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Delivery: <= 3 days. True-PDF full-copy in English will be manually translated and delivered via email. GB 15581-2016: Discharge standard of water pollutants for caustic alkali and polyvinyl chloride industry Status: Valid GB 15581: Historical versions
Basic dataStandard ID: GB 15581-2016 (GB15581-2016)Description (Translated English): Discharge standard of water pollutants for caustic alkali and polyvinyl chloride industry Sector / Industry: National Standard Classification of Chinese Standard: Z64 Word Count Estimation: 15,149 Date of Issue: 2016-08-22 Date of Implementation: 2016-09-01 Older Standard (superseded by this standard): GB 15581-1995 Quoted Standard: GB/T 6920; GB/T 7469; GB/T 11893; GB/T 11901; GB/T 11910; GB/T 11912; GB/T 16157; GB/T 16489; HJ 77.2; HJ 493; HJ 494; HJ 495; HJ 505; HJ 535; HJ 536; HJ 537; HJ 542; HJ 543; HJ 547; HJ 548; HJ 549; HJ 585; HJ 586; HJ 597; HJ 602; HJ 603; HJ 629; HJ 636; Regulation (derived from): Ministry of Environmental Protection Notice No.56 of 2016; National Standard Notice No.2516 of 2016 Issuing agency(ies): General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China Summary: This standard specifies the emission limits, monitoring and monitoring requirements for water and air pollutants in caustic soda and polyvinyl chloride industrial enterprises, as well as the relevant provisions for the implementation and supervision of standards. This standard applies to the existing caustic soda, PVC industrial enterprises of water and air pollutant emissions management, as well as caustic soda, PVC industrial enterprises construction project environmental impact assessment, environmental protection facilities design, completion of environmental protection acceptance and put into operation Water Pollutants and Air Pollutant Emissions Management. This standard applies to pollutant discharge permitted by law. In addition to the implementation of this standard, should also be in accordance with the "People's Republic of China Water Pollution Control Law" "People's Republic of China Air Pollution Control Law", "People's Republic of China Ocean Environmental Protection Act " GB 15581-2016: Discharge standard of water pollutants for caustic alkali and polyvinyl chloride industry---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order. Discharge standard of water pollutants for caustic alkali and polyvinyl chloride industry ICS Replacing GB 15581-95 Caustic soda, PVC industrial pollutant discharge standards Emission standard of pollutants for caustic And polyvinyl chloride industry Ministry of Environmental Protection State Administration of Quality Supervision, Inspection and Quarantine issued 2016-08-22 released 2016-09-01 implementation National Standards of People's Republic of China I directory Preface ..ii 1 Scope of application2 normative reference documents3 terms and definitions4 Pollutant Emission Control Requirements 45 Pollutant Monitoring RequirementsImplementation and supervision of standards Appendix A (normative appendix) PCDD/Fs toxicity equivalent factorForewordIn order to implement the Environmental Protection Law of the People's Republic of China, the Law of the People's Republic of China on the Prevention and Control of Water Pollution, And the State Air Pollution Prevention Law "," the People's Republic of China Marine Environmental Protection Law "and other laws and regulations, to protect the environment, Pollution, promote caustic soda, PVC production process and pollution control technology progress, the development of this standard. This standard is the "caustic soda, PVC industrial water pollutant discharge standards" (GB 15581-95) revision, the standard The provisions of the caustic soda, PVC industrial enterprises water and air pollutant emission limits, monitoring and monitoring requirements. To promote regional economics Economic and environmental development, promote the adjustment of economic structure and economic growth mode change, guide caustic soda, polyvinyl chloride industry Production technology and pollution control technology development direction, this standard provides for water and air pollutants special emission limits. This standard was first published in.1995, this time for the first revision. The main contents of this revision. - Increased air pollutant emission control requirements. - Adjusted the water pollutant emission control project, tightening the water pollutant emission control requirements. - Added special limits on water and air pollutants. - Elimination of regulations for sewage management. The concentration of pollutants in this standard is the mass concentration. Caustic soda, PVC industrial enterprises emissions of stench pollutants, environmental noise and boiler emissions of air pollutants applicable to the corresponding Of the national pollutant discharge standards, resulting in solid waste identification, treatment and disposal of national solid waste pollution control standards. New caustic soda, PVC industrial enterprises since September 1,.2016 from the implementation of this standard, the existing enterprises since July 1,.2018 The implementation of this standard. Before July 1,.2018, the existing enterprises still implement the "caustic soda, PVC industrial water pollutant discharge standard (GB 15581-95), "Integrated Emission Standard for Air Pollutants" (GB 16297-1996) and "Industrial Furnace Air Pollution Discharge standards "(GB 9078-1996) in the relevant provisions. This standard is the caustic soda, PVC industrial pollutant discharge control of the basic requirements. Local provincial people 's government on this standard Unauthorized items can be formulated for local pollutant discharge standards; for this standard has been provided for the project, The standard of local pollutant discharge standards. Environmental impact assessment documents or the requirements of the sewage permit than this or local standards Strictly, should be approved in accordance with the environmental impact assessment or discharge permit documents. This standard is organized by the Ministry of Environmental Protection Science and Technology Standards Division. The main drafting of this standard. China Environmental Science Research Institute, Qingdao University of Science and Technology, China Chlor-Alkali Industry Association. The environmental protection department of this standard approved on May 11,.2016. This standard has been implemented since September 1,.2016. This standard is explained by the Ministry of Environmental Protection. 1 caustic soda, PVC industrial pollutant discharge standards1 Scope of applicationThis standard specifies the emission limits, monitoring and monitoring requirements for water and air pollutants in caustic soda and polyvinyl chloride industrial enterprises, As well as the implementation of standards and supervision and other relevant provisions. This standard applies to the existing caustic soda, PVC industrial enterprises of water and air pollutant emissions management, and caustic soda, polychlorination Ethylene industrial enterprise construction project environmental impact assessment, environmental protection facilities design, completion of environmental protection acceptance and put into operation Of water pollutants and air pollutant emissions management. This standard applies to pollutant discharge permitted by law. Newly established sources of pollution and existing areas of special protection The management of pollution sources, in addition to the implementation of this standard, should also be in accordance with the "People's Republic of China Water Pollution Control Law", "the Chinese people The Republic of China on the Prevention and Control of Atmospheric Pollution, the Law of the People's Republic of China on the Protection of the Marine Environment, the Solid Waste of the People's Republic of China Environmental Pollution Control Law of the People's Republic of China and other relevant laws, regulations and rules of the People's Republic of China carried out. Electrolytic potassium chloride production of potassium hydroxide in the process of water pollutants and air pollutant emissions management with reference to the implementation of this standard. This standard does not apply to the pollutant discharge management in caustic caustic soda production. The water pollutant emission control requirements stipulated in this standard apply to enterprises that directly or indirectly discharge water pollution outside their statutory borders The behavior of the dye.2 normative reference documentsThe contents of this standard refer to the following documents or their terms. Those who do not specify the date of the reference file, the effective version of the appropriate For this standard. GB/T 6920 Determination of water quality pH - Glass electrode method GB/T 7469 Determination of total mercury in water - Potassium permanganate - Potassium persulfate digestion method Dithizone spectrophotometric method Water quality - Determination of total phosphorus - Ammonium molybdate spectrophotometric method GB/T Water quality - Determination of suspended solids - Gravimetric method GB/T GB/T 11910 Determination of water quality - Determination of butanedione oxime spectrophotometric method Water quality - Determination of nickel - Flame atomic absorption spectrophotometric method GB/T Determination of particulate matter and sampling method of gaseous pollutants in exhaust gas of fixed pollution sources GB/T 16157 Water quality - Determination of sulfide - Methylene blue spectrophotometric method GB/T 16489 HJ 77.2 Ambient air and exhaust dioxins Determination of isotope dilution High resolution gas chromatography - High resolution Spectrum method Technical specification for preservation and management of water quality samples Technical Guidance for Water Quality Sampling Design Technical Guidance for Water Quality Sampling Scheme Determination of Biodegradation and Inoculation of DOD Biochemical Oxygen Demand (BOD5) HJ 535 - Determination of ammonia nitrogen - Nessler 's reagent spectrophotometric method HJ 536 Water quality - Determination of ammonia - Salicylic acid spectrophotometric method Determination of ammonia nitrogen in water - Distillation - neutralization titration method 2HJ 542 Ambient air - Determination of mercury - Mercapto cotton enrichment - cold atomic fluorescence spectrophotometry (provisional) HJ 543 Fixed sources of waste - Determination of mercury - Cold atomic absorption spectrophotometric method (provisional) HJ 547 Fixed source of waste gas Determination of chlorine gas Iodometric method (provisional) HJ 548 Fixed source of waste gas - Determination of hydrogen chloride - Silver nitrate volumetric method HJ 549 Determination of ambient air and waste gas - Determination of hydrogen chloride - Ion chromatography Determination of free chlorine and total chlorine in water - Determination of N, N - diethyl - 1,4 - phenylenediamine titration HJ 586 Water quality Determination of free chlorine and total chlorine N, N-diethyl-1,4-phenylenediamine spectrophotometric method HJ 597 Water quality - Determination of total mercury - Cold atomic absorption spectrophotometric method Determination of barium in water - Graphite furnace atomic absorption spectrophotometric method Determination of barium in water - Flame atomic absorption spectrophotometric method HJ 629 Fixed sources - Determination of waste gas - Determination of sulfur dioxide - Non - dispersive infrared absorption method HJ 636 Water quality - Determination of total nitrogen - Alkaline persulfate digestion - Ultraviolet spectrophotometric method HJ 637 Water quality - Determination of petroleum and animal and vegetable oils - Infrared spectrophotometric method HJ 639 Water quality - Determination of volatile organic compounds - Purge and trap - gas chromatography - mass spectrometry HJ 644 Ambient air - Determination of volatile organic compounds Adsorption tube sampling - Thermal desorption/Gas chromatography - mass spectrometry HJ 645 Ambient air - Determination of volatile halogenated hydrocarbons - Activated carbon adsorption - Carbon disulfide desorption/gas chromatography HJ 665 - Determination of ammonia nitrogen - Continuous flow - Salicylic acid spectrophotometric method Determination of ammonia nitrogen in water - Flow injection - salicylic acid spectrophotometric method Determination of total nitrogen content - Continuous flow - Naphthylenediamine hydrochloride spectrophotometric method Determination of total nitrogen content - Flow injection - Naphthylenediamine hydrochloride spectrophotometric method HJ 670 Water quality - Determination of phosphate and total phosphorus - Continuous flow - Ammonium molybdate spectrophotometric method Determination of total phosphorus in water - Flow injection - Ammonium molybdate spectrophotometric method HJ 675 Fixed sources - Determination of exhaust nitrogen oxides - Acid - base titration method HJ 692 Fixed sources - Determination of waste nitrogen oxides - Non - dispersive infrared absorption method Determination of nitrogen oxides for fixed sources of pollution - Determination of potential oxides Determination of Mercury, Arsenic, Selenium, Bismuth and Antimony in Water by HJ 694 - Atomic Fluorescence Spectrometry Determination of 65 kinds of elements in water quality of HJ 700 - Inductively coupled plasma mass spectrometry HJ 776 Water quality - Determination of 32 elements - Inductively coupled plasma - atomic emission spectrometry HJ 732 Sampling Air Bag Method for Volatile Organic Compounds of Fixed Pollutants HJ 759 Ambient air - Determination of volatile organic compounds - Tank sampling/gas chromatography - mass spectrometry Determination of Volatile Organic Compounds in Water Quality by Headspace/Gas Chromatography - Mass Spectrometry HJ/T 27 Determination of hydrogen chloride in fixed sources - Mercury thiocyanate spectrophotometric method HJ/T 30 Determination of chlorine in exhaust gas from stationary sources - Methyl orange spectrophotometric method HJ/T 34 Determination of vinyl chloride in the exhaust gas of fixed sources - Gas chromatographic method Determination of non - methane total hydrocarbons in exhaust gas from fixed sources of pollution - Gas chromatographic method HJ/T 42 Determination of nitrogen oxides in the exhaust gas of fixed sources - Ultraviolet spectrophotometric method HJ/T 43 Determination of nitrogen oxides in fixed exhaust gases - Naphthylenediamine hydrochloride spectrophotometric method Technical Guidelines for Unorganized Emissions Monitoring of Air Pollutants 3HJ/T 56 Determination of sulfur dioxide in exhaust gas from stationary sources - Iodometric method Determination of Sulfur Dioxide in Fixed Air Pollutants by HJ/T 57 HJ/T 60 Determination of water quality sulfide iodometric method HQ/T 70 Determination of chemical oxygen demand for high chlorine wastewater - Chlorine calibration method Technical specification for continuous monitoring of flue gas emissions from fixed pollution sources of HJ/T 75 (for trial implementation) HJ/T 76 fixed pollution source flue gas emissions continuous monitoring system technical requirements and testing methods (Trial) Technical specification for surface water and wastewater monitoring Determination of ammonia nitrogen in water. Determination of ammonia nitrogen by gas phase molecular absorption spectrometry Water quality - Determination of total nitrogen - Gas phase molecular absorption spectrometric method HJ/T.200 - Determination of water quality Sulfide - Gas phase molecular absorption spectrometric method HJ/T 373 fixed pollution source monitoring quality assurance and quality control technical specifications (Trial) Technical specification for HJ/T 397 fixed source exhaust gas monitoring "Administrative Measures for Automatic Monitoring of Pollution Sources" (State Environmental Protection Administration Decree No. 28) "Environmental Monitoring Management Measures" (State Environmental Protection Administration Decree No. 39)3 terms and definitionsThe following terms and definitions apply to this standard. 3.1 caustic soda industry caustic acid industry Sodium chloride as raw material using ion exchange membrane electrolysis production of liquid alkali, caustic soda and chlorine hydrogen treatment industry. PVC polyvinyl chloride industry The use of acetylene and ethylene oxychloride production of PVC industry. This standard refers to the use of acetylene production of PVC or Production Process of Polyvinyl Chloride from Vinyl Chloride Monomer in Ethylene Oxychlorination Process. 3.3 acetylene method Production of Polyvinyl Chloride from Acetylene and Hydrogen Chloride as Raw Materials. This standard mainly refers to calcium carbide method. O ethylene oxychlorination process Production of Polyvinyl Chloride from Chlorine, Ethylene and Oxygen as Raw Materials. 3.5 Features Production process and installation Processes and devices for the production of caustic soda, polyvinyl chloride, and contaminant treatment processes and devices associated with these processes. 3.6 existing enterprises existing facility The implementation of this standard has been completed before the production or environmental impact assessment documents have been approved by the caustic soda, PVC industrial enterprises Industry or production facilities. 3.7 new enterprise new facility The environmental impact assessment documents from the date of implementation of this standard through the approval of the new, alteration and expansion of caustic soda, polyvinyl chloride Production facilities construction projects. 3.8 public sewage treatment system public wastewater treatment system Collect waste water through pipelines, etc. Provide waste water treatment services for two or more sewage units and drain To the relevant emission standards required by enterprises or institutions, including the size and type of urban sewage treatment plants, areas (including the Industrial parks, development zones, industrial clusters, etc.) wastewater treatment plants, the degree of wastewater treatment should reach two or two to on. 43.9 direct discharge direct discharge Discharge units directly to the environmental water discharge of water pollutants. Indirect discharge Discharge of sewage to the public sewage treatment system of water pollutant behavior. 3.11 displacement effluent volume Caustic soda, PVC production facilities or the amount of wastewater discharged by enterprises outside the legal boundary, including direct production (Such as factory sewage, cooling wastewater, etc.). 3.12 unit product baseline displacement benchmark effluent volume per unit product The upper limit of the amount of wastewater discharged from the production unit for the purpose of approving the concentration of water pollutants. 3.13 Emissions of atmospheric pollutants per unit product air pollutant emission amount per unit product Production unit PVC product upper limit of air pollutant emissions (kg/t). 3.14 standard state standard condition The temperature is 273.15K, the pressure is 101325Pa when the state. The limits of atmospheric pollutant emission limits specified in this standard Are based on the standard state of dry gas as a benchmark. Oxygen content After the fuel is burned, the excess free oxygen contained in the flue gas is usually expressed as a percentage of dry basis volume. 3.16 enterprise boundary Caustic soda, the legal boundary of PVC industrial enterprises. If there is no boundary, it refers to the actual boundary. 3.17 dioxin dioxins Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) collectively. 3.18 toxic equivalence factor (TEF) The ratio of dioxins to the affinity of 2,3,7,8-tetrachlorodibenzo-p-dioxin to Ah receptors. 3.19 toxic equivalence quantity (TEQ) The concentration of dioxins is equivalent to the equivalent concentration of 2,3,7,8-tetrachlorodibenzo-p-dioxin, The toxicity equivalent concentration is the product of the measured concentration and the toxicity equivalent factor of the isomer.4 Pollutant Emission Control Requirements4.1 Water Pollutant Emission Control Requirements 4.1.1 Since September 1,.2016, the new enterprises have implemented the water pollutant discharge limits set out in Table 1. 4.1.2 Prior to 1 July.2018, existing enterprises should continue to implement the current standards. Since July 1,.2018, the existing The enterprise implements the water pollutant discharge limits specified in Table 1. Table 1 Water pollutant emission limits Unit. mg/L (except pH) No. Contaminant Project Control Pollution Source Emission limits Direct discharge of the monitoring position 1 pH caustic soda enterprises, PVC enterprises 6 ~ 9 6 ~ 9 enterprise wastewater Total Discharge Port 2 Chemical Oxygen Demand Caustic Soda Enterprise, Polyvinyl Chloride Enterprise 60 250 5 (CODCr) Five days of biochemical oxygen Volume (BOD5) Polyvinyl Chloride Enterprise 4 suspended matter caustic soda enterprises, PVC enterprises 30 70 5 oil caustic soda enterprises, PVC enterprises 3 10 6 ammonia nitrogen caustic soda enterprises, PVC enterprises 15 40 7 total nitrogen caustic soda enterprises, PVC enterprises 20 50 8 Calcium Phosphate Enterprise, PVC Enterprise 1.0 5.0 9 Sulfide Acetylene Process Polyvinyl Chloride Enterprise 0.5 0.5 Total barium caustic soda business 5 5 11 active chlorine caustic soda enterprises 0.5 Workshop or production Device discharge port 12 Vinyl Chloride Polyvinyl Chloride Enterprise Total Mercury Acetylene Process PVC Com......Tips & Frequently Asked Questions:Question 1: How long will the true-PDF of GB 15581-2016_English be delivered?Answer: Upon your order, we will start to translate GB 15581-2016_English as soon as possible, and keep you informed of the progress. 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