for liquids c/L 0.5 - 5 - 30 60 60 225d NOTE. metal container, comprising a container and a combination of an outer container or container assembly container of the compound container, only be used for packing methods OP7 and OP8. In Group Closing the container, the reservoir can only be used as a glass container, the maximum solids loading container 0.5kg, liquid 0.5L. Composition container liner material used Material should not flammable. Need "EXPLOSIVE" subsidiary risk label of self-reactive substances shall conform to the provisions of "Model Regulations" explosive contained in the product. For certain B-type or C-type self-reactive substances, UN3221, UN3222, UN3223, UN3224, UN3231, UN3232, UN3233 and UN3234, use a smaller container than the packing methods OP5 or OP6 are allowed. UN3241,2--bromo-2-nitropropane-1,3-diol, should Accordance with packing method OP6 packaging. a If two values, the maximum net value applies to each of the first container, the second maximum net value applies to the entire package. b cans of 60kg, box 200kg, in combination with an outer container of the container. The solid was 400kg, a combination of a box container (4C1,4C2,4D, 4F, 4G, 4H1 And 4H2) and a plastic or a fiber with a maximum net 25kg. c viscous liquid does not comply with. at 50 ℃ vapor pressure of not greater than 300kPa, and at a pressure of 101.3kPa 20 ℃ not completely gaseous at 101.3kPa Melting point or melting point at a pressure equal to or lower than the initial 20 ℃, it should be treated as a solid. d tank is 60L.5 Requirements5.1 General requirements 5.1.1 Packaging self-reactive substances shall meet the requirements of "Model Regulations" of 6.1, and in accordance with GB 19432 Ⅱ predetermined class package and GB 19433 Loading required performance level. 5.1.2 packaging self-reactive substances to be self-reactive substance that meets the requirements and method of packaging of a maximum load capacity. It has been delineated from Packing method should meet the requirements of the reaction mass in Appendix A. 5.1.3 allows the IBC transport packaging self-reactive substances shall meet the requirements of "Model Regulations" IBC520, allowing portable Self-reactive substances transported in tanks packaging "Model Regulations" T23 requirements. 5.1.4 After the new formulation of the new self-reactive substance or self-reactive substances has been delineated, should be classified in accordance with the determination GB 21178 And then select the appropriate packaging. 5.2 Special Requirements 5.2.1 B self-reactive substances 5.2.1.1 packing method OP5 1 of Table. Neither rapid nor deflagrate 5.2.1.2 detonate any explosive substance formulation having a self-reactive properties, such as for transport, packed in containers, But thermal explosion may occur in the vessel, it should be labeled "explosive" subsidiary risk label. This number of self-reactive substances contained in the container Up to 25kg, but in order to exclude rapid deflagration or detonation in the package and the need to limit the maximum number of a lower number otherwise. 5.2.2 C self-reactive substances 5.2.2.1 packing method OP6 1 of Table. Neither rapid nor deflagrate 5.2.2.2 detonate any explosive substance formulation having a self-reactive properties, such as for transport, packed in containers, But thermal explosion may occur in the vessel, it should be labeled "explosive" subsidiary risk label. This number of self-reactive substances contained in the container Up to 25kg. 5.2.2.3 If only packed in packing method OP6 than the allowable container smaller containers in order to meet these criteria, you should use the number of OP Smaller packaging appropriate methods, such as OP5. 5.2.3 D self-reactive substances A method of packaging in Table OP7 1. 5.2.4 E self-reactive substances A method of packaging in Table OP8 1. 5.2.5 F self-reactive substances A method of packaging in Table OP8 1. 5.3 IBC packaging requirements Self-reactive substances 5.3.1 currently assigned to "Model Regulations" packing instruction IBC520 specifically listed, according to standard medium Bulk transport container, IBC should meet the requirements of 6.5 and meets the test requirements of Ⅱ packaging. Substances country of origin by the competent authorities according to the conditions of the reaction 5.3.2 other self-contained in F IBCs transport, such as the competent Board satisfied that such transport may be safely based on the results of the appropriate test. Trials should include tests required for the following. --- proof of self-reactive substances in line with F self-reactive substances; --- proof during transport materials typically in contact with all substances having compatibility; --- the temperature control from the time the SADT estimation (if applicable) the product contained in the relevant intermediate bulk containers and transport critical temperature; --- design safety relief devices and emergency-relief device (if applicable); --- determine if any special requirements necessary for safe transport of the substance. 5.3.3 SADT of not more than 45 ℃ F should be self-reactive substances in transport temperature control. 5.3.4 should be considered an emergency situation is self-accelerating decomposition and fire engulfment. To prevent the portable tank having a metal housing complete explosion Fracture design relief devices should be able to self-accelerating decomposition during, or according to formula (1) is computed completely engulfed in flames generated in less than 1h All the decomposition products and vapors discharged out. q = 70961FA0.82 (1) Where. --- the rate of heat absorption Q, in watts (W is); A --- wetted area in square meters (m2); F --- insulation factor. Non-insulated tanks, F = 1, insulated tank type, F according to formula (2). F = U (923-T) (2) Where. The thermal conductivity K --- insulating layer, opening watts (W · m-1 · K-1) per meter; L --- insulation thickness, in meters (m); --- the U-insulating layer heat transfer coefficient, U = K/L, open units of watts per square meter (W · m-2 · K-1); T --- temperature of the substance at reduced pressure release conditions in Kelvin (K). 5.4 in portable tanks packaging requirements 5.4.1 for each substance shall be tested and will report to the competent authority of the country of origin for approval. The competent authorities of the country of destination shall send off The notice of the substance. Notification shall contain relevant transport information and test results contained in the report. The safe transport of the required material Any additional provisions should be clearly described in the report. It shall include the necessary tests conducted following the test object can be achieved. --- proof during transport materials generally all contact with the substances having compatibility; --- provide data security and the required blood pressure relief devices designed, taking into account the design characteristics of the portable tank. 5.4.2 Portable tanks Holds self-reactive substances shall conform to the provisions of "Model Regulations" 4.2.1.13 of.6 Marking and labeling6.1 mark Packaging and labeling 6.1.1 Code Packing Code See GB 19432 and GB 19433. Neutral bulk packaging containers and portable tank tag code section "Model Regulations." 6.1.2 Self-reactive substances labeled 6.1.2.1 Dangerous goods shipping name and preceded by the letters "UN" appropriate UN number shall be displayed on each package. in case Unpackaged goods, mark should appear on the article, or on a bracket which, in its handling, storing, or transmitting device. 6.1.2.2 Except for self-reactive substances already contained in the name of the list of dangerous goods listed in "stable" word should be added to "stable The "word as the substance of a case where a part of the proper shipping name, or no transportation. 6.1.2.3 All package labeling requirements. --- should be readily visible and legible; --- should be able to withstand weather exposure without a significant reduction in effectiveness; --- should be displayed on the outer surface of the upper package contrasting background; --- should not be marked with other packages may greatly reduce their effectiveness together. 6.1.2.4 450L capacity than the intermediate bulk containers and large containers, to be marked in two opposing sides. 6.2 Label 6.2.1 Self-reactive substances (4.1) black flame symbol tag, a white background, with seven vertical red stripe, a digital writing on the bottom 4 Angle, shown in Figure 1. 6.2.2 B self-reactive substances to be labeled "explosive" subsidiary risk label (see FIG. 2), unless the test data have proved self-reactive substances Such container does not exhibit explosive behavior, the competent authorities permitted this label to be specific container. 6.2.3 based on "Model Regulations" and "Globally Harmonized System of Classification and Labeling" (GHS) (third edition) (hereinafter referred to as GHS) from reaction Configuring elements of the material classification and labeling requirements shown in Table 2. FIG reactive substances 1 (4.1)2 explosive labelTable 2 Self-reactive species classification and labeling configuration table element IMDG Code A B C and D E F type and G-type GHS Danger Danger Danger Warning heating May cause an explosion Heating can cause Fire or explosion heating It can cause a fire heating It can cause a fire This category None Labeling Requirements "Regulation Template " Same with explosives (Follow same symbol Select the program) "Model Regulations" in the Does not require Note 1. For Type B, in the "Model Regulations", the clause can be applied to 181 (exempt explosion label approved by the competent national authorities, see "Model Regulations This "3.3 to obtain more details). Note 2. "Model Regulations", the color pictograph see description of explosives and flammable solids.Appendix A(Normative) "Model Regulations" are set out in 4.1 self-reactive substances and packaging specifications Name Table A.1 gives the "Model Regulations" are set out in 4.1 self-reactive substances name and packaging specifications. Table A.1 "Model Regulations" are set out in 4.1 self-reactive substances and packaging specifications Name No. Self-reactive substances concentration/ method of packing temperature control/ Emergency temperature / UN Numbering Acetone - pyrogallol copolymer 2-diazo-1-naphthol sulfonate -5- 100 OP8 3228 2 B-type azodicarbonamide formulations, to control the temperature of a, b < 100 OP5 3232 3 C Type azodicarbonamide formulation c < 100 OP6 3224 4 C azodicarbonamide formulation type, temperature control d < 100 OP6 3234 5 D-type azodicarbonamide formulation e < 100 OP7 3226 6 D azodicarbonamide formulation type, temperature control f < 100 OP7 3236 7 2,2'-azobis (2,4-dimethyl-4-methoxy valeronitrile) 100 OP7 -5 5 3236 8 2,2'-azobis (2,4-dimethylvaleronitrile) 100 OP7 10 15 3236 9 2,2'-azobis (2-methylpropionate) 100 OP7 20 25 3235 10 1,1'-azobis (cyclohexyl-carbonitrile) 100 OP7 3226 2,2'-azobisisobutyronitrile 11 100 OP6 40 45 3234 12 2,2'-azobisisobutyronitrile, water-based paste ≤50 OP6 3224 13 2,2'-azobis (2-methylbutyronitrile) 100 OP7 35 40 3236 Benzene-1,3-sulfonyl hydrazide 14, the paste 52 OP7 3226 15 benzenesulfo...... |
